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Differentially-grown cobalt regulators cooperatively involved in the tandem catalysis for high-yield production of second amines

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Nano Research 2024年第4期17卷 2444-2450页

作者： Jinhui Xu xiao Wang Ying Wang Fei Wang Lingling Zhang Wenjie Cui Shuyan Song Hongjie Zhang State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China School of applied Chemistry and Engineering University of Science and Technology of ChinaHefei 230026China Department of Chemistry Tsinghua UniversityBeijing 100084China

One-pot tandem catalysis has been regarded as one of the most atomic economic ways to produce secondary amines,the important platform molecules for chemical synthesis and pharmaceutical manufacture,but it is facing serious issues in overall *** promotional effects are highly desired for boosting the activity and regulating the selectivity of conventional tandem *** this work,we report a high-performance tandem catalyst with maximized synergistic effect among each counterpart by preciously manipulating the spatial structure,which involves the active CeO_(2./Pt component as kernel,the densely-coated N-doped C(NC)layer as selectivity controller,and the differentially-grown Co species as catalytic performance *** comprehensive investigations,the unique growth mechanism and the promotion effect of Co regulators are ***,the surface-landed Co clusters(Cocs)are crucial to selectivity by altering the adsorption configuration of benzylideneaniline ***,the inner Co particles(Cops)are essential for activity by denoting their electrons to neighboring *** from the unique promotion effect,a remarkably-improved catalytic efficiency(100%nitrobenzene conversion with 94%N-benzylaniline selectivity)is achieved at a relatively low temperature of 80℃,which is much better than that of CeO_(2./Pt(100%nitrobenzene conversion with 12.N-benzylaniline selectivity)and CeO_(2./Pt/NC(35%nitrobenzene conversion with 94%benzylideneaniline selectivity).

关键词： tandem catalysis CeO_(2. hierarchical structure heterogeneous catalyst dual-site materials

Experimental study on wax deposition of highly paraffinic oil in intermittent gas-oil flow in pipelines

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Petroleum science 2024年第3期21卷 2080-2088页

作者： Chuan-Shuo Wang Qian-Li Ma xiao-Fang Lv Jie Zhang Yang Liu Shi-Dong Zhou Jiangsu Key Laboratory of Oil and Gas Storage and Transportation technology Changzhou UniversityChangzhou213164JiangsuPR China Hade Oil and Gas Development Department Tarim Oilfield BranchKorla841000XinjiangPR China

Oil-gas two phase wax deposition is a fairly common and open-ended question in flow assurance of multiphase transportation *** paper investigated the two main aspects of oil-gas two phase wax deposition layer:apparent thickness and crystal structure characteristics.A typical highly paraffinic oil in Bohai Sea,china,was used as the experimental material to investigate the wax deposition thickness in oil-gas two phase under the influence of different oil temperatures,superficial gas/liquid phase velocities and gas-oil ratios by using multiphase flow loop experimental *** as in the classical theory of wax molecular diffusion,it showed that wax deposition thickness of oil-gas two phase increased with increasing oil *** of the impact of different superficial phase velocities found that the actual liquid flow heat transfer and shear stripping was the gas phase dominant mechanisms determining wax deposit *** addition,the crystal structure of the wax deposition layer was characterized with the help of small-angle X-ray scattering(SAXS)for different circumferential positions,flow rates and gas-oil *** bottom deposition layer had a complex crystal structure and high hardness,which were subject to change over flow rate ***,the SAXS results provided evidence that the indirect effect of the actual liquid velocity modified by the gas phase was the main *** study of the effect of gas phase on the wax deposition of oil-gas two phase will help shed light onto the mechanism by which this important process *** findings address a very urgent need in the field of wax deposition of highly paraffinic oil to understand the flow security of oilgas two phase that occurs easily in multiphase field pipelines.

关键词： Oil-gas two phase Highly paraffinic oil Wax deposition SAXS

Nursing effect of narrative nursing intervention on postoperative patients with severe lung cancer

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World Journal of Clinical Cases 2024年第1期12卷 76-85页

作者： Bin Wen Ying Liu xiao-Xia Min An-Qi Wang Department of Intensive Care Tongren Hospital of Wuhan University and Wuhan Third HospitalOptics Valley BranchWuhan 430074Hubei ProvinceChina The First Department of Thoracic Oncology Hubei Cancer Hospital Affiliated to Tongji Medical CollegeHuazhong University of Science and TechnologyWuhan 430079Hubei ProvinceChina Department of Emergency Medicine Taizhou First People's HospitalTaizhou 318020Zhejiang ProvinceChina

BACKGROUND Lung cancer is a common disease with high mortality,and psychological support is very important in the diagnosis and treatment of postoperative patients with cancer *** To explore the application effect of the narrative nursing method in postoperative lung cancer patients in the intensive care *** A total of 12. patients diagnosed with lung cancer and experiencing cancer-related pain were randomly allocated into two groups:an observation group and a control group,each consisting of 60 *** control group was given routine analgesic and psychological care,while the research group applied the five-step narrative nursing method based on routine care,comparing the visual analogue scale scores,sleep status,anxiety and depression status,and quality of life of the two groups of patients before and after the *** The pain scores,anxiety scores,and depression scores of the study group were lower than those of the control group after the intervention using the narrative nursing method,and the difference was statistically significant(P<0.05).CONCLUSION Using narrative nursing methods to intervene in patients with lung cancer combined with cancerous pain can help patients to correctly recognize their disease,adjust their mentality,establish confidence,alleviate patients'subjective pain feelings,and improve their adverse emotions.

关键词： Narrative care Lung cancer Care unit Pain Quality of life

Achieving structurally stable O3-type layered oxide cathodes through site-specific cation-anion co-substitution for sodium-ion batteries

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Journal of Energy Chemistry 2024年第6期93卷 411-418,I0011页

作者： Yihao Shen Chen Cheng xiao Xia Lei Wang Xi Zhou Pan Zeng Jianrong Zeng Liang Zhang Institute of Functional Nano&Soft Materials(FUNSOM) Soochow UniversitySuzhou 215123JiangsuChina Institute for Advanced Study School of Mechanical EngineeringChengdu UniversityChengdu 610106SichuanChina Shanghai Synchrotron Radiation Facility Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201204China Shanghai Institute of applied Physics Chinese Academy of SciencesShanghai 201800China Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow UniversitySuzhou 215123JiangsuChina

O3-type layered oxides have garnered great attention as cathode materials for sodium-ion batteries because of their abundant reserves and high theoretical ***,challenges persist in the form of uncontrollable phase transitions and intricate Na^(+)diffusion pathways during cycling,resulting in compromised structural stability and reduced capacity over *** study introduces a special approach employing site-specific Ca/F co-substitution within the layered structure of O_(3)-NaNi_(0.5)Mn_(0.5)O_(2. to effectively address these ***,the strategically site-specific doping of Ca into Na sites and F into O sites not only expands the Na^(+)diffusion pathways but also orchestrates a mild phase transition by suppressing the Na^(+)/vacancy ordering and providing strong metal-oxygen bonding strength,*** as-synthesized Na_(0.95)Ca_(0.05)Ni_(0.5)Mn_(0.5)O_(1.95)F_(0.05)(NNMO-CaF)exhibits a mild O3→O3+O'3→P3 phase transition with minimized interlayer distance variation,leading to enhanced structural integrity and stability over extended *** a result,NNMO-CaF delivers a high specific capacity of 119.5 mA h g^(-1)at a current density of 12. mA g^(-1)with a capacity retention of 87.1%after 100 *** study presents a promising strategy to mitigate the challenges posed by multiple phase transitions and augment Na^(+)diffusion kinetics,thus paving the way for high-performance layered cathode materials in sodium-ion batteries.

关键词： Sodium-ion batteries O3-type layered oxides Site-specific co-doping Phase transition

Single-element amorphous metals

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Interdisciplinary Materials 2024年第4期3卷 480-491页

作者： xiao Han Geng Wu Dong Sheng He Xun Hong Center of Advanced Nanocatalysis(CAN) Department of Applied ChemistryHefei National Research Center for Physical Sciences at the MicroscaleUniversity of Science and Technology of ChinaHefeiAnhuiChina Core Research Facilities Southern University of Science and TechnologyShenzhenChina

To unveil the nature of amorphous states,single-element amorphous metals have been the perfect research subject due to the simplest ***,the extreme crystal nucleation and growth rate in single-element metal make the synthesis of single-element amorphous metals seemingly impossible in the ***,benefited by several delicate synthetic strategies developed recently,the single-element amorphous metals have been successfully *** review aims to provide a systematic overview of the synthesis of single-element amorphous metals covering the challenges in physics and recent *** addition,current understanding of the atomic and electronic structures of single-element amorphous metal has also been ***,the challenges that worth further investigation are *** identifying the potential avenues for further exploration,this review aims to contribute valuable insights that will propel the cognition of single-element amorphous metals.

关键词： amorphous metal single-element structure synthesis

Data-driven casting defect prediction model for sand casting based on random forest classification algorithm

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china Foundry 2024年第2期21卷 137-146页

作者： Bang Guan Dong-hong Wang Da Shu Shou-qin Zhu xiao-yuan Ji Bao-de Sun Shanghai Key Lab of Advanced High-Temperature Materials and Precision Forming School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China State Key Lab of Metal Matrix Composites Shanghai Jiao Tong UniversityShanghai 200240China Hefei Casting and Forging Factory of Anhui Heli Co. LtdHefei 230000China State Key Laboratory of Materials Processing and Die&Mould technology Huazhong University of Science and TechnologyWuhan 430074China

The complex sand-casting process combined with the interactions between process parameters makes it difficult to control the casting quality,resulting in a high scrap rate.A strategy based on a data-driven model was proposed to reduce casting defects and improve production efficiency,which includes the random forest(RF)classification model,the feature importance analysis,and the process parameters optimization with Monte Carlo *** collected data includes four types of defects and corresponding process parameters were used to construct the RF *** results show a recall rate above 90% for all *** Gini Index was used to assess the importance of the process parameters in the formation of various defects in the RF ***,the classification model was applied to different production conditions for quality *** the case of process parameters optimization for gas porosity defects,this model serves as an experimental process in the Monte Carlo method to estimate a better temperature *** prediction model,when applied to the factory,greatly improved the efficiency of defect *** show that the scrap rate decreased from 10.16% to 6.68%.

关键词： sand casting process data-driven method classification model quality prediction feature importance

Engineering oxygen vacancies on Tb-doped ceria supported Pt catalyst for hydrogen production through steam reforming of long-chain hydrocarbon fuels

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Chinese Journal of Chemical Engineering 2024年第4期68卷 181-192页

作者： Zhourong xiao Changxuan Zhang Peng Li Desong Wang Xiangwen Zhang Li Wang Jijun Zou Guozhu Li State Key Laboratory of Metastable Materials science and technology(MMST) Hebei Key Laboratory of Applied ChemistryCollege of Environmental and Chemical EngineeringYanshan UniversityQinhuangdao 066004China Key Laboratory for Green Chemical technology of Ministry of Education School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China

Steam reforming of long-chain hydrocarbon fuels for hydrogen production has received great attention for thermal management of the hypersonic vehicle and fuel-cell *** this work,Pt catalysts supported on CeO_(2.and Tb-doped CeO_(2.were prepared by a precipitation *** physical structure and chemical properties of the as-prepared catalysts were characterized by powder X-ray diffraction,scanning electron microscopy,transmission electron microscopy,Raman spectroscopy,H_(2.temperature programmed reduction,and X-ray photoelectron *** results show that Tb-doped CeO_(2.supported Pt possesses abundant surface oxygen vacancies,good inhibition of ceria sintering,and strong metal-support interaction compared with CeO_(2.supported *** catalytic performance of hydrogen production via steam reforming of long-chain hydrocarbon fuels(n-dodecane)was *** with 2.t/CeO_(2.,2.t/Ce_(0.9)Tb_(0.1)O_(2.,and 2.t/Ce_(0.5)Tb_(0.5)O_(2.,the 2.t/Ce_(0.7)Tb_(0.3)O_(2.has higher activity and stability for hydrogen production,on which the conversion of n-dodecane was maintained at about 53.2.after 600 min reaction under 700℃at liquid space velocity of 9 ml·g^(-1)·h^(-1).2.t/CeO_(2.rapidly deactivated,the conversion of n-dodecane was reduced to only 41.6%after 600 min.

关键词： Steam reforming n-Dodecane Hydrogen production Pt-based catalyst Oxygen vacancy CeO_(2.

Integrated assessment of yield,nitrogen use efficiency and ecosystem economic benefits of use of controlled-release and common urea in ratoon rice production

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Journal of Integrative Agriculture 2024年第9期23卷 3186-3199页

作者： Zijuan Ding Ren Hu Yuxian Cao Jintao Li Dakang xiao Jun Hou Xuexia Wang College of Agriculture Yangtze University/MARA Key Laboratory of Sustainable Crop Production in the Middle Reaches of the Yangtze River(Co-construction by Ministry and Province)Jingzhou 434025China College of Life science Yangtze UniversityJingzhou 434025China Institute of Plant Nutrition Resources and EnvironmentBeijing Agricultural Forestry Academy SciencesBeijing 100097China

Controlled-release urea(CRU)is commonly used to improve the crop yield and nitrogen use efficiency(NUE).However,few studies have investigated the effects of CRU in the ratoon rice *** rice is the practice of obtaining a second harvest from tillers originating from the stubble of the previously harvested main *** this study,a 2.year field experiment using a randomized complete block design was conducted to determine the effects of CRU on the yield,NUE,and economic benefits of ratoon rice,including the main crop,to provide a theoretical basis for fertilization of ratoon *** experiment included four treatments:(i)no N fertilizer(CK);(ii)traditional practice with 5 applications of urea applied at different crop growth stages by surface broadcasting(FFP);(iii)one-time basal application of CRU(BF1);and(iv)one-time basal application of CRU combined with common urea(BF2..The BF1 and BF2.treatments significantly increased the main crop yield by 17.47 and 15.99%in 2.19,and by 17.91 and 16.44%in 2.2.,respectively,compared with FFP *** BF2.treatment achieved similar yield of the ratoon crop to the FFP treatment,whereas the BF1 treatment significantly increased the yield of the ratoon crop by 14.81%in 2.19 and 12.2.%in 2.2. compared with the FFP *** BF1 and BF2.treatments significantly improved the 2.year apparent N recovery efficiency,agronomic NUE,and partial factor productivity of applied N by 11.47-16.66,2..31-44.49,and 9.2.-15.60%,respectively,compared with FFP *** BF1 and BF2.treatments reduced the chalky rice rate and chalkiness of main and ratoon crops relative to the FFP ***,emergy analysis showed that the production efficiency of the BF treatments was higher than that of the FFP *** BF treatments reduced labor input due to reduced fertilization times and improved the economic benefits of ratoon *** with the FFP treatment,the BF1 and BF2.treatments increased the net income by 14.2.-16

关键词： ratoon rice controlled-release urea yield nitrogen use efficiency economic benefit

Dynamic recrystallization behavior and strengthening mechanism of a novel Mo-Ti_(3)AlC_(2. alloy at ultrahigh temperature

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Rare Metals 2024年第8期43卷 3946-3960页

作者： Lu Yang Xin-Yuan Zheng Yang Zhao Xi-Ran Wang Fang-Nao xiao Shi-Zhong Wei School of Materials science and Engineering Henan University of Science and TechnologyLuoyang 471023China National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials Henan University of Science and TechnologyLuoyang 471003China Department of applied Mechanics Univ.Bourgogne FrancheComteFEMTO-ST InstituteCNRS/UF/ENSMM/UTBM25000BesangonFrance

Increasing the recrystallization temperature to achieve better high-temperature performance is critical in the development of molybdenum alloys for ultrahightemperature applications,such as the newest generation of multitype high-temperature nuclear *** this study,an innovative strategy was proposed to improve the performance of molybdenum alloys at high temperature by using the two-dimensional MAX(where M is an early transition metal,A is an A-group element and X is C or N)ceramic material Ti_(3)AlC_(2..The relationships between flow stress,strain rate and temperature were *** microstructure,distribution of misorientation and evolution of dislocations in the Mo-Ti_(3)AlC_(2. alloy were *** microscopic mechanism of the Ti_(3)AlC_(2. phase in the molybdenum alloy at high temperatures was *** experimental results showed that the peak flow stress of Mo-Ti_(3)AlC_(2. at 1600℃ reached 155 MPa,which was161.8% greater than that of pure *** activation energy of thermal deformation of Mo-Ti_(3)AlC_(2. was as large as537 kJ·mol~(-1),which was 17.6% more than that of pure *** recrystallization temperature reached 1600℃ or even *** topological reaction of the Ti_(3)AlC_(2. phase consumed a large amount of energy at high temperatures,resulting in increases in the deformation activation *** structures of AlTi_3 and Ti-O Magneli-phase oxides(Ti_nO_(2.-1)) were formed in-situ,which relied on kink bands and interlayer slip,resulting in many dislocations during ***,the special two-dimensional of the structure Ti_(3)AlC_(2. ceramic inhibited the recrystallization behavior of the Mo *** results of this study can provide theoretical guidance for the development of a new generation of molybdenum alloys for use in ultrahigh-temperature environments.

关键词： Mo alloy Two-dimensional reinforcement Dynamic recrystallization behavior Hot deformation Mechanical properties