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Microstructures and properties of Cu-Cr-W composite coatings fabricated by surface mechanical alloying technique

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Rare Metals 2022年第12期41卷 4248-4256页

作者： jia-ping zhang Xiao-Mei Feng Yi-Fu Shen Cheng Chen Cui-Yuan Duan College of Materials Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing 210016China

Cu-Cr-W composite coatings were prepared by mechanical alloying(MA)method using different powder ratios,rotational speeds and milling *** micro structures and chemical compositions of as-synthesized coatings were analyzed by scanning electron microscopy(SEM)and energy-dispersive spectroscopy(EDS).Phases of ball-milled powders were identified by X-ray diffraction(XRD).The results indicate that the coating fabricated with powder ratio of 40 wt%Cu-Cr-W has better surface and cross-sectional microstructures and higher *** comparisons of cross-sectional micro structures of the coatings fabricated at different rotational speeds suggest that rotational speed of 300 r·min-1is the optimal for fabrication the coating,and the optimal milling time for the formation of coating is 7 *** results of microhardness test show that the hardness of the substrate is largely improved because of the as-fabricated *** results of the friction and wear tests indicate that the wear resistance of the copper substrate is improved after the deposition of Cu-Cr-W coating on *** coating fabricated for 7 h exhibits the lowest friction coefficient,indicating its favorable friction and wear *** formation mechanism of the coating was *** to the investigations in this work,the Cu-Cr-W coating fabricated by MA method is considered to be effective to reinforce the copper substrate.

关键词： Mechanical alloying Composite coating Powder ratio Processing parameter

Low humic acids promote in vitro lily bulblet enlargement by enhancing roots growth and carbohydrate metabolism

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Journal of Zhejiang University-Science B(Biomedicine & Biotechnology) 2016年第11期17卷 892-904页

作者： Yun WU Yi-ping XIA jia-ping zhang Fang DU Lin zhang Yi-di MA Hong ZHOU Department of Horticulture College of Agriculture and Biotechnology Zhejiang University College of Horticulture Shanxi Agricultural University

Bulblet development is a problem in global lily bulb production and carbohydrate metabolism is a crucial factor. Micropropagation acts as an efficient substitute for faster propagation and can provide a controllable condition to explore bulb growth. The present study was conducted to investigate the effects of humic acid （HA） on bulblet swelling and the carbohydrate metabolic pathway in Li/ium Oriental Hybrids ＇Sorbonne＇ under in vitro conditions. HA greatly promoted bulblet growth at 0.2, 2.0, and 20.0 mg/L, and pronounced increases in bulblet sucrose, total soluble sugar, and starch content were observed for higher HA concentrations （_〉2.0 mg/L） within 45 d after transplanting （DAT）. The activities of three major starch synthetic enzymes （including adenosine 5＇-diphosphate glucose pyro- phosphorylase, granule-bound starch synthase, and soluble starch synthase） were enhanced dramatically after HA application especially low concentration HA （LHA）, indicating a quick response of starch metabolism. However, higher doses of HA also caused excessive aboveground biomass accumulation and inhibited root growth. Accordingly, an earlier carbon starvation emerged by observing evident starch degradation. Relative bulblet weight gradually decreased with increased HA doses and thereby broke the balance between the source and sink. A low HA concentration at 0.2 mg/L performed best in both root and bulblet growth. The number of roots and root length peaked at 14.5 and 5.75 cm respectively. The fresh bulblet weight and diameter reached 468 mg （2.9 times that under the control treatment） and 11.68 mm, respectively. Further, sucrose/starch utilization and conversion were accelerated and carbon famine was delayed as a result with an average relative bulblet weight of 80.09%. To our knowledge, this is the first HA application and mechanism research into starch metabolism in both in vitro and in vivo condition in bulbous crops.

关键词： Bulblet development Humic acid Starch metabolism Source-sink conversion Lilium Oriental Hybrids ‘Sorbonne'

Dielectric-ion-conductive ZnNb2O6 layer enabling rapid desolvation and diffusion for dendrite-free Zn metal batteries

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Journal of Energy Chemistry 2025年第1期100卷 693-701页

作者： Haifeng Yang jian Wang Panpan zhang Xiaomin Cheng Qinghua Guan Jing Dong Bixian Chen Lujie jia Jing zhang Yongzheng zhang Yunjian Liu Hongzhen Lin School of Materials Science and Engineering Jiangsu University i-Lab & CAS Key Laboratory of Nanophotonic Materials and Devices Suzhou Institute of Nano-Tech and Nano-Bionics Chinese Academy of Sciences Helmholtz Institute Ulm (HIU) Karlsruhe Institute of Technology (KIT) School of Materials Science and Engineering Xi'an University of Technology State Key Laboratory of Chemical Engineering East China University of Science and Technology

Rechargeable aqueous zinc-metal batteries （AZMBs） are promising candidates for large-scale energy storage systems due to their low cost and high ***,their performance and sustainability are significantly hindered by the sluggish desolvation kinetics at the electrode/electrolyte interface and the corresponding hydrogen evolution reaction where active water molecules tightly participate in the Zn（H2O）62+solvation ***,learnt from self-generated solid electrolyte interphase （SEI） in anodes,the dielectric but ion-conductive zinc niobate nanoparticles artificial layer is constructed on metallic Zn surface （ZNB@Zn）,acting as a rapid desolvation *** zincophilic and dielectric-conductive properties of ZNB layer accelerate interfacial desolvation/diffusion and suppress surface corrosion or dendrite formation,achieving uniform Zn plating/stripping behavior,as confirmed by electronic/optical microscopies and interface spectroscopical measurements together with theoretical ***,the as-prepared ZNB@Zn electrode exhibits excellent cycling stability of over 2000 h and robust reversibility （99.54%） even under high current density and depth of discharge ***,the assembled ZNB@Zn-based full cell displays high capacity-retention rate of 80.21%after 3000 cycles at 5 A g-1and outstanding rate performance up to 10 A *** large-areal pouch cell is stabilized for hundreds of cycles,highlighting the bright prospects of the dielectric but ion-conductive layer in further application of AZMBs.

关键词： Zn metal battery Dielectric artificial layer Rapid ion diffusion Zincophilic diffusion Active water inhibition

基于RASM的紧支撑径向基函数自适应并行地形插值方法

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武汉大学学报（信息科学版） 2017年第9期42卷 1316-1322页

作者：吕海洋盛业华李佳段平张思阳南京师范大学虚拟地理环境教育部重点实验室江苏南京210023 南京师范大学江苏省地理信息资源开发与利用协同创新中心江苏南京210023 云南师范大学旅游与地理科学学院云南昆明650500

快速、准确地对地形进行重建以生成数字高程模型是地理信息表达的重要研究内容,径向基函数(radial basis function,RBF)作为一种插值性能较优的空间插值方法,特别适合于重建复杂的地形模型,但随着已知地形采样点数量的增加,RBF插值模型... 详细信息

快速、准确地对地形进行重建以生成数字高程模型是地理信息表达的重要研究内容,径向基函数(radial basis function,RBF)作为一种插值性能较优的空间插值方法,特别适合于重建复杂的地形模型,但随着已知地形采样点数量的增加,RBF插值模型求解速度变慢,同时插值矩阵过于庞大而导致插值模型求解困难甚至求解失败。针对这个问题,本文基于区域分解和施瓦兹并行原理进行地形插值,以紧支撑径向基函数(compact support RBF,CSRBF)构建基于所有地形采样数据的全局插值矩阵,并自适应求解子区域CSRBF插值节点紧支撑半径,基于限制性加性施瓦兹方法(restricted additive Schwarz method,RASM)采用多核并行架构对各局部子区域的插值矩阵进行求解。以某地区数字高程模型(DEM)数据进行插值实验,结果表明,本文方法能够对大规模地形数据进行准确重建,并且具有较高的求解效率。

关键词：地形重建区域分解并行自适应 RASM 紧支撑径向基函数

SiC-MoSi_2/ZrO_2-MoSi_2 coating to protect C/C composites against oxidation

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Transactions of Nonferrous Metals Society of China 2013年第7期23卷 2113-2117页

作者：付前刚张佳平张正中李贺军孙粲西北工业大学凝固技术国家重点实验室 C/C复合材料工程技术研究中心西安710072

To improve the oxidation resistance of carbon/carbon （C/C） composites in air at high temperatures, a SiC- MoSi2/ZrO2-MoSi2 coating was prepared on the surface of C/C composites by pack cementation and slurry method. The microstructures and phase compositions of the coated C/C composites were analyzed by scanning electron microscopy and X-ray diffraction, respectively. The result shows that the SiC-MoSi2/ZrO2-MoSi2 coating is dense and crack-free with a thickness of 250-300 μm. The preparation and the high temperature oxidation property of the coated composites were investigated. The as-received coating has excellent oxidation protection ability and can protect C/C composites from oxidation for 260 h at 1773 K in air. The excellent anti-oxidation performance of the coating is considered to come from the formation of ZrSiO4, which improves the stability of the coating at high temperatures.

关键词： carbon/carbon composites SiC-MoSi2/ZrO2-MoSi2 coating oxidation resistance

Double SiC coating on carbon/carbon composites against oxidation by a two-step method

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Transactions of Nonferrous Metals Society of China 2013年第7期23卷 2107-2112页

作者：孙粲李贺军付前刚张佳平彭晗西北工业大学凝固技术国家重点实验室西安710072

To improve the oxidation resistance of C/C composites, a double SiC protective coating was prepared by a two-step technique. Firstly, the inner SiC layer was prepared by a pack cementation technique, and then an outer uniform and compact SiC coating was obtained by low pressure chemical vapor deposition. The microstructures and phase compositions of the coatings were characterized by SEM, EDS and XRD analyses. Oxidation behaviour of the SiC coated C/C composites was also investigated. It was found that the double SiC coating could protect C/C composites against oxidation at 1773 K in air for 178 h with a mass loss of 1.25%. The coated samples also underwent thermal shocks between 1773 K and room temperature 16 times. The mass loss of the coated C/C composites was only 2.74%. Double SiC layer structures were uniform and dense, and can suppress the generation of thermal stresses, facilitating an excellent anti-oxidation coating.

关键词： carbon/carbon composites SiC oxidation coating

金属有机骨架材料MOF-235的合成及其对甲基橙吸附性能的研究

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福州大学学报（自然科学版） 2017年第5期45卷 725-730页

作者：何聿黄巧高佳童萍张兰福州大学化学学院福建福州350116

对金属有机骨架材料MOF-235的合成、表征及其对甲基橙染料的吸附性能进行研究.采用水热法合成MOF-235材料,通过X-射线衍射、IR、SEM验证并表征其结构特点.运用动力学模型和热力学模型,研究MOF-235对甲基橙溶液的吸附性能.结果显示,该材... 详细信息

对金属有机骨架材料MOF-235的合成、表征及其对甲基橙染料的吸附性能进行研究.采用水热法合成MOF-235材料,通过X-射线衍射、IR、SEM验证并表征其结构特点.运用动力学模型和热力学模型,研究MOF-235对甲基橙溶液的吸附性能.结果显示,该材料对甲基橙的吸附可在极短的时间内达到平衡,温度对吸附效果的影响不大.对实验结果进行吸附等温线和动力学方程拟合,结果表明,MOF-235材料吸附甲基橙的Langmuir等温方程拟合效果更好,吸附过程更符合二级动力学模型.

关键词：金属有机骨架材料甲基橙吸附性能

Deciphering the role of ultra-low-loaded rhodium in NiFe-MIL-53 for superior oxygen evolution reaction

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Journal of Energy Chemistry 2025年第1期100卷 77-86页

作者： Jinzhi jia Jinhua zhang Kailu Guo Lanyue zhang Gening Du Hao You Junfeng Huang Mudong Tu Hua Li Yong Peng Wei Dou Cailing Xu State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering School of Materials and Energy Lanzhou University College of Chemistry and Chemical Engineering Luoyang Normal University

Designing highly active and stable electrocatalysts of oxygen evolution reaction （OER） is one of the crucial *** this study,a novel OER electrocatalyst,NiFe-MIL-53 modified with ultra-low rhodium（Rh@NiFe-MIL-53）,is successfully prepared via the hydrothermal ***-situ Raman spectroscopy and electrochemical impedance spectroscopy reveal that the doped Rh accelerates the phase transformation of NiFe-MIL-53 and the in-situ formed Rh@NiFeOOH is the actual active *** importantly,the enhanced reversibility of electrochemical reconstruction between NiFeOOH and NiFe（OH）2after doping Rh is beneficial for improving the electrochemical stability of the catalyst.X-ray photoelectron spectroscopy spectra show the strong electronic interaction between single-atom Rh and Ni/Fe in Rh@***,theoretical calculations confirm that the integration of single-atom Rh into the NiFeOOH successfully reduces the band gap,regulates the d-band center （εd）,accelerates the charge transfer,and optimizes the adsorption behavior of oxygen-containing intermediates,thereby lowering the energy barrier of rate-determining ***,the optimized Rh@NiFe-MIL-53 exhibits excellent OER activity （240 mV） with a small Tafel slope of 48.2 mV dec-1and long-term durability (over1270 h at 10 m A cm-2and 110 h at 200 mA cm-2).This work presents a new perspective on designing highly efficient OER electrocatalysts.

关键词： NiFe-MIL-53 Rh Electrochemical reconstruction Catalytic mechanism Oxygen evolution reaction

Viscosity and structure relationship with equimolar substitution of CaO with MgO in the CaO–MgO–Al_(2)O_(3)–SiO_(2)slag melts

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 70-79页

作者： Yong Hou Shuo zhang Jie Dang jia Guo Hanghang Zhou Xuewei Lü College of Materials Science and Engineering Chongqing UniversityChongqing 400044China Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and New Materials Chongqing UniversityChongqing 400044China

Currently,the Al_(2)O_(3)content in the high-alumina slag systems within blast furnaces is generally limited to 16wt%–18.5wt%,making it challenging to overcome this *** most studies that concentrated on managing the MgO/Al_(2)O_(3)ratio or basicity,this paper explored the effect of equimolar substitution of MgO for CaO on the viscosity and structure of a high-alumina CaO-MgO-Al_(2)O_(3)-SiO_(2)slag system,providing theoretical guidance and data to facilitate the application of high-alumina *** results revealed that the viscosity first decreased and then increased with higher MgO substitution,reaching a minimum at 15mol%MgO *** transform infrared spectroscopy(FTIR)results found that the depths of the troughs representing[SiO_(4)]tetrahedra,[AlO_(4)]tetrahedra,and Si-O-Al bending became progressively deeper with increased MgO *** of the Raman spectra showed that the average number of bridging oxygens per Si atom and the X_(Q^(3))/X_(Q^(2))(X_(Q^(i))is the molar fraction of Q^(i) unit,and i is the number of bridging oxygens in a[SiO_(4)]tetrahedral unit)ratio increased from 2.30 and 1.02 to 2.52 and 2.14,respectively,indicating a progressive polymerization of the silicate structure.X-ray photoelectron spectroscopy(XPS)results highlighted that non-bridging oxygen content decreased from 77.97mol% to 63.41mol% with increasing MgO concentration,whereas bridging oxygen and free oxygen contents *** analysis demonstrated a gradual increase in the polymerization degree of the tetrahedral structure with the increase in MgO ***,bond strength is another important factor affecting the slag *** occurrence of a viscosity minimum can be attributed to the complex evolution of bond strengths of non-bridging oxygens generated during depolymerization of the[SiO_(4)]and[AlO_(4)]tetrahedral structures by CaO and MgO.

关键词： aluminosilicate viscosity structure spectroscopy