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Combination of S…N and S…Cl Noncovalently Conformational Locks for Constructing High-Planarity and Low-Cost Nonfused-Ring Electron Acceptors

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Chinese Journal of Chemistry 2023年第15期41卷 1797-1802页

作者： Ziyang Han Congqi Li Xiaobin Gu Xiao Han Sixuan Wang Yanan Wei jinhua gao Zhixiang Wei Yunhao Cai Xin Zhang Hui Huang College of Materials Science and Opto-Electronic Technology&Center of Materials Science and Optoelectronics Engineering&CAS Center for Excellence in Topological Quantum Computation&CAS Key Laboratory of Vacuum Physics University of Chinese Academy of SciencesBeijing 100049China Center for Excellence in Nanoscience(CAS)&Key Laboratory of Nanosystem and Hierarchical Fabrication(CAS) National Center for Nanoscience and TechnologyBeijing 100190China

Comprehensive Summary By employing thiazole and 4-chlorothiazole as the A′units,two A-D-A′-D-A type nonfused-ring electron acceptors(NFREAs)Tz-H and Tz-Cl were designed and synthesized.Replacing thiazole in Tz-H with 4-chlorothiazole can not only remarkably shorten the synthetic route through C—H direct arylation but also enhance molecular planarity with the simultaneous incorporation of S…N and S…Cl noncovalently conformational locks(NoCLs).The photovoltaic devices based on PM6:Tz-Cl exhibited a power conversion efficiency as high as 11.10%,much higher than that of PM6:Tz-H(6.41%),mainly due to more efficient exciton dissociation,better and more balanced carrier mobility,less charge recombination,and more favorable morphology.These findings demonstrate the great potential of NoCLs in achieving low-cost and high-performance NFREAs.

关键词： Organic solar cells Nonfused-ring electron acceptors Noncovalently conformational locks High-planarity and low-cost acceptors 4-Chlorothiazole

Low-cost polymer acceptors with noncovalently fused-ring backbones for efficient all-polymer solar cells

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Science China Chemistry 2022年第5期65卷 926-933页

作者： Xiaobin Gu Yanan Wei Xingzheng Liu Na Yu Laiyang Li Ziyang Han jinhua gao Congqi Li Zhixiang Wei Zheng Tang Xin Zhang Hui Huang College of Materials Science and Opto-Electronic Technology Center of Materials Science and Optoelectronics EngineeringCAS Center for Excellence in Topological Quantum ComputationCAS Key Laboratory of Vacuum PhysicsUniversity of Chinese Academy of SciencesBeijing 100049China Center for Advanced Low-dimension Materials State Key Laboratory for Modification of Chemical Fibers and Polymer MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghai 201620China CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijing 100190China

The polymerization of fused-ring acceptors(FRAs) to afford their corresponding polymeric acceptors for high-performance all-polymer solar cells(all-PSCs) has achieved remarkable progress in the past few years.However,due to the high degree of synthetic complexity for the monomer,the high-cost of these polymeric acceptors may limit their commercial applications.Thus,it is urgent to develop inexpensive and high-performance polymeric acceptors for all-PSCs.Herein,two novel polymeric acceptors(PBTzO and PBTzO-2F) have been designed and synthesized by copolymerization of noncovalently fused ring acceptors(NFRAs),which were employed in all-PSCs for the first time.Upon introducing the “noncovalently conformational locks(NoCLs)” in the backbone and selective fluorination of the end-group,photophysical and electrical properties,and solidstate packing properties of the NFRAs have been rationally tuned.As a result,the PBDB-T:PBTzO-2F based devices presented an excellent power conversion efficiency(PCE) of 11.04%,much higher than that of PBTzO based ones due to the increased charge generation and extraction,improved hole transfer and carrier mobilities,and reduced energy loss.More importantly,PBTzO-2F exhibited a much lower synthetic complexity(SC) index and higher figure-of-merit(FOM) values than the high-performance fused-ring acceptor based polymer acceptors(FRA-PAs) due to the simpler structures and more effective synthesis.This contribution provided a novel idea to achieve low-cost and high-performance all-PSCs.

关键词： all-polymer solar cells low-cost polymer acceptors noncovalently fused-ring backbones figure-of-merit values

Inclusion complex of tamibarotene with hydroxypropyl-β-cyclodextrin: Preparation,characterization, in-vitro and in-vivo evaluation

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Asian Journal of Pharmaceutical Sciences 2017年第2期12卷 187-192页

作者： Ying Yang jinhua gao Xiaoyu Ma Guihua Huang School of Pharmaceutical Sciences Shandong University

The goal of this study was to improve the solubility and oral bioavailability of tamibarotene by complexing it with hydroxypropyl-β-cyclodextrin(HP-β-CD).The inclusion complex of tamibarotene with hydroxypropyl-β-cyclodextrin(Am80-HP-β-CD)was prepared through a freeze-drying method at the mole ratio of 1:1(Am80:HP-β-CD).Fourier transform infrared spectroscopy(FT-IR)and differential scanning calorimetry(DSC)indicated the formation of Am80-HP-β-CD.In vitro dissolution studies showed that the solubility and dissolution percentage of Am80-HP-β-CD was improved substantially compared to Am80.An improved dissolution with approximately 97%drug release in 3 min was observed,in comparison with Am80 with approximately 60% release in 45 min.In vivo studies indicated that the AUC0-∞ has increased 2.79 times and the Cmax 4.37 times after the formation of inclusion complex.The decrease of tmaxindicated the Am80-HP-β-CD inclusion complex can be absorbed into blood faster.In short,the solubility and bio-availability of Am80 has notably increased with the complexation of HP-β-CD.Therefore,using the inclusion technique is a promising method to improve the solubility of insoluble drugs.

关键词： Tamibarotene Hydroxypropyl-β-cyclodextrin Solubility Bio-availability

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H3亚型禽流感流行的潜在危害和防控建议

科学通报 2024年第10期69卷 1315-1319页

作者：刘金华孙洪磊高福中国农业大学动物医学院兽医公共卫生安全全国重点实验室农业农村部禽流感等家禽重大疾病防控重点实验室北京100193 中国科学院微生物研究所病原微生物与免疫学重点实验室北京100101 中国疾病预防控制中心病毒病预防控制所中国国家流感中心北京102206

21世纪短短的20年间,人类已经历了两次大流行传染病,即2009年甲型H1N1大流行流感和2019年新型冠状病毒感染.另外发生了5次世界卫生组织宣布的“全球关注的公共卫生应急事件”,给全球经济发展、社会稳定和人类健康造成了严重危害(https:/... 详细信息

21世纪短短的20年间,人类已经历了两次大流行传染病,即2009年甲型H1N1大流行流感和2019年新型冠状病毒感染.另外发生了5次世界卫生组织宣布的“全球关注的公共卫生应急事件”,给全球经济发展、社会稳定和人类健康造成了严重危害(https://www.***.int/emergencies/situations).大流行传染病的频繁出现警示我们,人兽共患性病毒是引发大流行疫病的重要病原.动物源性流感病毒在历史上导致了至少5次流感大流行,尤其是最近几年,动物流感病毒频繁跨种感染人类的现象让人们担忧其可能催生下一次人类流感大流行[1].

关键词：冠状病毒感染流感病毒防控建议禽流感 H3亚型跨种感染动物源性流感大流行

基于理论承载性能与应力扩散计算的高强预应力锚索适配垫板设计方法

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铁道科学与工程学报 2024年第5期21卷 1942-1953页

作者：郭新新高新强吴锦花成都理工大学环境与土木工程学院四川成都610059 石家庄铁道大学河北省交通工程结构力学行为演变与控制重点实验室河北石家庄050043

垫板是高强预应力锚索系统的核心组成构件,当其与锚索间适配性不足时,会出现结构可靠性低以及围岩支护效果差等问题。基于垫板的承载力学特性及其应力扩散作用,提出适配高强预应力锚索的垫板设计方法。为此,首先分析垫板的应力扩散作用... 详细信息

垫板是高强预应力锚索系统的核心组成构件,当其与锚索间适配性不足时,会出现结构可靠性低以及围岩支护效果差等问题。基于垫板的承载力学特性及其应力扩散作用,提出适配高强预应力锚索的垫板设计方法。为此,首先分析垫板的应力扩散作用与锚索的支护效应间的关联性。其次,基于不同形式垫板的结构受力特征,提出碗形垫板和平板形垫板的理论承载力计算公式,并由此计算得到满足高强预应力锚索承载性能需求的垫板型式及其结构参数。接着,通过建立“垫板(碗形、平板形)-围岩”三维数值仿真模型,分析不同型式及结构参数垫板的围岩应力扩散效果,并由此优选得到适配高强预应力锚索的垫板型式及其结构参数。最后,通过现场应用案例,分析适配垫板下高强预应力锚索系统支护效果。研究结果表明:提出的垫板设计方法实现了对高强预应力锚索系统中垫板的有效选用,适配加载300 kN的高强预应力锚索系统垫板为25 cm×25 cm×16 mm的碗形垫板,其拱高35 mm、孔口半径32 mm、碗底半径75 mm;同时,适配垫板下高强预应力锚索系统的围岩变形控制效果提升了11.9%~15.2%。研究结果有助于提升高强预应力锚索系统的可靠性与支护效果,并为预应力锚固系统中垫板的设计提供了一种可行且有效的方法。

关键词：高强预应力锚索承载性能应力扩散碗形垫板平板垫板

Exhaust hood performance and its improvement technologies in industrial buildings:A literatu rereview

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Building Simulation 2024年第1期17卷 23-40页

作者： Jing Zhang Jian Wang Jun gao Weimin Zhang Architectural Engineering Institute Jinhua PolytechnicJinhua 321017China Institute of HVAC Engineering Schoolof Mechanical EngineeringTongji UniversityShanghai 200092China Tongji Architectural Design(Group)Co .LtdShanghai 200092China

The pollutant control performance of exhaust hoods plays a crucial role in the indoor air quality and energy consumption of ventilation systems in industrial buildings.To better understand the impact of local ventilation on the industrial indoor environment,this paper presents a literature review of exhaust hood performance and its improvement technologies.To create an index for evaluating the performance of exhaust hoods,the capture velocity,capture efficiency,flow ratio of pollutant emissions and exhaust airflow and energy consumption are first introduced.A number of factors affecting exhaust hood performance are assessed such as hood type,hood opening size,exhaust rate,installation distance,pollution source emission and environmental disturbance.Compared to structural improvement methods,the use of active airflow is a more effective way to improve the exhaust hood performance.The most commonly used methods for determining the exhaust rate are the controlled speed method and the flow ratio method.The use of an exhaust hood with an appropriate exhaust rate and jet parameters(for an active air-assisted hood)can effectively improve the pollutant control performance and reduce the energy consumption that would be wasted on the redundant exhaust rate.With more information focused on exhaust hood performance,this work suggests more effective strategies for improving indoor air quality and reducing energy consumption in industrial buildings.

关键词： industrial ventilation exhaust hood capture efficiency exhaust rate performance improvement

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旋转机械健康状态评估方法研究现状与展望

排灌机械工程学报 2024年第3期42卷 304-318页

作者：苏红朱勇刘金华高强江苏大学国家水泵及系统工程技术研究中心江苏镇江212013 共青科技职业学院国际航运研究院江西九江332020

旋转机械是机械装备的重要组成部分,其内部结构复杂度高,关键零部件与子系统之间耦合度强,长期在复杂工况下运行易发生故障.一旦发生故障,会导致整机性能下降,甚至造成重大经济损失或人员伤亡.因此,旋转机械健康状态评估研究已成为现代... 详细信息

旋转机械是机械装备的重要组成部分,其内部结构复杂度高,关键零部件与子系统之间耦合度强,长期在复杂工况下运行易发生故障.一旦发生故障,会导致整机性能下降,甚至造成重大经济损失或人员伤亡.因此,旋转机械健康状态评估研究已成为现代国防与工业装备发展中的重点之一.从旋转机械的健康管理与智能运维需求出发,首先,论述了健康状态评估在机械设备智能运维中的地位和作用;其次,介绍了健康状态评估技术的概念、状态等级的划分以及评估指标;再次,阐述了基于知识经验、模型驱动和数据驱动的典型评估方法;进而,综述了近年来国内外学者在泵、轴承、齿轮箱和航空发动机等典型旋转机械健康状态评估方面的研究成果;最后,基于健康状态评估方法研究面临的技术挑战和发展趋势,对旋转机械健康状态评估方法的发展方向进行了探讨和展望.

关键词：旋转机械健康状态评估故障识别剩余寿命预测评估方法

Full-parameter omnidirectional transformation optical devices

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National Science Review 2024年第3期11卷 92-99页

作者： Yuan gao Yu Luo Jingjing Zhang Zhengjie Huang Bin Zheng Hongsheng Chen Dexin Ye Interdisciplinary Center for Quantum Information State Key Laboratory of Extreme Photonics and InstrumentationZJU-Hangzhou Global Scientific and Technological Innovation CenterZhejiang University School of Electrical and Electronic Engineering Nanyang Technological University CNRS-InternationalNTU-Thales Research Alliance Nanyang Technological University Institute of Electromagnetic Space Southeast University State Key Laboratory of Millimeter Waves Southeast University International Joint Innovation Center The Electromagnetics Academy at Zhejiang University Zhejiang University Key Laboratory of Advanced Micro/Nano Electronic Devices&Smart Systems of Zhejiang Jinhua Institute of Zhejiang UniversityZhejiang University Shaoxing Institute of Zhejiang University Zhejiang University

Transformation optics(TO) provides an unprecedented technique to control electromagnetic(EM) waves by engineering the constitutive parameters of the surrounding medium through a proper spatial transformation. In general, ideal transformation optical devices require simultaneous electric and magnetic responses along all three dimensions. To ease the practical implementation, previous studies usually made use of reduced parameters or other simplified approaches, which inevitably introduce extra reflection or unwanted phase shift. Up to today, experimental realizations of full-parameter transformation optical devices in free space are still quite limited. Here, a general design strategy is proposed to solve this problem.As a specific example, a full-parameter spatial-compression TO medium with constitutive parameters taking the diagonal form diag(a, a, 1/a) for the TM wave incidence was designed and realized experimentally. Such spatial-compression TO media were then applied to the implementation of an ideal omnidirectional invisibility cloak capable of concealing a large-scale object over a wide range of illumination angles. Both the simulation and experiment confirm that the cloak allows for nearly unity transmission of EM waves in the forward direction without introducing extra scattering or phase shift. This work constitutes an important stepping stone for future practical implementation of arbitrary full-parameter omnidirectional transformation optical devices.

关键词： transformation optical devices omnidirectional impedance matching full-parameter invisibility cloak

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岸基BDS-R海面测高及其观测值加权方法

北京航空航天大学学报 2024年第3期50卷 1015-1026页

作者：侯金华贺凯飞高凡储倜吴宇中国石油大学(华东)海洋与空间信息学院青岛266580 山东大学空间科学研究院威海264209 山东大学空间科学与物理学院威海264209

随着北斗三号卫星导航系统(BDS-3)的全球组网完成,其反射信号在全球导航卫星系统反射测量(GNSS-R)海面测高领域的应用也更加广泛。为研究BDS-3 B1C反射信号码延迟海面测高性能,以及多星测高数据组合方法,进行了基于B1C码信号的双天线岸... 详细信息

随着北斗三号卫星导航系统(BDS-3)的全球组网完成,其反射信号在全球导航卫星系统反射测量(GNSS-R)海面测高领域的应用也更加广泛。为研究BDS-3 B1C反射信号码延迟海面测高性能,以及多星测高数据组合方法,进行了基于B1C码信号的双天线岸基北斗卫星导航系统反射测量(BDS-R)码延迟海面测高实验。利用自主研发的GNSS-R测高软件接收机对实验数据进行事后处理,将测高结果与岸基同步观测的雷达测高仪所测海面高度值进行对比分析,并基于反射信号信噪比(SNR)和卫星高度角加权的方法对多星测高观测值进行加权计算,评定BDS-R海面测高精度。结果表明:自主研发的GNSS-R测高软件接收机可用于海面测高,基于B1C码信号的BDS-R海面测高精度有达到分米级的可能性;根据10 s观测数据平滑可以得到,单颗卫星B1C码信号最优测高结果的均方根误差(RMSE)为0.634 m,平均绝对误差(MAE)为0.507 m,多星测高观测值加权组合最优结果的均方根误差为0.538 m,平均绝对误差为0.500 m,明显优于单星观测精度,最大可提升70%,最小可提升17%;针对同一信号多星GNSS-R测高数据加权方法,应用综合考虑卫星高度角和反射信号信噪比的加权模型优于其他加权模型,测高精度分别比信噪比分段模型、正弦函数模型、指数函数模型、等权模型提升9.4%、9.5%、20.5%、35.2%。

关键词： B1C 北斗卫星导航系统反射测量软件接收机海面测高加权模型