检索结果-南通市图书馆

Stable graphene oxide-based lyotropic liquid crystals for interfacial lubrication

Friction 2024年第5期12卷 954-967页

作者： Yumei GUO Hanglin li jiusheng li Xiangqiong ZENG Laboratory for Advanced Lubricating Materials Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai201210China University of Chinese Academy of Sciences Beijing100049China

Lyotropic liquid crystals have lubricating properties due to their ordered assembly and fluidity,whose mesogens are often characterized by amphiphilic properties.Despite the attention that graphene oxide(GO)has been studied as a novel amphiphilic lyotropic mesogen this decade,and GO applied as a lubrication additive has been demonstrated in both oil and water-based systems,little research reveals the interfacial lubrication of GO liquid crystals yet.This work reports that GO aqueous dispersion can form lyotropic liquid crystals above a specific critical concentration of 5.00 mg/mL,providing a form of stable water-based lubricant,which can keep stable for several months and can reduce friction by 37.3%and wear by 25.24%.The liquid crystal phase was verified by polarizing microscope and synchrotron radiation small-angle X-ray scattering,and its rheological properties and viscoelasticity were studied by interfacial rheometer.The formation of lyotropic liquid crystals can enhance the stability of GO aqueous dispersions at high density,simultaneously ensuring friction decrease and anti-wear effect.It is attributed to the stable nematic network by the ordered GO sheets.The ordered assembly structure bears vertical shear force,therefore,reducing the wear.It is also assumed that the wide lateral size of graphene oxide promotes the nematic phase thus smoothes the graphene oxide film composed spontaneously under the coincidence of lamellar liquid crystal and 2D layered material.Through this work,the interlayer lubrication of GO was optimized,and the problem of GO dispersion sedimentation was solved by self-assembly.The range of interfacial lubrication of GO aqueous dispersion has been expanded and the synergistic effect is conducive to the environmentally friendly lubricants.

关键词： lyotropic liquid crystal graphene oxide aqueous lubrication tribological behavior

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Water lubrication of graphene oxide-based materials

引用

Friction 2022年第7期10卷 977-1004页

作者： Shaoqing XUE Hanglin li Yumei GUO Baohua ZHANG jiusheng li Xiangqiong ZENG Laboratory for Advanced Lubricating Materials Shanghai Advanced Research InstituteChinese Academy of SciencesUniversity of Chinese Academy of SciencesShanghai 201210China School of Environmental and Chemical Engineering Shanghai UniversityShanghai 200444China Key Laboratory for Advanced Materials School of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai 200237China

Water is as an economic,eco-friendly,and efficient lubricant that has gained widespread attention for manufacturing.Using graphene oxide(GO)-based materials can improve the lubricant efficacy of water lubrication due to their outstanding mechanical properties,water dispersibility,and broad application scenarios.In this review,we offer a brief introduction about the background of water lubrication and GO.Subsequently,the synthesis,structure,and lubrication theory of GO are analyzed.Particular attention is focused on the relationship between pH,concentration,and lubrication efficacy when discussing the tribology behaviors of pristine GO.By compounding or reacting GO with various modifiers,amounts of GO-composites are synthesized and applied as lubricant additives or into frictional pairs for different usage scenarios.These various strategies of GO-composite generate interesting effects on the tribology behaviors.Several application cases of GO-based materials are described in water lubrication,including metal processing and bio-lubrication.The advantages and drawbacks of GO-composites are then discussed.The development of GO-based materials for water lubrication is described including some challenges.

关键词： tribology water lubrication graphene oxide(GO)

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Formulation of lyotropic liquid crystal emulsion based on natural sucrose ester and its tribological behavior as novel lubricant

引用

Friction 2022年第11期10卷 1879-1892页

作者： Yumei GUO jiusheng li Xiaojie ZHOU Yuzhao TANG Xiangqiong ZENG Laboratory for Advanced Lubricating Materials Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201210China University of Chinese Academy of Sciences Beijing 100049China National Facility for Protein Science in Shanghai Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201210China

The tribological behavior of oil-in-water emulsions formulated with natural lyotropic liquid crystal(LLC)emulsifiers based on natural sucrose ester was studied for the first time.Polarized optical microscopy,synchrotron radiation small-angle X-ray scattering,wide-angle X-ray scattering,and synchrotron radiation infrared microspectroscopy demonstrated that LLC emulsifiers were tightly ordered at the oil–water interface with a distinct nematic texture.The viscosity of emulsion was observed to change over time.Moreover,the zeta potential and laser particle size distribution verified the emulsion’s satisfactory stability.The frictional shearing test proved that the coefficient of friction of the emulsion versus pure oil decreased by 34.2%.The coefficient of friction of the emulsion with liquid crystal decreased 10.1%versus that without liquid crystal.Although liquid crystal emulsion did not exhibit outstanding anti-wear performance compared with pure oil,its wear volume was 29.4%less than the emulsion without liquid crystal.X-ray photoelectron spectroscopy and scanning electron microscope–energy dispersive X-ray spectroscopy(SEM–EDS)proved that the tribo-film of the emulsion with liquid crystal was formed synergistically by the liquid crystal phase with the base oil.The formulation affecting the lubricant quality was further studied by orthogonal experiments.The resulting Stribeck curve behavior suggested that proper composition with a slightly higher viscosity can better reduce friction in both boundary lubrication and mixed lubrication regimes.The lubrication mechanism indicated that the periodically ordered liquid crystal was transported to the sliding asperity in the form of emulsion droplets,which bored the pressure and released the oil to form a tribo-film.This LLC emulsion is environmentally friendly and potentially non-irritant to the skin.Thus,it has promising application prospects as novel water-based and biological lubricants.

关键词： lyotropic liquid crystal(LLC) emulsion aqueous lubrication tribological behavior

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

全向双功能太赫兹超表面器件

引用

光学学报 2024年第3期44卷 247-259页

作者：张丽娜李九生中国计量大学太赫兹波研究所浙江杭州310018

传统太赫兹多功能超表面器件只适用于对圆极化波或线极化波进行单独操控,应用场景受到局限。针对这一问题,提出一种全向双功能太赫兹超表面用于对圆极化和线极化波进行操控。该超表面单元由4层聚酰亚胺介质以三明治形式分隔5个金属层(... 详细信息

传统太赫兹多功能超表面器件只适用于对圆极化波或线极化波进行单独操控,应用场景受到局限。针对这一问题,提出一种全向双功能太赫兹超表面用于对圆极化和线极化波进行操控。该超表面单元由4层聚酰亚胺介质以三明治形式分隔5个金属层(顶层和底层椭圆金属图案、第3和第7层的金属光栅以及中间矩形金属条结构)组成。当圆极化太赫兹波入射时,该超表面结构在频率1.4 THz和1.5 THz处产生拓扑荷数l=±1、±2涡旋波束,在1.3 THz处产生l=-1四个涡旋波束和l=+2偏移涡旋波束,并且在1.5 THz处同时产生l=-1、+2叠加涡旋波束。当线极化太赫兹波从±z方向入射时,所设计的超表面在频率0.72 THz处实现透射波极化转换功能,极化转换率大于95%。研究结果表明,该超表面为实现双向多功能太赫兹波调控器件设计提供了一种创新思路。

关键词：太赫兹涡旋波束发生器极化转换多功能

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Tribological behavior of nanocarbon materials with different dimensions in aqueous systems

引用

Friction 2020年第1期8卷 29-46页

作者： Hongmei YANG jiusheng li Xiangqiong ZENG Laboratory for Advanced Lubricating Materials Shanghai Advanced Research InstituteChinese Academy of SciencesUniversity of Chinese Academy of SciencesShanghai 201210China

Due to the widespread use of nanocarbon materials(NCMs),more researchers are studying their tribological performances.In this work,the tribological behaviors of the following five types of NCMs with different geometric shapes were evaluated in a novel oil‐in‐water system:spherical fullerenes(C60,0D),tubular multi‐walled carbon nanotubes(MWCNT,1D),sheet graphene oxide(GO,2D),sheet graphene oxide derivative(Oct‐O‐GO,2D),and lamellar graphite(G,3D).Among these,GO with two types of oxidation degrees,i.e.,GO(1),GO(2),and Oct‐O‐GO(1)were synthesized and characterized using Fourier‐transform infrared spectroscopy,Raman spectroscopy,x‐ray diffraction,thermogravimetric analysis,scanning electron microscopy,and contact angle measurements.The load‐carrying capacity of the NCM emulsions were evaluated using a four‐ball test machine,and the lubrication performances were investigated using a high‐frequency reciprocating friction and wear tester with a sliding distance of 1,800 mm under different loads(50 N and 100 N)at 0.5 Hz.The results revealed that the Oct‐O‐GO(1)emulsion exhibited the best load‐carrying capacity,and the best friction‐reducing and anti‐wear properties compared to other emulsions.Moreover,the anti‐wear advantage was more prominent under high load conditions,whereas the other emulsions exhibited a certain degree of abrasive or adhesive wear.The lubrication mechanism was determined through the analysis of worn surfaces using scanning electron microscopy/energy‐dispersive x‐ray spectroscopy,micro‐Raman spectroscopy,and x‐ray photoelectron spectroscopy.The results revealed that during frictional sliding,the ingredients in the emulsion can absorb and react with the freshly exposed metal surface to form surface‐active films to protect the surfaces from abrasion.Moreover,it was found that the higher the amount of ingredients that contain alkyl and O‐H/C=O,the better was the lubrication performance in addition to an increase in the carbon residue in the tribofilm generated on the meal surface.

关键词： nano‐carbon materials tribological behavior modified graphene oxide oil‐in‐water emulsion

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

A mild phenoxysilyl linker for self-immolative release of antibody-drug conjugates

引用

Chinese Chemical Letters 2023年第5期34卷 494-498页

作者： Ding Wei Yurong Mao Huihui Wang Siqi Qu Jiakang Chen jiusheng li Biao Jiang Hongli Chen Shanghai Advanced Research Institute Chinese Academy of SciencesShanghai 201210China Shanghai Institute for Advanced Immunochemical Studies ShanghaiTech UniversityShanghai 201210China University of Chinese Academy of Sciences Beijing 100049China

Self-immolative linkers have been widely used to construct prodrugs to improve their efficacy and safety.In this study,we report the use of phenoxysilyl linker as a self-immolative unit to prepare antibody-drug conjugates(ADCs).Phenoxysily based ADC Ate-PPS-CA4 was prepared and its release was systematically investigated by mass spectrometry.Biological evaluation showed that Ate-PPS-CA4 displayed the ability to target delivery and self-immolative release the active payload CA4 on PD-L1 positive cells MDA-MB-231.As the same with its payload CA4,it could arrest the cell cycle to the G2/M phase and induced changes in cell morphology at the dose of its IC_(50).The development of this linker with novel drug release mechanisms will expand the methodology to construct ADCs,especially for non-internalizing ADCs by extracellular cleavage.

关键词： Antibody-drug conjugates Self-immolative release Phenoxysilyl linker Combretastatin A4(CA4)

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

华北平原夏玉米喷灌施氮制度优化

引用

农业工程学报 2024年第11期40卷 77-84页

作者：范欣瑞赵伟霞李久生中国水利水电科学研究院流域水循环模拟与调控国家重点实验室北京100048 水利部海河水利委员会科技咨询中心天津300170

不合理的氮肥施用和较大的降雨量时空变化特征是限制华北平原夏玉米增产和肥料利用效率提高的关键因素。为探究华北平原夏玉米最优喷灌施肥管理制度,于2020年和2021年在河北省邢台市大曹庄管理区开展试验,以地面灌溉肥料撒施处理为对照... 详细信息

不合理的氮肥施用和较大的降雨量时空变化特征是限制华北平原夏玉米增产和肥料利用效率提高的关键因素。为探究华北平原夏玉米最优喷灌施肥管理制度,于2020年和2021年在河北省邢台市大曹庄管理区开展试验,以地面灌溉肥料撒施处理为对照,研究了喷灌施肥下3种施氮量确定方法(农户经验值、养分平衡法和改进养分平衡法)和3种氮肥追施方法(不追肥、在大喇叭口-灌浆期内较大降雨后追施1次和追施2次)对土壤水氮分布、作物生长、产量以及氮肥利用效率的影响。结果表明,受降雨影响,夏玉米生育期内0~100 cm土层的土壤含水率始终保持在较高水平。施氮量和氮肥追施次数的增加均提高了夏玉米关键需肥阶段根区的土壤无机氮含量,且喷灌处理的增加量大于对照处理。2 a夏玉米收获后,养分平衡法确定施氮量处理和氮肥全部基施处理的土壤氮素残留量均低于参考盈余水平(50 kg/hm^(2))。不同处理叶面积指数未出现显著差异,但氮肥追施2次的喷灌处理显著增加了玉米干物质量和植株吸氮量,产量和氮肥偏生产力均分别比对照处理显著提高了20%。考虑氮素盈余的改进养分平衡法和在大喇叭口期-灌浆期内较大降雨后追施2次的施肥方法有助于维持土壤氮库平衡,且具有显著的增产和氮肥利用效率提高作用,可推荐为华北平原夏玉米喷灌施肥制度。研究可为大型喷灌机在华北平原的推广应用提供参考。

关键词：灌溉氮肥圆形喷灌机水肥一体化半湿润气候氮素盈余

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

五龄黑水虻油脂衍生物作为润滑油添加剂的性能研究

引用

摩擦学学报（中英文） 2024年第1期44卷 87-96页

作者：吴晗冯思静胡文敬李久盛辽宁工程技术大学环境科学与工程学院辽宁阜新123000 上海建桥学院商学院上海201306 中国科学院上海高等研究院先进润滑材料实验室上海201210 中国科学院低碳转化科学与工程重点实验室上海201210

为探索黑水虻幼虫体内的粗油脂作为生物润滑油添加剂的应用可行性,本文中以五龄黑水虻虫体的粗油脂为原料,通过纯化、水解反应和酯化反应合成了虫体油脂衍生物.采用核磁共振波谱、傅里叶红外光谱和热重分析仪对其结构和热稳定性进行表征... 详细信息

为探索黑水虻幼虫体内的粗油脂作为生物润滑油添加剂的应用可行性,本文中以五龄黑水虻虫体的粗油脂为原料,通过纯化、水解反应和酯化反应合成了虫体油脂衍生物.采用核磁共振波谱、傅里叶红外光谱和热重分析仪对其结构和热稳定性进行表征,发现其热稳定性良好.采用UMT-TriboLab摩擦磨损试验机和四球摩擦试验机分别研究了虫体油脂衍生物作为润滑油添加剂在点-面和点-点接触模式下的摩擦学性能,并与商用合成酯的性能进行对比.结果表明,在基础油150N中添加质量分数为1%的虫体油脂衍生物时,油品表现出较优的减摩和抗磨效果.在点-面接触模式下,摩擦系数和磨损率相对于基础油分别降低25.0%和92.0%,且在200℃高温下仍能保持减摩效果.在点-点接触模式下,磨损率相对于基础油降低了84.5%.可见虫体油脂衍生物作为润滑油添加剂能够有效提高油品的摩擦学性能.采用接触角试验验证了虫体油脂衍生物作为润滑油添加剂在金属表面的吸附性能.结果表明,虫体油脂衍生物在润滑过程中能够优先吸附在摩擦副的金属表面,形成润滑保护膜,使油品的减摩和抗磨性能提升.通过显微红外光谱和拉曼光谱研究了虫体油脂衍生物的润滑作用机理,表明磨痕表面存在的铁氧化物和碳能够形成润滑膜,防止摩擦副表面的微凸体直接接触,进而改善了油品的摩擦学性能.

关键词：黑水虻幼虫虫体油脂衍生物热稳定性能润滑油添加剂摩擦学性能

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

基于变量灌溉动态分区管理的冬小麦产量与节水效果

引用

农业工程学报 2024年第5期40卷 109-117页

作者：赵伟霞张敏讷祝长鑫李久生黄乾中国水利水电科学研究院流域水循环模拟与调控国家重点实验室北京100048 山东省水利科学研究院济南250014

喷灌机机载式红外温度传感器系统是动态监测农田作物水分亏缺状况、构建变量灌溉(variable rate irrigation,VRI)决策支持系统的重要工具。为了评估圆形喷灌机机载式红外温度传感器系统在变量灌溉动态分区管理中的应用效果,该研究以气... 详细信息

喷灌机机载式红外温度传感器系统是动态监测农田作物水分亏缺状况、构建变量灌溉(variable rate irrigation,VRI)决策支持系统的重要工具。为了评估圆形喷灌机机载式红外温度传感器系统在变量灌溉动态分区管理中的应用效果,该研究以气象参数和土壤水分传感器网络构建的均一灌溉(uniform rate irrigation, URI)决策方法为对照,评估了基于气象参数、土壤水分传感器网络和作物冠层温度的变量灌溉决策方法对华北平原冬小麦灌溉制度、土壤含水率空间分布均匀性和节水增产效果的影响。在河北省邢台市大曹庄中国水利水电科学研究院智慧灌溉技术与装备创新示范推广基地开展试验,试验区为三跨加悬臂圆形喷灌机控制灌溉面积7.07 hm^(2),2021年试验区等分为2个子区,布置URI和VRI处理,2022年试验区等分为4个子区,布置URI处理、基于等间隔法进行管理区聚类划分的VRI(T1)处理、基于“Jenks”自然断点法进行管理区聚类划分的VRI(T2)处理和基于几何间隔断点法进行管理区聚类划分的VRI(T3)处理。结果表明,在冬小麦生育期内,URI和VRI处理灌水7~10次,2 a平均灌水量分别为201和173 mm。开展VRI管理后,冬小麦主根区的土壤含水率空间分布均匀性和产量均匀性提高。2021年URI和VRI处理的冬小麦产量分别为9 470和9 574 kg/hm^(2),2022年的冬小麦产量较2021年分别降低6.7%和6.0%。变量灌溉处理的管理区聚类划分方法未对灌溉制度和产量产生显著影响。与URI处理相比,VRI处理能够减少灌溉水量,且对产量和水分利用效率无显著影响。研究结果可为基于喷灌机机载式红外温度传感器系统的变量灌溉动态分区管理方法的建立提供指导,为变量灌溉决策支持系统的开发升级提供技术支持。

关键词：灌溉土壤水分作物圆形喷灌机冠层温度变量灌溉处方图

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Synthesis of Pillar[n]arene[5−n]quinines via Partial Oxidation of Pillar[5]arene

引用

中国化学:英文版 2015年第3期33卷 379-383页

作者： Changdong Xie Weibo Hu Wenjing Hu Yahu A.liu Jichuan Huo jiusheng li Biao Jiang Ke Wen School of Materials Science and Engineering Southwest University of Science and TechnologyMianyangSichuan 621010China Shanghai Advanced Research Institute Chinese Academy of SciencesShanghai 201210China Medicinal Chemistry ChemBridge Research Laboratories Inc.San DiegoCA 92127USA University of Chinese Academy of Sciences Beijing 100039China School of Physical Science and Technology Shanghai Tech UniversityShanghai 201210China

An improved partial oxidation of 1,4-dimethoxypillar[5]arene(DMP[5])was described,through which selected pillar[n]arene[5−n]quinones,such as pillar[4]arene[1]quinone,pillar[3]arene[2]quinone,pillar[2]arene[3]quinone and pillar[1]arene[4]quinone,were synthesized by manipulating the ratio of oxidative reagent(NH4)2[Ce(NO3)6]to DMP[5].

关键词： pillararene pillararene oxidation pillar[n]arene[5−n]quinones

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：