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Regulating intramolecular hydrogen bonds of p-phenylenediimidazole-based small-molecule compounds towards the enhanced lithium storage capacity

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Journal of Energy Chemistry 2024年第9期96卷 406-413页

作者： Liping Zheng Bei Wang jianze zhang Wenjie Zhou Jiayi Ren Huige Ma Rui Li Chengming Li Mingjun Hu Jun Yang Institute for Advanced Materials and Technology University of Science and Technology BeijingBeijing 100083China Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of SciencesBeijing 101400China College of Chemistry Nankai UniversityTianjin 300071China School of Materials Science and Engineering Beihang UniversityBeijing 100191China ShenSi Lab Shenzhen Institute for Advanced StudyUniversity of Electronic Science and Technology of ChinaShenzhen 518110GuangdongChina

The use of redox-active organic electrode materials in energy storage is restricted due to their inferior solvent resistance,abysmal conductivity,and the resultant low practical *** address these issues,a class of bipolar p-phenylenediimidazole-based small-molecule compounds are designed and ***π-conjugated backbone of these small molecules allows for electron delocalization on a big conjugation plane,endowing them with good conductivity and reaction ***,when the para-positions of phenylene are occupied by hydroxyl groups,as-formed intramolecular hydrogen bonds(N-H...O)between phenolic hydroxyl groups and the–NH groups of imidazole rings further enhance the structural planarity,resulting in higherπ-conjugation degree and better conductivity,and thus higher utilization of active sites and electrode capacity,proved by both experimental results and theoretical *** optimized composite electrode DBNQ@rGO-45 shows a high specific capacity(∼308 mA h g^(−1)at 100 mA g^(−1))and a long cycling stability(112.9 mA h g^(−1)after 6000 cycles at 2000 mA g^(−1)).The significantly better electrochemical properties for hydroxyl group-containing compounds than those without hydroxyl groups attributed to intramolecular hydrogen bond-induced conjugation enhancement will inspire the structure design of organic electrodes for better energy storage.

关键词： Bipolar P-phenylenedimidazole Intramolecular hydrogenbonds Planarity and conjugationd egree High capacity

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水微液滴气–液界面单电子介导的氧化还原过程

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中国科学：化学 2024年第1期54卷 59-72页

作者：金水慧朱乘慧张鉴泽张新星南开大学化学学院天津300071

水通常被认为是一种稳定的溶剂,然而当把水分散成微米级大小的微液滴后,其将展现出许多独特的性质.这些性质中最引人注目的就是微液滴表面自发形成的高达10^(9)V m^(-1)的电场,该电场能够将水中的氢氧根离子或其他闭壳层分子中的电子撕... 详细信息

水通常被认为是一种稳定的溶剂,然而当把水分散成微米级大小的微液滴后,其将展现出许多独特的性质.这些性质中最引人注目的就是微液滴表面自发形成的高达10^(9)V m^(-1)的电场,该电场能够将水中的氢氧根离子或其他闭壳层分子中的电子撕扯出来,生成自由基和电子,从而进一步触发氧化还原反应.本文综述了40余种单电子介导水微液滴表面自发的氧化还原反应并讨论了相应的反应动力学,论证了此类反应的本质是以电子作为“载流子”的过程.最后,结合合成化学和大气化学的背景,我们对微液滴的氧化还原能力的潜在且广泛的影响进行了讨论和展望.

关键词：微液滴气–液界面质谱氧化还原反应气溶胶

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电光源检测中心的设计与建设

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城市照明 2024年第1期28卷 8-10页

作者：钱伟张舰铎陈柏羽李靖秦大为无锡照明股份有限公司 214028 盐城师范学院信息工程学院 224002 盐城师范学院电光源检测技术研究所 224002

本文主要介绍了作为城市照明管理部门,为了满足户外道路照明施工质量的现场验收需要,同时也具备本单位对所采购的电光源、灯具及配套电器的使用性能和安全性能的检测工作需要,对所配置的电光源检测中心的设计思想与建设方案以及主要检... 详细信息

本文主要介绍了作为城市照明管理部门,为了满足户外道路照明施工质量的现场验收需要,同时也具备本单位对所采购的电光源、灯具及配套电器的使用性能和安全性能的检测工作需要,对所配置的电光源检测中心的设计思想与建设方案以及主要检测仪器介绍与检测中心平面布置图。

关键词：光源检测中心仪器配置现场检测室内检测平面布置图

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基于PMF模型的吉木萨尔县土壤重金属空间分布特征与来源解析

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新疆大学学报（自然科学版中英文） 2024年第3期41卷 354-363,374页

作者：张锦明张建泽王洲瑜汪世轩赵东阳阿不都艾尼·阿不里新疆大学地理与遥感科学学院新疆乌鲁木齐830017 新疆大学新疆绿洲生态重点实验室新疆乌鲁木齐830017 新疆大学智慧城市与环境建模自治区普通高校重点实验室新疆乌鲁木齐830017

土壤重金属污染对区域土壤环境和人类健康构成严重威胁,因此土壤重金属污染评价和预警在土壤资源保护和区域可持续发展中至关重要.共采集了48个土壤样本,并测定了其中六种重金属含量,运用潜在生态风险指数法、地累积指数法和克里金插值... 详细信息

土壤重金属污染对区域土壤环境和人类健康构成严重威胁,因此土壤重金属污染评价和预警在土壤资源保护和区域可持续发展中至关重要.共采集了48个土壤样本,并测定了其中六种重金属含量,运用潜在生态风险指数法、地累积指数法和克里金插值分别对该区域土壤中Zn、Cu、Cr、Pb、Hg和As六种重金属元素的污染状况和空间分布特征进行了分析,并利用PMF模型对土壤重金属来源进行解析.1)研究区土壤Cu、Pb和As含量均超出中国新疆土壤背景值和全国土壤背景值,Zn和Cr的含量未超过这两种标准.2)污染评价结果显示:土壤未受到Zn、Cu和Cr的污染,Hg处于轻-中污染,Pb和As处于中等和中-强污染.结合潜在生态风险指数分析可知,Zn、Cu、Cr和Pb为低风险状态,Hg和As为中风险状态.3)从重金属元素空间分布来看,Zn元素的空间分布呈中心区域低、四周高的格局;Cu和Hg元素的分布规律存在一定的相似性,均为从西北向东南递减的变化趋势;Cr元素的空间分布呈现从西向东递减的趋势;Pb元素在研究区的分布较均匀.4)PMF模型结果显示:煤炭开采、煤化工和一系列煤电等人类活动容易引起土壤中Hg和As的积累;Cr和Pb主要来自汽车排放;Zn和Cu主要与土壤母质等自然因素密切相关;煤矿开采和工业活动对土壤重金属的贡献最高.吉木萨尔县土壤受到Hg、Pb和As不同程度污染,且该区域污染来源主要为工业生产和汽车尾气.

关键词：土壤重金属污染特征空间分布 PMF模型

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金属有机框架材料在环境化学中的研究进展

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中国科学：化学 2018年第3期48卷 231-242页

作者：张鉴泽刘文贤王兵庆刘军枫北京化工大学化工资源有效利用国家重点实验室北京100029

金属有机框架(MOFs)是一类由有机桥连配体与无机金属中心通过自组装形成的新型多孔材料.相比传统的多孔材料,MOFs具有比表面积高、孔径均一、结构可调节等优点,在基础理论研究和实际应用方面都表现出巨大的潜力.近年来,环境问题日益突出... 详细信息

金属有机框架(MOFs)是一类由有机桥连配体与无机金属中心通过自组装形成的新型多孔材料.相比传统的多孔材料,MOFs具有比表面积高、孔径均一、结构可调节等优点,在基础理论研究和实际应用方面都表现出巨大的潜力.近年来,环境问题日益突出,开发新型材料解决环境问题迫在眉睫,MOFs材料在环境化学中的应用受到了广泛关注.本文主要介绍MOFs材料在催化、气体存储、气体吸附与分离、气敏传感和水体净化等多个领域的理论研究与应用现状,并进一步讨论了MOFs材料在该领域面临的挑战和发展趋势.

关键词：金属有机框架环境化学催化气体吸附与分离重金属离子净化

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吉林省下三叠统卢家屯组LA-ICP-MS锆石U-Pb定年及其地质意义

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吉林大学学报（地球科学版） 2015年第2期45卷 453-470页

作者：聂立军于宏斌张建泽王聪李栋李阳吉林省区域地质矿产调查所长春130022

卢家屯组按岩性组合自下而上分为影背山砾岩段、漏斗山杂色岩段、杨树河子黑色岩段,前人采集到的Palaeanodonta-Palaeomutela动物群、Pleuroneia?sp.和叶肢介等生物化石组合指示时代为二叠纪。本次对九台市影背山—双顶山卢家屯组建组... 详细信息

卢家屯组按岩性组合自下而上分为影背山砾岩段、漏斗山杂色岩段、杨树河子黑色岩段,前人采集到的Palaeanodonta-Palaeomutela动物群、Pleuroneia?sp.和叶肢介等生物化石组合指示时代为二叠纪。本次对九台市影背山—双顶山卢家屯组建组剖面下、中、上段进行了系统的碎屑锆石U-Pb同位素年代学研究,证实卢家屯组由下至上存在3个最小锆石年龄峰值,分别为(283.4±7.9)、(262.4±3.9)、(255.5±5.8)Ma,确定了卢家屯组的上限为晚二叠世。根据卢家屯组中碎屑锆石存在1 800 Ma和2 500Ma左右的典型华北板块基底年龄,认为华北板块北缘与其北侧地块群最终闭合时间应为P3-T1。

关键词：卢家屯组下三叠统碎屑锆石 LA-ICP-MS锆石U-Pb定年吉林省

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Diatomic Pd catalyst with conjugated backbone for synergistic electrochemical CO_(2)reduction

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Nano Research 2024年第6期17卷 4850-4855页

作者： Wenxuan zhang Mengran zhang Hongjuan Wang Wen zhang Min zhang MOE International Joint Laboratory of Materials Microstructure Institute for New Energy Materials and Low Carbon TechnologiesSchool of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion School of Chemistry and Chemical EngineeringTianjin University of TechnologyTianjin 300384China

Double-site catalysts have attracted widespread attention in the field of electrocatalysis due to their high metal loading,adjustable active centres,and electronic valence ***,the development of bimetallic sites catalysts that coordinate with definite atoms is still in the exploratory ***,we designed and synthesized a bimetallic palladium complex(BPB-Pd_(2))with conjugated *** supported BPB-Pd_(2)was applied to electrochemical CO_(2)reduction reaction(CO_(2)RR)for the first *** as-obtained BPB-Pd_(2)gives an exceptional Faradaic efficiency of CO(FECO)of 94.4%at−0.80 V *** hydrogen electrode(RHE),which is significantly superior to monoatomic palladium catalyst(BPB-Pd1).The density functional theory(DFT)calculations revealed that the essential reason for the outstanding activity of BPB-Pd_(2)toward CO_(2)RR was that the electronic effect between diatomic palladium reduces the free energy change for CO_(2)RR ***,BPB-Pd_(2)exhibits moderate free energy change to form COOH*intermediate,which was beneficial for the generation of CO in CO_(2)RR.

关键词： synthesis electrocatalysis CO_(2)reduction bimetallic palladium complex synergistic catalysis

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N-doped graphene quantum dot-decorated N-TiO2/P-doped porous hollow g-C_(3)N_(4) nanotube composite photocatalysts for antibiotic photodegradation and H2 production

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International Journal of Minerals,Metallurgy and Materials 2024年第1期31卷 165-178页

作者： Jingshu Yuan Yao zhang Xiaoyan zhang Junjie zhang Shen’gen zhang Institute for Advanced Materials and Technology University of Science and Technology BeijingBeijing 100083China Xi’an Fanyi University Xi’an 710105China Shunde Graduate School of University of Science and Technology Beijing Foshan 528399China State Key Laboratory of Lunar and Planetary Sciences Macao University of Science and TechnologyMacao SAR 820000China

Exclusive responsiveness to ultraviolet light (~3.2 eV) and high photogenerated charge recombination rate are the two primary drawbacks of pure TiO_(2). We combined N-doped graphene quantum dots (N-GQDs), morphology regulation, and heterojunction construction strategies to synthesize N-GQD/N-doped TiO_(2)/P-doped porous hollow g-C_(3)N_(4) nanotube (PCN) composite photocatalysts (denoted as G-TPCN). The optimal sample (G-TPCN doped with 0.1wt% N-GQD, denoted as 0.1% G-TPCN) exhibits significantly enhanced photoabsorption, which is attributed to the change in bandgap caused by elemental doping (P and N), the improved light-harvesting resulting from the tube structure, and the upconversion effect of N-GQDs. In addition, the internal charge separation and transfer capability of0.1% G-TPCN are dramatically boosted, and its carrier concentration is 3.7, 2.3, and 1.9 times that of N-TiO_(2), PCN, and N-TiO_(2)/PCN(TPCN-1), respectively. This phenomenon is attributed to the formation of Z-scheme heterojunction between N-TiO_(2) and PCNs, the excellent electron conduction ability of N-GQDs, and the short transfer distance caused by the porous nanotube structure. Compared with those of N-TiO_(2), PCNs, and TPCN-1, the H2 production activity of 0.1%G-TPCN under visible light is enhanced by 12.4, 2.3, and 1.4times, respectively, and its ciprofloxacin (CIP) degradation rate is increased by 7.9, 5.7, and 2.9 times, respectively. The optimized performance benefits from excellent photoresponsiveness and improved carrier separation and migration efficiencies. Finally, the photocatalytic mechanism of 0.1% G-TPCN and five possible degradation pathways of CIP are proposed. This study clarifies the mechanism of multiple modification strategies to synergistically improve the photocatalytic performance of 0.1% G-TPCN and provides a potential strategy for rationally designing novel photocatalysts for environmental remediation and solar energy conversion.

关键词： N-doped TiO_(2) N-doped graphene quantum dots P-doped g-C_(3)N_(4) porous hollow nanotube heterojunction photocatalysis

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Reversing free-electron transfer of sulfide cocatalyst for exceptional photocatalytic H_(2)evolution

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Journal of Materials Science & Technology 2024年第4期171卷 147-149页

作者： Yanfeng zhang Zhenyi zhang National Experimental Chemistry Teaching Center Hebei Key Laboratory of Inorganic Nano-materialsCollege of Chemistry and Materials ScienceHebei Normal UniversityShijiazhuang 050024China Key Laboratory of New Energy and Rare Earth Resource Utilization of State Ethnic Affairs Commission Key Laboratory of Photosensitive Materials and Devices of Liaoning ProvinceSchool of Physics and Materials EngineeringDalian Minzu UniversityDalian 116600China

Recently,Yu and co-workers deeply explore the potential impact of free electron transfer between co-catalysts and photocatalyst carriers on H_(2)evolution efficiency of active sites over MoS_(2+x).They pro-pose an electron-reversal tactics to evade the unexpected electron transfer and synchronously regulate the above transfer in a beneficial orientation for weakening hydrogen adsorption on S ***,this highlight not only discusses and summarizes the essences of electron reversal and the optimized H ad-sorption/desorption mechanism,but also emphasizes the significance of femtosecond transient absorp-tion spectroscopy(fs-TAS)and in-situ irradiated X-ray photoelectron spectroscopy(ISI-XPS)for revealing charge transfer dynamics and *** anticipate that this highlight can disseminate a new per-spective on the roles of photocatalyst carriers in improving cocatalytic H_(2)-production kinetics.

关键词： Photocatalysis Cocatalyst Electron reversal Antibonding-orbital occupancy S–H bonds

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Inter-well internal resonance analysis of rectangular asymmetric cross-ply bistable composite laminated cantilever shell under transverse foundation excitation

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Applied Mathematics and Mechanics(English Edition) 2024年第8期45卷 1353-1370页

作者： Lele REN Wei zhang Yufei zhang State Key Laboratory of Mechanical System and Vibration Shanghai Jiao Tong UniversityShanghai 200240China Department of Mechanics Guangxi UniversityNanning 530004China Beijing Key Laboratory of Nonlinear Vibrations and Strength of Mechanical Structures College of Mechanical EngineeringBeijing University of TechnologyBeijing 100124China

The chaotic dynamic snap-through and complex nonlinear vibrations are investigated in a rectangular asymmetric cross-ply bistable composite laminated cantilever shell,in cases of 1:2 inter-well internal resonance and primary *** transverse foundation excitation is applied to the fixed end of the structure,and the other end is in a free *** first-order approximate multiple scales method is employed to perform the perturbation analysis on the dimensionless two-degree-of-freedom ordinary differential motion control *** four-dimensional averaged equations are derived in both polar and rectangular coordinate *** from the obtained frequency-amplitude and force-amplitude response curves,a detailed analysis is conducted to examine the impacts of excitation amplitude,damping coefficient,and tuning parameter on the nonlinear internal resonance characteristics of the *** nonlinear softening characteristic is exhibited in the upper stable-state,while the lower stable-state demonstrates the softening and linearity *** simulation is carried out using the fourth-order Runge-Kutta method,and a series of nonlinear response curves are *** the excitation amplitude further elucidates the global bifurcation and chaotic dynamic snap-through characteristics of the bistable cantilever shell.

关键词： bistable composite laminated cantilever shell inter-well internal resonance primary resonance chaotic dynamic snap-through complex nonlinear vibration

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