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A porous biochar supported nanoscale zero-valent iron material highly efficient for the simultaneous remediation of cadmium and lead contaminated soil

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Journal of Environmental Sciences 2022年第3期34卷 231-241页

作者： Wei Qian jing-Yi Liang Wen-Xuan Zhang Shi-Ting Huang zeng-hui Diao Guangdong Provincial Engineering and Technology Research Center for Agricultural Land Pollution Prevention and Control Zhongkai University of Agriculture and EngineeringGuangzhou 510225China

Risk associated with heavy metals in soil has been received widespread attention.In this study,a porous biochar supported nanoscale zero-valent iron(BC-nZVI)was applied to immobilize cadmium(Cd)and lead(Pb)in clayey soil.Experiment results indicated that the immobilization of Cd or Pb by BC-nZVI process was better than that of BC or nZVI process,and about 80%of heavy metals immobilization was obtained in BC-nZVI process.Addition of BC-nZVI could increase soil pH and organic matter(SOM).Cd or Pb immobilization was inhibited with coexisting organic compound 2,4-dichlorophenol(2,4-DCP),but 2,4-DCP could be removed in a simultaneous manner with Cd or Pb immobilization at low concentration levels.Simultaneous immobilization of Cd and Pb was achieved in BC-nZVI process,and both Cd and Pb availability significantly decreased.Stable Cd species inculding Cd(OH)_(2),CdCO_(3)and CdO were formed,whereas stable Pb species such as PbCO_(3),PbO and Pb(OH)_(2)were produced with BC-nZVI treatment.Simultaneous immobilization mechanism of Cd and Pb in soil by BC-nZVI was thereby proposed.This study well demonstrates that BC-nZVI has been emerged as a potential technology for the remediation of multiple heavy metals in soil.

关键词： Cadmium(Cd) Lead(Pb) Biochar Nano zero valent iron(nZVI) Contaminated soil

Plasmonic silver/silver oxide nanoparticles anchored bismuth vanadate as a novel visible-light ternary photocatalyst for degrading pharmaceutical micropollutants

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Journal of Environmental Sciences 2020年第10期32卷 21-32页

作者： Shengyan Pu zeng Yang jing Tang hui Ma Shengyang Xue Yingchen Bai State Key Laboratory o f Geohazard Prevention and Geoenvironment Protection Chengdu University of TechnologyChengdK 610059SichitcmChina State Key Laboratory of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental SciencesBeijing 100012China Department of Plant and Environmental Sciences Uniuersity of CopenhagenThorvaldsensvej 401871 FrederiksbergDenmark

The degradation of pharmaceutical micropollutants is an intensifying environmental problem and synthesis of efficient photocatalysts for this purpose is one of the foremost challenges worldwide.Therefore,this study was conducted to develop novel plasmonic Ag/Ag2O/BiVO4 nanocomposite photocatalysts by simple precipitation and thermal decomposition methods,which could exhibit higher photocatalytic activity for mineralized pharmaceutical micropollutants.Among the different treatments,the best performance was observed for the Ag/Ag2O/BiVO4 nanocomposites (5 wt.%;10 min’s visible light irradiation)which exhibited 6.57 times higher photodegradation rate than the pure BiVO4.Further,the effects of different influencing factors on the photodegradation system of tetracycline hydrochloride (TC-HCl) were investigated and the feasibility for its practical application was explored through the specific light sources,water source and cycle experiments.The mechanistic study demonstrated that the photogenerated holes (h^+),superoxide radicals (·O2^-)and hydroxyl radicals (·OH) participated in TC-HCl removal process,which is different from the pure BiVO4 reaction system.Hence,the present work can provide a new approach for the formation of novel plasmonic photocatalysts with high photoactivity and can act as effective practical application for environmental remediation.

关键词： Ag/Ag_2O/BiVO_4 Tetracycline hydrochloride Photocatalytic degradation Pharmaceutical micropollutants

Metal-organic interface engineering for boosting the electroactivity of Pt nanodendrites for hydrogen production

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Journal of Energy Chemistry 2020年第12期29卷 105-112页

作者： Juan Bai Nan Jia Pujun Jin Pei Chen Jia-Xing Jiang Jing-Hui Zeng Yu Chen Key Laboratory of Macromolecular Science of Shaanxi Province Key Laboratory of Applied Surface and Colloid Chemistry(MOE)Shaanxi Key Laboratory for Advanced Energy DevicesSchool of Materials Science and EngineeringShaanxi Normal UniversityXi'an 710062ShaanxiChina

Recently, the surface chemical functionalization and morphology control of precious metal nanostructures have been recognized as two efficient strategies for improving their electroactivity and/or selectivity. In this work, 1, 10-phenanthroline monohydrate(PM) functionalized Pt nanodendrites(Pt-NDs) on carbon cloth(CC)(denoted as PM@Pt-NDs/CC) and polyethylenimine(PEI) functionalized Pt-NDs on CC(denoted as PEI@Pt-NDs/CC) are successfully achieved by immersing Pt-NDs/CC into PM and PEI aqueous solutions, respectively. PEI functionalization of Pt-NDs/CC improves its electroactivity for hydrogen evolution reaction(HER) due to local proton enrichment whereas PM functionalization of Pt-NDs/CC improves its electroactivity for formic acid oxidation reaction(FAOR) by facilitating dehydrogenation pathway. With such high activity, a two-electrode electrolyzer is assembled using PM@Pt-NDs/CC as the anodic electrocatalyst and PEI@Pt-NDs/CC as the cathodic electrocatalyst for electrochemical reforming of formic acid, which only requires 0.45 V voltage to achieve the current density of 10 mA cm^(-1) for highpurity hydrogen production, much lower than conventional water electrolysis(1.59 V). The work presents an example of interfacial engineering enhancing electrocatalytic activity and indicates that electrochemical reforming of formic acid is an energy-saving electrochemical method for high-purity hydrogen production.

关键词： Pt nanodendrites Chemical functionalization Catalytic activity Hydrogen evolution reaction Formic acid oxidation reaction

Evaluation of the binding affinity and antioxidant activity of phlorizin to pepsin and trypsin

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Food Science and Human Wellness 2024年第1期13卷 392-400页

作者： jing Zhang Lan Tang Xia Hu Zhen zeng Wen Wu Fang Geng hui Li Di Wu Meat Processing Key Laboratory of Sichuan Province School of Food and Biological EngineeringChengdu UniversityChengdu 610106China School of Chemical Engineering Sichuan UniversityChengdu 610065China

Phlorizin(PHL)is a natural compound with strong antioxidant properties mainly found in apples.In this paper,the interaction mechanism of PHL with pepsin and trypsin was comparatively evaluated by computer simulation,fluorescence spectra,circular dichroism(CD),and Fourier transform infrared(FT-IR)spectra at a molecular level.Fluorescence spectra showed that PHL quenches the pepsin/trypsin by static quenching.Thermodynamic parameters indicated that PHL binds to pepsin mainly through hydrogen bonds and van der Waals forces,and that of trypsin was electrostatic forces.The ground state complexes PHL and protease have a moderate affinity of 105 L/mol PHL binds more strongly to trypsin than to pepsin.CD and FT-IR spectra results showed that pepsin/trypsin decreased theβ-sheet content and slightly changed its secondary structure upon PHL.These experimental results are mutually verified with the predicted computer-aid simulation results.Upon PHL and trypsin binding,the antioxidant capacity of PHL was elevated.Nevertheless,the antioxidant capacity of PHL was decreased after binding to pepsin.This work elucidates the binding of PHL binding mechanisms to pepsin/trypsin and provides useful information for the digestion of PHL to improve the application of PHL in food processing.

关键词： Interaction Phlorizin Pepsin Trypsin Antioxidation

Overexpression of mitogen-activated protein kinase phosphatase-1 in endothelial cells reduces blood-brain barrier injury in a mouse model of ischemic stroke

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Neural Regeneration Research 2023年第8期18卷 1743-1749页

作者： Xiu-De Qin Tai-Qin Yang Jing-Hui Zeng Hao-Bin Cai Shao-Hua Qi Jian-Jun Jiang Ying Cheng Long-Sheng Xu Fan Bu Department of Neurology&Psychology Shenzhen Traditional Chinese Medicine HospitalThe Fourth Clinical Medical College of Guangzhou University of Chinese MedicineShenzhenGuangdong ProvinceChina Department of Cardiothoracic Surgery Shenzhen Traditional Chinese Medicine HospitalThe Fourth Clinical Medical College of Guangzhou University of Chinese MedicineShenzhenGuangdong ProvinceChina Department of Neurology The University of Texas Health Science Center at HoustonHoustonTXUSA Department of Nephrology Shenzhen Traditional Chinese Medicine HospitalThe Fourth Clinical Medical College of Guangzhou University of Chinese MedicineShenzhenGuangdong ProvinceChina Department of Anesthesiology and Pain Medicine The Affiliated Hospital of Jiaxing UniversityJiaxingZhejiang ProvinceChina

Ischemic stroke can cause blood-brain barrier(BBB)injury,which worsens brain damage induced by stroke.Abnormal expression of tight junction proteins in endothelial cells(ECs)can increase intracellular space and BBB leakage.Selective inhibition of mitogen-activated protein kinase,the negative regulatory substrate of mitogen-activated protein kinase phosphatase(MKP)-1,improves tight junction protein function in ECs,and genetic deletion of MKP-1 aggravates ischemic brain injury.However,whether the latter affects BBB integrity,and the cell type-specific mechanism underlying this process,remain unclear.In this study,we established an adult male mouse model of ischemic stroke by occluding the middle cerebral artery for 60 minutes and overexpressed MKP-1 in ECs on the injured side via lentiviral transfection before stroke.We found that overexpression of MKP-1 in ECs reduced infarct volume,reduced the level of inflammatory factors interleukin-1β,interleukin-6,and chemokine C-C motif ligand-2,inhibited vascular injury,and promoted the recovery of sensorimotor and memory/cognitive function.Overexpression of MKP-1 in ECs also inhibited the activation of cerebral ischemia-induced extracellular signal-regulated kinase(ERK)1/2 and the downregulation of occludin expression.Finally,to investigate the mechanism by which MKP-1 exerted these functions in ECs,we established an ischemic stroke model in vitro by depriving the primary endothelial cell of oxygen and glucose,and pharmacologically inhibited the activity of MKP-1 and ERK1/2.Our findings suggest that MKP-1 inhibition aggravates oxygen and glucose deprivation-induced cell death,cell monolayer leakage,and downregulation of occludin expression,and that inhibiting ERK1/2 can reverse these effects.In addition,co-inhibition of MKP-1 and ERK1/2 exhibited similar effects to inhibition of ERK1/2.These findings suggest that overexpression of MKP-1 in ECs can prevent ischemia-induced occludin downregulation and cell death via deactivating ERK1/2,thereby protecting the integrity of BBB

关键词： blood-brain barrier brain injury cerebral ischemia endothelial cells extracellular signal-regulated kinase 1/2 functional recovery mitogenactivated protein kinase phosphatase 1 occludin oxygen and glucose deprivation transient middle cerebral artery occlusion

Lateral stability regulation of intelligent electric vehicle based on model predictive control

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Journal of Intelligent and Connected Vehicles

Journal of Intelligent and Connected Vehicles 2021年第3期4卷 104-114页

作者： Cong Li YunFeng Xie Gang Wang XianFeng zeng hui jing Guilin University of Aerospace Technology GuilinChina Guilin University of Electronic Technology GuilinChina huizhou Desay SV Automotive Co.LtdHuizhouChina

Purpose–This paper studies the lateral stability regulation of intelligent electric vehicle(EV)based on model predictive control(MPC)algorithm.Design/methodology/approach–Firstly,the bicycle model is adopted in the system modelling process.To improve the accuracy,the lateral stiffness of front and rear tire is estimated using the real-time yaw rate acceleration and lateral acceleration of the vehicle based on the vehicle dynamics.Then the constraint of input and output in the model predictive controller is designed.Soft constraints on the lateral speed of the vehicle are designed to guarantee the solved persistent feasibility and enforce the vehicle’s sideslip angle within a safety range.Findings–The simulation results show that the proposed lateral stability controller based on the MPC algorithm can improve the handling and stability performance of the vehicle under complex working conditions.Originality/value–The MPC schema and the objective function are established.The integrated active front steering/direct yaw moments control strategy is simultaneously adopted in the model.The vehicle’s sideslip angle is chosen as the constraint and is controlled in stable range.The online estimation of tire stiffness is performed.The vehicle’s lateral acceleration and the yaw rate acceleration are modelled into the two-degree-of-freedom equation to solve the tire cornering stiffness in real time.This can ensure the accuracy of model.

关键词： Intelligent electric vehicle Model predictive control Lateral stability control

Ocular manifestations and quality of life in patients after hematopoietic stem cell transplantation

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International Journal of Ophthalmology(English edition) 2023年第7期16卷 1138-1144页

作者： Shu-Xian Fan Wen-hui Wang Peng zeng Ke-Zhi Huang Yu-Xin Hu jing Wang Yi-Qing Li Jian-hui Xiao Department of Ophthalmology Sun Yat-sen Memorial HospitalSun Yat-sen UniversityGuangzhou 510120Guangdong ProvinceChina Department of Hematology Sun Yat-sen Memorial HospitalSun Yat-sen UniversityGuangzhou 510120Guangdong ProvinceChina

AIM:To explore the relationship between ocular and systemic conditions and the impact of ocular complications on the quality of life(QOL)in patients after allogeneic hematopoietic stem cell transplantation(ALLO-HSCT).METHODS:Forty-four patients with severe hematopoietic disease were enrolled after ALLO-HSCT at our center from July 2018 to October 2020.They completed two questionnaires:the Ocular Surface Disease Index(OSDI)and the quality-of-life scale for Chinese patients with visual impairment(SQOL-DV1).Ocular conditions and systemic conditions were also assessed.RESULTS:Eye damage was correlated with total bilirubin(P=0.005),and gamma-glutamyl transferase(GGT)(P=0.021).There was no significant correlation between the overall QOL score and OSDI(P=0.8226)or SQOLDV1(P=0.9526)scores.The OSDI and the overall QOL score were not correlated with ocular conditions,including best-corrected visual acuity(BCVA),intraocular pressure,Schirmer tear test II,sodium fluorescein staining,tear film breakup time,and tear meniscus height.SQOLDV1 was correlated with BCVA(P=0.0007),sodium fluorescein staining(P=0.007),and tear film breakup time(P=0.0146).CONCLUSION:In some patients,early ocular symptoms are not evident after ALLO-HSCT,while ocular surface complications can be observed after a comprehensive ophthalmological examination.Especially for those with elevated total bilirubin or GGT,regular ophthalmic follow-up visits are essential to diagnose and treat ocular graft versus host disease(o GVHD),especially for patients with elevated total bilirubin or GGT.

关键词： allogeneic stem cell transplantation ocular graft versus host disease ocular surface disease quality of life quality-of-life scale for Chinese patients with visual impairment Ocular Surface Disease Index

A redox-active conjugated microporous polymer cathode for highperformance lithium/potassium-organic batteries

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Science China Chemistry 2021年第1期64卷 72-81页

作者： Lian-Wei Luo Chong Zhang Peixun Xiong Yongbo Zhao Wenyan Ma Yu Chen jing hui zeng Yunhua Xu Jia-Xing Jiang Key Laboratory for Macromolecular Science of Shaanxi Province Shaanxi Engineering Laboratory for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi'an 710062China Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education Tianjin Key Laboratory of Composite and Functional MaterialsSchool of Materials Science and EngineeringTianjin UniversityTianjin 300072China

Organic redox-active materials have emerged as a class of electrode materials for rechargeable batteries due to their high redox activity,low cost,structure diversity and flexibility.However,the high solubility of organic small molecules in organic electrolytes commonly leads to the fast capacity decay with cycling.Herein,we report a redox-active conjugated microporous polymer of poly(pyrene-co-anthraquinone)(Py Aq)cathode material consisting of pyrene and anthraquinone units.Benefiting from the highly cross-linked polymer structure with insoluble nature in organic electrolytes,the high surface area and the plentiful redox-active carbonyl groups,the Py Aq cathode demonstrates outstanding electrochemical performances for both lithium-ion batteries(LIBs)and potassium-ion batteries(KIBs).Specifically,the Py Aq cathode for LIBs delivers a high reversible capacity of 169 m Ah g^-1 at the current density of 20 m A g^-1,a high rate capability(142 m Ah g^-1 at 1000 m A g^-1)and an excellent cycling stability for 4000 cycles.Additionally,the Py Aq cathode for KIBs also exhibits a high reversible capacity of143 m Ah g^-1 with a long cycling life over 800 cycles.The excellent electrochemical performance demonstrates that the newly developed Py Aq could be an attractive cathode material for the advanced energy storage technologies.

关键词： conjugated microporous polymers anthraquinone organic cathode material lithium-ion battery potassium-ion battery

The Larix kaempferi genome reveals new insights into wood properties

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Journal of Integrative Plant Biology 2022年第7期64卷 1364-1373页

作者： Chao Sun Yun-hui Xie Zhen Li Yan-jing Liu Xiao-Mei Sun jing-jing Li Wei-Peng Quan Qing-Yin zeng Yves Van de Peer Shou-Gong Zhang State Key Laboratory of Tree Genetics and Breeding Chinese Academy of ForestryBeijing 100091China Key Laboratory of Tree Breeding and Cultivation of the State Forestry and Grassland Administration Research Institute of ForestryChinese Academy of ForestryBeijing 100091China Department of Plant Biotechnology and Bioinformatics Ghent UniversityGent B‐9052Belgium VIB Center for Plant Systems Biology Ghent B‐9052Belgium Nextomics Biosciences Co. LtdWuhan 430073China Department of Biochemistry Genetics and MicrobiologyPretoriaSouth Africa

Here,through single-molecule real-time sequencing,we present a high-quality genome sequence of the Japanese larch(Larix kaempferi),a conifer species with great value for wood production and ecological afforestation.The assembled genome is 10.97 Gb in size,harboring 45,828 protein-coding genes.Of the genome,66.8%consists of repeat sequences,of which long terminal repeat retrotransposons are dominant and make up 69.86%.We find that tandem duplications have been responsible for the expansion of genes involved in transcriptional regulation and stress responses,unveiling their crucial roles in adaptive evolution.Population transcriptome analysis reveals that lignin content in L.kaempferi is mainly determined by the process of monolignol polymerization.The expression values of six genes(LkC OMT7,LkC OMT8,LkL AC23,LkL AC102,LkP RX148,and LkP RX166)have significantly positive correlations with lignin content.These results indicated that the increased expression of these six genes might be responsible for the high lignin content of the larches’wood.Overall,this study provides new genome resources for investigating the evolution and biological function of conifer trees,and also offers new insights into wood properties of larches.

关键词： evolution gene expression genome Larix kaempferi wood properties