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How well does XAD resin extraction recover halogenated disinfection byproducts for comprehensive identification and toxicity testing?

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Journal of Environmental Sciences 2022年第7期34卷 264-275页

作者： Xiaobin Liao joshua m.allen Caroline O.Granger Susan D.Richardson Department of Chemistry and Biochemistry University of South CarolinaColumbiaSouth Carolina 29208USA Institute of municipal and Environmental Engineering College of Civil EngineeringHuaqiao UniversityFujian 361021China Currently at LanzaTech 535 Commerce DriveSopertonGeorgia 30457USA

Halogenated disinfection byproducts(DBPs) are an unintended consequence of drinking water disinfection, and can have significant toxicity. XAD resins are commonly used to extract and enrich trace levels of DBPs for comprehensive, nontarget identification of DBPs and also for in vitro toxicity studies. However, XAD resin recoveries for complete classes of halogenated DBPs have not been evaluated, particularly for low, environmentally relevant levels(ng/L to low μg/L). Thus, it is not known whether levels of DBPs or the toxicity of drinking water might be underestimated. In this study, DAX-8/XAD-2 layered resins were evaluated, considering both adsorption and elution from the resins, for extracting 66 DBPs from water. Results demonstrate that among the 7 classes of DBPs investigated, trihalomethanes(THms), including iodo-THms, were the most efficiently adsorbed, with recovery of most THms ranging from 50%-96%, followed by halonitromethanes(40%-90%). The adsorption ability of XAD resins for haloacetonitriles, haloacetamides, and haloacetaldehydes was highly dependent on the individual species. The adsorption capacity of XAD resins for haloacetic acids was lower(5%-48%), even after adjusting to p H 1 before extraction. Recovery efficiency for most DBPs was comparable with their adsorption, as most were eluted effectively from XAD resins by ethyl acetate. DBP polarity and molecular weight were the two most important factors that determine their recovery. Recovery of trichloromethane, iodoacetic acid, chloro-and iodo-acetonitrile, and chloroacetamide were among the lowest, which could lead to underestimation of toxicity, particularly for iodoacetic acid and iodo-acetonitrile, which are highly toxic.

关键词： XAD resins Disinfection byproducts DBPs Recovery Toxicity

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Relationships between regulated DBPs and emerging DBPs of health concern in U.S. drinking water

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Journal of Environmental Sciences 2022年第7期34卷 161-172页

作者： Stuart W.Krasner Ai Jia Chih-Fen T.Lee Raha Shirkhani joshua m.allen Susan D.Richardson michael J.Plewa metropolitan Water District of Southern California Water Quality LaboratoryCA 91750USA Department of Chemistry and Biochemistry University of South CarolinaSC 29208USA Department of Crop Sciences University of Illinois at Urbana-ChampaignIL 61801USA Safe Global Water Institute University of Illinois at Urbana-ChampaignIL 61801USA

A survey was conducted at eight U.S. drinking water plants, that spanned a wide range of water qualities and treatment/disinfection practices. Plants that treated heavily-wastewaterimpacted source waters had lower trihalomethane to dihaloacetonitrile ratios due to the presence of more organic nitrogen and HAN precursors. As the bromide to total organic carbon ratio increased, there was more bromine incorporation into DBPs. This has been shown in other studies for THms and selected emerging DBPs(HANs), whereas this study examined bromine incorporation for a wider group of emerging DBPs(haloacetaldehydes, halonitromethanes). moreover, bromine incorporation into the emerging DBPs was, in general, similar to that of the THms. Epidemiology studies that show an association between adverse health effects and brominated THms may be due to the formation of brominated emerging DBPs of heath concern. Plants with higher free chlorine contact times before ammonia addition to form chloramines had less iodinated DBP formation in chloraminated distribution systems, where there was more oxidation of the iodide to iodate(a sink for the iodide) by the chlorine. This has been shown in many bench-scale studies(primarily for iodinated THms), but seldom in full-scale studies(where this study also showed the impact on total organic iodine. Collectively, the THms, haloacetic acids, and emerging DBPs accounted for a significant portion of the TOCl, TOBr, and TOI;however, ~50% of the TOCl and TOBr is still unknown. The correlation of the sum of detected DBPs with the TOCl and TOBr suggests that they can be used as reliable surrogates.

关键词： Disinfection by-products Total organic bromine Total organic iodine Trihalomethanes Haloacetonitriles Haloacetaldehydes Iodo-trihalomethanes Iodoacetic acids

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Total organic halogen(TOX) in human urine: A halogen-specific method for human exposure studies

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Journal of Environmental Sciences 2017年第8期29卷 285-295页

作者： Susana Y.Kimura Weiwei Zheng Taylor N.Hipp joshua m.allen Susan D.Richardson Department of Chemistry and Biochemistry University of South Carolina Key Laboratory of Public Health Safety Ministry of Education Department of Environmental Health School of Public Health Fudan University

Disinfection by-products（DBPs） are a complex mixture of compounds unintentionally formed as a result of disinfection processes used to treat drinking water. Effects of long-term exposure to DBPs are mostly unknown and were the subject of recent epidemiological studies. However,most bioanalytical methods focus on a select few DBPs. In this study, a new comprehensive bioanalytical method has been developed that can quantify mixtures of organic halogenated compounds, including DBPs, in human urine as total organic chlorine（TOCl）, total organic bromine（TOBr）, and total organic iodine（TOI）. The optimized method consists of urine dilution, adsorption to activated carbon, pyrolysis of activated carbon, absorption of gases in an aqueous solution, and halide analysis with ion chromatography and inductively coupled plasma-mass spectrometry. Spike recoveries for TOCl, TOBr, and TOI measurements ranged between 78% and 99%. Average TOCl, TOBr, and TOI concentrations in five urine samples from volunteers who consumed tap water were 1850, 82, and 21.0 μg/L as X^-, respectively.Volunteers who consumed spring water（control） had TOCl, TOBr, and TOI average concentrations in urine of 1090, 88, and 10.3 μg/L as X^-, respectively. TOCl and TOI in the urine samples from tap water consumers were higher than the control. However, TOBr was slightly lower in tap water urine samples compared to mineral water urine samples, indicating other sources of environmental exposure other than drinking water. A larger sample population that consumes tap water from different cities and mineral water is needed to determine TOCl, TOBr, and TOI exposure from drinking water.

关键词： Adsorbable organic halogen（AOX） Total organic halogen（TOX） Disinfection by-products（DBPs） Total organic chlorine（TOCl） Total organic bromine（TOBr） Total organic iodine（TOI） Urine Drinking water

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Showering in Flint, mI: Is there a DBP problem?

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Journal of Environmental Sciences 2017年第8期29卷 271-284页

作者： joshua m.allen Amy A.Cuthbertson Hannah K.Liberatore Susana Y.Kimura Anurag mantha marc A.Edwards Susan D.Richardson Department of Chemistry and Biochemistry University of South Carolina the Department of Chemistry University of Calgary Civil and Environmental Engineering Virginia Tech

Lead contamination in the City of Flint, mI has been well documented over the past two years, with lead levels above the EPA Action Level until summer 2016. This resulted from an ill-fated decision to switch from Detroit water（Lake Huron） with corrosion control, to Flint River water without corrosion control. Although lead levels are now closer to normal,reports of skin rashes have sparked questions surrounding tap water in some Flint homes.This study investigated the presence of contaminants, including disinfection by-products（DBPs）, in the hot tap water used for showering in the homes of residents in Flint. Extensive quantitative analysis of 61 regulated and priority unregulated DBPs was conducted in Flint hot and cold tap water, along with the analysis of 50 volatile organic compounds and a nontarget comprehensive, broadscreen analysis, to identify a possible source for the reported skin rashes. For comparison, chlorinated hot and cold waters from three other cities were also sampled, including Detroit, which also uses Lake Huron as its source water.Results showed that hot water samples generally contained elevated levels of regulated and priority unregulated DBPs compared to cold water samples, but trihalomethanes were still within regulatory limits. Overall, hot shower water from Flint was similar to waters sampled from the three other cities and did not have unusually high levels of DBPs or other organic chemicals that could be responsible for the skin rashes observed by residents. It is possible that an inorganic chemical or microbial contaminant may be responsible.

关键词： Disinfection by-products Disinfection byproducts DBPs Flint Hot water Showering Bathing Drinking water

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Influence of indoor airflow on airborne disease transmission in a classroom

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Building Simulation 2024年第3期17卷 355-370页

作者： mojtaba Zabihi Ri Li joshua Brinkerhoff School of Engineering Faculty of Applied ScienceUniversity of British ColumbiaKelownaCanada

It has been widely accepted that the most effective way to mitigate airborne disease transmission in an indoor space is to increase the ventilation airflow,measured in air change per hour(ACH).However,increasing ACH did not effectively prevent the spread of COVID-19.To better understand the role of ACH and airflow large-scale patterns,a comprehensive fully transient computational fluid dynamics(CFD)simulation of two-phase flows based on a discrete phase model(DPm)was performed in a university classroom setting with people present.The investigations encompass various particle sizes,ventilation layouts,and flow rates.The findings demonstrated that the particle size threshold at which particles are deemed airborne is highly influenced by the background flow strength and large-scale flow pattern,ranging from 5µm to 10µm in the cases investigated.The effects of occupants are significant and must be precisely accounted for in respiratory particle transport studies.An enhanced ventilation design(UFAD-CDR)for university classrooms is introduced that places a premium on mitigating airborne disease spread.Compared to the baseline design at the same ACH,this design successfully reduced the maximum number density of respiratory particles by up to 85%.A novel airflow-related parameter,Horizontality,is introduced to quantify and connect the large-scale airflow pattern with indoor aerosol transport.This underscores that ACH alone cannot ensure or regulate air quality.In addition to the necessary ACH for air exchange,minimizing horizontal bulk motion is essential for reducing aerosol transmissibility within the room.

关键词： aerosol transmission airflow pattern horizontality COVID-19 simulation classroom ventilation

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mechanically driven assembly of biomimetic 2D-material microtextures with bioinspired multifunctionality

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Nano Research 2024年第2期17卷 663-678页

作者： Yang Li Lin Jing joshua m.Little Haochen Yang Tsai-Chun Chung Po-Yen Chen Department of Chemical and Biomolecular Engineering University of MarylandCollege ParkMD 20740USA maryland Robotics Center University of MarylandCollege ParkMD 20742USA School of materials Science and Engineering Nanyang Technological University50 Nanyang AvenueSingapore 639798Singapore

Nature provides a wealth of bio-inspiration for advanced material research.Assembling various nanomaterials into biomimetic microtextures with bioinspired functionalities has spurred increasing research interests and facilitated technological advances in various applications.In recent years,two-dimensional materials(2Dms)have emerged as important building block units in the biomimicry field due to their distinct chemical,physical,electrical,electrochemical,and catalytic properties.In this review article,various mechanically driven assembly approaches are summarized to fabricate various genealogies of biomimetic 2Dm microtextures with bio-inspired multifunctionality.First,sequential deformation strategies are discussed to programmably construct higher dimensional 2Dm microtextures,ranging from wrinkles/crumples(one-time deformation)to multiscale hierarchies(multiple deformations).Next,the current progress using higher dimensional 2Dm microtextures to imitate different biological structures and/or induce bio-inspired multifunctionality is systematically summarized.Four showcases of bio-inspiration and biomimicry using different 2Dm nanosheets are highlighted:(1)wrinkle patterns of an earthworm that spur the design of strain sensors with programmable working ranges and sensitivities,(2)wrinkle appearance of a Shar-Pei dog that motivates the fabrication of stretchable energy storage devices,(3)hierarchical scale textures of a desert lizard that inspire cation-induced gelation platforms for 2Dm aerogels,and(4)wrinkle skin of an elephant that influences the development of 2Dm protective skin for soft robots.Finally,challenges and future opportunities of adopting 2Dm nanosheets to assemble biomimetic microstructures with synergistic functionalities are discussed.

关键词： two-dimensional(2D)materials mechanically driven assembly biomimetic microtextures functional nanocomposite bio-inspired multifunctionality

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Protective effects of cyclosporine and its analog NIm-811 in a murine model of hepatic ischemia-reperfusion injury

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Liver Research 2024年第1期8卷 46-53页

作者： joshua Hefler Rena Pawlick Braulio A.marfil-Garza Aducio Thiesen Nerea Cuesta-Gomez Sanaz Hatami Darren H.Freed Constantine Karvellas David L.Bigam A.m.James Shapiro Department of Surgery Faculty of Medicine&DentistryUniversity of AlbertaEdmontonABCanada Department of medicine Faculty of Medicine&DentistryUniversity of AlbertaEdmontonABCanada CHRISTUS-LatAm Hub Excellence&Innovation Center MonterreyMexico Alberta Diabetes Institute University of AlbertaEdmontonABCanada Clinical Islet Transplant Program University of AlbertaEdmontonABCanada Department of Laboratory medicine&Pathology Faculty of Medicine&DentistryUniversity of AlbertaEdmontonABCanada

Background and aim:The liver is susceptible to ischemia-reperfusion injury(IRI)during hepatic surgery,when the vessels are compressed to control bleeding,or liver transplantation,when there is an obligate period of ischemia.The hallmark of IRI comprises mitochondrial dysfunction,which generates reactive oxygen species,and cell death through necrosis or apoptosis.Cyclosporine(CsA),which is a well-known immunosuppressive agent that inhibits calcineurin,has the additional effect of inhibiting the mito-chondrial permeability transition pore(mPTP),thereby,preventing mitochondrial swelling and injury.NIm-811,which is the nonimmunosuppressive analog of CsA,has a similar effect on the mPTP.In this study,we tested the effect of both agents on mitigating warm hepatic IRI in a murine model.materials and methods:Before ischemic insult,the mice were administered with intraperitoneal normal saline(control);CsA at 2.5,10,or 25 mg/kg;or NIm-811 at 10 mg/kg.Thereafter,the mice were subjected to partial warm hepatic ischemia by selective pedicle clamping for 60 min,followed by 6 h of recovery after reperfusion.Serum alanine transaminase(ALT)was measured,and the liver tissue was examined histologically for the presence of apoptosis and the levels of inflammatory cytokines.Results:Compared with the control mice,the mice treated with 10 and 25 mg/kg of CsA and NIm-811 had significantly lower ALT levels(Pmoreover,the liver tissue showed reduced histological injury scores after treatment with CsA at 2.5,10,and 25 mg/kg and NIm-811(P=0.041,ment with CsA at all doses(P=0.012,0.007,andmmatory cyto-kines,particularly interleukin(IL)-1β,IL-2,IL-4,IL-10,and keratinocyte chemoattractant/human growth-regulated oncogene significantly decreased in the mice treated with the highest dose of CsA(25 mg/kg)than those in the control mice.Conclusions:Premedication with CsA or NIm-811 mitig

关键词： Cyclosporine(CsA) Cyclosporine analogue Liver surgery Ischemia-reperfusion injury(IRI) Animal model NIm-811

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Synergistic Interactions of Soil and Vegetation in Agroforestry Systems in mitigating Climate Change in Upper East Region, Ghana

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American Journal of Climate Change 2024年第2期13卷 140-162页

作者： joshua A. Adombire Abdul-Wahab m. Imoro Eunice Essel Nang B. Douti Department of Environmental Science C. K. Tedam University of Technology and Applied Sciences Navrongo Ghana Department of Forestry and Forest Resources management University for Development Studies Tamale Ghana Department of Crop Science and Biotechnology C. K. Tedam University of Technology and Applied Sciences Navrongo Ghana

Climate change has been a global pandemic with its adverse impacts affecting environments and livelihoods. This has been largely attributed to anthropogenic activities which generate large amounts of Green House Gases (GHGs), notably carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) among others. In the Upper East of Ghana, climate change manifests in erratic rainfalls, drought, high temperatures, high wind speeds, high intensity rainfall, windstorms, flooding, declining vegetation cover, perennial devastating bushfires etc. Practices such as burning farm residues, use of dung as fuel for cooking, excessive application of nitrogenous fertilizers, and deforestation that are prevalent in the region exacerbate the situation. Although, efforts made by governmental and none-governmental organizations to mitigate climate change through afforestation, agroforestry and promotion of less fuelwood consuming cook stoves, land management practices antagonize these efforts as more CO2 is generated than the carrying capacity of vegetation in the region. Research findings have established the role of trees and soil in carbon sequestration in mitigating climate. However, there is limited knowledge on how the vegetation and soil in agroforestry interplay in mitigation climate change. It is against this background that this review seeks to investigate how vegetation and soil in an agroforestry interact synergistically to sequester carbon and contribute to mitigating climate change in Upper East region of Ghana. In this review, it was discovered soil stored more carbon than vegetation in an agroforestry system and is much effective in mitigating climate change. It was found out that in order to make soil and vegetation in an agroforestry system interact synergistically to effectively mitigate climate change, Climate Smart Agriculture practice which integrates trees, and perennials crops effectively mitigates climate. The review concluded that tillage practices that ensure retention and storage of soil organic carbon (SOC

关键词： Climate Change Carbon Sequestration Agroforestry Photosynthesis Nutrient mining Synergistic

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Dynamics of self-hybridized exciton–polaritons in 2D halide perovskites

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Light(Science & Applications) 2024年第1期13卷 13-22页

作者： Surendra B.Anantharaman Jason Lynch Christopher E.Stevens Christopher munley Chentao Li Jin Hou Hao Zhang Andrew Torma Thomas Darlington Francis Coen Kevin Li Arka majumdar PJames Schuck Aditya mohite Hayk Harutyunyan joshua R.Hendrickson Deep Jariwala Department of Electrical and Systems Engineering University of PennsylvaniaPhiladelphiaPA19104USA KBR Inc. BeavercreekOH45431USA Air Force Research Laboratory Sensors DirectorateWright-Patterson Air Force BaseOH45433USA Department of Physics University of WashingtonSeattleWA98195USA Department of Physics Emory UniversityAtlantaGA30322USA Department of Chemical and Biomolecular Engineering Rice UniversityHoustonTX77005USA Department of materials Science and Nanoengineering Rice UniversityHoustonTX77005USA Applied Physics Program Smalley‐Curl InstituteRice UniversityHoustonTX77005USA Department of mechanical Engineering Columbia UniversityNew YorkNY10027USA Department of Electrical and Computer Engineering University of WashingtonSeattleWA98195USA

Excitons,bound electron–hole pairs,in two-dimensional hybrid organic inorganic perovskites(2D HOIPs)are capable of forming hybrid light-matter states known as exciton-polaritons(E–Ps)when the excitonic medium is confined in an optical cavity.In the case of 2D HOIPs,they can self-hybridize into E–Ps at specific thicknesses of the HOIP crystals that form a resonant optical cavity with the excitons.However,the fundamental properties of these self-hybridized E–Ps in 2D HOIPs,including their role in ultrafast energy and/or charge transfer at interfaces,remain unclear.Here,we demonstrate that>0.5µm thick 2D HOIP crystals on Au substrates are capable of supporting multiple-orders of self-hybridized E–P modes.These E–Ps have high Q factors(>100)and modulate the optical dispersion for the crystal to enhance sub-gap absorption and emission.Through varying excitation energy and ultrafast measurements,we also confirm energy transfer from higher energy E–Ps to lower energy E–Ps.Finally,we also demonstrate that E–Ps are capable of charge transport and transfer at interfaces.Our findings provide new insights into charge and energy transfer in E–Ps opening new opportunities towards their manipulation for polaritonic devices.

关键词： charge polar excitation

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Author Correction:Enhanced CD19 activity in B cells contributes to immunodeficiency in mice deficient in the ICF syndrome gene Zbtb24

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Cellular & molecular Immunology 2024年第1期21卷 100-100页

作者： Zhengzhou Ying Swanand Hardikar joshua B.Plummer Tewfik Hamidi Bin Liu Yueping Chen Jianjun Shen Yunxiang mu Kevin m.mcBride Taiping Chen Department of Epigenetics and molecular Carcinogenesis The University of Texas MD Anderson Cancer Center Houston TX 77030 USA Program in Genetics and Epigenetics The University of Texas MD Anderson Cancer Center UTHealth Graduate School of Biomedical Sciences Houston TX 77030 USA

In the sentence beginning‘To trace cell proliferation,FO and mZ B cells’and the sentence beginning‘For cell activation,naïve B cells or CH12F3 cells’in this article,the[10 ng/ml]‘F(ab’)_(2)fragment goat anti-mouse Igm’should have read‘10μg/ml F(ab’)_(2)fragment goat anti-mouse Igm’.The original article has been corrected.

关键词： immunodeficiency CD19 deficient

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