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Low cycle fatigue behavior of micro-grain casting K4169 superalloy at room temperature

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Progress in Natural Science:Materials International 2022年第6期32卷 693-699页

作者： Rui Liu Xitao Wang Pinpin Hu Chengbo Xiao jinshan he Collaborative Innovation Center of Steel Technology University of Science and Technology Beijing Shandong Provincial Key Laboratory for High Strength Lightweight Metallic Materials Advanced Materials Institute Qilu University of Technology (Shandong Academy of Science) Science and Technology on Advanced High Temperature Structural Materials Laboratory AECC Beijing Institute of Aeronautical Materials

The strain-controlled low cycle fatigue tests were carried out at 298 K for the newly developed micro-grain casting K4169 superalloy,and the cyclic stress response,deformation and fracture behaviors of the alloy were studied.The results show that the fatigue life of the alloy was increased by more than two times compared with other casting K4169 alloys.This can be partly attributed to grain refinement impeding crack initiation and propagation.When the strain amplitude was in plastic range(Δεt/2≥ 0.5%),the alloy displayed a short period of initial cyclic stability followed by cyclic softening to fracture.By observing dislocation configurations,only a few dislocations moved around grain boundaries at initial cycles,leading to short cyclic stability.Afterwards,dislocations in the slip bands cut γ" phase continuously leading to cyclic softening.When the strain amplitude was in elastic range(Δεt/2 ≤ 0.4%),the alloy exhibited elastic deformation and the peak stress kept stable.In addition,the crack initiation site changed from the MC carbides to the persistent slip bands on surface with increasing strain amplitudes.

关键词： Micro-grain cast K4169 Low-cycle fatigue Cyclic softening Slip bands

Cobalt-nitrogen co-doped porous carbon sphere as highly efficient catalyst for liquid-phase cyclohexane oxidation with molecular oxygen and the active sites investigation

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Frontiers of Chemical Science and Engineering 2024年第3期18卷 101-112页

作者： Lei Chen Yuan Sun jinshan Chi Wei Xiong Pingle Liu Fang Hao College of Chemical Engineering National&Local United Engineering Research Centre for Chemical Process Simulation and IntensificationXiangtan UniversityXiangtan411105China

The selective oxidation of cyclohexane to cyclohexanone and cyclohexanol(KA oil)is a challenging issue in the chemical industry.At present the industrial conversion of cyclohexane to cyclohexanone and cyclohexanol is normally controlled at less than 5%selectivity.Thus,the development of highly active and stable catalysts for the aerobic oxidation of cyclohexane is necessary to overcome this low-efficiency process.Therefore,we have developed a cobalt-nitrogen co-doped porous sphere catalyst,Co-NC-x(x is the Zn/Co molar ratio,where x=0,0.5,1,2,and 4)by pyrolyzing resorcinol-formaldehyde resin microspheres.It achieved 88.28%cyclohexanone and cyclohexanol selectivity and a cyclohexane conversion of 8.88%under Co-NC-2.The results showed that the introduction of zinc effectively alleviated the aggregation of Co nanoparticles and optimized the structural properties of the material.In addition,Co0 and pyridinic-N are proposed to be the possible active species,and their proportion efficiently increased in the presence of Zn^(2+)species.In this study,we developed a novel strategy to design highly active catalysts for cyclohexane oxidation.

关键词： KA oil production cyclohexane selective oxidation cobalt-nitrogen co-doped porous carbon spheres metal-organic framework

Synergistic enhancement on mechanical properties and corrosion resistance of biodegradable Mg-Zn-Y alloy via V-microalloying

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Journal of Magnesium and Alloys 2024年第2期12卷 530-545页

作者： Jiaxin Zhang Xin Ding Ruirun Chen Wenchao Cao jinshan Zhang Rui Zhao National Key Laboratory for Precision Hot Processing of Metals Harbin Institute of TechnologyNo.92West Dazhi StreetHarbinHeilongjiang 150001China College of Materials Science and Engineering Taiyuan University of TechnologyNo.79West Yingze StreetTaiyuanShanxi 030024China

For the sake of improving the mechanical properties and corrosion resistance of biodegradable Mg alloy synergistically,various content of element V(0,0.05,0.10,0.15,0.20 wt.%)are introduced into an Mg-Zn-Y alloy with long-period stacking ordered(LPSO)structure,and the effects of V on its microstructure,mechanical properties and corrosion resistance are investigated systematically.The results indicate that the grains are effectively refined by V addition,and the primaryα-Mg in Mg-Zn-Y-V0.1 alloy is most significantly refined,with grain size being decreased by 62%.The amount of 18R LPSO structure is increased owing to the V addition.The growth mode of the second phase(W-phase and 18R LPSO structure)is transformed to divorced growth pattern,which ascribes to the thermodynamic drive force of V to promote the nucleation of LPSO phase.Thus,18R LPSO structure presents a continuous distribution.Due to grains refinement and modification of second phase,the tensile strength and strain of alloys are both enhanced effectively.Especially,the ultimate tensile strength and the elongation of V0.1 alloy are 254 MPa and 15.26%,which are 41%and 61%higher than those of V-free alloy,respectively.Owing to the continuously distributed 18R LPSO structure with refined grains and stable product film,the weight loss and hydrogen evolution corrosion rates of V0.1 alloy are 7.1 and 6.2 mmy^(-1),respectively,which are 42.6%and 45.4%lower than those of V-free alloy.

关键词： Corrosion Mechanical property V-microalloying LPSO SKPFM

A new type of lipophilic hydrophobic self-repairing cellulose insulating paper developed with ST-110/FAS/PTFE ternary system as coating substrate

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High Voltage 2024年第2期9卷 474-483页

作者： Zhenglin Zeng jinshan Qin Zuhao Wang Weimin Tan Chao Tang College of Engineering and Technology Southwest UniversityChongqingChina International R&D Center for New Technologies of Smart Grid and Equipment ChongqingChina

The moisture generated by the ageing of the oil-paper insulating system can easily lead to the deterioration of the performance of the insulating paper.In order to alleviate the impact of moisture on the performance of the insulating paper,we developed a kind of lipophilic hydrophobic self-repairing cellulose insulating paper(new insulating paper)based on the ternary system of polytetrafluoroethylene,fluorocarbon surfactant and fluorinated alkyl silane,and accelerated thermal ageing test for 45 days at 130°C was carried out.The experimental results show that the new insulating paper with excellent lipophilic property can realise hydrophobic self-repairing through heat treatment after physical damage.The tensile strength and elongation at break of the new insulating paper increased by 5%–8%and 6.25%–27%respectively compared with the original cellulose insulating paper.At the end of ageing,the relative dielectric constant and dielectric loss factor of new insulating paper are 10.4%and 9.9%lower than that of the original cel-lulose insulating paper,while the breakdown voltage is 6.8%higher.The acid and moisture content produced during the ageing process of the insulating oil impregnated with new insulating paper are also less,indicating that the coating can delay the ageing of the insulating paper.

关键词： coating moisture cellulose

Dynamic response and failure process of horizontal-layered fractured structure rock slope under strong earthquake

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Journal of Mountain Science 2024年第3期21卷 882-900页

作者： WANG Tong LIU Xianfeng HOU Zhaoxu XU Jiahang ZHANG Jun YUAN Shengyang JIANG Guanlu HU jinshan School of Civil Engineering Southwest Jiaotong UniversityChengdu 610031China Key Laboratory of High-Speed Railway Engineering of Ministry of Education Southwest Jiaotong UniversityChengdu 610031China School of Civil Engineering Xinjiang Institute of EngineeringUrumqi 830023China China Railway First Survey and Design Institute Group Co.LTD Xi'an 710043China

Rock slope with horizontal-layered fractured structure(HLFS)has high stability in its natural state.However,a strong earthquake can induce rock fissure expansion,ultimately leading to slope failure.In this study,the dynamic response,failure mode,and spectral characteristics of rock slope with HLFS under strong earthquake conditions were investigated based on the large-scale shaking table model test.On this basis,multiple sets of numerical calculation models were further established by UDEC discrete element program.Five influencing factors were considered in the parametric study of numerical simulations,including slope height,slope angle,bedding-plane spacing and secondary joint spacing as well as bedrock dip angle.The results showed that the failure process of rock slope with HLFS under earthquake action is mainly divided into four phases,i.e.,the tensile crack of the slope shoulder joints and shear dislocation at the top bedding plane,the extension of vertical joint cracks and increase of shear displacement,the formation of step-through sliding surfaces and the instability,and finally collapse of fractured rock mass.The acceleration response of slopes exhibits elevation amplification effect and surface effect.Numerical simulations indicate that the seismic stability of slopes with HLFS exhibits a negative correlation with slope height and angle,but a positive correlation with bedding-plane spacing,joint spacing,and bedrock dip angle.The results of this study can provide a reference for seismic stability evaluation of weathered rock slopes.

关键词： Seismic behavior Horizontal layered Weathered rock slope Shaking table test Failure mode

Discovering the ultralow thermal conductive A_(2)B_(2)O_(7)-type high-entropy oxides through the hybrid knowle dge-assiste d data-driven machine learning

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Journal of Materials Science & Technology 2024年第1期168卷 131-142页

作者： Ying Zhang Ke Ren William Yi Wang Xingyu Gao Ruihao Yuan Jun Wang Yiguang Wang Haifeng Song Xiubing Liang jinshan Li State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi’an 710072China Innovation Center NPU ChongqingChongqing 401135China Institute of Advanced Structure Technology Beijing Institute of TechnologyHaidian DistrictBeijing 100081China Laboratory of Computational Physics Institute of Applied Physics and Computational MathematicsBeijing 100088China Defense Innovation Institute Academy of Military Sciences of the PLA of ChinaBeijing 100071China

Lattice engineering and distortion have been considered one kind of effective strategies for discovering advanced materials.The instinct chemical flexibility of high-entropy oxides(heOs)motivates/accelerates to tailor the target properties through phase transformations and lattice distortion.here,a hybrid knowledge-assisted data-driven machine learning(ML)strategy is utilized to discover the A_(2)B_(2)O_(7)-type heOs with low thermal conductivity(κ)through 17 rare-earth(RE=Sc,Y,La-Lu)solutes optimized A-site.A designing routine integrating the ML and high throughput first principles has been proposed to predict the key physical parameter(KPPs)correlated to the targetedκof advanced heOs.Among the smart-designed 6188(5RE_(0.2))_(2)Zr_(2)O_(7)heOs,the best candidates are addressed and validated by the princi-ples of severe lattice distortion and local phase transformation,which effectively reduceκby the strong multi-phonon scattering and weak interatomic interactions.Particularly,(Sc_(0.2)Y_(0.2)La_(0.2)Ce_(0.2)Pr_(0.2))_(2)Zr_(2)O_(7)with predictedκbelow 1.59 Wm^(−1)K^(−1)is selected to be verified,which matches well with the ex-perimentalκ=1.69 Wm^(−1)K^(−1)at 300 K and could be further decreased to 0.14 Wm^(−1)K^(−1)at 1473 K.Moreover,the coupling effects of lattice vibrations and charges on heat transfer are revealed by the cross-validations of various models,indicating that the weak bonds with low electronegativity and few bond-ing charge density and the lattice distortion(r∗)identified by cation radius ratio(r A/r B)should be the KPPs to decreaseκefficiently.This work supports an intelligent designing strategy with limited atomic and electronic KPPs to accelerate the development of advanced multi-component heOs with proper-ties/performance at multi-scales.

关键词： High-entropy oxides Thermal conductivity Pyrochlore Key physical parameter First-Principles

Effect of grit blasting and subsequent heat treatment on stress rupture property of a Ni-based single-crystal superalloy SGX3

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Acta Metallurgica Sinica(English Letters) 2020年第12期33卷 1681-1688页

作者： jinshan he Zhengrong Yu Longfei Li Xitao Wang Qiang Feng Beijing Advanced Innovation Center for Material Genome Engineering Collaborative Innovation Center of Steel TechnologyUniversity of Science and Technology BeijingBeijing 100083China Beijing Advanced Innovation Center for Material Genome Engineering State Key Laboratory for Advanced Metals and MaterialsUniversity of Science and Technology BeijingBeijing 100083China Shandong Provincial Key Laboratory for High Strength Lightweight Metallic Materials Advanced Materials InstituteQilu University of Technology(Shandong Academy of Sciences)Jinan 250353China

In the present study,the effect of grit blasting and subsequent heat treatment on the stress rupture properties of a thirdgeneration nickel-based single-crystal superalloy SGX3 sheet was studied.It was found that the stress rupture life of alloy SGX3 sheet at 980℃/250 MPa was reduced by about 60%by only vacuum heat treatment at 1100℃ for 200 h and further reduced by 20%and 70%respectively with grit blasting of 0.3 MPa/1 min and 0.5 MPa/2 min before heat treatment.The microstructure analysis results indicated that the degradation of stress rupture life of alloy SGX3 sheet by vacuum heat treatment was mainly attributed to the variation ofγ/γ′microstructure,i.e.,the decrease inγ′volume fraction and the coarsening ofγ′precipitates.Furthermore,such degradation by grit blasting and subsequent vacuum heat treatment should be attributed to the formation of cellular recrystallization with different thicknesses at the surface of alloy SGX3 sheet,which not only acts as the vulnerable site for cracks to initiate and propagate but also reduces the effective loading area.

关键词： Ni-based single-crystal superalloy Creep life Degradation Recrystallization

框架梁与锚索桩板墙加固隧道洞口边坡的动力响应特性

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中国铁道科学 2024年第2期45卷 134-145页

作者：冯海洲蒋关鲁何梓雷郭玉丰何晓龙刘先峰胡金山西南交通大学土木工程学院四川成都610031 西南交通大学高速铁路线路工程教育部重点实验室四川成都610031 中铁第一勘察设计研究院有限公司陕西西安710043

针对山岭隧道洞口在降雨、地震等因素作用下易产生变形破坏的问题,以某处采用框架梁与锚索桩板墙支护的隧道洞口边坡工程为原型,开展几何比尺为1∶50的振动台模型试验,分析降雨后地震作用下边坡的动力响应特性及失稳变形规律。结果表明... 详细信息

针对山岭隧道洞口在降雨、地震等因素作用下易产生变形破坏的问题,以某处采用框架梁与锚索桩板墙支护的隧道洞口边坡工程为原型,开展几何比尺为1∶50的振动台模型试验,分析降雨后地震作用下边坡的动力响应特性及失稳变形规律。结果表明:降雨后坡面无局部破坏,地震作用下边坡的破坏过程可归纳为坡顶张拉破坏—坡脚剪切溃裂—坡体整体失稳滑动,边坡表现为张拉—剪切型破坏;边坡峰值加速度放大系数呈层状分布,“高程效应”与“趋表效应”显著,均随输入正弦波频率、幅值的增加而增大;边坡土体峰值应变分布与坡体滑动破坏面较吻合;桩体锚索轴力与输入正弦波频率、幅值呈正相关,强震作用下锚索轴力增幅显著;桩后峰值土压力近似呈三角形分布,桩体嵌固段内桩土压力最大;桩体弯矩呈“b”型分布,嵌固段内桩体峰值弯矩最大,抗震设计中应注意验算其抗弯强度;桩后土压力与桩体加速度FFT谱幅值主要集中于低频段,结构动力响应主要受地震波低频段部分影响。

关键词：隧道洞口边坡框架梁锚索桩板墙降雨地震动力响应振动台试验

氟化石墨烯的理化性能、制备改性及摩擦学研究进展

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摩擦学学报（中英文） 2024年第6期44卷 854-870页

作者：马立民何金山侯凯明王金清杨生荣中国科学院兰州化学物理研究所固体润滑国家重点实验室甘肃兰州730000 中国科学院大学材料科学与光电技术学院北京100049 兰州理工大学材料科学与工程学院甘肃兰州730050

氟化石墨烯(FG)作为1种石墨烯衍生物,兼具石墨烯材料低剪切、高承载的力学性能以及氟化碳材料独特的理化性能.相较于其他固体润滑材料,FG在极压性与减摩抗磨性等方面表现出了巨大的性能优势,成为当前固体润滑领域研究的热点材料.本文中... 详细信息

氟化石墨烯(FG)作为1种石墨烯衍生物,兼具石墨烯材料低剪切、高承载的力学性能以及氟化碳材料独特的理化性能.相较于其他固体润滑材料,FG在极压性与减摩抗磨性等方面表现出了巨大的性能优势,成为当前固体润滑领域研究的热点材料.本文中梳理总结了近年来FG在制备方法、修饰改性、分散稳定性、润滑机制与润滑应用等方面的研究进展以及在应用过程中存在的主要问题,并对未来FG在摩擦学领域的主要研究方向与应用前景提出了一些建议和展望.

关键词：氟化石墨烯研究进展制备方法微观/宏观摩擦机理润滑应用

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