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Application of annexation principle to the study of thermodynamic properties of Ag-Bi-In metallic melts

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北京科技大学学报 2003年第2期25卷 109-109页

作者： jian zhangmetallurgy school, university of science and technology beijing, beijing 100083, china

Based on the measured activities,the phase diagrams and the annexation principle,the calculating models of mass action concentrations for Ag-Bi and Ag-Bi-In melts have been *** calculated results agree with practice and obey the mass action law,showing that the models formulated can reflect the structural characteristics of both ***,it confirms that annexation principle is applicable to the Ag-Bi-In metallic *** melts involving eutectic which give rise to phase separation,and in which activcities exhibit positive deviation from Raoult's law is the basic cause of melts transforming from homogeneous to heterogeneous ones.

关键词： Ag-Bi-In金属融体热力学性质合并原则计算模型银铋铟

Application of the annexation principle to the thermodynamic property study of ternary metallic melts In-Bi-Cu and In-Sb-Cu

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Journal of university of science and technology beijing 2002年第3期9卷 170-176页

作者： Man zhangmetallurgy school, university of science and technology beijing, beijing 100083, china (Received 2001-10-27) Metall. Sch. Univ. of Sci. and Technol. Beijing Beijing 100083 China

Based on the phase diagrams, measured activities and the annexationprinciple, calculating models of mass action concentrations for In-Bi-Cu and In-Sb-Cu melts havebeen formulated. Calculated results not only agree well with practical values, but also obey themass action law, showing that the deduced model can reflect the structural reality of given meltasand that the annexation principles is applicable to these tow ternary metallic melts. So long asthere is one from three binary systems constituting the ternary melts, in which the activities ofone component exhibit positive deviation relative to Raoultian behavior, heterogeous meltsinevitably would form, so heterogeneous calculating model should be used to calculate their massaction concentrations. On the contrary, if all the binary melts are homogeneous and their activitiesexhibit negative deviation with respect to the Raoult's law, then the ternary melts formed fromthem will certainly be homogeneous, hence single phase model should be applied.

关键词： activity mass action concentration coexistence theory annexationprinciple

Applicability of mass action law to sulphur distribution between slag melts and liquid iron

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Journal of university of science and technology beijing 2002年第2期9卷 90-98页

作者： jian Zhang Metallurgy school, university of science and technology beijing, beijing 100083, china Metall. Sch. Univ. of Sci. and Technol. Beijing Beijing 100083 China

According to the mass action law and the coexistence theory of slagstructure, the calculating models of mass action concentration for CaO-MgO-FeO-Fe_2O_3-SiO_2,CaO-MgO-MnO-FeO-Fe_2O_3-P_2O_5-SiO_2 and CaO-MgO-MnO-FeO-Fe_2O_3-Al_2O_3-P_2O_5-SiO_2 slag melts areformulated and sulphur distribution between the slag melts and liquid iron is treated. It is foundthat CaO, MnO and FeO promote desulphurization, while MgO is detrimental to desulphurization. Inaddition, the sulphur distribution coefficients between the slag melts and liquid iron andpresented.

关键词： mass action law coexistence theory of slag structure activity massaction concentration

Calculating model of mass action concentrations for Ag-Au-Cu melts

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Rare Metals 2002年第1期21卷 43-47页

作者： ZHANG jian Metallurgy school, university of science and technology beijing, beijing 100083, china Metallurgy school University of Science and Technology Beijing 北京 100083

Based on phase diagrams and measured activities, the calculatingmodel of mass action concentrations for het- erogeneous meltsAg-Au-Cu was formulated. Calculated results agree with the improvedresults of recent research work, Showing that the model formulatedcan reflect the structural characteristics of these melts. In thismodel, without the help Of any empirical parameters, only threeequilibrium constants are used, hence it is simple, lear, andfavorable to the sim- Plification of calculation.

关键词： activity mass action concentration eutectic Solid solution

Calculating Model of Mass Action Concentrations for Mn-C Melts and Optimization of Thermodynamic Parameters

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International Journal of Minerals,Metallurgy and Materials 1998年第4期12卷 208-211页

作者： jian Zhang(Metallurgy school, university of science and technology beijing, beijing 100083, china) Metallurgy school University of Science and Technology Beijing Beijing 100083 China

Based on the phase diagram, the coexistence theory of the metallic melt structure involving compoundformation and the regularity of melts containing saturated phase, a calculating model of mass action concentrationsfor Mn-C melts was formulated. According to the activities (or activity coefficients AM. and γc.), obtained by theUnified Interaction Parameter Model (UIPM), the thermodynamic parameters G and G at higher temperatures (1628～1873 K) were optimized by the repeated try and error method. It is testified that G G(873～1273 K) and G (298～1623 K), obtained at lower temperatures, can also be used at the above-mentionedhigher temperatures. The calculated N. and N agree well with ac. and ac obtained by UIPM. This result showsthat the deduced model can reflect the structural reality of Mn-C melts.

关键词： Mn-C melts activity coexistence theory mass action concentration

Calculating Models of Mass Action Concentrations for Ni-Mn and Co-Mn Melts and Optimization of Their Thermodynamic Parameters

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International Journal of Minerals,Metallurgy and Materials 2000年第4期14卷 246-250页

作者： jian Zhang (Metallurgy school, university of science and technology beijing, beijing 100083, china) Metallurgy school University of Science and Technology Beijing Beijing 100083 China

According to phase diagrams, measured activities as well as the coexistence theory of motallic melts structure involving compound formation, the calculating models of mass action concentrations for Ni-Mn and Co-Mn melts are formulated and their thermodynamic parameters are optimized. As a result, the calculated mass action concentrations agree well with the corresponding measured activities, showing that these models can reflect the structural characteristics of both Ni-Mn and Co-Mn melts.

关键词： activity metallic melts coexistence theory mass action concentration

A Back Look on the Binary Phase Diagrams of Metals from the Mass Action Law and the Coexistence Theory of Metallic Melts

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Journal of university of science and technology beijing 2001年第1期8卷 15-19页

作者： jian Zhang Metallurgy school, university of science and technology beijing, beijing 100083, china Metallurgy school Univ. of Science/Technology Beijing Beijing 100083 China

According to the mass action law and the coexistence theory of metallic melts, the mass action concentrations of Cu-Mg, Bi-Tl and Ni-Al melts involving compound formation have been calculated. The calculated results show that, except the ultimate case of pure element, when two elements are present in the melts, all structural units (atoms and molecules) without exception will be present in the melts, i.e., their concentrations may change from great to small, but they will not vanish into nothing, and only under such conditions, the calculated results both agree with practice and obey the law of mass action. In view of that over considerable wide composition range, the activities of both elements of the three solid binary alloys mentioned above have been measured, this seems in contradiction with the present relevant phase diagrams, in which the structural units are determined by composition range, so the latter needs further investigation and consideration.

关键词： activity phase diagram the mass action law the coexistence theory

Calculating Models of Mass Action Concentrations for Fe-P and Cr-P Melts and Optimization of Their Thermodynamic Parameters

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International Journal of Minerals,Metallurgy and Materials 1999年第3期13卷 174-177页

作者： jian Zhang(Metallurgy school, university of science and technology beijing, beijing 100083, china) Metallurgy school University of Science and Technology Beijing Beijing 100083 China

Based on the phase diagrams, reliable reference experimental data and the coexistence theory of metallic melts structure involving compound formation, calculating models of mass action concentrations for Fe-P and Cr-P melts have been formulated. At the same time, some of their thermodynamic parameters have been optimized. The calculated results not only agree well with the measuredvalues, but also obey the mass action law rigorously, this in turn shows that these models can reflect the structural characteristics of corresponding melts.

关键词： activity phase diagram coexistence theory mass action concentration

Calculation Models of Mass Action Concentrations for Metallic Melts Involving Monotectic

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Journal of university of science and technology beijing 2001年第4期8卷 248-253页

作者： jian Zhang Metallurgy school, university of science and technology beijing, beijing 100083, china Metallurgy school University of Science and Technology Beijing Beijing 100083 China

Based on the phase diagrams, measured activities as well asDeltaG(m) and DeltaG(xs), calculating models of mass action concentrations for metallic melts involving monotectic have been formulated. The calculated results agree with practice on the whole, showing that the models deduced generally can reflect the structural characteristics of these melts. The metastable compounds formed in the melts are of the types A(2)B(3), AB(2), A(2)B(3) or AB and A(2)B(3)+AB etc..

关键词： metallic melts monotectic activity mass action concentration