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Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries

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Chinese Chemical Letters 2024年第6期35卷 216-221页

作者： Qianqian Song Yunting zhang jianli Liang Si Liu Jian Zhu Xingbin Yan School of Materials Science and Engineering Sun Yat-Sen UniversityGuangzhou 510275China College of Physics and Materials Science Tianjin Normal UniversityTianjin 300387China Department of Chemistry&Center of Super-Diamond and Advanced Films(COSDAF) City University of Hong KongHong Kong 999077China Guangdong-Hong Kong-Macao Joint Laboratory for Intelligent Micro-Nano Optoelectronic Technology School of Physics and Optoelectronic EngineeringFoshan UniversityFoshan 528225China

Polyethylene oxide(PEO)-based solid-state polymer electrolytes(SPEs)are limited by their poor cyclic stability and inferior ionic conductivity for applicating in high-safety,long-cycling and high-energy-density lithium metal batteries.Herein,porous boron nitride nanofibers(BNNFs)are filled into PEO-based SPE,which significantly suppresses Li dendrites growth and enhances the electrochemical performance of Li metal battery.BNNFs with high porosity have more active sites to connect with PEO,which can effectively reduce the crystallinity of the PEO matrix and enhance its ionic conductivity.Moreover,owing to the hardness and good stability of BNNFs,BNNFs/PEO/Li TFSI electrolyte exhibits a wider electrochemical window,better mechanical property and higher thermal stability compared with PEO/Li TFSI electrolyte.Consequently,the Li symmetric cell composed of 1%BNNFs/PEO/Li TFSI performs good cyclic stability(>1800 h),and the Li||1%BNNFs/PEO/Li TFSI||LFP full battery shows obviously improved performances in charge-discharge polarization voltage,discharge specific capacity,rate performance and cyclic stability than the Li||PEO/Li TFSI||LFP battery.

关键词： Solid-state polymer electrolyte Boron nitride nanofibers Lithium metal battery Ionic conductivity Li dendrite

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海洋工程小尺寸双相钢管的GTAW焊接工艺

焊接技术 2024年第3期53卷 64-67页

作者：朱大喜张剑利温振威刘亚杰李晓鹏殷兰兰海洋石油工程(青岛)有限公司山东青岛266520

针对公司圆筒形FPSO项目中的小尺寸双相钢管与法兰的对接接头,选择手工钨极氩弧焊作为焊接方法,按照欧标ISO 15614-1及项目焊接规格书要求进行了焊接工艺评定试验。试验结果表明,采用文中开发的工艺能够获得满足性能要求的焊接接头。

关键词：双相钢小尺寸氩弧焊焊接工艺

2 μm mid-infrared optical spectra of Tm3+-doped germanium gallate glasses

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Journal of Rare Earths 2009年第5期27卷 781-785页

作者： XIA Haiping LIN Qiongfei zhang jianli zhang Qinyuan Laboratory of Photo-electronic Materials Ningbo University Ningbo 315211 China Laboratory of Photo-electronic Materials Ningbo University Ningbo 315211 China Laboratory of Photo-electronic Materials Ningbo University Ningbo 315211 China Key Laboratory of Specially Functional Materials of Ministry of Education and Institute of Optical Communication Materials South China University of Technology Guangzhou 510641 China

Glasses with the composition of 65GeO212Ga2O3-10BaO-8Li2O-5La2O3(molar ratio) doped with 1.526 wt.%, 3.006 wt.%, 5.836 wt.%, 11.028 wt.%, and 15.678 wt.% Tm2O3, respectively, were fabricated by conventional melting method. According to the absorption spectra and the Judd-Ofelt theory, the J-O strength parameters (Ω2,Ω4, Ω6) were calculated, with which the radiative transition probabilities,branching ratios and radiative lifetimes were obtained. The infrared emission spectra (with 808 nm LD excitation) at～1.47 and～1.8 μm of various concentrations of Tm3+-doped glasses were studied. The emission intensity at～1.8 μm reached to the maximum when the Tm2O3-doping concentration was near to be～3.006 wt.% (1.0 mol.%), and then decreased as doping concentration increased further. The mechanism of the fluorescence intensity change was explained with the cross-relaxation effect and the concentration quenching effect of Tm3+. Meanwhile, according to McCumber theory, the absorption and emission cross-sections corresponding to the 3F4→3H6 transitions of Tm3+ at 1.8 μm was obtained. For Tm3+-doped germanate glasses, the maximum emission cross-section reached a value higher than that re-ported for fluorozircoaluminate glasses. It is expected to be a favorable candidate host for～2.0 μm mid-inflated laser because the glass shows favorable optical spectra.

关键词： Tm3+-doped germanium-gallate glasses spectral properties cross relaxation emission cross-section rare earths

Efficient InGaN-based yellow-light-emitting diodes

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Photonics Research 2019年第2期7卷 144-148页

作者： FENGYI JIANG jianli zhang LONGQUAN XU JIE DING GUANGXU WANG XIAOMING WU XIAOLAN WANG CHUNLAN MO ZHIJUE QUAN XING GUO CHANGDA ZHENG SHUAN PAN JUNLIN LIU National Institute of LED on Silicon Substrate Nanchang University Nanchang Yellow Green Lighting Company Limited

Realization of efficient yellow-light-emitting diodes(LEDs) has always been a challenge in solid-state lighting.Great effort has been made, but only slight advancements have occurred in the past few decades. After comprehensive work on InGaN-based yellow LEDs on Si substrate, we successfully made a breakthrough and pushed the wall-plug efficiency of 565-nm-yellow LEDs to 24.3% at 20 A∕cm^2 and 33.7% at 3 A∕cm^2. The success of yellow LEDs can be credited to the improved material quality and reduced compressive strain of InGaN quantum wells by a prestrained layer and substrate, as well as enhanced hole injection by a 3 D pn junction with V-pits.

关键词： InGaN Si Efficient InGaN-based

A near-infrared fluorescent probe for visualizing transformation pathway of Cys/Hcy and H2S and its applications in living system

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Chinese Chemical Letters 2024年第5期35卷 296-301页

作者： Yudi Cheng Xiao Wang Jiao Chen Zihan zhang Jiadong Ou Mengyao She Fulin Chen jianli Li Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education Xi’an Key Laboratory of Functional Supramolecular Structure and MaterialsCollege of Chemistry&Materials ScienceNorthwest UniversityXi’an 710127China Key Laboratory of Resource Biology and Biotechnology in Western China Ministry of EducationBiomedicine Key Laboratory of Shaanxi ProvinceLab of Tissue Engineeringthe College of Life SciencesFaculty of Life Science&MedicineNorthwest UniversityXi’an 710069China

Sulfydryl-contained(-SH)substances including hydrogen sulfide(H_(2)S),cysteine(Cys),homocysteine(Hcy)and glutathione(GSH)play crucial roles in living systems,and their variations are closely associated with various diseases.Herein,we developed a near-infrared intramolecular charge transfer(ICT)based fluorescent probe Y-NBD,achieving detection of Cys/Hcy and H_(2)S with different fluorescent signals(green-red for Cys/Hcy,red for H_(2)S),large Stokes shifts(∼100/105nm or 191 nm)and high signal-background-ratio,but not responding to GSH.Y-NBD was successfully applied to image exogenous/endogenous Cys/Hcy and H_(2)S in various living cancer cells(HeLa,A549,and HepG2)and in zebrafish.It not only visualized the transformation pathway of several thiols in HepG2 cells but also verified that the intestine is the main site for the activation and metabolism of Y-NBD in zebrafish,as well as realized to evaluate the degree of drug-induced liver injury.This work provides a promising tool for imaging Cys/Hcy and H_(2)S in living systems and shows great potency in evaluating drug-induced liver injury and its treatment.

关键词： Fluorescent probe Near-infrared Hydrogen sulfide Cysteine/homocysteine Large Stokes shift Dicyanoisophorone Drug-induced liver injury

Selective core-shell doping enabling high performance 4.6 V-LiCoO2

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Journal of Energy Chemistry 2024年第8期95卷 684-693页

作者： Yueming Xia Jianrui Feng Jinhui Li Yan Li Zhengfeng zhang Xiaoqi Wang jianli Shao Manling Sui Pengfei Yan Beijing Key Laboratory of Microstructure and Property of Solids College of Materials Science & Engineering Beijing University of Technology Petro China Research Institute of Petroleum Exploration & Development State Key Laboratory of Explosion Science and Technology Beijing Institute of Technology

Constructing robust surface and bulk structure is the prerequisite for realizing high performance high voltage LiCoO2（LCO）.Herein,we manage to synthesize a surface Mg-doping and bulk Al-doping coreshell structured LCO,which demonstrates excellent cycling performance.Half-cell shows 94.2% capacity retention after 100 cycles at 3.0-4.6 V（vs.Li/Li+） cycling,and no capacity decay after 300 cycles for fullcell test（3.0-4.55 V）.Based on comprehensive microanalysis and theoretical calculations,the degradation mechanisms and doping effects are systematically revealed.For the undoped LCO,high voltage cycling induces severe interfacial and bulk degradations,where cracks,stripe defects,fatigue H2 phase,and spinel phase are identified in grain bulk.For the doped LCO,Mg-doped surface shell can suppress the interfacial degradations,which not only stabilizes the surface structure by forming a thin rock-salt layer but also significantly improves the electronic conductivity,thus enabling superior rate performance.Bulk Al-doping can suppress the lattice "breathing" effect and the detrimental H3 to H1-3 phase transition,which minimizes the internal strain and defects growth,maintaining the layered structure after prolonged cycling.Combining theoretical calculations,this work deepens our understanding of the doping effects of Mg and Al,which is valuable in guiding the future material design of high voltage LCO.

关键词： Doping effect Electron microscopy Failure mechanism High-voltage LiCoO2 Lithium-ion battery

Effects of drought on non-structural carbohydrates and C,N,and P stoichiometric characteristics of Pinus yunnanensis seedlings

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Journal of Forestry Research 2024年第1期35卷 90-102页

作者： Zhijuan Zhao Lina Wang Yuanxi Liu jianli Sun Jiandong Xiao Qiong Dong Lianfang Li Wanjie zhang Chao Wang Junwen Wu College of Forestry Southwest Forestry UniversityKunming 650224YunnanPeople’s Republic of China

To study non-structural carbohydrate character-istics and nutrient utilization strategies of Pinus yunnanen-sis under continuous drought conditions,2-year-old seed-lings were planted in pots with appropriate water,light and moderate and severe drought treatments[(80±5),(65±5),(50±5),and(35±5)%of field water-holding capacity].Non-structural carbohydrates,carbon(C),nitrogen(N),and phosphorus(P)concentrations were measured in each plant component.The results show that:(1)With increasing drought,non-structural carbohydrates gradually increased in leaves,stems,and coarse roots,while gradually decreased in fine roots;(2)C concentrations of all were relatively stable under different stress levels.Phosphorous utilization of each component increased under light and moderate drought conditions,while N and P utilization efficiency of each plant component decreased under severe drought.Growth was mainly restricted by N,first decreasing and then increasing with increased drought;(3)There was a correlation between the levels of non-structural carbohydrates and C,N,and P in each component.Changes in N concentration affected the interconversion between soluble sugar and starch,which play a regulatory role in the fluctuation of the concentration of non-structural carbohydrates;and,(4)Plasticity analysis showed that P.yunnanensis seedlings responded to drought mainly by altering starch concentration,the ratio of soluble sugar to starch in leaves and stems,and further by alter-ing N and P utilization efficiencies.Overall,these results suggest that the physiological activities of all organs of P.yunnanensis seedlings are restricted under drought and that trade-offs exist between different physiological indicators and organs.Our findings are helpful in understanding non-structural carbohydrate and nutrient adaptation mechanisms under drought in P.yunnanensis seedlings.

关键词： Pinus yunnanensis seedlings Drought Non-structural carbohydrates C,N,P stoichiometric characteristics

Optical spectroscopy and crystal-field strength of Cr^(3+) in various solid matrixes

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Rare Metals 2006年第1期25卷 51-57页

作者： XIA Haiping WANG Jinhao WANG Hongyin zhang jianli zhang Yuepin XU Tiefeng The Laboratory of Photo-electronic Materials Ningbo University Ningbo 315211 China

The Cr^3＋：BeAl2O4 crystal, Cr^3＋：LiNbO3 crystal, and ZnO-Al2O3-SiO2 glass-ceramic were obtained by the Czochralski technique, Bridgman method, and melting processing, respectively. The optical absorption and emission spectra of the above Cr^3＋-incorporated solid-state materials were recorded. The technical parameters for growing high-quality Cr^3＋：BeAl2O4 and Cr^3＋：LINbO3 crystals were obtained. The results indicate that the optical absorption and fluorescence spectra of Cr^3＋ show quite a few differences in various matrixes. The sharp line emissions were observed in the Cr^3＋：BeAl2O4 and Cr^3＋：LiNbO3 crystals. The crystal-field parameters （Dq） for Cr^3＋. in different matrixes were calculated from their corresponding spectra. It is indicated that Cr^3＋：BeAl2O4 and Cr^3＋：LiNbO3 belong to the high-field site crystal, while the Cr^3＋ ZnO-Al2O3-SiO2 glass and glass-ceramic belong to the weak-field site crystal.

关键词： special functional inorganic materials optical spectroscopy optical measurement Cr^3＋ ion matrix

Sea-level variation/change and thermal contribution in the Bering Sea

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Acta Oceanologica Sinica 2005年第6期24卷 36-45页

作者： ZUO Juncheng zhang jianli DU Ling LI Peiliang LI Lei College of Physical and Environmental Oceanography Ocean University of China Qingdao 266003 China College of Physical and Environmental Oceanography Ocean University of China Qingdao 266003 China College of Physical and Environmental Oceanography Ocean University of China Qingdao 266003 China College of Physical and Environmental Oceanography Ocean University of China Qingdao 266003 China College of Physical and Environmental Oceanography Ocean University of China Qingdao 266003 China

The long-term sea-level trend in the Bering Sea is obtained by the analysisof TOPEX/Poseidon altimeter data, including the data of two tide gauges. The averaged sea-level inthe Bering Sea rises at a rate of 2.47 mm/a from 1992 to 2002. The mean sea-level is falling in themost part of the Bering Sea, especially in its central basin, and it is rising in the northeasternpart of the Bering Sea. During the 1998/99 change, the sea-level anomaly differences exhibit asignificant sea-level anomaly fall in the deep basin of the Bering Sea, which is roughly in the sameposition where a prominent SST fall exists. The maximal fall of sea-level is about 10 cm in thesouthwestern part of the Bering Sea, and the maximal fall of about 2℃ in the SST also appeared inthe same region as the sea level did. The steric sea-level change due to temperature variations isdiscussed. The results are compared with the TOPEX/Poseidon altimeter data at the different spatialscales. It is indicated that the seasonal amplitude of the steric height is about 35% of theobserved TOPEX/Poseidon amplitude, which is much smaller than the 83% in the mid-latitudes area. Thesystematic difference between the TOPEX/Poseidon data with the range of about 7.5 cm and thethermal contribution with the range of about 2.5 cm is about 5 cm. This indicates that the thermaleffect on the sea level is not as important as the case in the mid-latitudes area. In the BeringSea, the phase of the steric height leads the observed sea level by about three months.

关键词： sea-level variation steric bering sea