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Photodegradation of xylene isomers:Kinetics,mechanism,secondary pollutant formation potential and health risk evaluation

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Journal of Environmental Sciences 2024年第2期136卷 658-669页

作者： Xiaoyan chen Weikun Zhu Sufen Feng jiangyao chen Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control Guangdong Technology Research Center for Photocatalytic Technology Integration and Equipment EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China Guangzhou Key Laboratory of Environmental Catalysis and Pollution Control Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and HealthSchool of Environmental Science and EngineeringGuangdong University of TechnologyGuangzhou 510006China

Photodegradation technology has been widely applied in the purification of industrial aromatic ***,whether this technology efficiently removes the pollutants to prevent secondary pollution and health risk is still ***,the photodegradation processes of three xylenes were compared under designed reaction atmospheres and light *** lamp showed poor photodegradation ability toward xylenes,no matter in N_(2) or N_(2)+O_(2)system,while much higher photodegradation performance of xylenes were obtained under ultraviolet(UV)and vacuum ultraviolet(VUV)irradiation,especially in N_(2)+O_(2)+VUV system,where 97.9%of m-xylene,99.0%of o-xylene or 87.5%of p-xylene with the initial concentration of 860 mg/m^(3) was removed within 240 *** xylenes underwent three processes of photo-isomerization,photodecomposition and photo-oxidation to produce intermediates of aromatics,alkanes and *** them,the photo-isomerization products showed the highest concentration percentage(e.g.,≥50%in o-xylene system),confirming that photo-isomerization reaction was the dominated photodegradation process of ***,these isomerized products not only contributed about 97%and91%to the formation potential of O3(OFP)and secondary organic aerosols(SOAFP),but also displayed obvious non-carcinogenic risk,although one of photodecomposition product—benzene showed the highest occupational exposure ***,the secondary pollution and health risks of photodegradation products of xylenes were non-ignorable,although the OFP,SOAFP and health risks of the generated products reduced at least 4.5 times in comparison with that of the degraded *** findings are helpful for the appropriate application of this technology in the purification of industrial organic waste gas.

关键词： Isomer aromatics Photodegradation Ozone formation Secondary organic aerosols Health risk

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Underestimated contribution of fugitive emission to VOCs in pharmaceutical industry based on pollution characteristics, odorous activity and health risk assessment

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Journal of Environmental Sciences 2023年第4期126卷 722-733页

作者： Qinhao Lin Zhong Gao Weikun Zhu jiangyao chen Taicheng An Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control Guangdong Technology Research Center for Photocatalytic Technology Integration and Equipment EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health Guangzhou Key Laboratory of Environmental Catalysis and Pollution ControlSchool of Environmental Science and EngineeringGuangdong University of TechnologyGuangzhou 510006China

Fugitive emission has been becoming an important source of volatile organic compounds(VOCs) in pharmaceutical industry,but the exact contribution of fugitive emission remains incompletely *** present study,pollution characteristics,odorous activity and health risk of stack and fugitive emissions of VOCs from four functional units (e.g.,workshop,sewage treatment station,raw material storage and hazardous waste storage) of three representative pharmaceutical factories were *** was the dominant contributor to VOCs of fugitive emission in comparison with other functional *** high concentration of VOCs from fugitive emission in unsealed workshop (94.87 mg/m^(3))was observed relative to sealed one (1.18 mg/m^(3)),accounting for 31%and 5%of total VOCs,*** emission of VOCs in the unsealed workshop mainly consisted of nhexane,1-hexene and *** activity indexes and non-cancer hazard ratios of these VOCs from fugitive emission in the unsealed workshop were as high as that from stack ***,cancer risk of dichloromethane from fugitive emission and stack exhaust was up to (1.6-1.8)×10^(-5).Odorous activity or health risk index of the VOCs from fugitive emission was up to 13 or 11 times of the corresponding threshold value,posing remarkable health threat on pharmaceutical ***?ndings highlighted the possibly underestimated contribution of fugitive emission on VOCs in the pharmaceutical industry.

关键词： Pharmaceutical industry VOC pollution Fugitive emission Odorous activity index Health risk

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基于光通量计量法的紫外辐射测定方法建立及其应用研究

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大气与环境光学学报 2024年第2期19卷 175-184页

作者：杨栋森李婉赢陈江耀刘新然郑军南京信息工程大学环境科学与工程学院江苏南京210044 广东工业大学环境健康与污染控制研究院和环境科学与工程学院广东广州510006

近年来,我国大气一次污染颗粒物的浓度逐渐下降,二次生成的气溶胶已经成为了大气颗粒物的主要组成部分。新粒子生成作为二次生成气溶胶的重要来源,本世纪以来受到的关注也越来越高。而气态硫酸作为新粒子生成化学过程中一种极为重要的... 详细信息

近年来,我国大气一次污染颗粒物的浓度逐渐下降,二次生成的气溶胶已经成为了大气颗粒物的主要组成部分。新粒子生成作为二次生成气溶胶的重要来源,本世纪以来受到的关注也越来越高。而气态硫酸作为新粒子生成化学过程中一种极为重要的前体物,由于其浓度极低,检测所需的仪器灵敏度极高,因此如何准确定量气态硫酸是新粒子形成机制研究中最大的难点。现有的气态硫酸的定量方法主要是基于光化学法,利用紫外辐射光解水汽产生OH自由基后与过量的二氧化硫反应最终生成气态硫酸,气态硫酸的浓度由紫外光强与水汽浓度共同决定。其中紫外光强的直接测量存在着较大的不确定性,这主要是由于光强在气态硫酸标定装置的反应腔体中分布不均匀,此外,在实际大气条件下标定时还会受到背景气溶胶的散射、吸收作用的影响。因此,此研究建立并比较了两种分别基于臭氧和氧化亚氮光通量计量法的紫外辐射测定的间接测量方法。结果表明:基于臭氧的间接测量法的主要误差来自于氧气的吸收截面,理论误差>60%,实际实验室的重复实验误差约为12%;基于氧化亚氮的间接测量法的主要误差来自于二级反应速率kn的测量误差、反应产物检测仪器及流量控制装置的不确定性,理论误差<16%,实际实验室的重复实验误差<1%。将基于氧化亚氮的间接测量法应用于外场观测的气态硫酸检测时,在为期半个月每天一次的定标气态硫酸中,气态硫酸的测量误差约为24%,接近或优于国外观测结果,证明基于氧化亚氮的光通量计量法对于紫外辐射的测定方法具有较好的准确性和稳定度,可以有效应用于气态硫酸的定量测量。

关键词：紫外辐射光通量计量法气态硫酸

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信息管理软件自动化测试方法的设计

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自动化仪表 2024年第1期45卷 86-90页

作者：裘雨音张静陈江尧国网浙江省电力有限公司浙江杭州310012 国网浙江省电力有限公司培训中心浙江杭州310015 浙江华云信息科技有限公司浙江杭州310012

为了提高信息管理软件异常识别的准确率,基于深度神经网络设计了一种信息管理软件自动化测试方法。利用Markov链构建信息管理软件任务剖面模型,提取用于信息管理软件自动化测试的任务流。深度优先遍历剖面,融合自动化测试操作行为的变... 详细信息

为了提高信息管理软件异常识别的准确率,基于深度神经网络设计了一种信息管理软件自动化测试方法。利用Markov链构建信息管理软件任务剖面模型,提取用于信息管理软件自动化测试的任务流。深度优先遍历剖面,融合自动化测试操作行为的变化条件、后置条件、操作概率等信息。在此基础上,提取信息管理软件自动测试的任务流。结合已知的软件任务状态转移概率计算极限概率,将重要性显著的用例与参数信息作为优先测试的信息,完成网络训练。建立软件异常自动化识别模型,根据异常识别结果对软件异常位置进行定位,完成信息管理软件自动化测试。测试结果表明,该方法的软件自动化测试结果更准确、自动化效率更高,具有一定的应用价值。

关键词：深度神经网络信息管理软件自动化测试自编码器

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Competing pathways of cresol formation in toluene photooxidation:OH-toluene adducts react with NO_(2) or with O_(2)?

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Journal of Environmental Sciences 2022年第4期34卷 211-220页

作者： Baocong Zhao Yongpeng Ji Dandan Qin Yuemeng Ji jiangyao chen Taicheng An Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and HealthInstitute of Environmental Health and Pollution controlGuangdong University of TechnologyGuangzhou 510006China Key Laboratory of City Cluster Environmental Safety and Green development Guangzhou Key Laboratory of Environmental Catalysis and Pollution ControlSchool of Environmental Science and EngineeringGuangdong University of TechnologyGuangzhou 510006China

Methyl-hydroxy-cyclohexadienyl radicals(OTAs)are the key products of the photooxidation of toluene,with implications for the fate of ***,we investigated the photooxidation mechanisms and kinetics of three main OTAs(o-OTA,m-OTA,and p-OTA)with NO_(2)using quantum chemical calculations as well as the fate of OTAs under the different concentration ratios of NO_(2)and O_(2).The mechanism results show that the pathway of Habstraction by NO_(2)to anti-HONO(anti-H-abstraction)is more favorable than the syn-Habstraction pathway,because the strong interaction between OTAs and NO_(2)is formed in the transition states of the anti-H-abstraction *** branching ratios of the antiH-abstraction pathways are more than 99%in the temperature range of 216-298 *** total rate constant of the OTA-NO_(2)reaction is 9.9×10^(-12)cm^(3)/(molecule·sec)at 298 K,which is contributed about 90%by o-OTA+NO_(2),and the main products are o-cresol and *** half-lives of the OTA-NO_(2)reaction in some polluted areas of China are 35 times longer than those of the OTA-O_(2)*** the atmosphere,the NO_(2^(-))and O_(2^(-))initiated reactions of OTAs have the same ability to form cresols as[NO_(2)]is up to 142.1 ppmV,which is impossible to *** implies that under the experimental condition,the[NO_(2)]/[O_(2)]should be controlled to be less than 7.8×10^(-5)to simulate real atmospheric oxidation of *** results reveal that for the photooxidation of toluene,the yield of cresol is not affected by the concentration of NO_(2)under the atmospheric environment.

关键词： Methyl-hydroxy-cyclohexadienyl radicals Toluene photooxidation Reaction mechanism Kinetics Cresols

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基于模糊分簇的电力调度大数据检索方法

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电子设计工程 2024年第16期32卷 139-142页

作者：孙志华齐肇江陈江尧陈冰恽肖禹徐峰浙江华云信息科技有限公司浙江杭州330000

为精准检索所需数据,提升电力调度工作的智能化水平,提出基于模糊分簇的电力调度大数据检索方法。采用模糊分簇聚类对电力调度大数据样本数据分簇,为各簇设置一个参考节点。计算电力调度大数据对象值参考节点的一维距离信息,利用近似位... 详细信息

为精准检索所需数据,提升电力调度工作的智能化水平,提出基于模糊分簇的电力调度大数据检索方法。采用模糊分簇聚类对电力调度大数据样本数据分簇,为各簇设置一个参考节点。计算电力调度大数据对象值参考节点的一维距离信息,利用近似位置信息iDistance,缩小检索范围并快速定位到目标数据,实现高效检索。实验结果显示,模糊分簇的聚类结果较好,各个簇之间不存在明显重叠或交叉,且检索结果可精准响应不同检索目标,并给出深度分析结果。

关键词：模糊分簇聚类算法电力调度数据检索样本空间

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Reactor characterization and primary application of a state of art dual-reactor chamber in the investigation of atmospheric photochemical processes

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Journal of Environmental Sciences 2020年第12期32卷 161-168页

作者： Hao Luo Guiying Li jiangyao chen Yujie Wang Taicheng An Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control Guangzhou Key Laboratory Environmental Catalysis and Pollution ControlSchool of Environmental Science and EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China

Increasing attention has been paid to the air pollution more recently. Smog chamber has been proved as a necessary and effective tool to study atmospheric processes, including photochemical smog and haze formation. A novel smog chamber was designed to study the atmospheric photochemical reaction mechanism of typical volatile organic compounds(VOCs) as well as the aging of aerosols. The smog chamber system includes an enclosure equipped with black lights as the light source, two parallel reactors(2 m^3 of each) with separate control of light source and temperature, with a series of coupled instruments for online monitoring of gas phase and particle phase reactants and products. Chamber characterization, including air source stability, effective light intensity, temperature stability, as well as gas phase and particle phase wall losses, were carried out before further research. The results showed that our smog chamber systems developed by other domestic and international groups. It was also observed that the wall loss of aromatic VOCs varied with different functional groups as well as the isomerism. The results of preliminary simulation experiment from styrene-NO_x demonstrated that the chamber can be well utilized to simulate gas-particle conversion progresses in the atmosphere.

关键词： Smog chamber Dual-reactors Volatile organic compounds Ozone formation Secondary organic aerosol

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Assessing the role of mineral particles in the atmospheric photooxidation of typical carbonyl compound

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Journal of Environmental Sciences 2021年第7期33卷 56-63页

作者： Yongpeng Ji Xingyu chen Yuqi Xiao Yuemeng Ji Weina Zhang Jiaxin Wang jiangyao chen Guiying Li Taicheng An Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and HealthInstitute of Environmental Health and Pollution controlKey Laboratory of City Cluster Environmental Safety and Green developmentSchool of Environmental Science and EngineeringGuangdong University of TechnologyGuangzhou 510006China

Mineral particles are ubiquitous in the atmosphere and exhibit an important effect on the photooxidation of volatile organic compounds(VOCs).However,the role of mineral particles in the photochemical oxidation mechanism of VOCs remains ***,the photooxi-dation reactions of acrolein(ARL)with OH radical(OH)in the presence and absence of SiO_(2) were investigated by theoretical *** gas-phase reaction without SiO_(2) has two distinct pathways(H-abstraction and OH-addition pathways),and carbonyl-H-abstraction is the dominant *** the presence of SiO_(2),the reaction mechanism is changed,i.e.,the dominant pathway from carbonyl-H-abstraction to OH-addition to carbonyl *** energy barrier of OH-addition to carbonyl C-atom deceases 21.33 kcal/mol when SiO_(2) is *** H-atom of ARL is occupied by SiO_(2) via hydrogen bond,and carbonyl C-atom is ac-tivated by SiO_(2).Hence,the main product changes from H-abstraction product to OH-adduct in the presence of SiO_(2).The OH-adduct exhibits a thermodynamic feasibility to yield HO_(2) radical and carboxylic acid via the subsequent reactions with O_(2),with implications for O 3 formation and surface acidity of mineral particles.

关键词： Photochemical oxidation Mineral particles Acrolein Reaction mechanism

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废水脉冲电解处理节能高效的原因分析

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环境工程学报 2008年第1期2卷 23-26页

作者：陈彬朱又春李彦旭陈江耀广东工业大学环境科学与工程学院广州510090

将脉冲电源和直流电源分别作为废水电解处理的电源，试验探明其对废水电解处理的电能消耗和COD去除率的影响，并分析废水脉冲电解处理节能高效的原因。试验结果表明，脉冲电流相对直流电流能够更加有效减缓电极的极化，降低电极过电位... 详细信息

将脉冲电源和直流电源分别作为废水电解处理的电源，试验探明其对废水电解处理的电能消耗和COD去除率的影响，并分析废水脉冲电解处理节能高效的原因。试验结果表明，脉冲电流相对直流电流能够更加有效减缓电极的极化，降低电极过电位，使电能消耗降低15%-35%；在脉冲电解处理废水过程中电流效率稳定、Fe^2＋能够有效扩散到废水中，使去污效果增强5%-7%。

关键词：脉冲电解电能消耗 COD去除率极化过电位

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金属Bi原位修饰具有(110)暴露面和表面氧空位的BiOBr以增强太阳光催化降解气相正己烷

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Chinese Journal of Catalysis 2020年第10期41卷 1603-1612页

作者：余晴晴陈江耀李彦旭温美成刘宏利李桂英安太成广东工业大学环境健康与污染控制研究院环境科学与工程学院广东省环境催化与健康风险控制重点实验室广州市环境催化与污染控制重点实验室广东广州510006 汕头广工大协同创新研究院广东汕头515041

烷烃是石油化工行业排放的一类重要的人为污染物.烷烃排放到大气后,很容易与大气中的活性物质发生反应,转化为复杂的臭氧和有机气溶胶等二次污染物.而这些二次污染物对大气环境和人类的负面影响更为显著.因此,有效地消除排放源中的烷烃... 详细信息

烷烃是石油化工行业排放的一类重要的人为污染物.烷烃排放到大气后,很容易与大气中的活性物质发生反应,转化为复杂的臭氧和有机气溶胶等二次污染物.而这些二次污染物对大气环境和人类的负面影响更为显著.因此,有效地消除排放源中的烷烃以实现对大气环境和人类健康的保护是迫切需要的.近些年来,基于太阳光和Bi基半导体的光催化降解气相污染物受到了研究人员的广泛关注.然而,目前有关光催化在气相直链烷烃净化中的应用仍然很少.本文采用溶剂法合成了一系列Bi/BiOBr复合材料,并将其应用于太阳光催化降解典型的气相直链烷烃正己烷.XRD, SEM和TEM表征结果表明,反应溶剂中官能团数量的增加(从甲醇、乙二醇到甘油)和溶剂热温度的提高(从160, 180到200℃)均有助于实现具有(110)暴露面的BiOBr纳米板上金属Bi纳米球的原位修饰.同时Raman和XPS表征结果表明, Bi与BiOBr在(110)暴露面上形成了化学键,进而导致表面氧空位形成.在实验室自制的光催化反应器中研究了Bi/BiOBr复合材料的太阳光催化降解正己烷性能.120 min的降解反应结果表明,适量金属Bi原位修饰有利于促进BiOBr对正己烷的太阳光催化降解性能(初始浓度为15 ppmv的正己烷去除效率最高达97.4%).进一步结合UV-Vis, EPR,光电流和PL的表征结果发现,适量Bi原位修饰Bi OBr后复合材料表现出更高的可见光响应、更窄的带隙、更大的光电流、更低的电荷载流子复合率以及更强的·O2–和h+形成,最终实现高的光催化性能.本文的结论可有效拓宽Bi基光催化技术在净化石油化工行业排放的气体直链污染物中的应用.

关键词： Bi/BiOBr复合材料 (110)暴露面表面氧空位太阳光催化气相烷烃降解

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