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Hydrogen release of NaBH_(4) below 60 ℃ with binary eutectic mixture of xylitol and erythritol additive

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Chinese Journal of Chemical Engineering 2024年第7期71卷 225-234页

作者： Yugang Shu jiaguang zheng Chengguo Yan Ao Xia Meiling Lv Zhenxuan Ma Zhendong Yao School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin 300071China College of Materials and Chemistry China Jiliang UniversityHangzhou 310018China

NaBH_(4) was widely regarded as a low-cost hydrogen storage material due to its high-mass hydrogen capacity of approximately 10.8%(mass)and high volumetric hydrogen capacity of around 115 g·L^(–1).However,it exhibits strong stability and requires temperatures above 500℃ for hydrogen release in practical *** this study,two polyhydric alcohols,xylitol and erythritol(XE),were prepared as a binary eutectic sugar alcohol through a grinding-melting *** binary eutectic sugar alcohol was used as a proton-hydrogen carrier to destabilize NaBH_(4).The 19NaBH_(4)-16XE composite material prepared by ball milling could start releasing hydrogen at 57.5℃,and the total hydrogen release can reach over 88.8%(4.45%(mass))of the theoretical *** the 19NaBH_(4)-16XE composite was pressed into solid blocks,the volumetric hydrogen capacity of the block-shaped composite could reach 67.2 g·L^(–1).By controlling the temperature,the hydrogen desorption capacity of the NaBH_(4)-XE composite material was controllable,which has great potential for achieving solid-state hydrogen production from NaBH_(4).

关键词： Hydrogen Desorption Binary mixture NaBH_(4) Xylitol Erythritol

Significantly improved hydrogen storage behaviors in MgH_(2) with Nb nanocatalyst

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International Journal of Minerals,Metallurgy and Materials 2022年第9期29卷 1788-1797页

作者： Farai Michael Nyahuma Liuting Zhang Mengchen Song Xiong Lu Beibei Xiao jiaguang zheng Fuying Wu School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China Analysis and Testing Center Jiangsu University of Science and TechnologyZhenjiang 212003China

The study explores the excellent modification effect of Nb nanocatalyst prepared via surfactant assisted ball milling technique(SABM)on the hydrogen storage properties of MgH_(2).Optimal catalyst doping concentration was determined by comparing onset decomposition temperature,released hydrogen capacity,and reaction rate for different MgH_(2)-ywt%Nb(y=0,3,5,7,9)*** MgH_(2)-5wt%Nb composite started releasing hydrogen at 186.7℃ and a total of 7.0wt%hydrogen was released in the dehydrogenation *** addition,5wt%Nb doped MgH_(2) also managed to release 4.2wt%H_(2) within 14 min at 250℃ and had the ability to absorb 4.0wt%hydrogen in 30 min at 100℃.Cycling tests revealed that MgH_(2)-5wt%Nb could retain 6.3wt%H_(2) storage capacity(89.2%)after 20 *** and hydrogenation activation energy values were decreased from 140.51±4.74 and 70.67±2.07 kJ·mol^(−1) to 90.04±2.83 and 53.46±3.33 kJ·mol^(−1) after doping MgH_(2) with Nb,*** analysis proved that homogeneously distributed NbH acted as active catalytic unit for improving the hydrogen storage performance of MgH_(2).These results indicate SABM can be considered as an option to develop other nanocatalysts for energy related areas.

关键词： hydrogen storage magnesium hydride surfactant assisted ball milling Nb nanosheets

Metal organic framework supported niobium pentoxide nanoparticles with exceptional catalytic effect on hydrogen storage behavior of MgH_(2)

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Green Energy & Environment 2023年第2期8卷 589-600页

作者： Liuting Zhang Farai Michael Nyahuma Haoyu Zhang Changshan Cheng jiaguang zheng Fuying Wu Lixin Chen School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China Analysis and Testing Center Jiangsu University of Science and TechnologyZhenjiang 212003China State Key Laboratory of Silicon Materials Department of Materials Science andEngineeringZhejiang UniversityHangzhou 310027China

Nb_(2)O_(5)nanoparticles with an average particle size of 10 nm supported on a rhombic dodecahedral metal organic framework(MOF)were successfully synthesized by a facile one-pot hydrothermal reaction and subsequent calcination *** results demonstrated that the prepared catalyst drastically improved the hydrogen storage behavior of MgH_(2).7 wt%Nb_(2)O_(5)@MOF doped MgH_(2)started to desorb hydrogen at 181.9℃and 6.2 wt%hydrogen could be released within 2.6 min and 6.3 min at 275℃and 250℃,*** fully dehydrogenated composite also displayed excellent hydrogenation by decreasing the onset absorption temperature to 25℃and taking up4.9 wt%and 6.5 wt%hydrogen within 6 min at 1750C and 1500C,***,the corresponding activation energy was calculated to be 75.57±4.16 kJ mol^(-1)for desorption reaction and 51.38±1.09 kJ mol^(-1)for absorption *** 20 cycles,0.5 wt%hydrogen capacity was lost for the MgH_(2)+7 wt%Nb_(2)O_(5)@MOF composite,much lower than 1.5 wt%of the MgH_(2)+7 wt%Nb_(2)O_(5)***,the addition of Nb_(2)O_(5)@MOF had limited effect on reducing the dehydrogenation enthalpy of MgH_(2).Microstructure analysis revealed that Nb_(2)O_(5)particles were uniformly distributed on surface of the MgH_(2)matrix and synergistically improved the hydrogen storage property of MgH_(2)with MOF.

关键词： Hydrogen storage MgH_(2) Nb_(2)O_(5)@MOF Reversibility Catalytic mechanism

Boosting the hydrogen storage performance of magnesium hydride with metal organic framework-derived Cobalt@Nickel oxide bimetallic catalyst

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Chinese Journal of Chemical Engineering 2022年第12期52卷 161-171页

作者： Yan Zhang jiaguang zheng Zhiyu Lu Mengchen Song Jiahuan He Fuying Wu Liuting Zhang School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China Analysis and Testing Center Jiangsu University of Science and TechnologyZhenjiang 212003China State Key Laboratory of Silicon Materials Department of Materials Science and EngineeringZhejiang UniversityHangzhou 310027China

In this study,a MOF-derived bimetallic Co@NiO catalyst was synthesized and doped into MgH_(2)to improve the hydrogen desorption and resorption *** Co@NiO catalyst decreased the onset dehydrogenation temperature of MgH_(2)by 160℃,compared with un-doped MgH_(2).The MgH^(2+)9%(mass)Co@NiO composite released 6.6%(mass)hydrogen in 350 s at 315℃and uptook 5.4%(mass)hydrogen in500 s at 165℃,showing greatly accelerated de/rehydrogenation ***,the desorption activation energy of MgH^(2+)9%(mass)Co@NiO was decreased to(93.8±8.4)kJ·mol^(-1).Noteworthy,symbiotic Mg_(2)NiH_(4)/Mg_(2)CoH_(5)clusters were in-situ formed from bimetallic precursors and inlaid on MgH_(2)surface,which are considered as"multi-step hydrogen pumps",and provides surface pathways for hydrogen ***,the introduced Mg_(2)NiH_(4)/Mg_(2)CoH_(5)interfaces could provide numerous low energy barrier H diffusion channels,therefore accelerating the hydrogen release and *** research proposes new insights to design high-efficiency bimetallic catalyst for MgH_(2)hydrogen storage.

关键词： Hydrogen Absorption Catalyst MgH_(2) Bimetallic materials Synergistic effect

Bullet-like vanadium-based MOFs as a highly active catalyst for promoting the hydrogen storage property in MgH_(2)

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International Journal of Minerals,Metallurgy and Materials 2023年第1期30卷 44-53页

作者： Zhiyu Lu Jiahuan He Mengchen Song Yan Zhang Fuying Wu jiaguang zheng Liuting Zhang Lixin Chen School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China Instrumental Analysis Center Jiangsu University of Science and TechnologyZhenjiang 212003China State Key Laboratory of Silicon Materials Department of Materials Science and EngineeringZhejiang UniversityHangzhou 310027China

The practical application of magnesium hydride(MgH_(2))was seriously limited by its high desorption temperature and slow desorp-tion *** this study,a bullet-like catalyst based on vanadium related MOFs(MOFs-V)was successfully synthesized and doped with MgH_(2) by ball milling to improve its hydrogen storage *** analysis demonstrated that the as-synthesized MOFs was consisted of V_(2)O_(3) with a bullet-like *** adding 7wt%MOFs-V,the initial desorption temperature of MgH_(2) was reduced from 340.0 to 190.6℃.Besides,the MgH_(2)+7wt%MOFs-V composite released 6.4wt%H_(2) within 5 min at 300℃.Hydrogen uptake was started at 60℃under 3200 kPa hydrogen pressure for the 7wt%MOFs-V containing *** desorption and absorption apparent activity energies of the MgH_(2)+7wt%MOFs-V composite were calculated to be(98.4±2.9)and(30.3±2.1)kJ·mol^(-1),much lower than(157.5±3.3)and(78.2±3.4)kJ·mol^(−1) for the as-prepared MgH_(2).The MgH_(2)+7wt%MOFs-V composite exhibited superior cyclic *** the 20 cycles isothermal dehydrogenation and hydrogenation experiments,the hydrogen storage capacity stayed almost unchanged.X-ray diffraction(XRD)and X-ray photoelectron spectrometer(XPS)measurements confirmed the presence of metallic vanadium in the MgH_(2)+7wt%MOFs-V composite,which served as catalytic unit to markedly improve the hydrogen storage properties of Mg/MgH_(2) system.

关键词： hydrogen storage magnesium hydrides vanadium based MOFs catalytic mechanism

The effect of different Co phase structure(FCC/HCP)on the catalytic action towards the hydrogen storage performance of MgH_(2)

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Chinese Journal of Chemical Engineering 2022年第3期35卷 343-352页

作者： Liuting Zhang Haijie Yu Zhiyu Lu Changhao Zhao jiaguang zheng Tao Wei Fuying Wu Beibei Xiao School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China Analysis and Testing Center Jiangsu University of Science and TechnologyZhenjiang 212003China

High hydrogen desorption temperature and sluggish reaction kinetics are the major limitations for the practical application of MgH_(2).In this study,Co particles with a face centered cubic(FCC)structure and a hexagonal close packed(HCP)structure were prepared facilely and proved to be good catalysts for magnesium *** particles with FCC structure presented better catalytic effect on MgH_(2)than that with HCP *** 7%(mass)Co FCC and HCP particle modified MgH_(2)decreased the initial dehydrogenation temperature from 301.3℃ to approximately 195.0℃,but 7%(mass)Co with FCC structure modified MgH_(2)has a faster desorption rate,and around 6.5%(mass)H_(2)was desorbed in 10 min at325℃.Hydrogen uptake was detected at 70℃ under 3.25 MPa hydrogen pressure and 6.0%(mass)H_(2)was recharged in 40 min at 150℃.The hydrogen desorption and absorption activation energy for 7%(mass)FCC Co modified MgH_(2)was significantly decreased to(76.6±8.3)kJ·mol^(-1) and(68.3±6.0)kJ·mol^(-1),*** property was also studied,the plateau pressures of MgH_(2)+7%(mass)FCC Co were determined to be 0.14,0.28,0.53 and 0.98 MPa for 300℃,325℃,350℃ and375℃.The decomposition enthalpy of hydrogen(ΔH)for MgH_(2)+7%(mass)FCC Co was(80.6±0.1)kJ·mol^(-1),5.8 kJ·mol^(-1)lower than that of as-prepared MgH_(2).Moreover,cycling performance for the first20 cycles revealed that the reaction kinetics and capacity of MgH_(2)-FCC Co composite remained almost *** result of density functional theory calculation demonstrated that cobalt could extract the Mg AH bond and reduced the decompose energy of magnesium *** paper can be presented as a reference for searching highly effective catalysts for hydrogen storage and other energy-related research fields.

关键词： Hydrogen storage MgH_(2) FCC/HCP Co particles Catalysis Density functional theory

Extreme high reversible capacity with over 8.0 wt% and excellent hydrogen storage properties of MgH2 combined with LiBH4 and Li3AlH6

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Journal of Energy Chemistry 2020年第11期29卷 296-306页

作者： Wenping Lin Xuezhang Xiao Xuancheng Wang Jie-Wei Wong Zhendong Yao Man Chen jiaguang zheng Zhencan Hu Lixin Chen State Key Laboratory of Silicon Materials School of Materials Science and EngineeringZhejiang UniversityHangzhou 310027ZhejiangChina Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province.Hangzhou 310013 ZhejiangChina Guangdong Provincial Key Laboratory of Advance Energy Storage Materials South China University of TechnologyGuangzhou 510640GuangdongChina

Magnesium hydride has attracted great attention because of its high theoretical capacity and outstanding reversibility, nevertheless, its practical applications have been restricted by the disadvantages of the sluggish kinetics and high thermodynamic stability. In this work, an unexpected high reversible hydrogen capacity over 8.0 wt% has been achieved from MgH2 metal hydride composited with small amounts of LiBH4 and Li3AlH6 complex hydrides, which begins to release hydrogen at 276 ℃ and then completely dehydrogenates at 360 ℃. The dehydrogenated MgH2+LiBH4/Li3AlH6 composite can fully reabsorb hydrogen below 300 ℃ with an excellent cycling stability. The composite exhibits a significant reduction of dehydrogenation activation energy from 279.7 kJ/mol(primitive MgH2) to 139.3 kJ/mol(MgH2+LiBH4/Li3AlH6),as well as a remarkable reduction of dehydrogenation enthalpy change from 75.1 k J/mol H2(primitive MgH2) to 62.8 kJ/mol H2(MgH2+LiBH4/Li3AlH6). The additives of LiBH4 and Li3AlH6 not only enhance the cycling hydrogen capacity, but also simultaneously improve the reversible de/rehydrogenation kinetics, as well as the dehydrogenation thermodynamics. This notable improvement on the hydrogen absorption/desorption behaviors of the MgH2+LiBH4/Li3AlH6 composite could be attributed to the dehydrogenated products including Li3Mg7, Mg17Al12 and MgAlB4, which play a key role on reducing the dehydrogenation activation energy and increasing diffusion rate of hydrogen. Meanwhile, the LiBH4 and Li3AlH6 effectively destabilize MgH2 with a remarkable reduction on dehydrogenation enthalpy change in terms of thermodynamics. In particular, the Li3Mg7, Mg17Al12 and MgAlB4 phases can reversibly transform into MgH2, Li3AlH6 and LiBH4 after rehydrogenation, which contribute to maintain a high cycling *** constructing strategy can further promote the development of high reversible capacity Mg-based materials with suitable de/rehydrogenation properties.

关键词： Magnesium hydride Complex hydride Hydrogen storage High reversible capacity Synergistic effect

Enhanced hydrogen storage properties of Mg by the synergistic effect of grain refinement and NiTiO_(3)nanoparticles

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Journal of Magnesium and Alloys 2022年第12期10卷 3542-3552页

作者： Nianhua Yan Xiong Lu Zhiyu Lu Haijie Yu Fuying Wu jiaguang zheng Xiuzhen Wang Liuting Zhang School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang212003China Analysis and Testing Center Jiangsu University of Science and TechnologyZhenjiang212003China

As a promising hydrogen storage material,the practical application of magnesium is obstructed by the stable thermodynamics and sluggish *** this paper,three kinds of NiTiO3catalysts with different mole ratio of Ni to Ti were successfully synthesized and doped into nanocrystalline Mg to improve its hydrogen storage *** results indicated that all the Mg-NiTiO3composites showed prominent hydrogen storage ***,the Mg-NiTiO3/TiO2composite could take up hydrogen at room temperature and the apparent activation energy for hydrogen absorption was dramatically decreased from 69.8±1.2(nanocrystalline Mg)k J/mol to 34.2±0.2 k J/*** addition,the hydrogenated sample began to release hydrogen at about 193.2℃and eventually desorbed 6.6 wt%*** desorption enthalpy of the hydrogenated Mg-NiTiO3-C was estimated to be 78.6±0.8 k J/mol,5.3 k J/mol lower compared to 83.9±0.7 k J/mol of nanocrystalline ***,the sample revealed splendid cyclic stability during 20 *** obvious recession occurred in the absorption and desorption kinetics and only 0.3 wt%hydrogen capacity degradation was *** structural analysis demonstrates that nanosizing and catalyst doping led to a synergistic effect on the enhanced hydrogen storage performance of Mg-NiTiO3-C composite,which might serve as a reference for future design of highly effective hydrogen storage materials.

关键词： Hydrogen storage NiTiO3 Nanocrystalline Mg Reversibility Synergistic effect

Hydrogen release of NaBH 4 below 60 °C with binary eutectic mixture of xylitol and erythritol additive

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