检索结果-南通市图书馆

Intramolecular Hydrogen Bond Improved Durability and Kinetics for Zinc‑Organic Batteries

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano-Micro Letters 2024年第3期16卷 138-148页

作者： Tianjiang Sun Jun Pan Weijia Zhang Xiaodi Jiang Min Cheng Zhengtai Zha Hong jin fan Zhanliang Tao Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Renewable Energy Conversion and Storage CenterCollege of ChemistryNankai UniversityHaihe Laboratory of Sustainable Chemical TransformationsTianjin 300071People’s Republic of China School of Physical and Mathematical Sciences Nanyang Technological UniversitySingapore 637371Singapore Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology School of Physics Science and EngineeringTongji UniversityShanghai 200092People’s Republic of China

Organic compounds have the advantages of green sustainability and high designability,but their high solubility leads to poor durability of zinc-organic batteries.Herein,a high-performance quinone-based polymer(H-PNADBQ)material is designed by introducing an intramolecular hydrogen bonding(HB)strategy.The intramolecular HB(C=O⋯N-H)is formed in the reaction of 1,4-benzoquinone and 1,5-naphthalene diamine,which efficiently reduces the H-PNADBQ solubility and enhances its charge transfer in theory.In situ ultraviolet-visible analysis further reveals the insolubility of H-PNADBQ during the electrochemical cycles,enabling high durability at different current densities.Specifically,the H-PNADBQ electrode with high loading(10 mg cm^(-2))performs a long cycling life at 125 mA g^(-1)(>290 cycles).The H-PNADBQ also shows high rate capability(137.1 mAh g^(−1)at 25 A g^(−1))due to significantly improved kinetics inducted by intramolecular HB.This work provides an efficient approach toward insoluble organic electrode materials.

关键词： Zn-organic batteries H-PNADBQ polymer Intramolecular hydrogen bond Reduced solubility Improvedπ-conjugated level

Asymptomatic low-grade appendiceal mucinous neoplasm:A case report

在线全文

学校读者我要写书评

暂无评论

World Journal of Clinical Cases 2024年第2期12卷 361-366页

作者： Min-Quan Yao Yu-Peng Jiang Yuan-Yu Wang Yi-Ping Mou jin-Xing fan Department of Gastrointestinal Surgery Tongxiang First People’s HospitalJiaxing 314500Zhejiang ProvinceChina Department of General Surgery Zhejiang Provincial People’s HospitalHangzhou 310014Zhejiang ProvinceChina Endoscopy Center Tongxiang First People’s HospitalJiaxing 314500Zhejiang ProvinceChina

BACKGROUND Low-grade appendiceal neoplasms(LAMN)are characterized by low incidence and atypical clinical presentations,often leading to misdiagnosis as acute or chronic appendicitis before surgery.The primary diagnostic tool for LAMN is abdominal computed tomography(CT)imaging.Surgical resection remains the cornerstone of LAMN management,necessitating en bloc tumor excision to minimize the risk of iatrogenic rupture.Laparoscopy,known for its minimal invasiveness,reduced postoperative discomfort,and expedited recovery,is a safe and reliable approach for LAMN treatment.Despite the possibility of pseudomyxoma peritonei development,appendectomy and partial appendectomy generally result in negative tumor margins and favorable outcomes,which can be attributed to the disease’s slow growth and lower malignancy.CASE SUMMARY A 71-year-old male patient was admitted to our hospital with a pelvic spaceoccupying lesion detected 1 mo prior.Physical examination showed a soft abdomen without tenderness or rebound and no palpable masses.No shifting dullness was noted,and digital rectal examination revealed no palpable mass.Enteroscopy revealed a raised,smooth-surfaced mass measuring 3.0 cm in the cecum.Abdominal contrast-enhanced CT showed a markedly thickened and dilated appendix with visible cystic shadows.Laparoscopic surgery was performed and revealed a significantly dilated appendix,leading to laparoscopic resection of the appendix and part of the cecum.Post-surgical pathologic analysis confirmed LAMN.The patient received symptomatic and supportive post-operative care and was discharged on postoperative day 4 without complications such as abdominal bleeding,intestinal obstruction,or incision infection.No tumor recurrence was observed during a 7-mo follow-up period.CONCLUSION LAMN is a rare disease that lacks specific clinical manifestations.Abdominal CT plays a crucial role in diagnosing LAMN,and laparoscopic surgery is a safe and effective diagnostic and therapeutic approach.

关键词： Low-grade appendiceal mucinous neoplasm Pseudomyxoma peritonei Computed tomography Laparoscopy appendectomy Case report

Highly efficient and stable electrocatalyst for hydrogen evolution by molybdenum doped Ni-Co phosphide nanoneedles at high current density

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第3期17卷 1066-1074页

作者： Chengyu Huang Zhonghong Xia jing Wang jing Zhang Chenfei Zhao Xingli Zou Shichun Mu Jiujun Zhang Xionggang Lu Hong jin fan Shengjuan Huo Yufeng Zhao College of Sciences&Institute for Sustainable Energy Shanghai UniversityShanghai 200444China State Key Laboratory of Metastable Materials Science and Technology Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource ReuseYanshan UniversityQinhuangdao 066004China State Key Laboratory of Advanced Special Steel and Shanghai Key Laboratory of Advanced Ferrometallurgy School of Materials Science and EngineeringShanghai UniversityShanghai 200444China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Physical and Mathematical Sciences Nanyang Technological UniversitySingapore639798

There is an increasingly urgent need to develop cost-effective electrocatalysts with high catalytic activity and stability as alternatives to the traditional Pt/C in catalysts in water electrolysis.In this study,microspheres composed of Mo-doped NiCoP nanoneedles supported on nickel foam were prepared to address this challenge.The results show that the nanoneedles provide sufficient active sites for efficient electron transfer;the small-sized effect and the micro-scale roughness enhance the entry of reactants and the release of hydrogen bubbles;the Mo doping effectively improves the electrocatalytic performance of NiCoP in alkaline media.The catalyst exhibits low hydrogen evolution overpotentials of 38.5 and 217.5 mV at a current density of 10 mA·cm^(-2) and high current density of 500 mA·cm^(-2),respectively,and only 1.978 V is required to achieve a current density of 1000 mA·cm^(-2) for overall water splitting.Density functional theory(DFT)calculations show that the improved hydrogen evolution performance can be explained as a result of the Mo doping,which serves to reduce the interaction between NiCoP and intermediates,optimize the Gibbs free energy of hydrogen adsorption(△G_(*H)),and accelerate the desorption rate of *OH.This study provides a promising solution to the ongoing challenge of designing efficient electrocatalysts for high-current-density hydrogen production.

关键词： transition metal phosphides Mo-doped NiCoP hydrogen evolution reaction gradient hydrothermal water splitting

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

量子自注意力神经网络的时间序列预测

电子科技大学学报 2024年第1期53卷 110-118页

作者：陈欣李闯金凡中金金融认证中心有限公司北京100176

在“量子-经典”混合模式下,设计了多头量子自注意力神经网络预测模型(MQSAPN)用以进行时间序列预测,模型包括多头量子自注意力模块以及变分量子线路预测模块两部分。通过对输入数据按时间步长分别进行量子态编码以及K、Q、V的计算,借... 详细信息

在“量子-经典”混合模式下,设计了多头量子自注意力神经网络预测模型(MQSAPN)用以进行时间序列预测,模型包括多头量子自注意力模块以及变分量子线路预测模块两部分。通过对输入数据按时间步长分别进行量子态编码以及K、Q、V的计算,借鉴已有研究使用高斯函数进行自注意力系数的估计方式,将量子自注意力特征提取后的数据再次编码到变分预测线路中,经过线路演化及测量,最终获取预测结果。完整流程与模型搭建均采用VQNet框架实现。在天气学变量的时间序列预测任务中,该模型表现出与经典多头自注意力模型预测模型以及长短期记忆单元网络模型相当的预测精度。此外,相对于同样是量子机器学习的data-reuploading变分线路而言,在近乎同等规模线路深度与参数量的前提下,表现出更高的预测精度,这也进一步验证了引入量子自注意力机制的有效性。值得指出的是,作为预测部分的变分线路会随着输入数据量的增多(如时间窗加长、特征变量规模增加等),其参数量与线路深度也会显著增加,尽管多层QSA能够较好地进行特征表达,但依然有可能因遇到“贫瘠高原”困难而成为整个网络的瓶颈。

关键词：量子计算量子机器学习自注意力机制时间序列预测

在线全文

学校读者我要写书评

暂无评论

农村居民收入分配政策的模拟研究

系统工程理论与实践 2024年第5期44卷 1437-1449页

作者：范金张晓兰胡超南京林业大学经济管理学院南京210037 国家信息中心经济预测部北京100045

党的二十大报告特别强调将追求全体人民共同富裕融入到现代化建设过程中.本文通过构建中国农村居民消费社会核算矩阵,模拟不同分配政策下社会商品和服务消费以及农村居民消费基尼系数的变化,以探寻完善农村居民共同富裕的分配政策有效路... 详细信息

党的二十大报告特别强调将追求全体人民共同富裕融入到现代化建设过程中.本文通过构建中国农村居民消费社会核算矩阵,模拟不同分配政策下社会商品和服务消费以及农村居民消费基尼系数的变化,以探寻完善农村居民共同富裕的分配政策有效路径.研究发现:扩大中等、扶持弱者分配政策不仅能促进社会商品和服务消费增长,而且能将农村居民消费差距控制在合理范围之内,是相对较优选择,而绝对公平、绝对效率分配政策是相对较次选择;政策模拟显示,教育文化和娱乐和医疗保健消费增长幅度最多,食品烟酒消费反而减少,显示有效的分配政策有助于我国农村居民消费升级转型;初次分配制度是促进农村居民共同富裕的主导机制,再分配制度是促进农村居民共同富裕重要手段,第三次分配制度是有益补充.为此,提出政策建议:完善收入分配制度,推进实现共同富裕;缩小居民收入差距,促进农民富裕富足;完善社会保障制度,不断增进民生福祉.

关键词：农村居民共同富裕分配政策社会核算矩阵

在线全文

学校读者我要写书评

暂无评论

新型分离式实心板梁桥全过程受力性能分析

华南理工大学学报（自然科学版） 2024年第1期52卷 38-51页

作者：蒋冬启吴浩范进南京理工大学理学院江苏南京210094

为研究新型分离式实心板梁桥的全过程受力性能,以主梁净距、主梁数目和预应力筋配置情况等为关键参数,基于ABAQUS有限元软件平台对该桥梁体系开展非线性数值分析,探究分离式实心板梁桥从施工、运营到加载破坏的损伤演变及失效模式。结... 详细信息

为研究新型分离式实心板梁桥的全过程受力性能,以主梁净距、主梁数目和预应力筋配置情况等为关键参数,基于ABAQUS有限元软件平台对该桥梁体系开展非线性数值分析,探究分离式实心板梁桥从施工、运营到加载破坏的损伤演变及失效模式。结果表明:主梁破坏与主梁-桥面板组合破坏为分离式实心板梁桥结构的两类主要破坏模式。当主梁净距较小时,全桥各梁变形基本一致,承载能力较高,易发生主梁破坏;反之,主梁净距较大时,桥梁横向传力性能较弱,不同主梁之间存在变形滞后现象,易发生主梁-桥面板组合破坏。对于相近桥宽和跨径的分离式实心板梁桥,主梁间距过大不利于横向协同受力,全桥承载能力会降低约40%~50%;主梁数目较少的桥例可通过增加预应力筋配置数量来改善承载性能,单梁承载力提高幅度可达10%~30%,但预制阶段的上拱问题在设计中应予以重视。与一次浇筑整体式梁桥相比,该组合梁桥体系全过程受力分析所得的位移和应力响应历程有所区别,但极限承载能力差异较小。总体而言,新型分离式实心板梁桥具有良好的承载和变形能力,且自重小、建筑高度低、施工便捷,在国内具有良好的应用前景。

关键词：桥梁工程全过程受力性能损伤演变破坏机理承载性能

在线全文

学校读者我要写书评

暂无评论

《纸质档案抢救与修复规范》解读与思考

北京档案 2024年第3期 33-36页

作者：金凡郑州大学信息管理学院

国家市场监督管理总局、国家标准化管理委员会于2023年3月17日发布《纸质档案抢救与修复规范》(GB/T42468—2023)系列标准,以国家标准的形式来规范和指导我国纸质档案抢救与修复工作。论文对该系列标准的出台背景、显著特点、主要内容... 详细信息

国家市场监督管理总局、国家标准化管理委员会于2023年3月17日发布《纸质档案抢救与修复规范》(GB/T42468—2023)系列标准,以国家标准的形式来规范和指导我国纸质档案抢救与修复工作。论文对该系列标准的出台背景、显著特点、主要内容进行解读,并提出建议。

关键词：纸质档案抢救纸质档案修复工作规范

Research on Integrating Data Assets Into Accounting Discipline System

在线全文

学校读者我要写书评

暂无评论

Journal of Modern Accounting and Auditing 2023年第4期19卷 101-112页

作者： jin fan Northwestern Polytechnical University Xi’anChina

As data is incorporated into production factors,the Accounting discipline should intensively study the new data asset.Starting from the analysis of the value attribute,right attribute,and relationship attribute of the data,it is found that under certain conditions,the data has complete Accounting attributes and can be included in the assets.The Accounting discipline shall establish the research direction of Data Asset Accounting and focus on the research,including the recognition and measurement of data assets,the value evaluation of data assets,information disclosure,and Data Asset Accounting standards.Data assets are facing the major challenge of integrating into the Accounting discipline.We can carry out the Accounting professional reform and textbook construction facing the practice of data assets management from the aspects of theoretical construction,talent training,and industry research cooperation.

关键词： data assets Accounting discipline Accounting attribute

计及时变演化特征的硅泡沫垫层非线性黏弹性模型研究

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

应用数学和力学 2024年第2期45卷 167-174页

作者：范志庚万强牛红攀靳凡中国工程物理研究院总体工程研究所四川绵阳621900

基于黏弹性基本理论,引入材料非线性特征,考虑了材料加载、保载应力松弛历史、老化效应以及黏弹性模型各运动单元退化的差异性,并从两种老化机制出发,获得了老化硅泡沫垫层力学模型以及长时应力松弛硅泡沫垫层接续加载力学模型.模型机... 详细信息

基于黏弹性基本理论,引入材料非线性特征,考虑了材料加载、保载应力松弛历史、老化效应以及黏弹性模型各运动单元退化的差异性,并从两种老化机制出发,获得了老化硅泡沫垫层力学模型以及长时应力松弛硅泡沫垫层接续加载力学模型.模型机理清晰,能够反映材料服役历史信息及其对力学效应的影响.

关键词：硅泡沫垫层非线性黏弹性应力松弛老化力学模型