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Green synthesis of luminescent La-MOF nanoparticle from waste poly(ethylene terephthalate) for high-performance in Fe(Ⅲ) detection

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Rare Metals 2024年第8期43卷 3833-3843页

作者： Zhi Gong Zhi-kui Dai Zhi-Yue Dong Qiu-Xuan Liu Valentin A.Milichko Hua-jian Liu Jie Liu Ran Niu jiang Gong Key Laboratory of Material Chemistry for Energy Conversion and Storage Hubei Key Laboratory of Material Chemistry and Service FailureHubei Engineering Research Center for Biomaterials and Medical Protective MaterialsSemiconductor Chemistry CenterSchool of Chemistry and Chemical EngineeringMinistry of EducationHuazhong University of Science and TechnologyWuhan 430074China School of Chemical Engineering and Pharmacy Wuhan Institute of TechnologyWuhan 430073China Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical EngineeringHubei UniversityWuhan 430062China School of Physics and Engineering ITMO UniversitySt.Petersburg197101Russia School of Materials Science and Engineering Hubei UniversityWuhan430062China Guangdong Provincial Key Laboratory of Technique and Equipment for Macromolecular Advanced Manufacturing School of Mechanical and Automotive EngineeringKey Laboratory of Polymer Processing EngineeringMinistry of EducationSouth China University of TechnologyGuangzhou 510641China

Developing luminescent metal-organic frameworks(MOFs) capable of high-efficiency Fe^(3+)sensing has aroused great attraction in the fields of biology,chemistry,***,previous solvothermal methods are limited by organic solvent usage,time consuming,high pressure,and high-energy ***,we propose the waste-toMOF strategy towards the scale-up production of La-MOF nanoparticles through the ball milling of recycled poly(-ethylene terephthalate)(PET) bottles and La(NO_(3))_(3)·_(6)H_(2)*** goes on alkaline hydrolysis to form 1,4-benzenedicarboxylic acid sodium salt(Na_(2)BDC) and ethylene glycol by ball ***,BDC reacts with La^(3+)to form *** as-prepared La-MOF crystal nanoparticles possess a rod-like morphology with the size of few hundred ***,La-MOF nanoparticles display high selectivity and sensitivity for Fe^(3+)*** quenching constant and limit of detection are 5.29×10^(3)(mol·L^(-1))^(-1) and 0.147 μmol·L^(-1),respectively,thus surpassing many advanced Fe^(3+) *** to the result of density functional theory,the high Fe^(3+) detection performance of La-MOF is related to the complexing of Fe^(3+)with La-MOF,which leads to the gradual dissociation of the coordination bond between terephthalic acid and La^(3+).It is anticipated that the mechanochemistry milling-based wasteto-MOF strategy provides a new platform for the massive production of functional MOFs in a green manner.

关键词： Metal-organic framework Waste polyester Mechanochemistry milling Fluorescence sensor

Comprehensive analysis of gene mutations and mismatch repair in Chinese colorectal cancer patients

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World Journal of Gastrointestinal Oncology 2024年第6期16卷 2673-2682页

作者： Huang Chen Rui-Ying jiang Zhan Hua Xiao-Wei Wang Xiao-Li Shi Ye Wang Qian-Qian Feng Jie Luo Wu Ning Yan-Fen Shi Da-kui Zhang Bei Wang jian-Zheng Jie Ding-Rong Zhong Department of Pathology China-Japan Friendship HospitalBeijing 100029China Department of Gastrointestinal Surgery China-Japan Friendship HospitalBeijing 100029China Department of Scientific Research GeneisBeijing 100012China

BACKGROUND RAS,BRAF,and mismatch repair(MMR)/microsatellite instability(MSI)are crucial biomarkers recommended by clinical practice guidelines for colorectal cancer(CRC).However,their characteristics and influencing factors in Chinese patients have not been thoroughly *** To analyze the clinicopathological features of KRAS,NRAS,BRAF,and PIK3CA mutations and the DNA MMR status in *** We enrolled 2271 Chinese CRC patients at the China-Japan Friendship *** proteins were tested using immunohistochemical analysis,and the KRAS/NRAS/BRAF/PIK3CA mutations were determined using quantitative polymerase chain *** status was determined using an MSI detection *** analyses were conducted using SPSS software and logistic *** The KRAS,NRAS,BRAF,and PIK3CA mutations were detected in 44.6%,3.4%,3.7%,and 3.9% of CRC patients,*** mutations were more likely to occur in patients with moderate-to-high *** mutations were more likely to occur in patients with right-sided CRC,poorly differentiated,or no perineural *** MMR(dMMR)was detected in 7.9% of all patients and 16.8% of those with mucinous ***,NRAS,BRAF,and PIK3CA mutations were detected in 29.6%,1.1%,8.1%,and 22.3% of patients with dMMR,*** dMMR was more likely to occur in patients with a family history of CRC,aged<50 years,right-sided CRC,poorly differentiated histology,no perineural invasion,and with carcinoma in situ,stage I,or stage II *** This study analyzed the molecular profiles of KRAS,NRAS,BRAF,PIK3CA,and MMR/MSI in CRC,identifying key influencing factors,with implications for clinical management of CRC.

关键词： Colorectal cancer Deficient mismatch repair Microsatellite instability Gene mutation Comprehensive analysis

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ICF激光驱动装置用大尺寸激光薄膜元件

中国激光 2024年第11期51卷 155-172页

作者：朱美萍孙建李静平易葵邵建达中国科学院上海光学精密机械研究所薄膜光学实验室上海201800

大尺寸高功率激光薄膜元件是我国神光系列等大型激光装置中的关键元件,常采用电子束蒸发技术,在高质量光学玻璃基底表面,通过交替沉积两种或多种材料制备而成。典型的高功率激光薄膜元件需具有特定的光谱性能以满足激光系统的光束传输需... 详细信息

大尺寸高功率激光薄膜元件是我国神光系列等大型激光装置中的关键元件,常采用电子束蒸发技术,在高质量光学玻璃基底表面,通过交替沉积两种或多种材料制备而成。典型的高功率激光薄膜元件需具有特定的光谱性能以满足激光系统的光束传输需求,优良的力学性能以最小化波前畸变,高的激光损伤阈值以保障高功率激光装置的安全稳定运行。基于大尺寸高功率激光薄膜元件的关键性能,在调研国内外相关研究工作的基础上,重点介绍了近年来本实验室在大尺寸高功率激光薄膜的高精度膜层厚度和膜层应力控制、激光诱导薄膜损伤机理和激光薄膜损伤阈值提升技术等方面的主要研究进展,最后对该方向的研究进行了简要的总结与展望。

关键词：激光薄膜高功率激光光谱性能膜层应力激光损伤阈值

Potentiation of the lateral habenula-ventral tegmental area pathway underlines the susceptibility to depression in mice with chronic pain

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Science China(Life Sciences) 2024年第1期67卷 67-82页

作者： Chun-kui Zhang Pan Wang Yuan-Yuan Ji jian-Shuai Zhao Jun-Xiang Gu Xian-Xia Yan Hong-Wei Fan Ming-Ming Zhang Yu Qiao Xiao-Die Liu Bao-Juan Li Ming-Hui Wang Hai-Long Dong Hao-Hong Li Peng-Cheng Huang Yun-Qing Li Wu-Gang Hou Jin-Lian Li Tao Chen Department of Anatomy and K.K.Leung Brain Research Centre Fourth Military Medical UniversityXi’an 710032China Beijing Institute of Basic Medical Sciences Beijing 100850China Key Laboratory of Ministry of Public Health for Forensic Science Xi’an Jiaotong UniversityXi’an 710061China Department of Anesthesiology Xijing HospitalFourth Military Medical UniversityXi’an 710032China Department of Neurosurgery the Second Affiliated Hospital of Xian Jiaotong UniversityXi’an 710004China School of Biomedical Engineering Fourth Military Medical UniversityXi’an 710032China Affiliated Mental Health Centre and Hangzhou Seventh People’s Hospital Zhejiang University School of MedicineHangzhou 310013China The MOE Frontier Research Center of Brain&Brain-machine Integration Zhejiang University School of Brain Science and Brain MedicineHangzhou 310058China Department of Neurology The First Affiliated Hospital of Nanchang UniversityNanchang 330006China Department of Anatomy School of MedicineNorthwest UniversityXi’an 710069China

Chronic pain often develops severe mood changes such as ***,how chronic pain leads to depression remains elusive and the mechanisms determining individuals’responses to depression are largely *** we found that depression-like behaviors could only be observed in 67.9%of mice with chronic neuropathic pain,leaving 32.1%of mice with depression *** determined that the spike discharges of the ventral tegmental area(VTA)-projecting lateral habenula(LHb)glutamatergic(Glu)neurons were sequentially increased in sham,resilient and susceptible mice,which consequently inhibited VTA dopaminergic(DA)neurons through a LHbGlu-VTAGABA-VTADA ***,the LHbGlu-VTADA excitatory inputs were dampened via GABAB receptors in a pre-synaptic *** of LHb-VTA pathway largely affected the development of depressive symptoms caused by chronic *** study thus identifies a pivotal role of the LHb-VTA pathway in coupling chronic pain with depression and highlights the activity-dependent contribution of LHbGlu-to-VTADA inhibition in depressive behavioral regulation.

关键词： chronic pain depression lateral habenula ventral tegmental area dopamine susceptibility

基于改进模糊故障树法的梯级水电站联合运行期风险分析

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水电能源科学 2024年第10期42卷 181-185,28页

作者：练继建于雷徐奎马超天津大学建筑工程学院天津300350 西藏自治区水风光储能源技术创新中心西藏林芝860000

以我国某大型梯级水电站为例,基于文献分析法识别其联合运行期的风险源,建立风险指标体系,对传统的模糊故障树法进行改进,在其量化风险概率的基础上,利用层次分析法确定基本事件重要性权重,二者相结合对梯级水电站联合运行期进行风险分... 详细信息

以我国某大型梯级水电站为例,基于文献分析法识别其联合运行期的风险源,建立风险指标体系,对传统的模糊故障树法进行改进,在其量化风险概率的基础上,利用层次分析法确定基本事件重要性权重,二者相结合对梯级水电站联合运行期进行风险分析,计算出梯级水电站联合运行期的风险发生概率。结果表明,梯级水电站联合运行期的风险发生概率为4.22×10^(-3),根据《水电站大坝运行安全评价导则》综合判定,风险等级较高,应合理制定相应措施加强风险防范,降低风险损失。研究结果为制定梯级水电站风险防控措施以及进行风险管理提供了基础和支持。

关键词：梯级水电站运行期故障树风险分析

Interfacial engineering by multifunctional ruthenium complex for CsPbI_(2)Br perovskite solar cells with a fill factor over 0.82

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Science China Materials 2024年第10期67卷 3245-3252页

作者： Shuai Chen Binxia Jia Depeng Chu Hua Li jian Cui Wangen Zhao Zicheng Ding kui Zhao Shengzhong(Frank)Liu Yaohong Zhang Guohua Wu Key Laboratory of Applied Surface and Colloid Chemistry Ministry of EducationShaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Laboratory for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi’an 710119China School of Physics Northwest UniversityXi’an 710127China Qingdao Innovation and Development Base of Harbin Engineering University Harbin Engineering UniversityHarbin 150001China The Key Laboratory of Functional Molecular Solids Ministry of EducationWuhu 241002China

The interface is of paramount importance in heterostructures,as it can be considered as a device in accordance with Kroemer’s *** perovskite solar cells(PSCs),optimizing the interface between the perovskite layer and the hole transport layer is known to be an effective method for enhancing PSC device ***,a metal ruthenium complex coded as C101 is introduced to the perovskite(CsPbI_(2)Br)/hole transport layer(PTAA)interface as a“charge driven motor”to selectively extract holes from CsPbI_(2)Br and then transfer them to PTAA,minimizing the voltage loss in *** significantly,the introduction of C101 layer effectively passivates the surface of CsPbI_(2)Br film and reduces the defect density of CsPbI_(2)Br film due to the covalent bond between the CsPbI_(2)Br and the–C=O group in *** photovoltaic performance of CsPbI_(2)Br PSCs is enhanced by 23.60%upon the introduction of C101 interfacial layer,with the champion CsPbI_(2)Br PSC exhibiting a power conversion efficiency of 14.96%in a reverse scan,a short-circuit current of 15.84 mA·cm^(−2),an open-circuit voltage of 1.15 V,and a fill factor of 82.03%.Additionally,the introduction of C101 simultaneously enhances the humidity tolerance of CsPbI_(2)Br PSCs.

关键词： perovskite solar cells CsPbI_(2)Br interfacial engineering ruthenium complex multifunctional

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电流体雾化双液滴电聚结行为研究

机械设计与制造 2024年第5期399卷 278-282,289页

作者：刘振东陈建魁华中科技大学机械科学与工程学院湖北武汉430074

电流体喷印技术具有分辨率高,溶液参数适应性广等优点,是新型显示制造工艺创新突破的重要载体之一,可用于OLED微米厚度有机TFE膜高效制造。为深入探索电流体雾化技术制备微纳液膜过程,解决现阶段对液膜制备过程中各因素作用机理了解不... 详细信息

电流体喷印技术具有分辨率高,溶液参数适应性广等优点,是新型显示制造工艺创新突破的重要载体之一,可用于OLED微米厚度有机TFE膜高效制造。为深入探索电流体雾化技术制备微纳液膜过程,解决现阶段对液膜制备过程中各因素作用机理了解不清的问题,基于相场方法建立了液滴电聚结两相流耦合模型,分析了制备过程中“双液滴电聚结”单元。研究外加电压、基板接触角、液滴间隙和直径对液滴聚结的影响,并总结了液滴可聚结工艺参数相图。研究结果表明,外加电压越大、液滴隙径比越小,聚结后液滴高径比越大,聚结越快;基板接触角越大,聚结后高径比越大,聚结越慢,甚至可能使液滴无法聚结。在亲水基板上外加适当电压或增加液滴密度缩短液滴间隙有助于促成基板上液滴电聚结.该研究结论和工艺相图可应用与电流体雾化制膜时工艺参数调控。

关键词：电流体喷印电流体雾化液滴电聚结两相流多场耦合数值仿真

爆破震动作用下高地应力巷道动力响应特征与稳定性研究

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振动工程学报 2024年第3期37卷 414-422页

作者：乔国栋刘泽功高魁刘健傅师贵安徽理工大学安全科学与工程学院安徽淮南232001 合肥综合性国家科学中心能源研究院安徽合肥230031

为了研究爆破震动作用下高地应力巷道的动力响应特征及其稳定性,以淮南潘三矿超前预裂卸压爆破扰动瓦斯综合治理巷为工程背景,通过理论分析建立了爆破作业扰动巷道围岩模型,并根据应力波传播理论及波前动量守恒定理推导出了爆破震动作... 详细信息

为了研究爆破震动作用下高地应力巷道的动力响应特征及其稳定性,以淮南潘三矿超前预裂卸压爆破扰动瓦斯综合治理巷为工程背景,通过理论分析建立了爆破作业扰动巷道围岩模型,并根据应力波传播理论及波前动量守恒定理推导出了爆破震动作用下巷道围岩振动方程。使用数值模拟研究了巷道围岩质点峰值振动速度(Peak Particle Velocity,PPV)的衰减特征,从应力分布规律的角度对理论分析进行了补充,并根据模拟结果对巷道围岩稳定性进行了分析。结果表明:巷道围岩振动方程显示,爆炸应力波入射角度的不同会导致巷道围岩不同区域的动态响应特征存在差异。随着爆心距增大,巷道轮廓面附近围岩PPV出现波动,并在自由面处获得最大峰值振速;地应力对巷道围岩PPV具有抑制作用,地应力越大抑制作用越明显,且不同位置围岩的PPV对地应力敏感度存在差异;随着地应力增大,爆破震动作用下巷道围岩受力状态从拉剪变为压剪,最大主应力和剪切应力也随之增大。研究认为随着埋深增加,在对爆破震动作用下巷道围岩的稳定性进行评估时地应力因素不可忽略。对于潘三矿超前预裂卸压爆破工程现场而言,除了巷道的直墙外,墙角、拱墙也是危险区域,应当着重予以加固并加强监测。

关键词：地应力动力响应爆破震动围岩失稳质点峰值振动速度

Diffusion Approximation of a Multitype Re-entrant Line under Smaller-buffer-first-served Policy

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Acta Mathematica Sinica,English Series 2011年第12期27卷 2481-2492页

作者： jian kui YANG School of Science Beijing University of Posts and Telecommunications Beijing 100876 P. R. China

This paper studies a multitype re-entrant line under smaller-buffer-first-served policy, which is an extension of first-buffer-first-served re-entrant line. We prove a heavy traffic limit theorem. The key to the proof... 详细信息

关键词： Multitype re-entrant line heavy traffic reflecting Brownian motion fluid model diffusion approximation