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HVOF-sprayed HAp/s53P4 BG composite coatings on an AZ31 alloy for potential applications in temporary implants

Journal of Magnesium and Alloys 2024年第1期12卷 345-360页

作者： Carlos A.Poblano-salas john Henao Astrid L.Giraldo-Betancur Paola Forero-sossa Diego German Espinosa-Arbelaez Jorge A.González-sánchez Luis R.Dzib-Pérez susana T.Estrada-Moo Idelfonso E.Pech-Pech CIATEQ A.C. Av.Manantiales 23-AParque Industrial Bernardo QuintanaEl MarquésQuerétaro 76246Mexico CONAHCYT-CIATEQ A.C. Av.Manantiales 23-AParque Industrial Bernardo QuintanaEl MarquésQuerétaro 76246Mexico CONAHCYT-Cinvestav Libramiento Norponiente#2000.Fraccionamiento Real de JuriquillaQuerétaro 76230Mexico Universidad Tecnológica de Querétaro Av.Pie de la Cuesta N°2501Querétaro 76148Mexico CIDEsI Av.Playa Pie de la Cuesta No 702Col.San PabloQuerétaro 76125Mexico Center for Corrosion Research Autonomous University of CampecheAv.Héroe de Nacozari No.480P.C.24070San Francisco de CampecheCam.Mexico

Bioactive thermal spray coatings produced via high-velocity oxygen fuel spray(HVOF)from hydroxyapatite(HAp)and bioactive glasses(BG)have the potential to be employed on temporary implants due to the ability of both HAp and BG to dissolve and promote osseointegration,considering that both phases have different reaction and dissolution rates under in-vitro *** the present work,75%***-25%wt.s53P4 bioactive glass powders were HVOF-sprayed to obtain HAp/s53P4 BG composite coatings on a bioresorbable AZ31 *** study is focused on exploring the effect of the stand-off distance and fuel/oxygen ratio variation as HVOF parameters to obtain stable structural coatings and to establish their effect on the phases and microstructure produced in those *** characterization techniques,such as scanning electron microscopy,X-ray diffraction,and Fourier transform infrared spectroscopy,were employed to characterize relevant structural and microstructural properties of the composite *** results showed that thermal gradients during coating deposition must be managed to avoid delamination due to the high temperature achieved(max 550℃)and the differences in coefficients of thermal *** was also found that both spraying distance and oxygen/fuel ratio allowed to keep the hydroxyapatite as the main phase in the *** addition,in-vitro electrochemical studies were performed on the obtained HAp/s53P4 BG composite coatings and compared against the uncoated AZ31 *** results showed a significant decrease in hydrogen evolution(at least 98%)when the bioactive coating was applied on the Mg alloy during evaluation in simulated body fluid(sBF).

关键词： Coatings Composites Thermal spray Temporary implants Hydrogen evolution

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Extractable and kerogen-bound hopanoids from typical Eocene oil shales in China

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Energy Geoscience 2024年第2期5卷 171-179页

作者： Changbo Zhai Zhirong Zhang john K.Volkman Hong Lu Yan'e Chen sINOPEC Key Laboratory of Petroleum Accumulation Mechanisms Wuxi Institute of Petroleum GeologySINOPEC2060 Lihu RoadWuxiJiangsu213126China sINOPEC Petroleum Exploration and Production Research Institute 31 Xueyuan RoadBeijing100083China state Key Laboratory of Organic Geochemistry Guangzhou Institute of GeochemistryChinese Academy of ScienceGuangzhou510640GuangdongChina

This study conducted a comparative analysis of extractable hopanoid hydrocarbons and those released via stepwise pyrolysis of typical Eocene immature oil shales in China,namely the Huadian,Maoming,and Fushun *** the Huadian and Maoming shales exhibit immature indicators in extractable and kerogen-bound hopanoids(notably,high abundance of C_(29)to C_(32)17β,21β-hopanes and unsaturated hopenes).In contrast,the Fushun oil shale's hopanoids from extracts and pyrolyzates suggest a higher maturity *** absence of neohopenes in the pyrolyzates of the shales underpins that the kerogenbound hopanoid skeletons resist ***,the Huadian oil shale's asymmetric distribution of C_(29)and C_(30)hopenes and neohopenes hints at the presence of an additional *** unsaturated hopenes,such as hop-20(21)-enes,identified in pyrolyzates of the three kerogens at various pyrolysis temperatures,reveal the occurrence of double bonds in kerogen-bound hopanoid skeletons without methyl *** absence of hop-20-(21)-ene in extracts suggests that it might act as an intermediate of these novel hopenes during the epimerization of hopanoid skeletons within *** extractable and pyrolytic hopanoids'stereochemical alignment indicates that epimerization may occur in both ring systems and alkyl side chains of kerogen-bound hopanoid *** stepwise pyrolysis proves to be a quick screening method for geological hopanoids without causing any significant alteration to the original skeletons even when cracking multiple covalent bonds is necessary.

关键词： Hopanoid Hopane Hopene Neohopene stepwise pyrolysis Kerogen Eocene oil shale

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Orchard sports Injury and Illness Classification system (OsIICs) Version 15

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Journal of sport and Health science 2024年第4期13卷 599-604页

作者： john W.Orchard Ebonie Rio Kay M.Crossley Jessica J.Orchard Margo Mountjoy school of Public Health University of SydneySydneyNSW 2006Australia La Trobe sport and Exercise Medicine Research Centre La Trobe UniversityMelbourneVIC 3083Australia Department of Family Medicine McMaster UniversityHamilton L8S 4L8Canada

Background:sports medicine(injury and illnesses)requires distinct coding systems because the International Classification of Diseases is insuf-ficient for sports medicine *** Orchard sports Injury and Illness Classification system(OsIICs)is one of two sports medicine coding systems recommended by the International Olympic *** updates of coding systems are ***:For Version 15,updates for mental health conditions in athletes,sports cardiology,concussion sub-types,infectious diseases,and skin and eye conditions were considered particularly ***:Recommended codes were added from a recent International Olympic Committee consensus statement on mental health conditions in *** landmark sports cardiology papers were used to update a more comprehensive list of sports cardiology *** union protocols on head injury assessment were used to create additional concussion ***:It is planned that OsIICs Version 15 will be translated into multiple new languages in a timely fashion to facilitate international *** large number of recently published sport-specific and discipline-specific consensus statements on athlete surveillance warrant regular updating of OsIICs.

关键词： sports cardiology Dermatology Eye injuries Concussion Infectious diseases sports injury classification

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A four-band index for both liquid and solid water and its applications in the Aral sea Basin

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science China Earth sciences 2024年第3期67卷 769-788页

作者： Bing YUE Xi CHEN saibo LI Zhengping DU john WILsON Junhui YANG Yimen JIAO shuangyan HUANG Chenghu ZHOU Xinjiang Institute of Ecology and Geography Chinese Academy of SciencesUrumqi 830011China College of Resources and Environment University of Chinese Academy of SciencesBeijing 100049China Institute of Geographical sciences and Natural Resources Research Chinese Academy of SciencesBeijing 100101China spatial sciences Institute University of Southern CaliforniaLos AngelesCA 90089-0374USA

Various investigations have been conducted to analyze the water-coverage area of the Aral sea and the Aral sea Basin(AsB). However, the investigations incorporated considerable uncertainty and the used water indices had misclassification problem, which made different research groups present different results. Thus we first ascertain the boundaries of the AsB, the syr and Amu river basins as well as their upper, middle and lower reaches. Then a four-band index for both liquid and solid water(ILsW) is proposed to address the misclassification problems of the classic water indices. ILsW is calculated by using the reflectance values of the green, red, near infrared, and thermal infrared bands, which combines the normalized difference water index(NDWI) and land surface temperature(LsT) together. Validation results show that the ILsW water index has the highest accuracy by far in the Aral sea Basin. Our results indicate that annual average decline of the water-coverage area was 963 km^(2) in the southern Aral sea, whereas the northern Aral sea has experienced little change. In the meanwhile, permanent ice and snow in upper reach of AsB has retreated considerably. Annual retreating rates of the permanent ice and snow were respectively 6233and 3841 km^(2) in upper reaches of Amu river basin(UARB) and syr river basin(UsRB). One of major reasons is that climate has become warmer in AsB. The climate change has caused serious water deficit problem. The water deficit had an increasing trend since the 1990s and its increasing rates was 3.778 billion m^(3) yearly on average. The total water deficit was 76.967 billion m^(3) on average in the whole area of AsB in the 2010s. However, up reaches of syr river basin(UsRB), a component area of AsB, had water surplus of 25.461 billion m^(3). These conclusions are useful for setting out a sustainable development strategy in AsB.

关键词： Aral sea Basin syr river basin Amu river basin Water indices Water-coverage area Water deficit Climate change

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Dynamic knowledge graph approach for modelling the decarbonisation of power

Energy and AI

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Energy and AI 2024年第3期17卷 48-64页

作者： Wanni Xie Feroz Farazi john Atherton Jiaru Bai sebastian Mosbach Jethro Akroyd Markus Kraft Department of Chemical Engineering and Biotechnology University of CambridgePhilippa Fawcett DriveCambridge CB30ASUK CAREs Cambridge Centre for Advanced Research and Education in Singapore1 Create WayCREATE Tower#05-05Singapore138602Singapore school of Chemical and Biomedical Engineering Nanyang Technological University62 Nanyang DriveSingapore637459Singapore The Alan Turing Institute LondonNW12DBUK

This paper presents a dynamic knowledge graph approach that offers a reusable,interoperable,and extensible framework for modelling power *** ontologies have been developed to support a linked data representation of infrastructure data,socio-demographic data,areal attributes like demand,and models describing power *** knowledge graph links the data with a hierarchical representation of administrative regions,supporting geospatial queries to retrieve information about the population within the vicinity of a power plant,the number of power plants,total generation capacity,and demand within specific *** agents were developed to operate on the knowledge *** agents performed tasks including data uploading,updating,retrieval,processing,model construction and scenario analysis.A derived information framework was used to track the provenance of information calculated by agents involved in each *** knowledge graph was populated with data describing the UK power *** alternative models of the transmission grid with different levels of structural resolution were instantiated,providing the foundation for the power system simulation and optimisation tasks performed by the *** application of the dynamic knowledge graph was demonstrated via a case study that investigates clean energy transition trajectories based on the deployment of small Modular Reactors in the UK.

关键词： Power system modelling Decarboni sation Dynanic knowledge graph Ontology and semantic Web

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A parsimonious Bayesian predictive model for forecasting new reported cases of West Nile disease

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Infectious Disease Modelling 2024年第4期9卷 1175-1197页

作者： saman Hosseini Lee W.Cohnstaedt john M.Humphreys Caterina scoglio Department of Electrical and Computer Engineering Kansas State UniversityManhattanKSUSA Foreign Arthropod-Borne Animal Diseases Research Unit National Bio-and Agro-defense Facility USDA ARSManhattanKSUSA Foreign Animal Disease Research Unit National Bio-and Agro-defense FacilityUSDA ARSManhattanKSUSA

Upon researching predictive models related toWest Nile virus disease,it is discovered that there are numerous parameters and extensive information in most models,thus contributing to unnecessary *** challenge frequently encountered is the lead time,which refers to the period for which predictions are made and often is too *** paper addresses these issues by introducing a parsimonious method based on ICC curves,offering a logistic distribution model derived from the vector-borne sEIR *** existing models relying on diverse environmental data,our approach exclusively utilizes historical and present infected human cases(number of new cases).With a yearlong lead time,the predictions extend throughout the 12 months,gaining precision as new data *** conditions are derived to minimize Bayesian loss,enhancing predictive *** construct a Bayesian forecasting probability density function using carefully selected prior *** these functions,we predict monthspecific infections nationwide,rigorously evaluating accuracy with probabilistic ***,HPD credible intervals at 90%,95%,and 99%levels is *** assessment is conducted for HPD intervals,measuring the proportion of intervals that does not include actual reported cases for 2020e2022.

关键词： West nile virus ICC curve Bayesian model Logistic distribution HPD credible interval

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Assessment of clinical depression metrics in cardiac patients using the patient health Questionnaire-9 before and after phase-II cardiac rehabilitation

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sports Medicine and Health science 2024年第3期6卷 240-245页

作者： john C.Quindry Michael McNamara Carrie Oser Crystelle Fogle Integrative Physiology and Athletic Training University of MontanaMissoulaMTUSA st.Patrick's Hospital MissoulaMTUSA Cardiovascular Health Program–Montana Department of Public Health and Human services HelenaMTUSA

Cardiovascular disease remains a leading cause of morbidity and mortality,a fact that is commonly associated with co-morbidities such as clinical *** phase II cardiac rehabilitation is an established intervention for those with cardiovascular disease,its effect on patients who also suffer from depression are under ***:To quantify Pre-and Post-cardiac rehabilitation questionnaire scores collected from a large patient data *** this investigation,27670 patients completed Patient Health Questionnaire-9 questionnaires both Pre-and Post-rehabilitation(averaging[28.08.7]phase II sessions).Findings reveal that questionnaire scores decreased by 40%–48%across all groups,a finding that was independent of assigned sex,race,and ***,when data were stratified for questionnaire scores that may indicate major and minor depressive disorder,phase II cardiac rehabilitation outcomes were lower by 61%and 49%*** all groups exhibited lower questionnaire scores following cardiac rehabilitation participation,numerical differences at Preand Post-rehabilitation time points indicate that males and White patients have more favorable *** latter observation,while not confirmed currently,appears to be linked to referral rates to phase II cardiac rehabilitation,which remain poor for females,racial and ethnic minorities.

关键词： Clinical depression Exercise Psychological health

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Bile acid metabolism and signaling in health and disease:molecular mechanisms and therapeutic targets

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signal Transduction and Targeted Therapy 2024年第5期9卷 2014-2064页

作者： Joshua s.Fleishman sunil Kumar Department of Pharmaceutical sciences College of Pharmacy and Health SciencesSt.John’s UniversityQueensNYUSA

Bile acids,once considered mere dietary surfactants,now emerge as critical modulators of macronutrient(lipid,carbohydrate,protein)metabolism and the systemic pro-inflammatory/anti-inflammatory *** acid metabolism and signaling pathways play a crucial role in protecting against,or if aberrant,inducing cardiometabolic,inflammatory,and neoplastic conditions,strongly influencing health and *** curative treatment exists for any bile acid influenced disease,while the most promising and well-developed bile acid therapeutic was recently rejected by the ***,we provide a bottom-up approach on bile acids,mechanistically explaining their biochemistry,physiology,and pharmacology at canonical and non-canonical *** this mechanistic model of bile acids,we explain how abnormal bile acid physiology drives disease pathogenesis,emphasizing how ceramide synthesis may serve as a unifying pathogenic feature for cardiometabolic *** provide an in-depth summary on pre-existing bile acid receptor modulators,explain their shortcomings,and propose solutions for how they may be ***,we rationalize novel targets for further translational drug discovery and provide future *** than dismissing bile acid therapeutics due to recent setbacks,we believe that there is immense clinical potential and a high likelihood for the future success of bile acid therapeutics.

关键词： metabolism rejected shortcomings

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Targeting TrkB–PsD-95 coupling to mitigate neurological disorders

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Neural Regeneration Research 2025年第3期20卷 715-724页

作者： Xin Yang Yu-Wen Alvin Huang john Marshall Department of Molecular Biology Cell Biology and BiochemistryBrown UniversityProvidenceRIUSA Department of Neurology Warren Alpert Medical School of Brown UniversityProvidenceRIUSA Center for Translational Neuroscience Robert J.and Nancy D.Carney Institute for Brain Science and Brown Institute for Translational ScienceBrown UniversityProvidenceRIUSA

Tropomyosin receptor kinase B(TrkB)signaling plays a pivotal role in dendritic growth and dendritic spine formation to promote learning and *** activity-dependent release of brain-derived neurotrophic factor at synapses binds to pre-or postsynaptic TrkB resulting in the strengthening of synapses,reflected by long-term ***,the association of postsynaptic density protein-95 with TrkB enhances phospholipase Cγ-Ca^(2+)/calmodulin-dependent protein kinaseⅡand phosphatidylinositol 3-kinase-mechanistic target of rapamycin signaling required for long-term *** this review,we discuss TrkB-postsynaptic density protein-95 coupling as a promising strategy to magnify brain-derived neurotrophic factor signaling towards the development of novel therapeutics for specific neurological disorders.A reduction of TrkB signaling has been observed in neurodegenerative disorders,such as Alzheimer's disease and Huntington's disease,and enhancement of postsynaptic density protein-95 association with TrkB signaling could mitigate the observed deficiency of neuronal connectivity in schizophrenia and *** with brain-derived neurotrophic factor is problematic,due to poor pharmacokinetics,low brain penetration,and side effects resulting from activation of the p75 neurotrophin receptor or the truncated TrkB.T1 *** TrkB agonists and antibodies that activate TrkB are being intensively investigated,they cannot distinguish the multiple human TrkB splicing isoforms or cell type-specific *** TrkB–postsynaptic density protein-95 coupling provides an alternative approach to specifically boost TrkB signaling at localized synaptic sites versus global stimulation that risks many adverse side effects.

关键词： Angelman syndrome autism brain-derived neurotrophic factor depression neurodegenerative disorder neurodevelopmental disorder postsynaptic density protein-95 synaptic plasticity TrkB

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Oscillating spacetime: The Foundation of the Universe

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Journal of Modern Physics 2024年第8期15卷 1097-1143页

作者： john A. Macken santa Rosa California USA

In this article, spacetime is modeled as a quantum mechanical sonic medium consisting of Planck length oscillations at Planck frequency. Planck length-time oscillations give spacetime its physical constants of c, G and ħ. Oscillating spacetime is proposed to be the single universal field that generates and unifies everything in the universe. The 17 fields of quantum field theory are modeled as lower frequency resonances of oscillating spacetime. A model of an electron is proposed to be a rotating soliton wave in this medium. An electron appears to have wave-particle duality even though it is fundamentally a quantized wave. This soliton wave can momentarily be smaller than a proton in a high energy collision or can have a relatively large volume of an atom’s orbital wave function. Finding an electron causes it to undergo a superluminal collapse to a smaller wave size. This gives an electron its particle-like properties when detected. The proposed wave-based electron model is tested and shown to have an electron’s approximate energy, de Broglie wave properties and undetectable volume. Most important, this electron model is shown to also generate an electron’s electrostatic and gravitational forces. The gravitational properties are derived from the nonlinearity of this medium. When an electron’s gravitational and electrostatic forces are modeled as distortions of soliton waves, the equations become very simple, and a clear connection emerges between these forces. For example, the gravitational force between two Planck masses equals the electrostatic force between two Planck charges. Both force magnitudes equal ħc/r2.

关键词： Unification of Forces Electron Model Cosmological Constant Problem Foundation of Physics Aether

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