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A universal method for rapid and large‐scale growth of layered crystals

SmartMat 2020年第1期1卷 77-84页

作者： Apoorva Chaturvedi Bo Chen Keke Zhang Qiyuan He Gwang‐Hyeon Nam Lu You Zhuangchai Lai Chaoliang Tan Thu Ha Tran Guigao Liu jiadong zhou Zheng Liu Junling Wang Edwin H.T.Teo Hua Zhang Center for Programmable Materials School of Materials Science and EngineeringNanyang Technological UniversitySingaporeSingapore Department of Chemistry City University of Hong KongHong KongChina Department of Materials Science and Engineering City University of Hong KongHong KongChina Jiangsu Key Laboratory of Thin Films School of Physical Science and TechnologySoochow UniversitySuzhouChina Department of Electrical Engineering City University of Hong KongHong KongChina Department of Physics Southern University of Science and TechnologyShenzhenGuangdongChina School of Electric and Electronic Engineering Nanyang Technological UniversitySingaporeSingapore Hong Kong Branch of National Precious Metals Material Engineering Research Center(NPMM) City University of Hong KongHong KongChina

Layered van der Waals(vdW)materials,consisting of atomically thin layers,are of paramount importance in physics,chemistry,and materials science owing to their unique properties and various promising applications.However,their fast and large‐scale growth via a general approach is still a big challenge,severely limiting their practical implementations.Here,we report a universal method for rapid(~60 min)and large‐scale(gram scale)growth of phase‐pure,high‐crystalline layered vdW materials from their elementary powders via microwave plasma heating in sealed ampoules.This method can be used for growth of 30 compounds with different components(binary,ternary,and quaternary)and properties.The ferroelectric and transport properties of mechanically exfoliated flakes validate the high crystal quality of the grown materials.Our study provides a general strategy for the fast and large‐scale growth of layered vdW materials with appealing physiochemical properties,which could be used for various promising applications.

关键词： 2D materials ferroelectric field‐effect transistors layered compounds universal method

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Lattice-distorted Pt wrinkled nanoparticles for highly effective hydrogen electrocatalysis

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Nano Research 2024年第5期17卷 3819-3826页

作者： Xue Li Xiang Han Zhenrui Yang Shun Wang Yun Yang Juan Wang jiadong Chen Zhongwei Chen Huile Jin Wenzhou Key Lab of Advanced Energy Storage and Conversion Zhejiang Province Key Lab of Leather EngineeringCollege of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325035China Institute of New Materials and Industry Technology College of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325035China Department of Chemical Engineering Waterloo Institute for NanotechnologyUniversity of WaterlooWaterlooOntario N2L 3G1Canada

Modulating Pt surfaces through the introduction of lattice distortion emerges as immensely effective strategy that enhances the kinetics of alkaline hydrogen evolution and oxidation processes.In this study,we fabricated lattice-distorted Pt wrinkled nanoparticles(LD-Pt WNPs)for efficient hydrogen electrocatalysis.The LD-Pt WNPs not only outperform the Pt/C benchmark in hydrogen oxidation reaction,achieving an excellent mass-specific current of 968.5 mA·mg_(Pt)^(-1)(9 times that of Pt/C),but also demonstrate outstanding hydrogen evolution reaction activity with a small overpotential of 58.0 mV.Comprehensive experiments and density functional theory calculations reveal that lattice defects introduce an abundance of unsaturated coordination atoms while modifying the d-band center of Pt.This dual effect optimizes the binding strength of crucial H and OH intermediates,leading to a significant reduction in the energy barrier of the reaction bottleneck,commonly known as the Volmer step.This work unveils a fresh viewpoint on projecting and developing high efficiency electrocatalysts through defect engineering.

关键词： distortion nanoparticle hydrogen evolution reaction defect engineering hydrogen oxidation reaction

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苝酰亚胺受体的聚集形态对有机太阳电池中激子过程与电子传输的影响

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高等学校化学学报 2023年第9期44卷 1-12页

作者：张煜陈介焕周家东刘琳琳解增旗华南理工大学发光材料与器件国家重点实验室高分子光电材料及器件研究所广州510640

末端烷基链分叉位置对苝酰亚胺(PBI)线性二联体的堆积模式具有显著影响,进而影响激子过程与载流子传输.二联体两端烷基链分叉位点紧靠苝酰亚胺能够抑制分子长程有序堆积,形成具有较少能量陷阱的无定形聚集态;而两端烷基链分叉位点远离... 详细信息

末端烷基链分叉位置对苝酰亚胺(PBI)线性二联体的堆积模式具有显著影响,进而影响激子过程与载流子传输.二联体两端烷基链分叉位点紧靠苝酰亚胺能够抑制分子长程有序堆积,形成具有较少能量陷阱的无定形聚集态;而两端烷基链分叉位点远离苝酰亚胺则导致多种聚集结构共存,分子间强π-π相互作用位点成为能量陷阱.结果表明, PBI受体的聚集方式对有机太阳电池的性能产生重要影响,需要尽量减少活性层中的多种聚集结构共存以免引起激子解离受限以及载流子传输迟滞.

关键词：苝酰亚胺无定形态多种堆积共存有机太阳电池

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Rapid characterization of non-volatile phenolic compounds reveals the reliable chemical markers for authentication of traditional Chinese medicine Xiang-ru among confusing Elsholtzia species

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Chinese Journal of Natural Medicines 2024年第4期22卷 375-384页

作者： ZENG Zhen ZHANG Chen HU jiadong WANG Feiyan WU Ziding WANG Jing ZHANG Jun YANG Shuda CHEN Junfeng LI Mingming TONG Qi QIU Shi CHEN Wansheng The SATCM Key Laboratory for New Resources&Quality Evaluation of Chinese Medicine Institute of Chinese Materia MedicaShanghai University of Traditional Chinese MedicineShanghai 201203China Department of Pharmacy Second Affiliated Hospital of Navy Medical UniversityShanghai 200003China Kunming Plant Classification Biotechnology Co. Ltd.Kunming 650500China School of Pharmaceutical Sciences and Yunnan Key Laboratory of Pharmacology for Natural Products Kunming Medical UniversityKunming 650500China State Key Laboratory for Quality Ensurance and Sustainable Use of Dao-di Herbs Beijing100700China

The aerial parts of Mosla chinensis Maxim.and Mosla chinensis cv.'Jiangxiangru'(MCJ)are widely utilized in traditional Chinese medicine(TCM),known collectively as Xiang-ru.However,due to clinical effectiveness concerns and frequent misidentification,the original plants have increasingly been substituted by various species within the genera Elsholtzia and Mosla.The challenge in distinguishing between these genera arises from their similar morphological and metabolic profiles.To address this issue,our study introduced a rapid method for metabolic characterization,employing high-resolution mass spectrometry-based metabolomics.Through detailed biosynthetic and chemometric analyses,we pinpointed five phenolic compounds—salviaflaside,cynaroside,scutellarein-7-O-D-glucoside,rutin,and vicenin-2—among 203 identified compounds,as reliable chemical markers for distinguishing Xiang-ru from closely related Elsholtzia species.This methodology holds promise for broad application in the analysis of plant aerial parts,especially in verifying the authenticity of aromatic traditional medicinal plants.Our findings underscore the importance of non-volatile compounds as dependable chemical markers in the authentication process of aromatic traditional medicinal plants.

关键词： Genus Elsholtzia Genus Mosla Traditional Chinese medicine Xiang-ru Non-volatile phenolic compounds Liquid chromatography-mass spectrometry

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基于孤立森林算法的计算机网络潜在攻击检测

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信息与电脑 2023年第22期35卷 60-62页

作者：周家栋江苏省盐城技师学院江苏盐城224001

计算机网络安全在当今信息时代至关重要,网络攻击检测已成为网络管理和数据保护的一个核心任务。本研究提出一种基于孤立森林算法的创新方法,用于检测计算机网络中的潜在攻击。实验结果表明,该方法在计算机网络潜在攻击检测中表现出卓... 详细信息

计算机网络安全在当今信息时代至关重要,网络攻击检测已成为网络管理和数据保护的一个核心任务。本研究提出一种基于孤立森林算法的创新方法,用于检测计算机网络中的潜在攻击。实验结果表明,该方法在计算机网络潜在攻击检测中表现出卓越的性能和广泛的应用前景。

关键词：孤立森林算法计算机网络潜在攻击

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Heterointerface engineering of assembled CoP_(2) on N-modified carbon as efficient trifunctional electrocatalysts for Zn-Air batteries and overall water splitting

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Nano Research 2024年第5期17卷 3801-3809页

作者： Yan Chen Zhenrui Yang Juan Wang Yun Yang Xuedong He Yang Wang jiadong Chen Yaqing Guo Xin Wang Shun Wang Huile Jin Wenzhou Key Lab of Advanced Energy Storage and Conversion Zhejiang Province Key Lab of Leather EngineeringCollege of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325035China Zhejiang Engineering Research Center for Electrochemical Energy Materials and Devices Institute of New Materials and Industrial TechnologiesWenzhou UniversityWenzhou 325035China School of Chemical and Biomedical Engineering Nanyang Technological UniversitySingapore 637459Singapore

Enhancing catalytic activity through modulating the interaction between N-doped carbon and metal phosphides clusters is an effective approach.Herein,the electronic structure modulation of CoP_(2) supported N-modified carbon(CoP_(2)/NC)has been designed and prepared as efficient electrocatalysts for oxygen reduction reaction(ORR),oxygen evolution reaction(OER),and hydrogen evolution reaction(HER).Notably,CoP_(2)/NC-1 catalyst exhibits impressive performance in alkaline media,with an ORR half-wave potential of 0.84 V,as well as OER and HER overpotentials of 290 and 129 mV(at 10 mA·cm^(−2)),respectively.In addition,CoP_(2)/NC-1 produces a power density as high as 172.9 mW·cm^(−2),and excellent reversibility of 100 h at 20 mA·cm^(−2) in home-made Zn-air batteries.The experimental results demonstrate that the synergistic interactions between N modified carbon substrate and CoP_(2) material significantly enhance the kinetics of ORR,OER,and HER.Density functional theory(DFT)calculations reveal the strong electrons redistribution of CoP_(2) induced by high-density N atoms at the interface,thus optimizing the key intermediates and significantly lower the energy barrier of reactions.These electronic adjustments of CoP_(2) greatly enhance its kinetics of ORR/OER/HER,leading to faster reactions.This study provides profound insights into the specific modification of CoP_(2) by N-doped carbon,enabling the construction of efficient catalysts.

关键词： two-dimensional(2D)carbon metal-organic framework cobalt phosphide zinc air battery water splitting

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基于供需协调特性的养殖场沼气热电联供系统优化研究

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太阳能学报 2023年第4期44卷 231-237页

作者：费凡高立艾张瑞强周加栋温鹏霍利民河北农业大学机电工程学院保定071000 河北省畜禽养殖智能装备与新能源利用重点实验室保定071000 河北聚碳生物科技有限公司衡水053000

针对双碳目标下养殖场粪污资源化处理、能源供需间协调优化的问题,提出一种考虑粪污处理设施供能特性与动态热需求协同的优化运行模型。首先,根据数据拟合得到沼气产量与进料量的关系,构建以内燃机为动力系统的沼气热电联供系统的数学... 详细信息

针对双碳目标下养殖场粪污资源化处理、能源供需间协调优化的问题,提出一种考虑粪污处理设施供能特性与动态热需求协同的优化运行模型。首先,根据数据拟合得到沼气产量与进料量的关系,构建以内燃机为动力系统的沼气热电联供系统的数学模型。其次,考虑进料量、发酵温度以及外界环境温度对热负荷需求的影响,建立厌氧罐动态热负荷热平衡模型。在此基础上,考虑进料量、外界环境温度等因素的不确定性,以系统投资收益率最大为目标函数,构建热电联供系统优化运行模型。通过合理调配进料量,该模型可实现能源供给侧设备的最佳运行参数和能源需求侧的能量需求。算例结果表明,所提优化运行模型可实现沼气热电联供系统经济性的提升,同时能促进余热的有效利用。

关键词：生物质能沼气厌氧发酵热电联供系统供需关系优化

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Coordinated voltage regulation strategy of OLTC and BESS considering switching delay

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High Technology Letters 2024年第2期30卷 138-145页

作者：徐振宇 HUA Yongzhu CUI jiadong LI Chuangwei College of Information Science&Technology Zhejiang Shuren UniversityHangzhou 310015P.R.China The College of Electronics and Information Hangzhou Dianzi UniversityHangzhou 310018P.R.China

When large-scale distributed renewable energy power generation systems are connected to the power grid,the risk of grid voltage fluctuations and exceeding the limit increases greatly.Fortunately,the on-load tap changer(OLTC)can adjust the transformer winding tap to maintain the secondary side voltage within the normal range.However,the inevitable delay in switching transformer taps makes it difficult to respond quickly to voltage fluctuations.Moreover,switching the transformer taps frequently will decrease the service life of OLTC.In order to solve this critical issue,a cooperative voltage regulation strategy applied between the battery energy storage systems(BESSs)and OLTSs.is proposed By adjusting the charge and discharge power of BESSs,the OLTC can frequently switch the transformer taps to achieve rapid voltage regulation.The effectiveness of the proposed coordinated regulation strategy is verified in the IEEE 33 node distribution systems.The simulation results show that the proposed coordinated regulation strategy can stabilize the voltage of the distribution network within a normal range and reduce the frequency of tap switching,as such elongating the service life of the equipment.

关键词： distributed power generation voltage regulation distribution network on-load tapcharger(OLTC) battery energy storage system(BESS)

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非对称集中荷载下无腹筋RC梁受剪性能试验研究

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湖南大学学报（自然科学版） 2024年第3期51卷 141-148页

作者：袁健刘家栋段绍伟中南林业科技大学土木工程学院湖南长沙410004

非对称集中荷载作用下钢筋混凝土无腹筋简支梁具有两个不同的剪跨比,而两剪跨段受剪承载力与剪力作用之间的相对大小存在不确定性.通过开展6根非对称和4根对称集中荷载作用下钢筋混凝土无腹筋简支梁受剪性能试验研究,获取了破坏形态、荷... 详细信息

非对称集中荷载作用下钢筋混凝土无腹筋简支梁具有两个不同的剪跨比,而两剪跨段受剪承载力与剪力作用之间的相对大小存在不确定性.通过开展6根非对称和4根对称集中荷载作用下钢筋混凝土无腹筋简支梁受剪性能试验研究,获取了破坏形态、荷载-跨中位移曲线和纵向受拉钢筋应变,并分析了《混凝土结构设计规范》(GB 50010—2010)公式、修正压力场理论、基于截面应变分析的抗剪模型和Zsutty统计公式的适用性.结果表明,对于小剪跨比恒为1.0的无腹筋简支梁,大剪跨比为2.0~4.0的梁均在大剪跨段发生剪切破坏;当大剪跨比由3.0增大至3.5时,梁的极限承载力出现由大剪跨段控制转变为小剪跨段控制的现象《.混凝土结构设计规范》(GB50010—2010)预测非对称集中荷载作用下钢筋混凝土无腹筋简支梁发生剪切破坏的位置与试验结果相反,而Zsutty统计公式的预测效果最好.

关键词：非对称荷载钢筋混凝土无腹筋梁受剪性能静力试验

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分流喷管出口构型对红外抑制器性能影响的数值和实验研究

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红外与激光工程 2024年第2期53卷 58-70页

作者：杜家栋单勇张靖周南京航空航天大学能源与动力学院航空飞行器热管理与能量利用工业和信息化部重点实验室江苏南京210016

在模型实验验证的基础上,采用数值模拟的方法,对比分析了分流喷管出口构型对直升机红外抑制器气动性能、温度场和红外辐射强度的影响。研究结果表明:相比基准分流喷管模型(Origin),分流喷管出口带一定外扩张角的波瓣出口结构(Lobe_1)的... 详细信息

在模型实验验证的基础上,采用数值模拟的方法,对比分析了分流喷管出口构型对直升机红外抑制器气动性能、温度场和红外辐射强度的影响。研究结果表明:相比基准分流喷管模型(Origin),分流喷管出口带一定外扩张角的波瓣出口结构(Lobe_1)的引射系数略微降低、总压恢复系数降低,中间混合管出口排气温度峰值却降低了65.1 K,同时降低了混合管上下方区域的壁面温度,但造成混合管中后段外侧壁面局部区域温度升高;外扩张角为0的波瓣出口结构(Lobe_2)增加引射系数3.8%,总压恢复系数与Lobe_1结构基本相当,中间混合管出口排气温度峰值也降低了62.8 K,尤其是其降低混合管壁面温度的效果最佳;分流喷管出口突片结构(Tab)增加引射系数10.6%,但总压恢复系数降低0.7%,同时,内侧混合管出口排气平均温度降低19.3 K,混合管壁面降温效果相对较差。总体来看,波瓣和突片结构都起到增强引射、强化混合的作用,尤其是波瓣出口结构(Lobe_2)对降低抑制器总体红外辐射效果最好,在3~5μm波段的红外辐射强度最大可降低21%;在8~14μm波段,其红外辐射强度最大可降低15%。

关键词：红外抑制器分流喷管引射系数红外辐射气动性能

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