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Physicochemical principles of hydrogen metallurgy in blast furnace

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Journal of Iron and Steel Research International 2024年第1期31卷 46-63页

作者： han-jie Guo School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing100083China Beijing Key Laboratory of Special Melting and Preparation of High-End Metal Materials Beijing100083China

Based on the stoichiometric method and the free energy minimization method,an ideal model for the reduction of iron oxides by carbon and hydrogen under blast furnace conditions was established,and the reduction efficiency and theoretical energy consumption of the all-carbon blast furnace and the hydrogen-rich blast furnace were *** results show that after the reduction reaction is completed at the bottom of the blast furnace,the gas produced by reduction at 1600℃still has a certain excessive reduction capacity,which is due to the hydrogen brought in by the hydrogen-rich blast as well as the excess carbon monoxide generated by the reaction of the coke and the oxygen brought in by the *** the process of the gas with excessive reduction capacity rising from the bottom of the blast furnace and gas reduction process,the excessive reduction capacity of the gas gradually decreases with the increase in the dydrogen content in the *** the all-carbon blast furnace,the excess gas reduction capacity is the strongest,and the total energy consumption per ton of iron reduction is the *** shows that,for the current operation mode of the blast furnace,adding hydrogen in the blast furnace cannot reduce the consumption of carbon required for reduction per ton of iron,but rather increases the consumption of carbon.

关键词： Hydrogen metallurgy Excess gas reduction capacity Theoretical energy consumption Hydrogen-rich blast furnace Thermodynamic model Gibbs minimum free energy method

Geosynthetics used to stabilize vegetated surfaces for environmental sustainability in civil engineering

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Frontiers of Structural and Civil Engineering 2017年第1期11卷 56-65页

作者： jie han Jun GUO Department of Civil Environmental and Architectural Engineering the University of Kansas Lawrence KS 66044 USA

Geosynthetics, factory-manufactured polymer materials, have been successfully used to solve many geotechnical problems in civil engineering. Two common applications are earth stabilization and erosion control. Geosynthetics used for earth stabilization include but are not limited to stabilized slopes, walls, embankments, and roads. Geosynthetics used for erosion control are mostly related to slopes, river channels and banks, and pond spillways. To enhance environmental sustainability, vegetation has been increasingly planted on the facing or surfaces of these earth structures. Under such a condition, geosynthetics mainly function as surficial soil stabilization while vegetation provides green appearance and erosion protection of earth surfaces. Recently, geosynthetic or geosynthetic-like material has been used to form green walls outside or inside buildings to enhance sustainability. Geosynthetics and vegetation are often integrated to provide combined benefits. The interaction between geosynthetics and vegetation is important for the sustainability of the earth and building wall surfaces. This paper provides a review of the current practice and research in the geosynthetic stabilization of vegetated earth and building surfaces for environmental sustainability in civil engineering with the emphases on geosynthetic used for erosion protection, geosynthetic-stabilized slopes, geosynthetic-stabilized unpaved shoulders and parking lots, and geosynthetic-stabilized vegetated building surfaces.

关键词： erosion geosynthetic stabilization sustainability vegetation

Wheel tracking methods to evaluate moisture sensitivity of hot-mix asphalt mixtures

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Frontiers of Structural and Civil Engineering 2016年第1期10卷 30-43页

作者： jie han Harihar Shiwakoti Department of Civil Environmental and Architectural Engineering the University of Kansas Lawrence KS 66044 USA Virginia Department of Transportation 1401 E. Broad St. Richmond VA 23219 USA

Existing test methods to determine moisture sensitivity in hot-mix asphalt （HMA） mixtures are time consuming and inconsistent. This research focused on wheel tracking devices to evaluate moisture sensitivity. The Asphalt Pavement Analyzer （APA） and the Hamburg Wheel Tracking Device （HWTD） were used for this research. Compacted cylindrical samples were fabricated using a Superpave Gyratory compactor. This study selected two most commonly used mixtures, SM-12.5A with PG 64-22 binder in overlay projects and SM-19A mixtures with PG 64-22 binder for major modification projects at Kansas Department of Transportation. Test results show that APA tests could induce stripping in most samples without any anti-stripping agent, which could be identified visually. However, APA results did not indicate any stripping inflection point while the HWTD results showed stripping inflection points, which are important to identify stripping potential of mixtures. The APA results show that wet tests are severe at lower temperatures. The HWTD results show improvement in the performance using anti-stripping agents at later stage. The HWTD test is more effective as a rapid test method in case of determining moisture sensitivity. Laboratory results from this study should be verified and correlated with field performance.

关键词： hot-mix asphalt moisture sensitivity rutting wheel tracking test

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A short review of antibacterial Cu-bearing stainless steel:antibacterial mechanisms,corrosion resistance,and novel preparation techniques

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Journal of Iron and Steel Research International 2024年第1期31卷 24-45页

作者： Shuai Liu han-jie Guo School of Artificial Intelligence Beijing Technology and Business UniversityBeijing100048China Beijing Key Laboratory of Special Melting and Preparation of High-End Metal Materials University of Science and Technology BeijingBeijing100083China

Cu-bearing stainless steel is widely used in the fields of food,medical and household sanitary equipment because of its surface finish and corrosion ***,the growth of bacteria on stainless steel leads to the formation of biofilms,which causes ***,the antibacterial property of stainless steel is a worthy research *** of breakthroughs in the field of corrosion resistance and antimicrobial properties are still ***,due to the scarcity of publications on the antibacterial mechanisms and processing methods of antibacterial Cu-bearing stainless steel,we review the current state of relevant research and *** toxicity of Cu,corrosion resistance mechanism of stainless steel,and antibacterial mechanism and preparation method of antibacterial stainless steel are *** addition,alloying,surface modification and other methods are found to have limitations in balancing the toxicity and antibacterial properties of copper and the relationship between the antibacterial properties and corrosion resistance of Cu-bearing stainless steel.A new preparation method of antibacterial stainless steel associated with selective laser melting(SLM)is *** is becoming a powerful additive manufacturing technology that can be used to manufacture customized and complex *** research status of SLM applied in antibacterial stainless steel preparation is ***,the future research direction of Cu-bearing antibacterial stainless steel is discussed.

关键词： Cu-bearing stainless steel Antibacterial Processing Additive manufacturing Corrosion resistance

雨课堂结合CBL教学模式在中医骨伤科的应用

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中国中医药现代远程教育 2025年第2期23卷 36-38页

作者：宋春霖韩杰广西中医药大学瑞康临床医学院广西南宁530001 广西中医药大学附属瑞康医院关节科广西南宁530011

目的探索中医骨科临床教学运用雨课堂结合基于案例的学习(CBL)教学模式的效果。方法选取广西中医药大学中医骨伤科2021级108名本科生,以随机编号的方式分为实验组和对照组,每组54人。实验组应用雨课堂结合CBL教学法,对照组应用传统教学... 详细信息

目的探索中医骨科临床教学运用雨课堂结合基于案例的学习(CBL)教学模式的效果。方法选取广西中医药大学中医骨伤科2021级108名本科生,以随机编号的方式分为实验组和对照组,每组54人。实验组应用雨课堂结合CBL教学法,对照组应用传统教学模式,两组授课教师和教材均相同。教学结束后,比较两组考核成绩及教学满意度。结果实验组考核成绩及满意度调查评分均高于对照组,差异均有统计学意义(P<0.05)。结论雨课堂结合CBL教学模式是一种能够有效提高中医骨伤科课堂参与度,激发学生学习兴趣,提升学生综合能力的方法。

关键词：雨课堂案例教学法中医骨伤科临床教学远程网络教学

Recent advances in geosynthetic-reinforced retaining Nails for highway applications

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Frontiers of Structural and Civil Engineering 2018年第2期12卷 239-247页

作者： jie han Yan JIANG Chao XU Department of Civil Environmental and Architectural Engineering University of Kansas Lawrence KS 66044 USA Terracon Consultants Inc. 2201 Rowland Ave Savannah Georgia 31404 USA Department of Geotechnical Engineering College of Civil Engineering Tongji University Shanghai 200092 China

Geosynthetic-reinforced retaining （GRR） walls have been increasingly used to support roadways and bridge abutments in highway projects. In recent years, advances have been made in construction and design of GRR walls for highway applications. For example, piles have been installed inside GRR walls to support bridge abutments and sound barrier walls. Geosynthetic layers at closer spacing are used in GRR walls to form a composite mass to support an integrated bridge system. This system is referred to as a geosynthetic-reinforced soil （GRS）-integrated bridge systems （IBS） or GRS-IBS. In addition, short geosynthetic layers have been used as secondary reinforcement in a GRR wall to form a hybrid GRR wall （HGRR wall） and reduce tension in primary reinforcement and facing deflections. These new technologies have improved performance of GRR walls and created more economic solutions; however, they have also created more complicated problems for analysis and design. This paper reviews recent studies on these new GRR wall systems, summarizes key results and findings including but not limited to vertical and lateral earth pressures, wall facing deflections, and strains in geosynthetic layers, discusses design aspects, and presents field applications for these new GRR wall systems.

关键词： bridge geosynthetic highway reinforced wall

Thermodynamic and experimental study of high-temperature roasting of blast furnace gas ash for recovery of metallic zinc and iron

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Journal of Iron and Steel Research International 2024年第1期31卷 108-120页

作者： Zi-han Wang Jing Guo han-jie Guo Bin Li School of Metallurgical Engineering University of Science and Technology BeijingBeijing100083China School of Metallurgical Engineering Xi’an University of Architecture and TechnologyXi’an710055ShaanxiChina

A high-temperature reduction roasting method was used to achieve metallic iron and zinc recovery from blast furnace gas ash(BFA).The reduction processes for Zn-containing and Fe-containing oxides were analyzed in detail by using ther-modynamic equilibrium calculation and the principle of minimum free *** results showed that the main reaction in the system is the reduction of ZnFe_(2)_(4)and iron *** the full temperature range,iron oxides were more easily reduced than zinc *** of the amount of CO contained in the system,the reduction of ZnO to Zn was difficult to proceed below the boiling point(906℃)of *** the reduction temperature is below 906℃,the reduction process of zinc ferrate was ZnFe_(2)_(4)→ZnO;when the reduction temperature is above 906℃,its reduction process becomed ZnFe_(2)_(4)→ZnO→Zn(g).The metallization and dezincification rates of the BFA gradually increased with increasing reaction *** the C/O ratio increased,the metallization and dezincification rates first increased and then *** effect of reduction time on BFA reduction was similar to that of reaction temperature.

关键词： Blast furnace gas ash Thermodynamics Zinc removal Iron reduction High-temperature reduction roasting Integrated utilization

中药调控成骨细胞铁死亡治疗激素性股骨头坏死

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中国组织工程研究 2025年第1期29卷 185-192页

作者：张绵钰韩杰曾浩陈相汕高振罡广西中医药大学研究生学院广西壮族自治区南宁市530000 广西中医药大学附属瑞康医院广西壮族自治区南宁市530011

背景:有研究发现成骨细胞铁死亡可作为重要的发病机制诱导激素性股骨头坏死的发生与发展。随着祖国医学的发展,有学者发现某些中药单体、中药复方及中成药等可通过多种通路机制调控成骨细胞铁死亡,最终起到治疗激素性股骨头坏死的作用... 详细信息

背景:有研究发现成骨细胞铁死亡可作为重要的发病机制诱导激素性股骨头坏死的发生与发展。随着祖国医学的发展,有学者发现某些中药单体、中药复方及中成药等可通过多种通路机制调控成骨细胞铁死亡,最终起到治疗激素性股骨头坏死的作用。目的:探讨成骨细胞铁死亡与激素性股骨头坏死的关系及中草药调控成骨细胞铁死亡治疗激素性股骨头坏死的作用机制,为激素性股骨头坏死的诊治提供新的思路。方法:以“铁死亡,激素性股骨头坏死,成骨细胞,中草药,糖皮质激素,铁代谢,活性氧,谷胱甘肽过氧化物酶”为中文检索词,以“ferroptosis,Hormonal necrosis of the femoral head,osteoblast,Chinese herbal medicine,glucocorticoid,iron metabolism,ROS,GPX4”为英文检索词,检索中国知网、Pub Med、万方及维普数据库,筛选各数据库建库至2023年成骨细胞铁死亡与激素性股骨头坏死及中草药干预调控研究相关的文章,最终纳入74篇文献进行综述分析。结果与结论:(1)成骨细胞铁死亡在激素性股骨头坏死发病中起重要作用。(2)成骨细胞铁死亡的发生受到多种机制通路调控,如细胞内铁超载引起铁死亡;细胞发生脂质过氧化损伤细胞膜引起铁死亡;细胞膜上胱氨酸/谷氨酸逆向转运蛋白通过影响谷胱甘肽水平和谷胱甘肽过氧化物酶4活性,从而诱导铁死亡;细胞内发生芬顿反应产生大量活性氧引起铁死亡等。(3)中药单体淫羊藿苷等、中药复方青娥丸等及中成药补肾活血颗粒等均可通过调控成骨细胞铁死亡的发生,有助于防治激素性股骨头坏死。(4)目前关于成骨细胞铁死亡相关机制尚不明确,继续深入探明两者的作用机制,有望为临床治疗激素性股骨头坏死提供新选择。

关键词：股骨头坏死铁死亡中医药成骨细胞糖皮质激素铁代谢活性氧谷胱甘肽谷胱甘肽过氧化物酶脂质过氧化

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Flow hydrogen absorption of LaFe_(10.9)Co_(0.8)Si_(1.3) compound under constant low hydrogen gas pressure

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Rare Metals 2018年第3期37卷 243-248页

作者： Bin Fu Jun He jie han jie Hu Li-Wei Pang Tianjin Key Laboratory for Photoelectric Materials & Devices School of Materials Science and EngineeringTianjin University of Technology Division of Functional Material Research Central Iron and Steel Research Institute College of Science Tianjin University of Technology School of Materials Science and Engineering Shijiazhuang Tiedao University

The hydrogen absorption of the LaFe（10.9）-Co（0.8）Si（1.3） compound under constant 1.01 × 10-5 Pa H2 gas in a flow hydrogen atmosphere was studied. The effects of hydrogen absorption on structure, Curie temperature, phase transition and magnetic property were investigated by X-ray diffraction（XRD）, differential scanning calorimeter（DSC） and superconducting quantum interference device,respectively. The hydrides of LaFe（10.9）Co（0.8）Si（1.3） crystallize into NaZn（13）-type structural phase after hydrogen absorption at temperature from 548 to 623 K. Lower hydrogen absorption temperature is of no advantage for pure 1：13 phase formation in a flow H2 atmosphere. The Curie temperature（TC） of LaFe（10.9）Co（0.8）Si（1.3） compound increases by70 K or more after hydrogen absorption. For LaFe（10.9）-Co（0.8）Si（1.3）H（1.8） compound, the maximum magnetic entropy change and the relative cooling power under a magnetic field change of 0-2 T are 6.1 J·kg^-1·K^-1 and 170 J·kg^-1,respectively. Large refrigerant capacity, low hysteresis loss and wide temperature span of magnetic entropy change peak make it a competitive practical candidate for magnetic refrigerant.

关键词： La(FexSi1-x)13 compounds Magnetic refrigerant Hydrogen absorption Magnetic entropy change

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