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Chinese Journal of Chemical Engineering 2024年第4期68卷 16-26页

作者： Zhi Hu jiahong wang Tongtong Sun School of Environmental Science and Engineering Shaanxi University of Science&TechnologyXi'an 710021China Shaanxi Key Laboratory of Green Preparation and Functionalization of Inorganic Materials Xi'an 710021China

A novel tetraethylenepentamine(TEPA)functionalized magnetic mesoporous silica adsorbent(FNMs/TEPA)was prepared for the adsorption of Cr(III)-ethylenediaminetetraacetic acid(EDTA)from wastewater.The characterization of the prepared adsorbent certified that TEPA was modified onto the magnetic mesoporous silicon(FNMs),while FNMs/TEPA maintained the ordered mesoporous and pristine magnetic properties.The batch adsorption experiments demonstrated that TEPA significantly enhanced the removal capacity of the adsorbent for Cr(III)-EDTA.FNMs/TEPA exhibited an excellent adsorption property(13.84 mg·g^(-1))at pH 4.0.Even in the presence of high concentrations of coexisting ions and organic acids,the adsorption performance of FNMs/TEPA was stable.Experimental characterization and DFT demonstrated that the adsorption of Cr(III)-EDTA was ascribed to the electrostatic interaction,hydrogen bonding,and complexation between Cr(III)-EDTA and amino groups on the adsorbent surface.The analysis of the independent gradient model(IGM)shows that electrostatic interaction is the main mode of action in the adsorption process.Moreover,FNMs/TEPA demonstrated remarkable reusability in three regeneration cycles.These findings indicated that FNMs/TEPA possessed excellent application prospects in the disposal of wastewater containing Cr(III)-EDTA.

关键词： TEPA functionalized magnetic mesoporous silicon Adsorption Cr(III)-EDTA Density functional theory calculations

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Engineering the axial coordination of cobalt single atom catalysts for efficient photocatalytic hydrogen evolution

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Nano Research 2024年第6期17卷 5114-5121页

作者： Ning Kang Lingwen Liao Xue Zhang Zhen He Binlu Yu jiahong wang Yongquan Qu Paul KChu Seeram Ramakrishna Xue-Feng Yu Xin wang Licheng Bai Materials Interfaces Center Shenzhen Institute of Advanced TechnologyChinese Academy of Sciences(CAS)Shenzhen 518055China Key Laboratory of Materials Physics Anhui Key Laboratory of Nanomaterials and NanotechnologyCAS Center for Excellence in NanoscienceInstitute of Solid State PhysicsChinese Academy of SciencesHefei 230031China Department of Chemistry City University of Hong KongKowloonHong Kong 999077China Hong Kong Branch of National Precious Metals Material Engineering Research Center(NPMM) City University of Hong KongKowloonHong Kong 999077China Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology School of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi’an 710072China Department of Physics and Department of Materials Science and Engineering City University of Hong KongKowloonHong Kong 999077China National University of Singapore(NUS)Centre for Nanofibers and Nanotechnology Department of Mechanical EngineeringNational University of SingaporeSingapore 117542Singapore

Improving the catalytic activity of non-noble metal single atom catalysts(SACs)has attracted considerable attention in materials science.Although optimizing the local electronic structure of single atom can greatly improve their catalytic activity,it often involves in-plane modulation and requires high temperatures.Herein,we report a novel strategy to manipulate the local electronic structure of SACs via the modulation of axial Co-S bond anchored onto graphitic carbon nitride(C_(3)N_(4))at room temperature(RT).Each Co atom is bonded to four N atoms and one S atom(Co-(N,S)/C_(3)N_(4)).Owing to the greater electronegativity of S in the Co-S bond,the local electronic structure of the Co atoms is available to be controlled at a relatively moderate level.Consequently,when employed for the photocatalytic hydrogen evolution reaction,the adsorption energy of intermediate hydrogen(H*)on the Co atoms is remarkably low.In the presence of the Co-(N,S)/C_(3)N_(4)SACs,the hydrogen evolution rates reach up to 10 mmol/(g·h),which is nearly 10 and 2.5 times greater than the rates in the presence of previously reported transition metal/C_(3)N_(4)and noble platinum nanoparticles(PtNPs)/C_(3)N_(4)catalysts,respectively.Attributed to the tailorable axial Co-S bond in the SAC,the local electronic structure of the Co atoms can be further optimized for other photocatalytic reactions.This axial coordination engineering strategy is universal in catalyst designing and can be used for a variety of photocatalytic applications.

关键词： transition metal single-atom local electronic structure photocatalytic hydrogen evolution graphitic carbon nitride axial coordination environment

Multifunctional catalytic sites regulation of atomic-scale iridium on orthorhombic-CoSe_(2)for high efficiency dual-functional alkaline hydrogen evolution and organic degradation

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Journal of Energy Chemistry 2024年第5期92卷 271-281页

作者： Jingjing Huang Chenglin Zhong Yanjie Xia Jia Liu Guizhen Li Chao Yang jiahong wang Qian wang Zhenbao Zhang Feng Yan Jianghua Wu Yu Deng Zhenjiang Zhou Xingchen He Paul K.Chu Woon-Ming Lau Xue-Feng Yu College of Chemistry and Chemical Engineering Linyi UniversityLinyi 276005ShandongChina Shenzhen Engineering Center for the Fabrication of Two-Dimensional Atomic Crystals Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen 518055GuangdongChina National Laboratory of Solid State Microstructures Jiangsu Key Laboratory of Artificial Functional MaterialsCollege of Engineering and Applied Sciences and Collaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210093JiangsuChina College of Biosystems Engineering and Food Science Zhejiang UniversityHangzhou 310058ZhejiangChina Department of Physics Department of Materials Science and EngineeringDepartment of Biomedical EngineeringCity University of Hong KongTat Chee AvenueKowloonHong KongChina

The earth-abundant and high-performance catalysts are crucial for commercial implementation of hydrogen evolution reaction(HER).Herein,a multifunctional site strategy to construct excellent HER catalysts by incorporating iridium(Ir)ions on the atomic scale into orthorhombic-CoSe2(Ir-CoSe_(2))was reported.Outstanding hydrogen evolution activity in alkaline media such as a low overpotential of 48.7 mV at a current density of 10 mA cm^(-2)and better performance than commercial Pt/C catalysts at high current densities were found in the Ir-CoSe_(2) samples.In the experiments and theoretical calculations,it was revealed that Ir enabled CoSe_(2)to form multifunctional sites to synergistically catalyze alkaline HER by promoting the adsorption and dissociation of H_(2)O(Ir sites)and optimizing the binding energy for H^(*)on Co sites.It was noticeable that the electrolytic system comprising the Ir-CoSe_(2)electrode not only produced hydrogen efficiently via HER,but also degraded organic pollutants(Methylene blue).The cell voltage of the dual-function electrolytic system was 1.58 V at the benchmark current density of 50 mA cm^(-2),which was significantly lower than the conventional water splitting voltage.It was indicated that this method was a novel strategy for designing advanced HER electrocatalysts by constructing multifunctional catalytic sites for hydrogen production and organic degradation.

关键词： Orthorhombic-CoSe_(2) Multifunctional sites design Hydrogen evolution reaction Synergistically catalyze Methylene blue oxidation

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RNA-seq analysis of a zebrafish caudal fin cell line in response to infection with spring viraemia of carp virus

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Aquaculture and Fisheries 2024年第2期9卷 181-192页

作者： Wenji Huang Ning Ji Xin Zhao jiahong Guo Jianhua Feng Kangyong Chen Yaxin Wu Junya wang Jun Zou Key Laboratory of Exploration and Utilization of Aquatic Genetic Resources Ministry of EducationShanghai Ocean UniversityShanghai201306China International Research Center for Marine Biosciences Ministry of Science and TechnologyShanghai Ocean UniversityShanghai201306China National Demonstration Center for Experimental Fisheries Science Education Shanghai Ocean UniversityShanghai201306China Laboratory for Marine Biology and Biotechnology Qingdao National Laboratory for Marine Science and TechnologyQingdao266071China

A cell line,termed ZFIN,was established from the caudal fin of zebrafish and was shown to be susceptible to spring viremia of carp virus(SVCV).The ZFIN cells are epithelial like cells and have a moderate plasmid transfection efficiency of 13.9%.Using an RNA-seq approach,differentially expressed genes(DEGs)regulated by SVCV were identified.Infection of SVCV gave rise to 3931 DEGs and up-regulated DEGs were mostly enriched into the biological regulation and cellular processes,among which pathways for the type I interferon signaling and the response to exogenous dsRNA were the top two GO terms.Several KEGG signaling pathways including TLR signaling pathway,RLR receptor signaling pathway,cytosolic DNA-sensing pathway,NLR signaling pathway,cytokine-cytokine receptor interaction and ferroptosis were significantly enriched.Antiviral genes including ifnφ1,isg15 and mx were significantly up-regulated.In addition,key DEGs involved in autophagy were identified.The results indicate that the ZFIN cell line provides a useful in vitro tool for study on the gene functions and cellular responses to viral infection in fish.

关键词： Caudal fin cells SVCV RNA-seq DEGs Innate antiviral response

A laser powered EO sensor for measurement of EMP

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Optoelectronics Letters 2024年

作者： Zhang jiahong Ma Chao wang Zhuo Faculty of Information Engineering and Automation Kunming University of Science and Technology

This article presents an active electro-optic (EO) modulation electromagnetic pulse (EMP) sensor powered by laser. The sensor simulation model is established， and the temporal response characteristics of the sensor are analyzed based on finite element method (FEM). The laser powered supply circuit and receiving modulation circuit are designed and implemented. A monopole antenna is designed and used to revive the EMP. By integrating the supply circuit， the receiving modulation circuit and the antenna together， the sensor are finally fabricated and encapsulated. Experimental results indicate that with the designed laser powered supply circuit， the sensor can operate continuously and stably. The measured standard 1.2/50 μs lightning electromagnetic pulses (LEMP) in the time domain agrees well with the input LEMP voltage waveform. The linear maximum and minimum measurable electric field of the sensor is 20.8 kV/m and 221 V/m respectively. All the results demonstrate that the sensor can provide an effective technical means for measurement of EMP in the time domain.

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Corrigendum to"SEMA4D acts as a novel oligogenic pathogenic gene of idiopathic hypogonadotropic hypogonadism through the PlexinB1/MET/RND1/RHOA/RAF1/MAPK signaling axis"[Genes&Diseases 10(2023)65-68]

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Genes & Diseases 2024年第4期11卷 428-429页

作者： Daoqi wang Yonghua Niu jiahong Tan Jiaxin wang Le Ling Yinwei Chen Jianan Gong Hao Xu Qing Ling Jianhe Liu Jihong Liu Department of Urology The Second Affiliated Hospital of Kunming Medical UniversityKunmingYunnan 650033China Department of Urology Tongji HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhanHubei 430030China Department of Pediatric Surgery Tongji HospitalTongji Medical CollegeWuhanHubei 430030China Department of Obstetrics and Gynecology The First People's Hospital of Yunnan ProvinceKunmingYunnan 650034China Department of Urology First Affiliated Hospital of Harbin Medical UniversityHarbinHeilongjiang 150007China

The authors regret to correct the error in the order of the institute of the first author,which should go as the following.

关键词： Cor Diseases pogon

Size-dependent macrophage-targeting of mannose-modified rosiglitazone liposomes to alleviate inflammatory bowel disease

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Chinese Chemical Letters 2024年第1期35卷 385-391页

作者： Erjin wang Run Han Mingyue Wu Yuan He Yaxin Cheng jiahong Lu Ying Zheng State Key Laboratory of Quality Research in Chinese Medicine Institute of Chinese Medical Sciences(ICMS)University of MacaoMacao 999078China Department of Pharmacy Xuzhou Medical UniversityXuzhou 221004China Faculty of Health Sciences University of MacaoMacao 999078China Guangdong-Hong Kong-Macao Joint Lab on Chinese Medicine and Immune Disease Research University of MacaoMacao 999078China

Inflammatory bowel disease (IBD) is a refractory chronic intestinal inflammatory disease caused by a malfunction of immune system. As the key immune cells in the intestine, macrophages play an important role in maintaining intestinal homeostasis and tissue repair of the IBD. Pharmacological modulation of macrophage function exhibits the promising therapeutic effect for IBD. In this study, mannose-modified liposomes (MAN-LPs) are prepared for macrophage targeting to improve therapeutic efficiency. Rosiglitazone (ROSI) as an agonist of peroxisome proliferators-activated receptor γ (PPAR-γ) is used as the model drug to fabricate different sized liposomes. The impacts of mannose modification and particle size for macrophage targeting are investigated in cells, zebrafish, and mouse models and the therapeutic effects of the MAN-LPs are evaluated on dextran sulfate sodium (DSS)-induced IBD mouse. Compared to unmodified liposome, MAN-LPs display higher uptake by RAW 264.7 cells and better co-localization with macrophage in zebrafish model. Furthermore, MAN-LPs could effectively accumulate in the inflammatory intestinal sites in IBD mouse model. Most importantly, the targeting ability of MAN-LPs is obviously enhanced with the increasing of particle size, whereas the largest MAN-LPs particles achieve the best anti-inflammatory effect in cells, and a higher therapeutic efficiency in IBD mouse model. Therefore, mannose-modified liposome is a promising strategy for macrophage-targeting in IBD treatment. Particle size of MAN-LPs will affect macrophage targeting ability, as well as the therapeutic effect in-vivo.

关键词： Macrophage targeting Liposome Mannose Particle size Inflammatory bowel disease

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利益共识:社会建构视角下的校企合作逻辑

社会发展研究 2024年第2期 188-208,M0006,M0007页

作者：徐佳虹王星南开大学社会学院

产业转型与振兴需以技术型人才作为强大支撑。职业学校与企业的合作是产业技能人才培养的重要方式,而两者之间理性的利益关系是合作达成的关键。本研究基于当前我国技能形成的政策背景,构建了国家对职校和企业合作的治理机制与校企利益... 详细信息

产业转型与振兴需以技术型人才作为强大支撑。职业学校与企业的合作是产业技能人才培养的重要方式,而两者之间理性的利益关系是合作达成的关键。本研究基于当前我国技能形成的政策背景,构建了国家对职校和企业合作的治理机制与校企利益关系之间的理论分析框架,提出了校企合作中四种利益关系模式。基于对一个校企合作案例的追踪,本研究发现由当地政府主导的优惠性政策构筑了校企合作的外部环境,正向激励校企建立合作,而校企间形成的互惠互利交往模式以及校企内部对学生采用的技术换劳动、人情换人心、教导等策略,进一步推动了双方建立长期合作关系,最终达成了双方合作的利益共识。从中可见,内部治理是破解外部屏障、优化与均衡合作主体间利益的关键。

关键词：校企合作利益共识技能形成

基于知识图谱的城市洪涝灾害链推演及时空特性解析

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水科学进展 2024年第2期35卷 185-196页

作者：王浩杜伟刘家宏王佳梅超中国水利水电科学研究院流域水循环模拟与调控国家重点实验室北京100038 水利部数字孪生流域重点实验室(筹) 北京100038 北京工业大学城市建设学部北京100124

城市洪涝灾害具有链式传播特性,解析城市洪涝灾害链的传递规律和时空演变特征对于阻断灾害链具有重要意义。本研究以郑州“7·20”特大暴雨洪涝灾害中地铁5号线被淹和京广快速路隧道被淹2个事件为案例,构建知识图谱揭示灾害链传递规律... 详细信息

城市洪涝灾害具有链式传播特性,解析城市洪涝灾害链的传递规律和时空演变特征对于阻断灾害链具有重要意义。本研究以郑州“7·20”特大暴雨洪涝灾害中地铁5号线被淹和京广快速路隧道被淹2个事件为案例,构建知识图谱揭示灾害链传递规律。通过复盘灾害链的演变过程,从中识别灾害链中的诱发点、引爆点、扩散点以及放大点,并着重分析致灾机理以及灾害链的时空特性,以灾害曲线形式直观展示不同灾害链的影响程度。郑州“7·20”洪涝灾害典型案例解析表明,两事件存在多个灾害链阻断时机,在救灾过程中应综合考虑灾前、灾中因素的影响,果断采取断链措施,并且要充分发挥应急措施的时效性,及时阻断引爆点和扩散点,降低洪涝灾害损失。该方法能够应用于链式灾害的复盘,指导分析具体事件的致灾机理和救灾切入点。

关键词：城市洪涝灾害链知识图谱灾害链传递灾害链推演时空特性

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Data-driven structural descriptor for predicting platinum-based alloys as oxygen reduction electrocatalysts

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InfoMat 2023年第6期5卷 102-113页

作者： Xue Zhang Zhuo wang Adam Mukhtar Lawan jiahong wang Chang-Yu Hsieh Chenru Duan Cheng Heng Pang Paul.K.Chu Xue-Feng Yu Haitao Zhao Shenzhen Engineering Center for the Fabrication of Two-Dimensional Atomic Crystals Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhenthe People's Republic of China Department of Chemical and Environmental Engineering The University of Nottingham Ningbo ChinaNingbothe People's Republic of China Hubei Three Gorges Laboratory YichangHubeithe People's Republic of China Innovation Institute for Artificial Intelligence in Medicine College of Pharmaceutical SciencesZhejiang UniversityHangzhouthe People's RepublicofChina Department of Chemical Engineering Massachusetts Institute of TechnologyCambridgeMassachusettsUSA Department of Physics Department of Materials Science and Engineeringand Department of Biomedical EngineeringCity University of Hong KongKowloonHong Kongthe People's Republic of China

Owing to increasing global demand for carbon neutral and fossil-free energy systems,extensive research is being conducted on efficient and inexpensive electrocatalysts for catalyzing the kinetically sluggish oxygen reduction reaction(ORR)at the cathode of fuel cells.Platinum(Pt)-based alloys are considered promising candidates for replacing expensive Pt catalysts.However,the current screening process of Pt-based alloys is time-consuming and labor-intensive,and the descriptor for predicting the activity of Pt-based catalysts is generally inaccurate.This study proposed a strategy by combining high-throughput first-principles calculations and machine learning to explore the descriptor used for screening Pt-based alloy catalysts with high Pt utilization and low Pt consump-tion.Among the 77 prescreened candidates,we identified 5 potential candidates for catalyzing ORR with low overpotential.Furthermore,during the second and third rounds of active learning,more Pt-based alloys ORR candidates are identi-fied based on the relationship between structural features of Pt-based alloys and their activity.In addition,we highlighted the role of structural features in Pt-based alloys and found that the difference between the electronegativity of Pt and heteroatom,the valence electrons number of the heteroatom,and the ratio of heteroatoms around Pt are the main factors that affect the activity of ORR.More importantly,the combination of those structural features can be used as structural descriptor for predicting the activity of Pt-based alloys.We believe the findings of this study will provide new insight for predicting ORR activ-ity and contribute to exploring Pt-based electrocatalysts with high Pt utiliza-tion and low Pt consumption experimentally.

关键词： high-throughput DFT calculation machine learning oxygen reduction electrocatalysts platinum-based alloys structural descriptor