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Provenance of the Lower Jurassic pyroclastic sediments in the Zigui Basin:Implication for crustal thickening in the eastern Qinling orogenic belt

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Science China Earth Sciences 2024年第1期67卷 196-207页

作者： Rong CHAI jianghai yang Yuansheng DU Chengshan WANG School of Earth Sciences and Resources China University of Geosciences(Beijing)Beijing 100023China School of Earth Sciences China University of Geosciences(Wuhan)Wuhan 430074China Chinese Academy of Geological Sciences Beijing 100037China

The Late Triassic witnessed significant collisional orogenic events in the Qinling orogenic belt,accompanied by magma underplating and tectonic *** processes potentially resulted in substantial crustal thickening and uplift of the Qinling ***,due to the absence of igneous rock records from this period in the eastern section of the Qinling orogen,the changes in crustal thickness during this orogenic process have not been thoroughly investigated.A series of foreland basins emerged during the Early Mesozoic to the south of the East Qinling orogenic *** basins have preserved clastic sedimentary rocks derived from the uplift and erosion of the orogenic *** sedimentary records serve as crucial records to reconstruct the evolutionary history of the Qinling *** further clarify the collisional orogenic process of the Qinling orogenic belt,this study conducted in situ volcanic lithic fragment geochemistry,detrital zircon U-Pb chronology and trace element composition analysis on the sandstones of the Lower Jurassic Tongzhuyuan Formation in the Zigui *** results suggest that the sandstones,which exhibit a significant abundance of volcanic lithic fragments,has a characteristic detrital zircon age group of 250–200 Ma,indicating a major provenance from the Triassic volcanic *** with regional correlation and paleocurrent analysis,the detrital zircon U-Pb age data show that the source area of volcanic rocks should be in the Qinling orogenic belt to the north of the *** interpretation is further supported by the Triassic granitic rocks exposed in the western part of the orogenic belt,representing the magmatism during the Triassic collisional orogenesis in the Qinling *** on the co-varying relationships between present-day crust thickness with the chemical compositions of granite rocks and zircons,the La/Yb ratio of volcanic lithic fragments in the Tongzhuyuan Formation and the Eu/Eu*ratio of detrital zircon

关键词： Qinling orogenic belt Zigui Basin Late Triassic Detrital zircons Crustal thickening

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Geochemical significance of the Paleogene soda-deposits bearing strata in Biyang Depression,Henan Province

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Science China Earth Sciences 2015年第10期58卷 129-137页

作者： yang jianghai YI ChengLong DU YuanSheng ZHANG ZongHeng YAN JiaXin State Key Laboratory of Biogeology and Environmental Geology China University of Geosciences Geological Exploration Institute of Henan Henan Provincial Bureau of Geo-exploration and Mineral Development

The Biyang Depression, lying in the eastern Nanxiang Basin, has a dustpan-shape with faults developed to the southwest and southeast. The Paleogene Hetaoyuan Formation in this depression hosts one of the oldest soda-deposits, the Anpeng deposit. These sodium carbonate-bearing strata consist of lutites, muddy dolomites, and bedded soda-deposits, which are dominated by nahcolite with little trona, mirabilite, and halite. In the top Unit 3 and lower Unit 2 of Hetaoyuan Formation where the sodium carbonates are concentrated, dolomitic shale, muddy carbonate, and sodium carbonate can be separated based on their distinct A1203, TiO〉 Na20, MgO＋CaO, and LOI （loss on ignition） contents. By using Na20/（MgO＋CaO） ratio as an indicator for the relative concentration of Na carbonates to Mg-Ca carbonates, the muddy dolomites can be classified into two groups. One group with Na20/（MgO＋CaO）〈0.6 exhibits a positive correlation between this ratio and AI203＋TiO2 content, an proxy for ter- rigenous clastic input and the other group with Na20/（MgO＋CaO）〉0.6 presents a negative correlation. As the clastic propor- tion decreases, the former indicates that it tends to form pure Mg-Ca carbonates reflecting evaporation less than or equal to re- plenishment for the lake water in a relative humid climate, and the latter reveals a trend to form sodium carbonates with lake water＇s evaporation more than replenishment in a relatively dry climate. From muddy dolomite to sodium carbonate samples, with Na20/（MgO＋CaO） ratio increasing, the A1 normalized Zr, Ti, La, K, Rb, and Ba tend to be enriched and the post-Archean Average Shale （PAAS） normalized positive Eu anomaly becomes more obvious. Integrated with the high B contents and the report of searlesite in the bedded sodium carbonates and the regional extensional tectonic regime, the above geochemical characteristics were interpreted to signify hydrothermal contribution to forming these soda-deposits through the deep fault systems of basin margins.

关键词： sodium carbonate-bearing strata nahcolite evaporation and concentration hydrothermal activity

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Soft-sediment Deformation Structures Related to Earthquake from the Devonian of the Eastern North Qilian *** Its Tectonic Significance

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Acta Geologica Sinica(English Edition) 2008年第6期82卷 1185-1193页

作者： DU Yuansheng XU Yajun yang jianghai Key Laboratory of Biogeology and Environmental Geology of Education Ministry Wuhan 430074 Faculty of Earth Sciences China University of Geosciences Wuhan 430074

Devonian in the North Qilian orogenic belt and Hexi Corridor developed terrestrial molasse of later stage of foreland basin caused by collision between the North China plate and Qaidam microplate. The foreland basin triggered a intense earthquake, and formed seismites and earthquake-related soft-sediment deformation. The soft-sediment deformation structures of Devonian in the eastern North Qilian Mts. consist of seismo-cracks, sandstone dykes, syn-depositional faults, microfoids （micro-corrugated lamination）, fluidized veins, load casts, flame structures, pillow structures and brecciation. The seismo-cracks, syn-depositional faults and microfolds are cracks, faults and folds formed directly by oscillation of earthquake. The seismic dykes formed by sediment instilling into seismic cracks. Fluidized veins were made by instilling into the seismo-fissures of the fluidized sands. The load casts, flame structures and pillow structures were formed by sinking and instilling caused from oscillation of earthquake along the face between sandy and muddy beds. The brecciation resulted from the oscillation of earthquake and cracking of sedimentary layers. The seismites and soft-sediment deformations in Devonian triggered the earthquake related to tectonic activities during the orogeny and uplift of North Qilian Mts.

关键词： North Qilian Mts. seismites soft-sediment deformation Devonian tectonics

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U-Pb geochronology of hydrothermal zircon from the Mesoproterozoic Gaoyuzhuang Formation on the northern margin of the North China Block and its geological implications

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Science China Earth Sciences 2011年第11期54卷 1675-1685页

作者： GUO Hua DU YuanSheng yang jianghai GUO Liang Key Laboratory of Biogeology and Environmental Geology of Ministry of Education China University of Geosciences Wuhan 430074 China State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Wuhan 430074 China

This paper reports LA-ICP-MS zircon U-Pb ages and REE compositions on detrital zircons （Type 1） and hydrothermal zircons （Type 2） from low-metasedimentary rocks in the Mesoproterozoic Gaoyuzhuang Formation, Pingquan area, Hebei Province that provide important constraints on the tectonic evolution along the northern margin of the North China Block. The detrital zircons are characterized by an oscillatory magmatic core, surrounded by a narrow structureless rim in CL images. They yield 2~7pb/2~tpb ages ranging from 1703 to 2543 Ma with two age peaks at 2473 and 1794 Ma, which is consistent with the Neoarchean and Paleoproterozoic tectono-thermal events recorded in the NCB basement, indicating that the source of the detritus was locally derived. By contrast, the hydrothermal ones are euhedral, sector zoning or internally structureless. They have relatively higher U and Th contents and Th/U ratios （U=139-2918 ppm, Th=35-1327 ppm, Th/U （average） =0.78 vs. U=15-1044 ppm, Th=8-341 ppm, Th/U （average） =0.57 for detrital zircons）. Moreover, they are also enriched in REEs relative to detrital zircons and show a lower positive Ce anomaly （ZREE = 659-2418 ppm vs. 231-611 ppm for detrital zircon; Ce/Ce＊=2-13 vs. 33-174 for detrital zircons）, similar to known hydrothermal zircons derived from many locations. These characteristics, combined with our field petrographic observations, indicate that the hydrothermal zircons possibly formed from a low temperature aqueous fluid. Twelve concordant or near-concordant analyses on hydrothermal zircons yield weighted mean 206pb/238U ages of 325-327 Ma, which provide unambiguous evidence that the northern NCB underwent late Paleozoic low temperature hydrothermal modification. This timing of this hydrothermal event is compatible with that of the late Paleozoic magmatic and metamorphic-deformational events occurred on the northern margin of the NCB, it appears likely that the hydrothermal activity resulted from southward subduction of the Paleo-

关键词： hydrothermal zircon detrital zircon zircon geochronology late Paleozoic North China Block Central Asian Orogenicbelt

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Sedimentary geochemistry and provenance of the Lower and Middle Devonian Laojunshan Formation,the North Qilian Orogenic Belt

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Science China Earth Sciences 2010年第3期53卷 356-367页

作者： XU YaJun DU YuanSheng yang jianghai HUANG Hu Key Laboratory of Biogeology and Environmental Geology of China Education Ministry China University of GeosciencesWuhan 430074China State Key Laboratory of Geological Processes and Mineral Resources China University of GeosciencesWuhan 430074China

The Laojunshan Formation is a suite of molasse formed during the rapid uplift of the North Qilian Orogenic Belt (NQOB). Forty-one samples of sandstone have been collected from the Sunan and Minle sections in the western sector and the Gulang and Jingyuan sections in the eastern sector of the NQOB belt. Geochemical analyses of those samples indicated: 1) The MgO+Fe2O3T and Al2O3/SiO2 values are higher, and K2O/Na2O ratios are lower in the western sector than those in the eastern sector. 2) All of them are depleted in Nb and Ta elements. The samples from the western sector are depleted in Rb element and enriched with Sc, Co, Ni, V, and Cr elements in the Upper Crust-normalized patterns. However, those from the eastern sector are depleted in Sr without enrichments of Sc, Co, Ni, V, and Cr. 3) All of the samples display a right-inclined REE pattern af- ter Chondrite-normalized REE pattern. But LaN/YbN and Eu/Eu* ratios of the samples from the western sector are lower than those of the samples from the eastern sector. These geochemical characteristics suggest the prominent input of mafic clast with minor granitic rocks into the Sunan area, felsic clast into the Gulang and Jingyuan area, and both mafic and felsic clast into the Minle area. The angular shapes of gravels imply that these ill-sorted sediments were deposited near their sources without recy- cling. Geochemical features above also demonstrated that no major chemical weathering occurred for the western provenance, but deposits in the eastern sector resulted from low or middle degree chemical weathering. Evidences combining tectonic discriminations and comparisons with potential provenances revealed that sediments in the Sunan area were derived mainly from the North Qilian Continental arc, whereas sediments in the Minle, Gulang, and Jingyuan areas were derived not only from the North Qilian Continental arc but also from the basement of the Middle Qilian block. Integrated with the characteristics of development of

关键词： North Qilian Orogenic Belt (NQOB) Laojunshan Formation sedimentary geochemistry provenance orogeny

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New Zircon U-Pb Age of the Babu Ophiolites in Southeast Yunnan,China and Constrains of Plate Subduction Time

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Acta Geologica Sinica(English Edition) 2017年第3期91卷 1151-1152页

作者： HUANG Hu DU Yuansheng yang jianghai YU Wenchao State Key Laboratory of Oil/Gas Reservoir Geology and Exploitation Chengdu University of Technology State Key Laboratory of Biogeology and Environmental Geology China University of Geosciences

Objective The Babu ophiolite in Malipo County of southeastern Yunnan is interpreted as remanant ocean crust and represents a possible branch of Paleo-Tethyan Ocean in South China. It consists mainly of mafic and ultramafic rocks. These rocks are very important to understand the evolution of the Paleo-Tethyan Ocean. However, the Babu ophiolite is still disputed and the mafic and ultramafic rocks have been inferred to be part of the Emeishan large igneous province （LIP） by some researchers. In this paper, we present zircon U-Pb data on the metabasalts in Malipo to reveal the formation time of mafic and ultramafic rocks and their tectonic nature.

关键词： Pb ICP MS Th is New Zircon U-Pb Age of the Babu Ophiolites in Southeast Yunnan,China and Constrains of Plate Subduction Time of in

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Devonian-Carboniferous Pillow OIB-Type Basalts in the Youjiang Basin,SW China:Implications for the Eastern Extension of the Paleo-Tethys Branch Ocean

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Journal of Earth Science 2023年第3期34卷 690-705页

作者： Jie yang Yuansheng Du Hu Huang jianghai yang Hongwei Huang Zhiqiang Huang Shandong Provincial Key Laboratory of Water and Soil Conservation and Environmental Protection School of Resources and EnvironmentLinyi UniversityLinyi 276000China State Key Laboratory of Biogeology and Environmental Geology China University of GeosciencesWuhan 430074China State Key Laboratory of Oil/Gas Reservoir Geology and Exploitation Institute of Sedimentary GeologyChengdu University of TechnologyChengdu 610059China General Academy of Geological Survey of Guangxi Nanning 530023China

Late Paleozoic pillow basalts are well preserved in the Youjiang Basin of SW *** this study,we conducted geochemical and Sr-Nd isotopic study on the Late Devonian and Late Carboniferous basalts in Napo area,Youjiang *** analyzed samples comprise moderate SiO2,TiO2,Mg#,and REE contents,with slightly positive or negative Eu anomalies,similar to the chemical nature of OIB(Oceanic island basalt).All basalts show low(^(143)Nd/^(144)Nd)iand(^(87)Sr/^(86)Sr)ivalues,close to EMI-type(I-type Enriched Mantle)magma *** Carboniferous basalts display higher(^(87)Sr/^(86)Sr)i,Nb/Th,and lowerε_(Nd)(t),Zr/Nb values than those of the Late Devonian basalts,implying progressively decreased enrichment components in the magma source *** evolution trend reflects a continuous lithospheric thinning event,supporting a progressive rifting setting of the Youjiang Basin along the southwestern margin of the yangtze Block in Late *** with regional geological background,the Youjiang Basin is viewed as a continental rift basin related to the opening of the Paleo-Tethys Ocean in Late Devonian and became a passive continental margin basin in *** Paleo-Tethys branch ocean probably extended further to the southern Youjiang Basin,likely corresponding to the Song Ma suture zone.

关键词： basalts Late Paleozoic Paleo-Tethys ocean Youjiang Basin geochemistry

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川东地区天然气场站固化池渗滤液污染特征及其对地下水影响研究

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环境科学学报 2024年第5期44卷 264-272页

作者：袁增冯小波杨江海王珏裴逸智郭劲松高俊敏重庆大学材料科学与工程学院重庆400045 重庆大学环境与生态学院重庆400045 中国石油西南油气田公司重庆气矿重庆400707

为了解天然气开采过程中钻井废弃物用固化池处置前后污染物随时间的消减变化及固化池渗滤液对地下水的影响,本研究分别采集川东气田固化池的渗滤液和气田作业区域地下水样品,分析渗滤液和地下水中污染物浓度水平.结果显示,与2013年原完... 详细信息

为了解天然气开采过程中钻井废弃物用固化池处置前后污染物随时间的消减变化及固化池渗滤液对地下水的影响,本研究分别采集川东气田固化池的渗滤液和气田作业区域地下水样品,分析渗滤液和地下水中污染物浓度水平.结果显示,与2013年原完井废弃物浸出液污染物浓度相比,川东地区2022年各场站大部分固化池渗滤液中污染物仍以常规污染物COD为主(92.6%),而氯化物、石油类和硫化物等特征污染物浓度经固化池处理后均未达到GB/T 16848-2017《地下水质量标准》Ⅲ类标准所规定的标准限值.沿江地区和非沿江地区固化池渗滤液中氯化物浓度具有显著性差异(p0.05).2022年部分地下水监测井检测结果显示川东气田固化池渗滤液并未对周边地下水质产生明显影响,但渗滤液指数计算结果显示,240个场站中有3处场站固化池渗滤液呈较高环境风险,可能对当地地下水资源造成潜在污染风险.

关键词：天然气场站固化池渗滤液特征污染物地下水污染 LPI指数

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Conodont Biostratigraphic Constraint on the Lower Taiyuan Formation in Southern North China and Its Paleogeographic Implications

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Journal of Earth Science 2022年第6期33卷 1480-1493页

作者： Yuan Wang jianghai yang Dong-Xun Yuan Jia Liu Rui Ma School of Earth Sciences China University of GeosciencesWuhan430074China State Key Laboratory of Biogeology and Environmental Geology China University of GeosciencesWuhan430074China School of Resources and Geosciences China University of Mining and TechnologyXuzhou221116China State Key Laboratory of Palaeobiology and Stratigraphy Nanjing Institute of Geology and Palaeontology and Center for Excellence in Life and PaleoenvironmentChinese Academy of SciencesNanjing210008China

The Late Paleozoic Taiyuan Formation in North China is mainly composed of a mixed shallow-marine carbonate and terrigenous clastic *** basal limestones have been constrained in the late Pennsylvanian to Early *** further constrain the age of the lowest Taiyuan Formation,we obtained two genera and 16 species of conodonts from the bottom limestones of the Taiyuan Formation in two sections in Henan Province,southern North *** fauna includes Idiognathodus hebeiensis,Streptognathodus isolatus,***,***,***,***,***,***,***,***,***,***,***,***,***,and ***.A genus of Streptognathodus dominated conodont assemblage with some Idiognathodus *** indicates a late Gzhelian(latest Pennsylvanian)age for the lowest Taiyuan Formation in southern North *** is consistent with recently published high-precision zircon U-Pb ages from ash *** on conodont biostratigraphy,the basal limestones of the Taiyuan Formation in Henan Province(southern North China)can be correlated with the upper part of Miaogou limestones of the Taiyuan Formation in Shanxi Province(northern North China).This correlation might reflect a significant sea-level rise in North China,possibly corresponding to a deglaciation event at the Permo-Carboniferous transition.

关键词： Taiyuan Formation conodonts Gzhelian southern North China biostratigraphy

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Climate paleogeography knowledge graph and deep time paleoclimate classifications

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Geoscience Frontiers 2023年第5期14卷 362-372页

作者： Chenmin Yu Laiming Zhang Mingcai Hou jianghai yang Hanting Zhong Chengshan Wang State Key Laboratory of Biogeology and Environmental Geology School of the Earth Science and ResourcesChina University of GeosciencesBeijing 100083China Key Laboratory of Deep-time Geography and Environment Reconstruction and Applications MNR&Institute of Sedimentary GeologyChengdu University of TechnologyChengdu 610059China State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Institute of Sedimentary GeologyChengdu University of TechnologyChengdu 610059China State Key Laboratory of Biogeology and Environmental Geology School of Earth SciencesChina University of GeosciencesWuhan 430074China

The climate paleogeography,especially the climate classifications,helps to interpret the global and regional climate changes and intuitively compare the climate conditions in different ***,the application of climate classification in deep time(i.e.,climate paleogeography)is prohibited due to the usually qualitatively constrained paleoclimate and the inconsistent descriptions and semantic heterogeneity of the climate *** this study,a climate paleogeography knowledge graph is established under the framework of the Deep-Time Digital Earth program(DDE).The hierarchical knowledge graph consists of five paleoclimate classifications based on various *** classifications are described and their strengths and weaknesses are fully evaluated in four aspects:“simplicity,applicability,quantifiability,and comparability”.We also reconstruct the global climate distributions in the Late Cretaceous according to these *** results are compared and the relationships among these climate types in different classifications are *** study unifies scientific concepts from different paleoclimate classifications,which provides an important theoretical basis for the application of paleoclimate classifications in deep time.

关键词： Climate paleogeography Knowledge graph Paleoclimate classification Deep-Time Digital Earth program

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