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The Influence of the Sun and Moon on the Observation of Very High Energy Gamma-ray Sources Using EAS Arrays

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Research in Astronomy and Astrophysics 2024年第6期24卷 245-252页

作者： Tao Wen Songzhan Chen Benzhong dai School of Physics and Astronomy Yunnan UniversityKunming 650091China Key Laboratory of Particle Astrophysics Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China Tianfu Cosmic Ray Research Center Chengdu 610000China

With great advance of ground-based extensive air shower arrays,such as LHAASO and HAWC,many very high energy(VHE)gamma-ray sources have been discovered and are being monitored regardless of the day and the ***,the Sun and Moon would have some impacts on the observation of gamma-ray sources,which have not been taken into account in previous *** this paper,the influence of the Sun and Moon on the observation of very high energy gamma-ray sources when they are near the line of sight of the Sun or Moon is *** tracks of all the known VHE sources are scanned and several VHE sources are found to be very close to the line of sight of the Sun or Moon during some *** absorption of very high energy gamma rays by sunlight is estimated with detailed method and some useful conclusions are *** main influence is the block of the Sun and Moon on gamma rays and the shadow on the cosmic ray *** influence is investigated considering the detector angular resolution and some strategies on data analysis are proposed to avoid the underestimation of the gamma-ray emission.

关键词： astroparticle physics Sun:general methods:observational Sun:UV radiation

Development and performance evaluation of high temperature resistant strong adsorption rigid blocking agent

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Petroleum Science 2024年第4期21卷 2650-2662页

作者： Zhe Xu jin-Sheng Sun jing-Ping Liu Kai-He Lv Xiao-Dong Dong Zong-Lun Wang Tai-Feng Zhang Yuan-Wei Sun Zhi-Wen dai School of Petroleum Engineering China University of Petroleum (East China) CNPC Engineering Technology R&D Company Limited

As drilling wells continue to move into deep ultra-deep layers, the requirements for temperature resistance of drilling fluid treatments are getting higher and higher. Among them, blocking agent, as one of the key treatment agents, has also become a hot spot of research. In this study, a high temperature resistant strong adsorption rigid blocking agent(QW-1) was prepared using KH570 modified silica,acrylamide(AM) and allyltrimethylammonium chloride(TMAAC). QW-1 has good thermal stability,average particle size of 1.46 μm, water contact angle of 10.5., has a strong hydrophilicity, can be well dispersed in water. The experimental results showed that when 2 wt% QW-1 was added to recipe A(4 wt% bentonite slurry+0.5 wt% DSP-1(filtration loss depressant)), the API filtration loss decreased from 7.8to 6.4 m L. After aging at 240.C, the API loss of filtration was reduced from 21 to 14 m L, which has certain performance of high temperature loss of filtration. At the same time, it is effective in sealing 80-100mesh and 100-120 mesh sand beds as well as 3 and 5 μm ceramic sand discs. Under the same conditions,the blocking performance was superior to silica(5 μm) and calcium carbonate(2.6 μm). In addition, the mechanism of action of QW-1 was further investigated. The results show that QW-1 with amide and quaternary ammonium groups on the molecular chain can be adsorbed onto the surface of clay particles through hydrogen bonding and electrostatic interaction to form a dense blocking layer, thus preventing further intrusion of drilling fluid into the formation.

关键词： High adsorption Rigid microsphere High temperature resistance Blocking performance

Deactivation mechanism of acetone to isobutene conversion over Y/Beta catalyst

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Chinese Journal of Catalysis 2024年第9期64卷 133-142页

作者： Chang Wang Tingting yan Weili dai School of Materials Science and Engineering Nankai UniversityTianjin 300350China College of Science Civil Aviation University of ChinaTianjin 300300China

The conversion of acetone derived from biomass to isobutene has attracted extensive *** comparison with Brønsted acidic catalyst,Lewis acidic catalyst could exhibit a better catalytic performance with a higher isobutene ***,the catalyst stability remains a key problem for the long-running acetone conversion and the reasons for catalyst deactivation are poorly understood up to ***,the deactivation mechanism of Lewis acidic Y/Beta catalyst during the acetone to isobutene conversion was investigated by various characterization techniques,including acetone-temperature-programmed surface reaction,gas chromatography-mass spectrometry,in situ ultraviolet-visible,and 13C cross polarization magic angle spinning nuclear magnetic resonance spectroscopy.A successive aldol condensation and cyclization were observed as the main side-reactions during the acetone conversion at Lewis acidic Y *** comparison with the low reaction temperature,a rapid formation and accumulation of the larger cyclic unsaturated aldehydes/ketones and aromatics could be observed,and which could strongly adsorb on the Lewis acidic sites,and thus cause the catalyst deactivation *** a simple calcination,the coke deposits could be easily removed and the catalytic activity could be well restored.

关键词： Deactivation mechanism Acetone to isobutene Lewis acid sites Y/Beta Spectroscopy

Reduction of unactivated alkyl chlorides enabled by light-induced single electron transfer

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Science China Chemistry 2024年第2期67卷 471-481页

作者： Lei dai Zhao-Fei Zhang Xiang-Yu Chen School of Chemical Sciences University of the Chinese Academy of SciencesBeijing100049China Institute of Chemistry Chinese Academy of SciencesBeijing100190China Binzhou Institute of Technology Weiqiao-UCAS Science and Technology ParkBinzhou256606China

Alkyl chlorides are abundant and easily accessible starting ***,due to the high reduction potentials associated with unactivated alkyl chlorides,achieving their single electron reduction remains a persistent *** challenge has spurred the exploration of efficient activation methods to overcome this *** recent years,photocatalysis has emerged as a mild and potent tool for the single electron reduction of unactivated alkyl chlorides,opening up new possibilities in this *** the rapid advancements in this area,a comprehensive review that provides a conceptual understanding of this emerging field,with a specific focus on reaction design and catalytic mechanisms,would be timely and highly ***,we present an overview of various synthetic techniques for photoinduced single electron reduction of unactivated alkyl ***,we also discuss the limitations of the present methods and future directions that lie ahead in this field.

关键词： photocatalysis unactivated alkyl chlorides single electron transfer radical reactions

Study on a conical bearing for acceleration-sensitive equipment

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Earthquake Engineering and Engineering Vibration 2024年第1期23卷 103-128页

作者： Pang Hui Xu Wen dai Junwu Jiang Tao Key Laboratory of Earthquake Engineering and Engineering Vibration Institute of Engineering MechanicsChina Earthquake AdministrationHarbin 150080China Key Laboratory of Earthquake Disaster Mitigation Ministry of Emergency ManagementHarbin 150080China School of Civil Engineering and Transportation Beihua UniversityJilin 132013China

Seismic isolation effectively reduces seismic demands on building structures by isolating the superstructure from ground vibrations during ***,isolation strategies give less attention to acceleration-sensitive systems or ***,as the isolation layer’s displacement grows,the stiffness and frequency of traditional rolling and sliding isolation bearings increases,potentially causing self-centering and resonance *** a result,a new conical pendulum bearing has been selected for acceleration-sensitive equipment to increase self-centering capacity,and additional viscous dampers are incorporated to enhance system ***,the theoretical formula for conical pendulum bearings is supplied to analyze the device’s dynamic parameters,and shake table experiments are used to determine the proposed device’s isolation efficiency under various *** to the test results,the newly proposed devices have remarkable isolation performance in terms of minimizing both acceleration and displacement ***,a numerical model of the isolation system is provided for further research,and the accuracy is demonstrated by the aforementioned experiments.

关键词： seismic isolation acceleration-sensitive equipment the conical pendulum bearing shake table tests isolation performance,numerical model

Thermal Decomposition and Oxidative Decomposition Mechanism of HFC-134a by Experimental and DFT Method

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Journal of Thermal Science 2024年第5期33卷 1990-2003页

作者： XU Yunting ZHANG Kai dai Xiaoye SHI Lin Key Laboratory for Thermal Science and Power Engineering of Ministry of Education Department of Energy and Power EngineeringTsinghua UniversityBeijing 100084China

In response to the Kigali Amendment to the Montreal Protocol and global low-carbon emission environmental requirements,the phase-out and decomposition of numerous HFC refrigerants have become urgent,necessitating efficient and mild decomposition *** study investigates the thermal decomposition and oxidative thermal decomposition pathways of the typical hydrofluorocarbon refrigerant HFC-134a,employing a combination of experimental and quantum chemical DFT simulation *** chemical simulations reveal that the initial reaction bond cleavage serves as the rate-determining step during the thermal decomposition process,with the most easily detectable closed-shell products including CF_(2)=CHF,HF,CH_(3)F,CHF_(3),CH_(2)F_(2),and CF_(4).Reactive oxygen species can significantly reduce the Gibbs free energy barrier for HFC-134a *** achieve efficient degradation of HFC-134a,appropriate catalysts should be developed and selected to increase the level of reactive oxygen species in the reaction *** studies further corroborate that HFC-134a may undergo degradation through distinct reaction pathways under varying temperature(240℃to360℃)and pressure(0.1 MPa to 4.5 MPa)conditions,in agreement with simulation predictions.

关键词： HFC-134a pyrolysis oxidative thermal decomposition DFT refrigerant

Fast flow simulation study of pulsating ventilation performance on air contaminant removal

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Building Simulation 2024年第8期17卷 1309-1322页

作者： Pengzhi Zhou Haidong Wang Yuwei dai Chen Huang School of Environment and Architecture University of Shanghai for Science and Technology516 Jungong RoadShanghai200093China

Fast flow simulation is imperative in the design of pulsating ventilation,which is potentially efficient in indoor air contaminant *** execution of the conventional CFD method requires considerable amount of computational *** this study,five different numerical schemes were proposed based on fast fluid dynamics(FFD)and fractional step(FS)methods,and were evaluated to achieve quick simulation of airflow/contaminant *** of these numerical schemes was identified with the best overall computing efficiency for investigating the performance of pulsating *** this numerical scheme at hand,the air contaminant removal effectiveness of different ventilation types was *** kinds of pulsating ventilation and one kind of steady ventilation were tested upon a benchmark isothermal mixing *** effect of adjusting supply velocity parameters on the ventilation performance was also ***_(2)concentration,airflow pattern,and vortex structure of different ventilation types were illustrated and *** results reveal that the FS method is more suitable for transient simulation of wall-bounded indoor airflow than the FFD method,and 34%–51%of computing time could be saved compared to the conventional CFD *** the choice of ventilation type,steady ventilation might result in short-circuit airflow and stagnant zones;alternatively,pulsating ventilation has greater potential in air contaminant removal due to its ever-changing vortex structure.

关键词： pulsating ventilation fast fluid dynamics fractional step method contaminant removal efficiency time-periodic supply vortex structure

Grain refinement of 5A06 aluminum alloy welds caused by tungsten inert gas welding arc characteristics under Ar-He alternating gas supply conditions:a coupled method of water-cooled copper plate test/numerical simulation

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Journal of Iron and Steel Research International 2024年第3期31卷 767-777页

作者： Hong-bin dai Jian Miao Jia-xin Lin School of Materials Science and Engineering Harbin University of Science and TechnologyHarbin 150040HeilongjiangChina

The welding arc,as a carrier for the conversion of electrical energy to thermal energy,has a direct impact on the quality of welding by its properties and *** the tungsten inert gas(TIG)welding process under the condition of Ar-He alternating gas supply,the arc is alternately converted between Ar arc and He arc with an alternating gas supply cycle,which has obvious arc change *** FLUENT software was used to numerically simulate the characteristics of the TIG arc under the condition of alternating gas supply,and the arc temperature field,arc pressure,electric potential and current density distribution under the condition of alternating gas supply were *** with the real-time data of arc pressure measured by the water-cooled copper plate with holes,it is proved that the TIG arc has obvious dynamic characteristics under the condition of Ar-He alternating gas *** unique dynamic TIG arc acts on the 5A06 aluminum alloy weld,causing the molten pool to stir,resulting in uniform microstructure and grain refinement at the weld,and thereby improving the mechanical properties of the welded joint.

关键词： Alternating gas supply Grain refinement Numerical simulation Tungsten argon arc morphology Microstructure Mechanical property

Recent progress in photocatalytic NAD(P)H regeneration for photocatalytic-enzymatic-coupling system

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Frontiers of Chemical Science and Engineering 2024年第4期18卷 1-24页

作者： Wei Lan Maodi Wang Huicong dai Qihua yang Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Zhejiang Key Laboratory for Reactive Chemistry on Solid SurfacesInstitute of Physical ChemistryZhejiang Normal UniversityJinhua 321004China

The enzymatic redox reactions in natural photosynthesis rely much on the participation of cofactors,with reduced nicotinamide adenine dinucleotide/nicotinamide adenine dinucleotide phosphate(NADH/NADPH)or their oxidized form(NAD+/NADP+)as an important redox *** photocatalytic regeneration of expensive and unstable NADH/NADPH in vitro is an important process in enzymatic reduction and has attracted much research *** different types of photocatalysts have been developed for photocatalytic NADH/NADPH regeneration,the efficiency is still relatively *** elucidate the key factors affecting the performance of photocatalytic NADH/NADPH regeneration is helpful to rationally design the photocatalyst and improve the photocatalytic *** this paper,we overview the recent progress in photocatalytic NADH/NADPH regeneration with the focus on the strategies to improve the visible light adsorption,the charge separation and migration efficiency,as well as the surface reaction,which jointly determine the overall photocatalytic regeneration *** potential development of photocatalytic NADH/NADPH regeneration and photocatalyticenzymatic-coupling system is prospected finally.

关键词： photocatalytic-enzymatic coupling NAD(P)H regeneration photocatalysis efficiency