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Frontiers of Chemical Science and Engineering 2022年第11期16卷 1616-1622页

作者： Yijian Li jianbo hu Jiyu Cui Qingju Wang huabin Xing Xili Cui Zhejiang Key Laboratory of Smart Biomaterials Key Laboratory of Biomass Chemical Engineering of Ministry of EducationCollege of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310027China ZJU-Hangzhou Global Scientific and Technological Innovation Center Hangzhou 311215China

Adsorptive separation of acetylene/carbon dioxide mixtures by porous materials is an important and challenging task due to their similar sizes and physical properties.Here,remarkable acetylene/carbon dioxide separation featuring a high dynamic breakthrough capacity for acetylene(4.3 mmol·g^(–1))as well as an ultralow acetylene regeneration energy(29.5 kJ·mol^(–1))was achieved with the novel TiF_(6)^(2–)-pillared material ZU-100(TIFSIX-bpy-Ni).Construction of a pore structure with abundant TiF_(6)^(2–)anion sites and pores with appropriate sizes enabled formation of acetylene clusters through hydrogen bonds and intermolecular interactions,which afforded a high acetylene capacity(8.3 mmol·g^(–1))and high acetylene/carbon dioxide uptake ratio(1.9)at 298 K and 1 bar.Moreover,the NbO_(5)^(2–)anion-pillared material ZU-61 investigated for separation of acetylene/carbon dioxide.In addition,breakthrough experiments were also conducted to further confirm the excellent dynamic acetylene/carbon dioxide separation performance of ZU-100.

关键词： acetylene carbon dioxide separation dynamic capacity anion-pillared hybrid material

Efficient separation of C_(4) olefins using tantalum pentafluor oxide anion-pillared hybrid microporous material

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Chinese Journal of Chemical Engineering 2022年第2期35卷 49-54页

作者： Bin Gao Zhaoqiang Zhang jianbo hu Jiyu Cui Liyuan Chen Xili Cui huabin Xing Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310027China Hangzhou Global Scientific and Technological Innovation Center Zhejiang UniversityHangzhou 311215China

With the increasing demand for synthetic rubber,the purification of 1,3-butadiene(C_(4)H_(6))is of great industrial significance.Herein,the successful removal of n-butene(n-C_(4)H_(8))and iso-butene(iso-C_(4)H_(8))from 1,3-butadiene(C_(4)H_(6))was realized by synthesizing a novel TaOF_(5)^(2-) anion-pillared ultramicroporous material TaOFFIVE-3-Ni(also referred to as ZU-96,TaOFFIVE=TaOF_(5)^(2-),3=pyrazine).Single-component adsorption isotherms show that TaOFFIVE-3-Ni can achieve the exclusion of n-C_(4)H_(8) and iso-C_(4)H_(8) in the low pressure region(0–30 kPa),and uptake C_(4)H_(6) with a high capacity of 92.78 cm^(3)·cm^(-3)(298 K and 100 kPa).The uptake ratio of C_(4)H_(6)/iso-C_(4)H_(8) on TaOFFIVE-3-Ni was 20.83(298 K and 100 kPa),which was the highest among the state-of-the-art adsorbents reported so far.With the rotation of anion and pyrazine ring,the pore size changes continuously,which makes smaller-size C_(4)H_(6) enter the channel while larger-size n-C_(4)H_(8) and iso-C_(4)H_(8) are completely blocked.The excellent breakthrough performance of TaOFFIVE-3-Ni shows great potential in industrial separation of C4 olefins.The specific adsorption binding sites within ZU-96 was further revealed through the modeling calculation.

关键词： Adsorptive separation C4 olefin 13-Butadiene Anion-pillared hybrid microporous material

Robust adaptive control for uncertain nonlinear systems with unknown control directions and actuator nonlinearity

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控制理论与应用（英文版） 2012年第4期10卷 441-450页

作者： Jianhao WANG jianbo hu Engineering College Air Force Engineering University

A robust adaptive control scheme is proposed for a class of uncertain nonlinear systems in strict feedback form with both unknown control directions and non-symmetric dead-zone nonlinearity based on backstepping design. The conditions that the dead-zone slopes and the boundaries are equal and symmetric are removed by simplifying nonlinear dead-zone input model, the assumption that the priori knowledge of the control directions to be known is eliminated by utilizing Nussbaum-type gain technique and neural networks （NN） approximation capability. The possible controller singularity problem and the effect of dead-zone input nonlinearity are avoided perfectly by combining integral Lyapunov design with sliding mode control strategy. All the signals in the closed-loop system are guaranteed to be semi-globally uniformly ultimately bounded and the tracking error of the system is proven to be converged to a small neighborhood of the origin. Simulation results demonstrate the effectiveness of the proposed control scheme.

关键词： Uncertain nonlinear system Robust adaptive control Actuator nonlinearity Backstepping Sliding modecontrol Dead-zone

Effects of functional groups for CO_(2) capture using metal organic frameworks

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Frontiers of Chemical Science and Engineering 2021年第2期15卷 437-449页

作者： Chenkai Gu Yang Liu Weizhou Wang Jing Liu jianbo hu State Key Laboratory of Coal Combustion School of Energy and Power EngineeringHuazhong University of Science and TechnologyWuhan 430074China School of Chemical and Biomolecular Engineering Georgia Institute of TechnologyAtlantaGA 30332-0100USA Henan Key Laboratory of Function-Oriented Porous Materials College of Chemistry and Chemical EngineeringLuoyang Normal UniversityLuoyang 471934China

Metal organic frameworks(MOFs)are promising adsorbents for CO_(2)capture.Functional groups on organic linkers of MOFs play important roles in improving the CO_(2) capture ability by enhancing the CO_(2) sorption affinity.In this work,the functionalization effects on CO_(2) adsorption were systematically investigated by rationally incorporating various functional groups including–SO3H,–COOH,–NH_(2),–OH,–CN,–CH_(3) and–F into a MOF-177 template using computational methods.Asymmetries of electron density on the functionalized linkers were intensified,introducing significant enhancements of the CO_(2) adsorption ability of the modified MOF-177.In addition,three kinds of molecular interactions between CO_(2) and functional groups were analyzed and summarized in this work.Especially,our results reveal that–SO_(3)H is the best-performing functional group for CO_(2) capture in MOFs,better than the widely used–NH_(2) or–F groups.The current study provides a novel route for future MOF modification toward CO_(2) capture.

关键词： metal-organic frameworks functional groups CO_(2)capture GCMC DFT

Photophysics of metal-organic frameworks:A brief overview

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Chinese Physics B 2024年第1期33卷 122-133页

作者：刘晴硕余俊宏胡建波 State Key Laboratory for Environment-Friendly Energy Materials Southwest University of Science and TechnologyMianyang 621010China Laboratory for Shock Wave and Detonation Physics Institute of Fluid PhysicsChina Academy of Engineering PhysicsMianyang 621900China

Metal-organic frameworks(MOFs),which are self-assembled porous coordination materials,have garnered considerable attention in the fields of optoelectronics,photovoltaic,photochemistry,and photocatalysis due to their diverse structures and excellent tunability.However,the performance of MOF-based optoelectronic applications currently falls short of the industry benchmark.To enhance the performance of MOF materials,it is imperative to undertake comprehensive investigations aimed at gaining a deeper understanding of photophysics and sequentially optimizing properties related to photocarrier transport,recombination,interaction,and transfer.By utilizing femtosecond laser pulses to excite MOFs,time-resolved optical spectroscopy offers a means to observe and characterize these ultrafast microscopic processes.This approach adds the time coordinate as a novel dimension for comprehending the interaction between light and MOFs.Accordingly,this review provides a comprehensive overview of the recent advancements in the photophysics of MOFs and additionally outlines potential avenues for exploring the time domain in the investigation of MOFs.

关键词： metal-organic framework(MOF) ultrafast spectroscopy photophysics carrier dynamics

孔洞增长层裂模型的改进及其在模拟不同加载波形层裂实验结果方面的应用

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爆炸与冲击 2024年第5期44卷 48-53页

作者：张凤国王裴王言金胡建波北京应用物理与计算数学研究所北京100094 中国工程物理研究院流体物理研究所冲击波物理与爆轰物理全国重点实验室四川绵阳621999

冲击波在靶板自由面反射导致靶板材料内部产生动态拉伸层裂损伤是材料的典型损伤破坏形式之一,材料的初始微结构、冲击加载的强度和应变率、温度等因素直接影响材料内部的损伤演化过程。靶板自由面速度曲线变化间接反映材料内部损伤的... 详细信息

冲击波在靶板自由面反射导致靶板材料内部产生动态拉伸层裂损伤是材料的典型损伤破坏形式之一,材料的初始微结构、冲击加载的强度和应变率、温度等因素直接影响材料内部的损伤演化过程。靶板自由面速度曲线变化间接反映材料内部损伤的演化过程,在层裂损伤物理模型研究方面,目前采用适宜的层裂损伤模型较好地模拟不同冲击加载波形下靶板自由面速度曲线的相关文献很少,主要借助实验手段探讨加载波形与自由面速度曲线变化以及层裂损伤演化过程之间的关联。对于孔洞增长层裂损伤模型,通过解析加载应变率与层裂强度以及损伤模型初始损伤参数之间的相互关系,给出了模型初始损伤参数的计算方法,有效地将损伤模型初始损伤参数与加载应变率关联在一起。该计算方法不仅可以较好地模拟方波、三角波以及泰勒波冲击加载铝材料层裂实验的自由面速度曲线,同时,计算得到的层裂强度和层裂片厚度也与实验结果符合。此外,还进一步分析了靶板内部不同位置的初始损伤、层裂强度的分布与应变率之间的关联,以及其对自由面速度曲线的影响。

关键词：冲击加载波形层裂损伤自由面速度数值分析

Efficiency and convergence of China’s export trade embodied carbon emissions

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Chinese Journal of Population,Resources and Environment 2021年第2期19卷 133-142页

作者： jianbo hu Shuo Yan Lei Wang School of Economics Guizhou University of Finance and EconomicsGuiyang550025China Institute of Industrial Economy Chinese Academy of Social SciencesBeijing100006China

Based on the input-output data from 2002 to 2017,this paper combined the three-stage DEA model with the non-competitive I-O model and measured the embodied carbon efficiency of export trade in China’s 26 product sectors,and further investigated its influencing factors and convergence issues.The results of the study showed that:①The embodied carbon efficiency of export trade in China’s overall product sector demonstrated a positive development trend from 2002 to 2017,and this positive trend was more obvious after the implementation of conservation culture construction in 2012.But the differences of embodied carbon emission efficiency level among the product sectors were still significant.②Measured by the K-means clustering analysis method,this study found that agriculture,other service industries,wholesale and retail industries,catering industry,construction industry and manufacturing industry with strong innovation ability were mostly concentrated at high and medium efficiency levels,while industrial sectors with resource dependence and high energy consumption,such as metal smelting and rolling processing industries,non metallic mineral products industry,and coal mining industry,were at a low efficiency level.③All product sectors hadσconvergence,absoluteβconvergence and conditionalβconvergence during 2002-2010 and 2010-2017,and the level of each product sector in 2010-2017 was higher than that in 2002-2010 according to the perspective of convergence speed and degree of convergence.④Technological progress had not fully played a role in suppressing energy consumption and improving the efficiency of embodied carbon efficiency,and it would also widen the gap between the embodied carbon emission efficiency levels of various product sectors.The expansion of trade scale could effectively improve carbon emission efficiency and narrow the gap between sectors.Environmental regulation could effectively promote the improvement of embodied carbon emission efficiency but would widen the level gap between sectors.These findings

关键词： Export trade Embodied carbon efficiency Three-stage DEA model Non-competitive I-O model Convergence analysis

Dynamic Surface Backstepping Global Sliding Mode Control for CPS Based on NDO

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Journal of Harbin Institute of Technology(New Series) 2015年第1期22卷 73-78页

作者： Fei Li jianbo hu Jun Wu Jianhao Wang Materiel Management & Safety Engineering College Air Force Engineering University Institute of Cyber-Systems and Control Zhejiang University Unit 93286 People's Liberation Army

Based on dynamic surface control and the nonlinear disturbance observer technique,it proposes a nonlinear adaptive backstepping global sliding mode control system for a typical cyber physical system( CPS)with aerodynamic coefficients and external disturbance uncertainties. The dynamic surface control technique can provide the capability which can solve the problem of "explosion of complexity"in backstepping sliding mode controllers. The nonlinear disturbance observers are employed to observe the arbitrary model uncertainties of nonlinear flight dynamic system. The global sliding mode control method is used to improve the response rate and the precision of the tracking. The simulation results show the effectiveness of the proposed control system.

关键词： cyber physical system disturbance uncertainties dy

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青藏高原草地群落组成和结构的海拔梯度格局

Journal of Plant Ecology 2022年第4期15卷 808-817页

作者： Xin Wang Jiangling Zhu Shitao Peng Tianli Zheng Zhaoyu Qi jianbo hu Chengjun Ji State Key Laboratory of Grassland Agro-ecosystems College of Pastoral Agricultural Science and TechnologyLanzhou UniversityLanzhou 730020China Department of Ecology College of Urban and Environmental ScienceKey Laboratory for Earth Surface Processes of the Ministry of EducationPeking UniversityBeijing 100871China Environmental Science and Technology Research Center Tianjin Research Institute for Water Transport EngineeringM.O.T.Tianjin 300456China

青藏高原高寒草地是维持区域生态安全的天然屏障,也在一定程度上造就了该区域较高的生物多样性。然而,我们对青藏高原高寒草地植物群落组成和结构的海拔分布格局及其自身维持机制仍知之甚少。本研究在青藏高原东北部沿公路形成的海拔梯... 详细信息

青藏高原高寒草地是维持区域生态安全的天然屏障,也在一定程度上造就了该区域较高的生物多样性。然而,我们对青藏高原高寒草地植物群落组成和结构的海拔分布格局及其自身维持机制仍知之甚少。本研究在青藏高原东北部沿公路形成的海拔梯度设置了39个实验样地(海拔跨度为2800–5100m),每个样地设5个调查样方进行群落调查,包括物种组成、高度、盖度,评估青藏高原高寒草地植物群落的α和β多样性的海拔梯度格局及其影响因素。研究结果发现草地群落高度随着海拔的增加而显著降低,而群落盖度变化却不显著。随着海拔的增加,植物物种丰富度(α多样性)显著增加,而群落变异性(β多样性)显著降低。约束聚类分析表明,随海拔增加草地群落结构逐渐发生变化,基于此,在这种变化过程中,我们监测到3个渐变的海拔间断点,分别在海拔3640、4252和4333 m处。结构方程模型(SEM)表明,降水增加和温度降低对α多样性有显著的正向作用,但植物群落α多样性的变化显著改变群落变异性。以上结果表明,青藏高原的群落组成和结构沿海拔梯度发生了从量变到质变的过程。

关键词： α多样性 β多样性海拔梯度青藏高原海拔间断点

In situ observation of the phase transformation kinetics of bismuth during shock release

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Chinese Physics B 2024年第4期33卷 586-592页

作者：李江涛王倩男徐亮柳雷张航 Sota Takagi Kouhei Ichiyanagi Ryo Fukaya Shunsuke Nozawa 胡建波 Laboratory for Shock Wave and Detonation Physics Research Institute of Fluid PhysicsChina Academy of Engineering PhysicsMianyang 621900China State Key Laboratory for Environment-Friendly Energy Materials Southwest University of Science and TechnologyMianyang 621010China Japan Society for the Promotion of Science Tokyo102-0083Japan Institute of Materials Structure Science High Energy Accelerator Research OrganizationIbaraki305-8572Japan

A time-resolved x-ray diffraction technique is employed to monitor the structural transformation of laser-shocked bismuth.Results reveal a retarded transformation from the shock-induced Bi-Ⅴphase to a metastable Bi-Ⅳphase during the shock release,instead of the thermodynamically stable Bi-Ⅲphase.The emergence of the metastable Bi-Ⅳphase is understood by the competitive interplay between two transformation pathways towards the Bi-Ⅳand Bi-Ⅲ,respectively.The former is more rapid than the latter because the Bi-Ⅴto B-Ⅳtransformation is driven by interaction between the closest atoms while the Bi-Ⅴto B-Ⅲtransformation requires interaction between the second-closest atoms.The nucleation time for the Bi-Ⅴto Bi-Ⅳtransformation is determined to be 5.1±0.9 ns according to a classical nucleation model.This observation demonstrates the importance of the formation of the transient metastable phases,which can change the phase transformation pathway in a dynamic process.

关键词： phase transformation time-resolved x-ray diffraction(XRD) bismuth metastable phase nonequilibrium phase diagram