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Frontiers of Chemical Science and Engineering 2024年第2期18卷 69-81页

作者： Zulfiqar Ali jiliang ma Dongnv Jin Rui Cui Runcang Sun Liaoning Key Lab of Lignocellulose Chemistry and Biomaterials Liaoning Collaborative Innovation Center for Lignocellulosic BiorefineryCollege of Light Industry and Chemical EngineeringDalian Polytechnic UniversityDalian 116034China

The use of functional materials such as carbon-bismuth oxyhalides in integrated photorefineries for the clean production of fine chemicals requires restructuring.A facile biomass-assisted solvothermal fabrication of carbon/bismuth oxychloride nanocomposites(C/BiOCl)was achieved at various *** with BiOCl and C/BiOCl-120,C/BiOCl-180 exhibited higher crystallinity,wider visible light absorption,and a faster migration/separation rate of photoinduced *** the selective C–C bond cleavage of biomass-based feedstocks photocatalyzed by C/BiOCl-180,the xylose conversion and lactic acid yield were 100%and 92.5%,respectively.C/BiOCl-180 efficiently converted different biomass-based monosaccharides to lactic acid,and the efficiency of pentoses was higher than that of ***,lactic acid synthesis was favored by all active radicals including superoxide ion(·O_(2)^(−)),holes(h^(+)),hydroxyl radical(·OH),and singlet oxygen(^(1)O_(2)),with·O_(2)^(−)playing a key *** fabricated photocatalyst was stable,economical,and *** use of biomass-derived monosaccharides for the clean production of lactic acid via the C/BiOCl-180 photocatalyst has opened new research horizons for the investigation and application of C–C bond cleavage in biomass-based feedstocks.

关键词： carbon-carbon bond cleavage biomass reforming C/BiOCl lactic acid photocatalysis

Particle residence time distribution and axial dispersion coefficient in a pressurized circulating fluidized bed by using multiphase particle-in-cell simulation

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Chinese Journal of Chemical Engineering 2024年第5期69卷 167-176页

作者： Jinnan Guo Daoyin Liu jiliang ma Cai Liang Xiaoping Chen Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education Southeast UniversityNanjing 210096China

The particle residence time distribution(RTD)and axial dispersion coefficient are key parameters for the design and operation of a pressurized circulating fluidized bed(PCFB).In this study,the effects of pressure(0.1-0.6 MPa),fluidizing gas velocity(2-7 m·s^(-1)),and solid circulation rate(10-90 kg·m^(-2)·s^(-1))on particle RTD and axial dispersion coefficient in a PCFB are numerically investigated based on the multiphase particle-in-cell(MP-PIC)*** details of the gas-solid flow behaviors of PCFB are *** on the gas-solid flow pattern,the particles tend to move more orderly under elevated *** an increase in either fluidizing gas velocity or solid circulation rate,the mean residence time of particles decreases while the axial dispersion coefficient *** an increase in pressure,the core-annulus flow is strengthened,which leads to a wider shape of the particle RTD curve and a larger mean particle residence *** back-mixing of particles increases with increasing pressure,resulting in an increase in the axial dispersion coefficient.

关键词： Pressurized circulating fluidized bed MP-PIC method Residence time distribution Axial dispersion coefficient

流化床喷雾浸渍制备负载型钠基CO_(2)吸附剂脱碳性能

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化工进展 2024年第6期43卷 2961-2967页

作者：智远马吉亮陈晓平刘道银梁财东南大学能源与环境学院江苏南京210096

针对传统钠基CO_(2)固体吸附剂晶粒尺寸大、气体扩散阻力高、负载量有限导致的吸附量低的瓶颈问题,提出了基于流化床喷雾浸渍技术的吸附剂制备新方法。选取γ-Al_(2)O_(3)为载体,高纯度Na_(2)CO_(3)作为活性组分,利用溶液浸渍法和流化... 详细信息

针对传统钠基CO_(2)固体吸附剂晶粒尺寸大、气体扩散阻力高、负载量有限导致的吸附量低的瓶颈问题,提出了基于流化床喷雾浸渍技术的吸附剂制备新方法。选取γ-Al_(2)O_(3)为载体,高纯度Na_(2)CO_(3)作为活性组分,利用溶液浸渍法和流化床喷雾浸渍法分别制备了载体结构、活性组分负载量不同的多组吸附剂,并基于固定床实验装置结合比表面积和孔隙度分析仪、X射线衍射仪、扫描电子显微镜、X射线荧光光谱分析等手段对吸附剂的CO_(2)吸附性能以及孔隙结构、晶型、表面形态及负载量等关键参数进行表征。研究结果表明,相同活性组分负载量下,采用喷雾浸渍法制备的吸附剂的饱和吸附量和吸附活性皆优于传统浸渍法,其原因在于该方法可以控制活性组分在载体上的负载深度;同时,活性组分多为针状或棒状等利于反应的形态结晶;晶体尺寸较传统溶液浸渍法普遍小10%~20%。尽管如此,载体的孔隙结构,具体如比表面积和孔径分布等参数仍会限制流化床喷雾浸渍技术制备的吸附剂的反应性能。

关键词：二氧化碳捕集吸附剂碳酸钠喷雾浸渍流化床

Influence of cycle time distribution on coating uniformity of particles in a spray fluidized bed by using CFD-DEM simulations

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Particuology 2023年第5期76卷 151-164页

作者： Heng Li Daoyin Liu jiliang ma Xiaoping Chen Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education School of Energy&EnvironmentSoutheast UniversityNanjing210096China

Cycle Time Distribution(CTD)plays a critical role for determining uniformity of particle coating in spray fluidized ***,the CTD is influenced by both geometrical structure and operating conditions of fluidized *** this study,a spray fluidized bed of coating process is simulated by a comprehensive Computational Fluid Dynamics-Discrete Element Model(CFD-DEM).To achieve different behaviors of CTD,some modifications are designed on a pseudo-2D internally circulating fluidized bed,which traditionally composes of a high-velocity upward bed and low-velocity downward *** modifi-cations include making the air distributor slope and/or laying a baffle in the downward ***,the CTD and evolution of particle size distribution under different bed structures are *** CTD directly influences the coating *** making the particles flowing along a parallel direction in the downward bed through the geometrical modifications,the CTD becomes narrower and the coating uniformity is significantly ***,under the optimized bed structure,the influence of oper-ating conditions on the coating uniformity is *** increasing the fluidization gas velocity and the fluidization gas temperature and reducing the liquid spray rate can improve the coating uniformity.

关键词： Spray fluidized bed Particle coating Cycle time distribution CFD-DEM

Equilibrium charge and triboelectric coefficient of spheres in a rotating container

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Particuology 2022年第4期20卷 103-111页

作者： Jiawei Hu Cai Liang Qun Zhou jiliang ma Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education School of Energy and EnvironmentSoutheast UniversityNanjing 210096China

Contact electrification occurs in many granular material systems due to particle-particle and particle-wall *** this paper,we used a simple device to characterize the electrification of different spheres in a rotating spherical *** charge of the spheres was quantified by a Faraday cup after rotating for various time and the disperse behaviors of charged spheres were recorded by a *** effects of the rotational time,sphere size,rotational speed,sphere material,and relative humidity on the equilibrium charge and triboelectric coefficient were *** results show that the equilibrium surface charge density is independent of the sphere size and the rotating speed,whereas the larger rotating speed enhances the triboelectric *** is also shown that charge relaxation constants are two orders of magnitude lower than the charge generation constants for all spheres at a low relative *** increase of water molecules in the air was found to result in the decline of charge generation constant and the rise of charge relaxation constant,which together cause the decrease of the equilibrium surface charge density.

关键词： Particle charging Equilibriurm charge Charge relaxation Charge generation Electrostatics

Cuprous oxide/copper oxide interpenetrated into ordered mesoporous cellulose-based carbon aerogels for efficient photocatalytic degradation of methylene blue

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Frontiers of Chemical Science and Engineering 2023年第7期17卷 918-929页

作者： Rui Cui Dongnv Jin Gaojie Jiao Zhendong Liu jiliang ma Runcang Sun Liaoning Key Lab of Lignocellulose Chemistry and Biomaterials Liaoning Collaborative Innovation Center for Lignocellulosic BiorefineryCollege of Light Industry and Chemical EngineeringDalian Polytechnic UniversityDalian 116034China

The casual discharge of dyes from industrial settings has seriously polluted global water *** to the abundance of biomass resources,preparing photocatalysts for photocatalytic degradation of dyes is significant;however,it still remains *** this work,a cuprous oxide/copper oxide composite was interpenetrated onto carbon nanosheets of cellulose-based flexible carbon aerogels(Cu_(2)O/CuO@CAx)via a simple freeze-drying-calcination *** introduction of the carbon aerogel effectively prevents the aggregation of the cuprous oxide/copper oxide *** addition,Cu_(2)O/CuO@CA0.2 has a larger specific surface area,stronger charge transfer capacity,and lower recombination rate of photogenerated carriers than copper ***,Cu_(2)O/CuO@CA0.2 exhibited high photocatalytic activity in decomposing methylene blue,with a degradation rate reaching up to 99.09% in 60 *** active oxidation species in the photocatalytic degradation process were systematically investigated by electron spin resonance characterization and poisoning experiments,among which singlet oxygen played a major *** conclusion,this work provides an effective method for preparing photocatalysts using biomass resources in combination with different metal *** also promotes the development of photocatalytic degradation of dyes.

关键词： carbon aerogel photocatalysis dye degradation biomass cuprous oxide copper oxide

Operando modeling and measurements:Powerful tools for revealing the mechanism of alkali carbonate-based sorbents for CO_(2)capture in real conditions

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Frontiers in Energy 2023年第3期17卷 380-389页

作者： Tianyi CAI Mengshi WANG Xiaoping CHEN Ye WU jiliang ma Wu ZHOU School of Energy and Power Engineering Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power EngineeringUniversity of Shanghai for Science and TechnologyShanghai 200093China Key Laboratory of Energy Thermal Conversion and Control of the Ministry of Education School of Energy and EnvironmentSoutheast UniversityNanjing 210096China Key Laboratory of Thermal Control of Electronic Equipment and Advanced Combustion Laboratory of the Ministry of Industry and Information Technology School of Energy and Power EngineeringNanjing University of Science and TechnologyNanjing 210094China

Alkalicarbonate-based sorbents(ACSs),including Na_(2)CO_(3)-and K2CO_(3)-based sorbents,are promising for CO_(2)***,the complex sorbent components and operation conditions lead to the versatile kinetics of CO_(2)sorption on these *** paper proposed that operando modeling and measurements are powerful tools to understand the mechanism of sorbents in real operating conditions,facilitating the sorbent development,reactor design,and operation parameter *** reviewed the theoretical simulation achievements during the development of *** elucidated the findings obtained by utilizing density functional theory(DFT)calculations,ab initio molecular dynamics(AIMD)simulations,and classical molecular dynamics(CMD)simulations as *** hygroscopicity of sorbent and the humidity of gas flow are crucial to shifting the carbonation reaction from the gas-solid mode to the gas-liquid mode,boosting the ***,it briefly introduced a machine learning(ML)approach as a promising method to aid sorbent ***,it demonstrated a conceptual compact operando measurement system in order to understand the behavior of ACSs in the real operation *** proposed measurement system includes a micro fluidizedbed(MFB)reactor for kinetic analysis,a multi-camera sub-system for 3D particle movement tracking,and a combined Raman and IR sub-system for solid/gas components and temperature *** is believed that this system is useful to evaluate the real-time sorbent performance,validating the theoretical prediction and promoting the industrial scale-up of ACSs for CO_(2)capture.

关键词： CO_(2)capture carbonation theoretical modeling operando techniques reaction visualization

Experimental and Modelling Study on Emission of Volatile Nitrogen Derived NO during Pressured Oxy-fuel Combustion under Wet Flue Gas Environment

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Journal of Thermal Science 2023年第5期32卷 1750-1757页

作者： ZAN Haifeng CHEN Xiaoping PAN Suyang GENG Pengfei LIU Daoyin ma jiliang LIANG Cai Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education School of Energy&EnvironmentSoutheast UniversityNanjing 210096China

Pressurised oxy-fuel combustion(POFC)is a clean and efficient combustion technology with great *** to the recycling of flue gas,the concentration of steam in the flue gas is higher than that of conventional combustion,which enriches the free radical pool in the flue gas and thus affects the emission of gaseous ***,further research into the effect of high steam concentrations on NO_(x)emission mechanisms in POFC is *** this work,a fixed-bed reactor was used to conduct combustion experiments of volatiles and combined with chemical kinetic models to study the NO release characteristics for different pressures and steam concentrations in an O_(2)/CO_(2)atmosphere at 800℃/900℃*** results of the study indicated that the volatile nitrogen comes from the pyrolysis of part of pyrrole,pyridine,and all quaternary nitrogen in *** increase in temperature promoted the formation of NO during *** pressure affects the main reaction pathway for NO formation,promoting NO consumption by HCCO and C_(2)O groups while enhancing the overall NO *** promoted NO consumption by *** addition,steam increased the amount of H/OH groups during the reaction,which affected both NO formation and ***,from the overall effect,the steam still inhibits the emission of NO.

关键词： pressurized oxy-fuel combustion steam volatile nitrogen NO emission

Bubbling behavior of cohesive particles in a two-dimensional fluidized bed with immersed tubes

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Particuology 2017年第2期15卷 152-160页

作者： jiliang ma Daoyin Liu Xiaoping Chen Key Laboratory of Energy Thermal Conversion and Control of Ministry of Educotion School of Energy and Environment Southeast University Nanjing 210096 China

Fluidization hydrodynamics are greatly influenced by inter-particle cohesive forces. This paper studies the fluidization of large cohesive particles in a two-dimensional fluidized bed with immersed tubes using “polymer coating” to introduce cohesive force, to gain better understanding of bubbling behavior when particles become cohesive and its effect on chemical processes. The results show that the cohesive force promotes bubble splitting in the tube bank region, thereby causing an increase in the number and a decline in the aspect ratio of the bubbles. As the cohesive force increases within a low level, the bubble number increases and the bubble diameter decreases, while the aspect ratio exhibits different trends at different fluidization gas velocities. The difference in the evolution of bubble size under various cohesive forces mainly takes place in the region without tubes. When the cohesive force is large enough to generate stable agglomerates on the side walls of the bed, the bubble number and the bed expansion sharply decrease. The tubes serve as a framework that promotes the agglomeration, thus accelerating defluidization. Finally, the bubble profile around tubes was studied and found to greatly depend both on the cohesive forces and the location of tubes.

关键词： Fluidized bed Cohesive particle Immersed tube Bubble behavior

Oxygen-doped Carbon Nitride Nanocages with Efficient Photon-to-Electron Conversion for Selective Oxidation of Xylose/Xylan to Yield Xylonic Acid

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Paper And Biomaterials 2023年第2期8卷 53-65页

作者： Junqiang Zhang Zhuoyan Xie Zulfiqar Ali Ning Li Qimeng Liu Wenyue Fan jiliang ma Runcang Sun Liaoning Key Lab of Lignocellulose Chemistry and Biomaterials Liaoning Collaborative Innovation Center for Lignocellulosic BiorefineryCollege of Light Industry and Chemical EngineeringDalian Polytechnic UniversityDalianLiaoning Province116034China

Highly efficient photon-to-electron conversion is crucial for achieving photocatalytic *** this study,oxygen-doped carbon nitride nanocages(O@CNNCs)were engineered via dual strategies of morphology-controlled heteroatom doping,which was successfully used in the photocatalytic selective oxidation of xylose/xylan to xylonic *** nanocage-shaped O@CNNCs had a larger surface area,which was 4.02 times of carbon nitride(CN).Furthermore,with the assistance of morphology regulation and O-doping,O@CNNCs exhibit highly efficient photon-to-electron conversion,enhanced visible-light utilization,high photocurrent,low resistance,and fast separation/migration of electron-hole ***,the photocatalytic oxidation of xylose to xylonic acid using O@CNNCs was successfully achieved under mild reaction conditions with a yield of 83.4%.O@CNNCs have excellent recyclability,in which the yield of xylonic acid in the 5th cycle was 98.2%of its initial *** O@CNNC photocatalytic system was also suitable for macromolecular xylan,and a xylonic acid yield of 77.34 mg was obtained when 100 mg xylan was *** oxidation-active species captured experiments indicated that holes were crucial for the selective oxidation of xylose to xylonic ***,this study provides a new strategy for the preparation of photocatalysts with excellent photon-to-electron conversion and selective oxidation of biomass-derived feedstocks to xylonic acid.

关键词： photon-to-electron conversion morphology regulation oxygen doping selective oxidation xylonic acid