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Dynamically lithium-compensated polymer artificial SEI to assist highly stable lithium-rich manganese-based anode-free lithium metal batteries

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Rare Metals 2024年第6期43卷 2527-2535页

作者： Ming-Ji Peng jin-qiu zhou Ting-Ting Han Yang zhou Jie Liu Na Xu Zhen-Kang Wang Wen-Bin Lin Cheng-Lin Yan Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry College of EnergySoochow UniversitySuzhou 215006China Light Industry Instituteof Electrochemical Power Sources Suzhou 215006China School of Chemistry and Chemical Engineering Nantong UniversityNantong 226019China e-mail:jliu93@*** State Key Laboratory of Space Power-Sources Technology Shanghai Institute of Space Power-SourcesShanghai 200245China Centre Energie Materiaux et TélécommunicationsInstitut National de la Recherche ScientifiqueVarennesQC J3X 1S2Canada Zhangjiagang Industrial Technologies Soochow UniversitySuzhou 215006China

Owing to the unique structure,anode-free lithium metal batteries(AFLMBs)have higher energy density and lower production cost than traditional lithium metal batteries(LMBs)or lithium-ion batteries(LIBs),However,AFLMBs suffer from an inherently finite Li reservoir and exhibit poor cycle stability,low Coulombic efficiency(CE)and severe dendrite *** this work,polydiallyl lithium disulfide(PDS-Li)was successfully synthesized and coated on Cu current collector by electrochemical *** PDS-Li acts as an additional lithium resource to compensate for the irreversible loss of lithium during *** addition,the special structure and lithiophilicity of PDS-Li contribute to lower nucleation overpotential and uniform lithium *** coupled with Li-rich manganese-based(LRM)cathode of Li1.2Mn0.54Ni0.13Co0.13O2,the anode-free full cell exhibits significantly improved cycle stability over 100 cycles and capacity retention of 63.3%and 57%after 80 and 100 cycles,*** believe that PDS-Li can be used to ensure stable cycling performance and high-energy-density in AFLMBs.

关键词： Anode-free Artificial solid electrolyte interphase(SEI) Lithium metal batteries Lithium-rich cathode Finite element simulation

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Tel1 and Rif2 oppositely regulate telomere protection at uncapped telomeres in Saccharomyces cerevisiae

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Journal of Genetics and Genomics 2018年第9期45卷 467-476页

作者： Ling-Li Zhang Zhenfang Wu jin-qiu zhou CAS Center for Excellence in Molecular Cell Science Shanghai Institute of Biochemistry and Cell Biology Chinese Academy of Sciences University of Chinese Academy of Sdences Shanghai 200031 China School of Life Science and Technology Shanghai Tech University Shanghai 201210 China

It has been well documented that Tel1 positively regulates telomere-end resection by promoting Mre11-Rad50-Xrs2（MRX） activity, while Rif2 negatively regulates telomere-end resection by inhibiting MRX activity. At uncapped telomeres, whether Tel1 or Rif2 plays any role remains largely unknown. In this work, we examined the roles of Tel1 and Rif2 at uncapped telomeres in yku70△ and/or cdc13-1 mutant cells cultured at non-permissive temperature. We found that deletion of TEL1 exacerbates the temperature sensitivity of both yku70△ and cdc13-1 cells. Further epistasis analysis indicated that MRX and Tel1 function in the same pathway in telomere protection. Consistently, TEL1 deletion increases accumulation of Exo1-dependent telomeric single-stranded DNA（ssDNA） at uncapped telomeres, which stimulates checkpoint-dependent cell cycle arrest. Moreover, TEL1 deletion in yku70△ cells facilitates Rad51-dependent Y0 recombination. In contrast, RIF2 deletion in yku70△ cells decreases the accumulation of telomeric ssDNA after 8 h of incubation at the non-permissive temperature of 37℃ and suppresses the temperature sensitivity of yku70△ cells, likely due to the increase of Mre11 association at ***, our findings indicate that Tel1 and Rif2 regulate telomere protection at uncapped telomeres via their roles in balancing MRX activity in telomere resection.

关键词： Tel1 RiF2 MRX Uncapped telomeres Telomere protection

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Molecular dynamics of de novo telomere heterochromatin formation in budding yeast

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Journal of Genetics and Genomics 2016年第7期43卷 451-465页

作者： Yi-Min Duan Bo-O.zhou jing Peng Xia-jing Tong Qiong-Di Zhang jin-qiu zhou The State Key Laboratory of Molecular Biology Shanghai Institute of Biochemistry and Cell Biology Shanghai Institutes for Biological Sciences Chinese Academy of Sciences University of Chinese Academy of Sciences 320 Yue Yang Road Shanghai 200031 China School of Life Science and Technology Shanghai Tech University 100 Haike Road Shanghai 200031 China

In the budding yeast Saccharomyces cerevisiae, heterochromatin structure is found at three chromosome regions, which are homothallic mating-type loci, rDNA regions and telomeres. To address how telomere heterochromatin is assembled under physiological conditions, we employed a de novo telomere addition system, and analyzed the dynamic chromatin changes of the TRPI reporter gene during telomere elongation. We found that integrating a 255-bp, but not an 81-bp telomeric sequence near the TRP1 promoter could trigger Sir2 recruitment, active chromatin mark（s）＇ removal, chromatin compaction and TRP1 gene silencing, indicating that the length of the telomeric sequence inserted in the internal region of a chromosome is critical for determining the chromatin state at the proximal region. Interestingly, Rill but not Rif2 or yKu is indispensable for the formation of intra-chromosomal silent chromatin initiated by telomeric sequence. When an internal short telomeric sequence （e.g., 81 bp） gets exposed to become a de novo telomere, the herterochromatin features, such as Sir recruitment, active chromatin mark（s）＇ removal and chromatin compaction, are detected within a few hours before the de novo telomere reaches a stable length. Our results recapitulate the molecular dynamics and reveal a coherent picture of telomere het- erochromatin formation.

关键词： Telomere Heterochromatin Nucleosome positioning Siry Ku

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Yeast KEOPS complex regulates telomere length independently of its t6A modification function

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Journal of Genetics and Genomics 2018年第5期45卷 247-257页

作者： Ying-Ying Liu Ming-Hong He Jia-Cheng Liu Yi-Si Lu jing Peng jin-qiu zhou CAS Center for Excellence in Molecular Cell Science Shanghai Institute of Biochemistry and Cell BiologyChinese Academy of SciencesUniversity of Chinese Academy of SciencesShanghai 200031China School of Life Science and Technology.ShanghaiTech University Shanghai 201210China

In Saccharornyces cerevisiae, the highly conserved Sua5 and KEOPS complex （including five subunits Kael, Bud32, Cgi121, Pccl and Gon7） catalyze a universal tRNA modification, namely N6-threonylcarbamoy- ladenosine （t6A）, and regulate telomere replication and recombination. However, whether telomere regulation function of Sua5 and KEOPS complex depends on the t6A modification activity remains unclear. Here we show that Sua5 and KEOPS regulate telomere length in the same genetic pathway. Interestingly, the telomere length regulation by KEOPS is independent of its t6A biosynthesis activity. Cytoplasmic overexpression of Qri7, a functional counterpart of KEOPS in mitochondria, restores cytosolic tRNA t6A modification and cell growth, but is not sufficient to rescue telomere length in the KEOPS mutant kae1△ cells, indicating that a t6A modification-independent function is responsible for the telomere regulation. The results of our in vitro biochemical and in vivo genetic assays suggest that telomerase RNA TLC1 might not be modified by Sua5 and KEOPS. Moreover, deletion of KEOPS subunits results in a dramatic reduction of telomeric G-overhang, suggesting that KEOPS regulates telomere length by promoting G-overhang generation. These findings support a model in which KEOPS regulates telomere replication independently of its function on tRNA modification.

关键词： Telomere KEOPS complex Sua5 G-overhang t6A modification

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Both combinatorial K4me0-K36me3 marks on sister histone H3s of a nucleosome are required for Dnmt3a-Dnmt3L mediated de novo DNA methylation

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Journal of Genetics and Genomics 2020年第2期47卷 105-114页

作者： Ting Gong Xin Gu Yu-Ting Liu Zhen zhou Ling-Li Zhang Yang Wen Wei-Li Zhong Guo-Liang Xu jin-qiu zhou State Key Laboratory of Molecular Biology CAS Center for Exellence in Molecular Cell ScienceShanghai Institute of Biochemistry and Cell BiologyChinese Acadermy of SciencesUniversity of Chinese Academy of SciencesShanghai200031China School of Life Science and Technology Shanghai Tech UniversityShanghai201210China

A nucleosome contains two copies of each histone H2A,H2B,H3 and *** H3 K4me0 and K36me3are two key chromatin marks for de novo DNA methylation catalyzed by DNA methyltransferases in ***,it remains unclear whether K4me0 and K36me3 marks on both sister histone H3s regulate de novo DNA methylation independently or ***,taking advantage of the bivalent histone H3 system in yeast,we examined the contributions of K4 and K36 on sister histone H3s to genomic DNA methylation catalyzed by ectopically co-expressed murine Dnmt3a and *** results show that lack of both K4me0 and K36me3 on one sister H3 tail,or lack of K4me0 and K36me3 on respective sister H3s results in a dramatic reduction of 5mC,revealing a synergy of two sister H3s in DNA methylation ***,the Dnmt3a or Dnmt3L mutation that disrupts the interaction of Dnmt3aADD domain-H3K4me0,Dnmt3LADD domain-H3K4me0,orDnmt3aPWWP domain-H3K36me3 causes a significant reduction of DNA *** results support the model that each heterodimeric Dnmt3a-Dnmt3L reads both K4me0 and K36me3 marks on one tail of sister H3s,and the dimer of heterodimeric Dnmt3a-Dnmt3L recognizes two tails of sister histone H3s to efficiently execute de novo DNA methylation.

关键词： Asymmetrical nucleosome Histone H3K4 methylation Histone H3K36 methylation De novo DNA methylation Yeast

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Novel rockburst prediction criterion with enhanced explainability employing CatBoost and nature-inspired metaheuristic technique

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Underground Space 2024年第6期19卷 101-118页

作者： Yingui qiu Jian zhou School of Resources and Safety Engineering Central South UniversityChangsha 410083China

Rockburst is a major challenge to hard rock engineering at great *** and timely assessment of rockburst risk can avoid unnecessary casualties and property *** the existence of various methods for rockburst assessment,there remains an urgent need for a comprehensive and reliable criterion that is easy to both apply and *** a new rockburst criterion based on simple parameters can potentially fill this *** its advantages,this criterion can facilitate a more effective and efficient prediction of rockburst potential,thereby contributing significantly to enhancing safety *** this paper,combined with the internal and external factors of rockburst,four control variables(i.e.,integrity index,stress index,brittleness index,and elastic energy index)were selected to be incorporated into a comprehensive rockburstability index(RBSI).Based on 116 sets of rockburst cases,the rockburst potential was accurately quantified and predicted using the categorical boosting(CatBoost)model and the nature-inspired metaheuristic African vultures optimization algorithm(AVOA).In its performance validation,the criterion achieved the highest accuracy of 90.48%,verifying the reliability and effectiveness of the proposed RBSI ***,an interpretive method was applied to analyze the variable influence on the criterion,facilitating the explanation of predictions and the analysis of the formula’s robustness under different *** general,compared with existing criterion methods involving relevant indicators,the newly proposed RBSI criterion enhances the accuracy of rockburst potential prediction,and it can effectively and swiftly evaluate the preliminary risk of ***,a graphical user interface was developed to provide a clear visualization of the assessment of rockburst potential.

关键词： Rockburst criterion CatBoost Metaheuristic optimization Model interpretation Graphical user interface

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Analysis of China's Electricity Price and Electricity Burden of Basic Industries under the Carbon Peak Target before 2030

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CSEE Journal of Power and Energy Systems 2024年第2期10卷 481-491页

作者： Yue qiu Suyang zhou Wei Gu Xiao-Ping Zhang School of Electrical Engineering Southeast UniversityNanjingChina School of Electronic Electrical and System EngineeringUniversity of BirminghamU.K.

The Chinese government is deepening reformation of electricity prices during the 14th Five Year Plan period and has set a carbon emission reduction target of reaching carbon peak before *** this context,will the carbon emission target influence electricity pricing and will electricity price influence competitiveness of Chinese main industries are two questions needing to be *** paper compares China's electricity price level with the selected major countries in the world,and four typical industries are selected to evaluate their electricity burden ***,the correlation between residential electricity price and industrial electricity price and the influencing factors is analyzed,from the perspectives of scale,structure and *** to the model obtained by regression analysis,the electricity price level and corresponding residential and industrial electricity burden in 2025 and 2030 are *** Terms-Electricity burden,industrial electricity price,regression analysis,residential electricity price.

关键词： Electricity burden industrial electricity price regression analysis residential electricity price

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An Improved Bounded Conflict-Based Search for Multi-AGV Pathfinding in Automated Container Terminals

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Computer Modeling in Engineering & Sciences 2024年第6期139卷 2705-2727页

作者： Xinci zhou jin Zhu Shanghai Maritime University Logistics Science and Engineering Research InstituteShanghai200000China

As the number of automated guided vehicles(AGVs)within automated container terminals(ACT)continues to rise,conflicts have becomemore *** point and edge conflicts ofAGVs,amulti-AGVconflict-free path planning model has been formulated to minimize the total path length of AGVs between shore bridges and *** larger terminalmaps and complex environments,the grid method is employed to model AGVs’road *** improved bounded conflict-based search(IBCBS)algorithmtailored to ACT is proposed,leveraging the binary tree principle to resolve conflicts and employing focal search to expand the search *** experiments involving 60 AGVs indicate a reduction in computing time by 37.397%to 64.06%while maintaining the over cost within 1.019%.Numerical experiments validate the proposed algorithm’s efficacy in enhancing efficiency and ensuring solution quality.

关键词： Automated terminals multi-AGV multi-agent path finding(MAPF) conflict based search(CBS) AGV path planning

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Bridge Bidding via Deep Reinforcement Learning and Belief Monte Carlo Search

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IEEE/CAA Journal of Automatica Sinica 2024年第10期11卷 2111-2122页

作者： Zizhang qiu Shouguang Wang Dan You MengChu zhou School of Information and Electronic Engineering Zhejiang Gongshang UniversityHangzhou 310018China IEEE

Contract Bridge,a four-player imperfect information game,comprises two phases:bidding and *** computer programs excel at playing,bidding presents a challenging aspect due to the need for information exchange with partners and interference with communication of *** this work,we introduce a Bridge bidding agent that combines supervised learning,deep reinforcement learning via self-play,and a test-time search *** experiments demonstrate that our agent outperforms WBridge5,a highly regarded computer Bridge software that has won multiple world championships,by a performance of 0.98 IMPs(international match points)per deal over 10000 deals,with a much cost-effective *** performance significantly surpasses previous state-of-the-art(0.85 IMPs per deal).Note 0.1 IMPs per deal is a significant improvement in Bridge bidding.

关键词： Contract Bridge reinforcement learning search

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Characterization of ATPase Activity of Recombinant Human Pif1

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Acta Biochimica et Biophysica Sinica 2006年第5期38卷 335-341页

作者： Yu HUANG Deng-Hong ZHANG jin-qiu zhou Max-Planck Junior Research Group at the State Key Laboratory of Molecular Biology,Institute of Biochemistry and Cell Biology,Shanghai Institutes for Biological Sciences,Chinese Academy of Sciences,Shanghai 200031,China Max-Planck Junior Research Group at the State Key Laboratory of Molecular Biology Institute of Biochemistry and Cell Biology Shanghai Institutes for Biological Sciences Chinese Academy of SciencesShanghai 200031 China

Saccharomyces cerevisiae Piflp helicase is the founding member of the Pifl subfamily that isconserved from yeast to *** potential human homolog of the yeast PIFI gene has been cloned fromthe cDNA library of the Hek293 cell ***,we described a purification procedure of glutathione S-transferase（GST）-fused N terminal truncated human Pifl protein（hPif1ΔN）from yeast and characterizedthe enzymatic kinetics of its ATP hydrolysis *** ATPase activity of human Pif1 is dependent ondivalent cation,such as Mg2+,Ca2+and single-stranded *** for ATP for the ATPase activity isapproximately 200 μ*** the ATPase activity is essential for hPifl’s helicase activity,these results willfacilitate the further investigation on hPif1.

关键词： Pifl helicase telomere telomerase ATPase

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