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Chinese Journal of Structural Chemistry 2022年第11期41卷 71-83页

作者： Hao Zhang Ru Sun Da-Cheng Li jian-min dou Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology School of Chemistry and Chemical EngineeringLiaocheng UniversityShandong 252059China

Metal-organic frameworks(MOFs)have always been the focus of chemists due to their diverse structures,adjustable pore size and high stability since they came into *** recent years,as one of the most significant applications of MOFs porous materials,photocatalytic organic compounds transformation has made full-grown progress both in the preparation of the catalysts themselves and in the scope of specific ***,we summarize the research progress of MOFs catalysts for photocatalytic transformations of organic compounds in recent three *** outstanding works on the preparation and synthesis strategies of photocatalysts are introduced firstly,including internal optimization and modification of MOFs,POM@MOF composite and core-shell MOF@COF *** second part is about the application of diverse types of organic reactions,including dual-function organic reactions,catalytic oxidation reactions,comprehensive utilization of CO_(2) and degradation of organic ***,the development opportunities and some problems to be solved in this field are proposed.

关键词： metal-organic frameworks porous materials photocatalytic reaction organic transformations

[Na(DB18-C-6)(H2O)2][Na(DB18-C-6)(SCN)2]：Two-Di-mensional Network Complex Assembled by π-π Stacking Interactios,Hydrogen Bonds and Electrostatic Interactions

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Chinese Journal of Chemistry 2002年第5期20卷 424-426页

作者： De‐Zhong Zhu Xing‐min Song jian‐min dou Ying Liu Da‐Qi Wang Department of Chemistry Liaocheng Teacher's College Liaocheng 252000

A novel two‐dimensional network dibenzo‐18‐crown‐6 (DB18‐C6) complex: [Na (DB18‐C‐6) (H 2 O) 2 ] [Na (DB18‐C‐6) (SCN) 2 ] has been isolated and characterized by elemental, IR and X‐ray diffraction analysis. The crystal structure belongs to monoclinic, space group P 2 1 /c with cell dimensions a = 1.06178(7), b = 1.40243(8), c = 3.03496(19) nm, β = 90.4220(10)°, V = 4.5292(5) nm 3 , Z=4, D calcd =1.351 g/ cm 3 , F (000) = 1936, R 1 = 0.0369, wR 2 = 0.0821. The most interesting feature in this structure is that complex cation and complex anion form a two‐dimensional network via τ‐τ stacking interactions, hydrogen bonds and electrostatic interactions.

关键词： τ‐τ stacking interactions hydrogen bonds crown ether DB18‐crown‐6 crystal structure

Synthesis and Crystal Structure of a Binuclear Gadolinium（Ⅲ） Complex Bridged by Cucurbit[6]uril

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Chinese Chemical Letters 2006年第1期17卷 93-96页

作者： Gui Ling ZHANG Zhi Yong WU Yan Tuan LI Da Qi WANG jian min dou Marine Drug and Food Institute Ocean University of China Qingdao 266003 Department of Chemistry Liaocheng University Liaocheng 252059

A new cucurbit[6]uril bridsed binuclear complex {[Gd（H2O）6]2[Q6（H2O）]}C16·4H2O, where Q6 represents cucurbit[6]uril, has been synthesized and characterized by X-ray diffraction. The crystal structure shows that the complex has an extended cucurbit[6]uril-bridged structure consisting of two gadolinium（Ⅲ） ions, in which each gadolinium（Ⅲ） ion is coordinated with two neighboring carbonylic oxygen atoms of Q6 and six oxygen atoms of water molecules that leans toward one side of the portal. One disordered guest water molecule resides in the Q6 molecule cavity and occupies two different positions. Hydrogen bonds assemble the complcx to threedimensional supramolecular structure.

关键词： Cucurbituril binuclear gadolinium(Ⅲ) complex crystal structure

Syntheses and Supramolecular Structures of Two Nickel（II） Compounds Based on Two Thiosemicarbazone Ligands

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Chemical Research in Chinese Universities 2013年第3期29卷 414-418页

作者： Cheng-juan Li Ze-jing Feng Xiao-juan Zhao Su-na Wang jian-min dou Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology School of Chemistry and Chemical Engineering Liaocheng University Liaocheng 252059 P. R. China

Two new compounds, [Ni2（L1）（Py）6]Py·CH3OH（1） and [Ni3（LZ）2（PY）4]·2DMF（2）（H4L1=N,N＇-bisalicyl-bisthiocarbamide; H3L2=3-hydroxyl-2-naphthalene thiosemicarbazide; Py=pyridine; DMF=dimethyl fumarate）, based upon two thiosemicarbazone ligands have been obtained and characterized by elemental analysis, Fourier transform infrared（FTIR） and X-ray diffraetion（XRD）. Compound 1 possesses a binuclear cluster, in which the bisalicylbisthi- ocarbamide acts as a hexadentate bridge. Compound 2 exhibits a linear trinuclear cluster with the triply-deprotonated ligand acting as pentadentate bridge. C--H…O, C--H…π and C--…S weak interactions further link these molecules to form interesting supramolecular networks.

关键词： Thiosemicarbazone ligand Weak interaction Supramolecular framework

Rh^(III)-Catalyzed heteroarylation of N-2,6-difluoro-phenyl arylamides with heteroaryl boronate esters

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Organic Chemistry Frontiers 2022年第4期9卷 1077-1084页

作者： Jia-Xue Wu Qing-Xia Yao Wen-Zeng Duan Da-Cheng Li Xian-Qiang Huang jian-min dou Huai-Wei Wang Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology School of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252000China

Herein,an efficient strategy to achieve aryl-heteroaryl formation via Rh^(III)-catalyzed ortho-C(sp^(2))–H heteroarylation of(hetero)arenes with heterocyclic boronates using a readily removable N-2,6-difluoro-phenyl arylamide directing group has been disclosed.A variety of heteroaromatic boronates as the coupling partners were shown to be able to participate in this protocol,providing the desired hetero-arylated products with high reactivity and good tolerance of functional groups.

关键词： boron esters heterocyclic

The Novel Benzo-15-Crown-5 with Palladium(II) Complex: [Na(B15CS)]_2,[Pd(SCN)_4]

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Chinese Chemical Letters 2000年第9期11卷 835-838页

作者： Lan Ying ZHU jian min dou Ying LIU De Zhi SUN Pei Ju ZHENG Chen Xia DU Yu ZHU Department of Biology and Chemistry, Liaocheng Teacher’s University, Liaocheng 252000 Research Center of Analysis and Measurement, Fudan University, Shanghai 200433 Key Department of Biology and Chemistry Liaocheng Teacher"s University Research Center of Analysis and Measurement Fudan University Key Laboratory of Applied Chemistry Zhengzhou University

A novel Pd(II) Benzo-15-crown-5 complex [Na(B15CS)]_2[Pd(SCN)_4] has been isolated and characterized by IR and X-ray diffraction analysis. The crystal structure belongs to monoclinic, space group P2_1,/n with cell dimensions, a = l.0164(6), b = l.3743(3), c = l.4987(7) nm, β = 95.248(6) °, V = 2.0847 'nm_3, Z = 2, F(000) = 944, R = 0.053, Rw = 0.072. The compound consists of two [Na(B15CS)]+ complex canons and a [Pd(SCN)4_]^(2-) complex anion. Each sodium ion is coordinated by five crown ether oxygen atoms and one N atom from the SCN group of [Pd(SCN)_4]^(2-) to form stable neutral complex.

关键词： Benzo-15-crown-5 crown ether crystal structure palladium complex.

Canon-π Interactions. Synthesis and Crystal Structure of Palladium Complex:[K(DB18C6)]_2[Pd(SCN)_4]

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Chinese Chemical Letters 2000年第5期11卷 463-466页

作者： jian min dou Ying LIU Lan Ying ZHU De Zhi SUN Pei Ju ZHENGZ Chen Xia DU Yu ZHU (Department of Chemistry and Biology, Liaochcng Teacher’s University, Liaocheng 252000 Research Center of Analysis and Measurement Fudan University, Shanghai 200433 ~3Key La Department of Chemistry and Biology Liaocheng Teacher's University Liaocheng 252000 China Res. Ctr. of Anal. and Measurement Fudan University Shanghai 200433 China Key Laboratory of Applied Chemistry Zhengzhou University Zhengzhou 450052 China

A novel Pd(Ⅱ)-dibenzo-18-crown-6(DB18C6) complex [K(DB18C6)]_2, [Pd(SCN)_4] has been isolated and characterized by X-ray diffraction analysis. In the solid state, it displays a quasi- one-dimensional infinite chain of two [K(DB18C6)]+ complex canons and a [Pd(sCN)_4]^(2-) anion bridged by K+-π interactions between adjacent [K(DB18C6)] + units.

关键词： Canon-π interacions crown ether bestal Structure palladium complex.

Synthesis and Crystal Structure of Copper（Ⅱ） Complex Bearing m-Carborane Ligand

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Synthesis and Crystal Structure of Copper（Ⅱ） Complex Bear...

Synthesis and Crystal Structure of Copper（Ⅱ） Complex Bearing o-Carborane Ligand

第六届全国物理无机化学会议

作者： Zhong Han,Da-Cheng Li,jian-min dou~* Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering,Liaocheng University,Liaocheng 252059

＜正＞Derivatives of the polyhedral carborane cluster system attract some interest for pharmacokinetic studies in the fields of boron neutron capture therapy of cancer and radionuclide diagnostics and *** reports have... 详细信息

关键词： m-carborane dicarboxylic acid Copper(Ⅱ)Complex

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Synthesis and Crystal Structure of Copper（Ⅱ） Complex Bear...

Synthesis and Crystal Structure of organotin Complex {[(C2H5)3NH][(Ph3Sn)(m-CDC)]·2H2O}n

第六届全国物理无机化学会议

＜正＞The design and synthesis of functional complexes,constructed from multicarborane units and transition metals, have attracted much interest because of their high boron content,fundamental properties,and a variety... 详细信息

关键词： o-carborane mercapto group copper complex

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Synthesis and Crystal Structure of organotin Complex {[(C2H5...