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Synthesis of tetrahedrally coordinated CoO for higher alcohol synthesis directly from syngas

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Frontiers of Chemical Science and Engineering 2024年第8期18卷 99-109页

作者： Zhuoshi Li han yang Xiaofeng Pei Jiahui Li jing Lv Shouying huang Yue Wang Xinbin Ma Key Laboratory for Green Chemical Technology of Ministry of Education Collaborative Innovation Center of Chemical Science and EngineeringSchool of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China Joint School of National University of Singapore and Tianjin University International Campus of Tianjin UniversityBinhai New CityFuzhou 350207China haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China

higher alcohol synthesis directly from syngas is highly desirable as one of the efficient non-petroleum energy conversion ***0–Co^(O)catalysts showed great potential for this reaction,but the alcohol selectivity still needs to be improved and the crystal structure effect of Co^(O)on catalytic behaviors lacks ***,a series of tetrahedrally coordinated Co^(O)polymorphs were prepared by a thermal decomposition method,which consisted of wurtzite CoO and zinc blende CoO with varied *** diluting with SiO_(2),the catalyst showed excellent performance for higher alcohol synthesis with ROh selectivity of 45.8%and higher alcohol distribution of 84.1 wt%under the CO conversion of 38.0%.With increasing the content of wurtzite CoO,the Co^(0)/Co^(2+)ratio gradually increased in the spent catalysts,while the proportion of highly active hexagonal close packed cobalt in Co^(0)decreased,leading to first decreased then increased CO ***,the higher content of zinc blende CoO in fresh catalyst facilitated the retention of more Co^(2+)sites in spent catalysts,promoting the ROh selectivity but slightly decreasing the distribution of higher *** catalyst with 40%wurtzite CoO obtained the optimal performance with a space time yield toward higher alcohols of 7.9 mmol·gcat^(-1)·h^(-1).

关键词： higher alcohol synthesis CO hydrogenation wurtzite CoO zinc blende CoO hexagonal-closest-packed Co

Lamellar quasi-solid electrolyte with nanoconfined deep eutectic solvent for high-performance lithium battery

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Nano Research 2024年第7期17卷 6176-6183页

作者： Shiwei Liu jing Wang Keqi Wu Zhirong yang Yan Dai Junmei Zhang Wenjia Wu jingtao Wang School of Chemical Engineering Zhengzhou UniversityZhengzhou 450001China

Electrolytes with high-efficiency lithium-ion transfer and reliable safety are of great importance for lithium *** having superior ionic conductivity(10^(−3)–10^(−2) S·cm^(−1)),traditional liquid-state electrolytes always suffer from low lithium-ion transference number(tLi+hus undesirable battery ***,the deep eutectic solvent(DES)is vacuum-filtered into the~1 nm interlayer channel of vermiculite(Vr)lamellar framework to fabricate a quasi-solid electrolyte(Vr-DES QSE).We demonstrate that the nanoconfinement effect of interlayer channel could facilitate the opening of solvation shell around ***,the interaction from channel wall could inhibit the movement of *** enable high-efficiency lithium-ion transfer:2.61×10^(−4)S·cm^(−1)at 25℃.Importantly,the tLi+value reaches 0.63,which is 4.5 times of that of bulk DES,and much higher than most present liquid/quasi-solid *** addition,Vr-DES QSE shows significantly improved interfacial stability with Li anode as compared with *** assembled Li symmetric cell can operate stably for 1000 h at 0.1 mA·cm^(−2).The lithium iron phosphate(LFP)|Vr-DES QSE|Li cell exhibits high capacity of 142.1 mAh·g^(−1)after 200 cycles at 25℃ and 0.5 C,with a capacity retention of 94.5%.The strategy of open solvation shell through nanoconfinement effect of lamellar framework may shed light on the development of advanced electrolytes.

关键词： quasi-solid electrolyte deep eutectic solvent lamellar structure lithium-ion transference number solvation shell

Semaphorin 7A impairs barrier function in cultured human corneal epithelial cells in a manner dependent on nuclear factor-kappa B

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International Journal of Ophthalmology(English edition) 2024年第3期17卷 444-453页

作者： Cheng-Cheng yang Xiu-Xia yang Xiao-jing Zhao heng Wang Zi-han Guo Kai Jin yang Liu Bin-hui Li Department of Ophthalmology the Fifth Affiliated HospitalSun Yat-sen UniversityZhuhai 519000Guangdong ProvinceChina Department of Ophthalmology Hangzhou TCM Hospital Affiliated to Zhejiang Chinese Medical UniversityHangzhou 310006Zhejiang ProvinceChina Eye Institute of Xiamen University Fujian Provincial Key Laboratory of Ophthalmology and Visual ScienceSchool of MedicineXiamen UniversityXiamen 361005Fujian ProvinceChina

●AIM:To evaluate the role of semaphorin 7A(Sema7A)and its associated regulatory mechanisms in modulating the barrier function of cultured human corneal epithelial cells(hCEs).●METhODS:Barrier models of hCEs were treated with recombinant human Sema7A at concentrations of 0,125,250,or 500 ng/mL for 24,48,or 72h in *** electrical resistance(TEER)as well as Dextran-fluorescein isothiocyanate(FITC)permeability assays were conducted to assess barrier *** quantify tight junctions(TJs)such as occludin and zonula occludens-1(ZO-1)at the mRNA level,reverse transcriptionpolymerase chain reaction(RT-PCR)analysis was *** was used to examine the activity of the nuclear factor-kappa B(NF-κB)signaling pathway and the production of TJs *** analyses were employed to localize the ***-linked immunosorbent assay(ELISA)and RT-PCR were utilized to observe changes in interleukin(IL)-1β*** investigate the role of NF-κB signaling activation and IL^(-1)βin Sema7A’s anti-barrier mechanism,we employed 0.1μmol/L IκB kinase 2(IKK2)inhibitor IV or 500 ng/mL IL^(-1)receptor(IL-1R)antagonist.●RESULTS:Treatment with Sema7A resulted in decreased TEER and increased permeability of Dextran-FITC in hCEs through down-regulating mRNA and protein levels of TJs in a time-and dose-dependent manner,as well as altering the localization of ***,Sema7A stimulated the activation of inhibitor of kappa B alpha(IκBα)and expression of IL-1β.The anti-barrier function of Sema7A was significantly suppressed by treatment with IKK2 inhibitor IV or IL-1R antagonists.●CONCLUSION:Sema7A disrupts barrier function through its influence on NF-κB-mediated expression of TJ proteins,as well as the expression of IL-1β.These findings suggest that Sema7A could be a potential therapeutic target for the diseases in corneal epithelium.

关键词： human corneal epithelial barrier function transepithelial electrical resistance zonula occludens-1 occludin nuclear factor-kappa B

Co-harvest Phase-Change Enthalpy and Isomerization Energy for high-Energy heat Output by Controlling Crystallization of Alkyl-Grafted Azobenzene Molecules

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Energy & Environmental Materials 2024年第3期7卷 415-424页

作者： Jian Gao Yiyu Feng Wenyu Fang hui Wang jing Ge Xiaoyu yang huitao Yu Mengmeng Qin Wei Feng School of Materials Science and Engineering Tianjin UniversityTianjin 300350China Key Laboratory of Materials Processing and Mold Ministry of EducationZhengzhou UniversityZhengzhou 450002China

Photoisomerization-induced phase change are important for co-harvesting the latent heat and isomerization energy of azobenzene *** optimizing heat output and energy delivery at alternating temperatures are challenging because of the differences in crystallizability and *** article reports two series of asymmetrically alkyl-grafted azobenzene(Azo-g),with and without a methyl group,that have an optically triggered phase *** exothermic modes were designed to utilize crystallization enthalpy(△h_(c))and photothermal(isomerization)energy(△h_(p))at different temperatures determined by the ***-g has high heat output(275-303 J g^(-1))by synchronously releasing△h_(c)and△h_(p)over a wide temperature range(-79℃to 25℃).We fabricated a new distributed energy utilization and delivery system to realize a temperature increase of 6.6℃at a temperature of-8℃.The findings offer insight into selective utilization of latent heat and isomerization energy by molecular optimization of crystallization and isomerization processes.

关键词： crystallizability distributed energy utilization system energy density exothermic modes isomerization

Recent advances in photochemistry for positron emission tomography imaging

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Chinese Chemical Letters 2024年第8期35卷 149-162页

作者： jing-jing Zhang Lujun Lou Rui Lv Jiahui Chen Yinlong Li Guangwei Wu Lingchao Cai Steven h.Liang Zhen Chen Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-Forest BiomassJiangsu Key Lab of Biomass-Based Green Fuels and ChemicalsInternational Innovation Center for Forest Chemicals and MaterialsCollege of Chemical EngineeringNanjing Forestry UniversityNanjing 210037China Department of Radiology and Imaging Sciences Emory UniversityAtlantaGA 30322United States

As a powerful noninvasive imaging technology,positron emission tomography(PET)has been playing an important role in disease theranostics and drug *** successful application of PET relies on not only the biological properties of PET tracers but also the availability of facile and efficient radiochemical reactions to enable practical production and widespread use of PET *** recently,photochemistry is emerging as a novel,mild and efficient approach to generating PET *** this review,we focus on the recent advances in newly developed photocatalytic radiochemical reactions,innovation on automated photochemical radiosynthesis modules,as well as implementation in late-stage radiolabeling and radio-pharmaceutical synthesis for PET *** believe that this review will inspire the development of more promising radiolabeling protocols for the preparation of clinically useful PET agents.

关键词： Positron emission tomography(PET) Fluorine-18 Carbon-11 Photocatalysis Automation Late-stage functionalization

Ca and Sr co-doping induced oxygen vacancies in 3DOM La_(2-x)Sr_(x)Ce_(2-y)CayO_(7-δ)catalysts for boosting low-temperature oxidative coupling of methane

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Journal of Energy Chemistry 2024年第4期91卷 331-344页

作者： Tongtong Wu Yuechang Wei jing Xiong Yitao yang Zhenpeng Wang Dawei han Zhen Zhao Jian Liu State Key Laboratory of heavy Oil Processing China University of PetroleumBeijing 102249China Key Laboratory of Optical Detection Technology for Oil and Gas China University of PetroleumBeijing 102249China

It is urgent to develop catalysts with application potential for oxidative coupling of methane(OCM)at relatively lower ***,three-dimensional ordered macro porous(3 DOM)La_(2-x)Sr_(x)Ce_(2-y)CayO_(7-δ)(A_(2)B_(2)O_(7)-type)catalysts with disordered defective cubic fluorite phased structure were successfully prepared by a colloidal crystal template method.3DOM structure promotes the accessibility of the gaseous reactants(O2and Ch4)to the active *** co-doping of Ca and Sr ions in La_(2-x)Sr_(x)Ce_(2-y)CayO_(7-δ)catalysts improved the formation of oxygen vacancies,thereby leading to increased density of surface-active oxygen species(O_(2)^(-))for the activation of Ch4and the formation of C2products(C2h6and C2h4).3DOM La_(2-x)Sr_(x)Ce_(2-y)CayO_(7-δ)catalysts exhibit high catalytic activity for OCM at low temperature.3DOM La1.7Sr0.3Ce1.7Ca0.3O7-δcatalyst with the highest density of O_(2)^(-)species exhibited the highest catalytic activity for low-temperature OCM,i.e.,its Ch4conversion,selectivity and yield of C2products at 650℃are 32.2%,66.1%and 21.3%,*** mechanism was proposed that the increase in surface oxygen vacancies induced by the co-doping of Ca and Sr ions boosts the key step of C-h bond breaking and C-C bond coupling in catalyzing low-temperature *** is meaningful for the development of the low-temperature and high-efficient catalysts for OCM reaction in practical application.

关键词： 3DOM catalysts Ca ions Sr ions Low-temperature oxidative couplingof methane Oxygen vacancies O_(2)^(-) species

Morphology-Tailored Dynamic State Transition in Active-Passive Colloidal Assemblies

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Research 2024年第3期2024卷 751-760页

作者： Nan Yu Zameer h.Shah Mingcheng yang Yongxiang Gao Institute for Advanced Study Shenzhen University518060ShenzhenChina Key Laboratory of Optoelectronic Device and Systems of Ministry of Education and Guangdong Province College of Optoelectronic EngineeringShenzhen University518060ShenzhenChina Beijing National Laboratory for Condensed Matter Physics and Laboratory of Soft Matter Physics Institute of PhysicsChinese Academy of SciencesBeijing 100190China School of Physical Sciences University of Chinese Academy of SciencesBeijing 100049China Songshan Lake Materials Laboratory DongguanGuangdong 523808China.

Mixtures of active self-propelled and passive colloidal particles promise rich assembly and dynamic states that are beyond reach via equilibrium ***,controllable transition between different dynamic states remains ***,we reveal a plethora of dynamic behaviors emerging in assemblies of chemically propelled snowman-like active colloids and passive spherical particles as the particle shape,size,and composition are *** example,assembles of one or more active colloids with one passive particle exhibit distinct translating or orbiting states while those composed of one active colloid with 2 passive particles display persistent“8”-like cyclic motion or hopping between circling states around one passive particle in the plane and around the waist of 2 passive ones out of the plane,controlled by the shape of the active colloid and the size of the passive particles,*** morphology-tailored dynamic transitions are in excellent agreement with state diagrams predicted by mesoscale dynamics *** work discloses new dynamic states and corresponding transition strategies,which promise new applications of active systems such as micromachines with functions that are otherwise impossible.

关键词： Transition otherwise transitions

MicroRNA-146a-loaded magnesium silicate nanospheres promote bone regeneration in an inflammatory microenvironment

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Bone Research 2024年第1期12卷 153-164页

作者： Jiakang yang jing Shuai Lixuen Siow jingyi Lu Miao Sun Wenyue An Mengfei Yu Baixiang Wang Qianming Chen Stomatology hospital School of StomatologyZhejiang University School of MedicineZhejiang Provincial Clinical Research Center for Oral DiseasesKey Laboratory of Oral Biomedical Research of Zhejiang ProvinceCancer Center of Zhejiang UniversityHangzhou 310000China

Reconstruction of irregular oral-maxillofacial bone defects with an inflammatory microenvironment remains a challenge,as chronic local inflammation can largely impair bone ***,we used magnesium silicate nanospheres(MSNs)to load microRNA-146a-5p(miR-146a)to fabricate a nanobiomaterial,MSN+miR-146a,which showed synergistic promoting effects on the osteogenic differentiation of human dental pulp stem cells(hDPSCs).In addition,miR-146a exhibited an anti-inflammatory effect on mouse bone marrow-derived macrophages(BMMs)under lipopolysaccharide(LPS)stimulation by inhibiting the NF-κB pathway via targeting tumor necrosis factor receptor-associated factor 6(TRAF6),and MSNs could simultaneously promote M2 polarization of ***-146a was also found to inhibit osteoclast ***,the dual osteogenic-promoting and immunoregulatory effects of MSN+miR-146a were further validated in a stimulated infected mouse mandibular bone defect model via delivery by a photocuring ***,the MSN+miR-146a complex revealed good potential in treating inflammatory irregular oralmaxillofacial bone defects.

关键词： inflammatory healing stimulation

Microstructure development of Ti scaffold by laser powder bed fusion with chemical polishing and its mechanical properties,biocompatibility

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Biosurface and Biotribology 2024年第2期10卷 52-62页

作者： Changfu Lu jing Chen Teng Ma Yuxin Chen Da Zeng Yiliang Gan Youwen yang Double Medical Technology Inc. XiamenChina Institute of Additive Manufacturing Jiangxi University of Science and TechnologyNanchangChina Key Laboratory of Construction hydraulic Robots of Anhui higher Education Institutes Tongling UniversityTonglingChina College of Engineering and Applied Science Nanjing UniversityNanjingChina

Titanium(Ti)dental scaffolds are widely used in dental prosthetics due to their excellent mechanical properties and ***,conventional Ti scaffolds manufactured through machining often do not fit perfectly with the bone defect *** powder bed fusion(LPBF)technology enables the personalised manufacturing of custom-made Ti scaffolds.A custom-made Ti scaffold was prepared using LPBF and its surface roughness was improved through chemical *** enhance the surface roughness,a nitric acid mixed solution with a specific composition of hF:hNO_(3):C_(3)h_(6)O_(3)=2:2:3 was *** polishing mechanism was investigated by adjusting the F/Ti ratio to control the formation and dissolution of the oxide *** a result,the surface of the Ti scaffold after polishing exhibited a smooth and flat appearance compared to the LPBF part,with a reduced surface roughness(Ra)of 1.23±0.19μ*** custom-made Ti scaffold also demonstrated favourable mechanical properties,with a bending strength of 335.18±33.62 MPa and stiffness of 2.13±0.21 ***,in vitro cell tests confirmed the excellent biocompatibility of the custom-made Ti *** authors present a feasible strategy for the further clinical application of custom-made Ti scaffolds,offering enhanced surface properties and addressing the limitations of conventional machining methods.

关键词： additive manufacturing dental material property surface roughness