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Plasmonic tandem heterojunctions enable high-efficiency charge transfer for broad spectrum photocatalytic hydrogen production

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Journal of Energy Chemistry 2025年第1期100卷 710-720页

作者： Wenxuan Chen Xiu-Qing Qiao Guo Hui Bojing Sun Dongfang Hou Meidi Wang Xueqian Wu tao Wu Dong-Sheng Li College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials China Three Gorges University Hubei Three Gorges Laboratory College of Chemistry and Materials Science and Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry Jinan University

Rational engineering of semiconductor photocatalysts for efficient hydrogen production is of great significance but still challenging,primarily due to the limitations in charge transfer ***,a fascinating plasmonic tandem heterojunction with the hc-CdS/Mo2C@C heterostructure is aimfully prepared for effectively promoting the charge separation kinetics of the CdS photocatalyst via the synergistic strategy of phase junction,Schottky junction,and photothermal *** difference in atomic configuration between cubic-CdS （c-CdS） and hexagonal-CdS （h-CdS） leads to effective charge separation through a typical Ⅱ charge transfer mechanism,and plasmonic Schottky junction further extracts the electrons in the hc-CdS phase junction to realize gradient charge ***,the photothermal effect of Mo2C@C helps to expand the light absorption,accelerate charge transfer kinetics,and reduce the hydrogen evolution energy *** carbon layer provides a fast channel for charge transfer and protects the photocatalyst from *** a result,the optimized hc-CMC photocatalyst exhibits a significantly high photocatalytic H2production activity of 28.63 mmol/g/h and apparent quantum efficiency of 61.8%,surpassing most of the reported *** study provides a feasible strategy to enhance the charge transfer kinetics and photocatalytic activity of CdS by constructing plasmonic tandem heterogeneous junctions.

关键词： Cadmium sulfide

Layer-by-layer alloying of NIR-Ⅱ emissive M50(Au/Ag/Cu)superatomic nanocluster

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Nano Research 2022年第6期15卷 5569-5574页

作者： Xiao-Hong Ma Jing-tao jia Peng Luo Zhao-Yang Wang Shuang-Quan zang Thomas C.W.Mak Henan Key Laboratory of Crystalline Molecular Functional Materials Henan International Joint Laboratory of Tumor Theranostical Cluster MaterialsGreen Catalysis Centerand College of ChemistryZhengzhou UniversityZhengzhou 450001China Department of Chemistry The Chinese University of Hong KongHong Kong 999077China

The intermetallic synergy plays a critical role in exploring the chemical-physical properties of metal ***,the controlled doping or layer-by-layer alloying of atom-precise metal nanoclusters(NCs)has long been a challenging *** this work,two novel alloy nanoclusters[PPh_(4)]_(4)[Ag_(32)Cu_(18)(PFBT)_(36)]((AgCu)_(50))and[PPh_(4)]_(4)[Au_(12)Ag_(20)Cu_(18)(PFBT)_(36)](Au_(12)(AgCu)_(38)),where PFBT is pentafluorobenzenethiolate,with shell-by-shell configuration of M_(12)@Ag_(20)@Cu_(18)(PFBT)_(36)(M=Ag/Au)were synthesized by a facile one-pot co-reduction ***,a fingerprint library of[Ag_(50)−xCux(PFBT)_(36)]^(4−)(x=0 to 50)from Ag_(50)to Cu_(50)has been successfully established as revealed by electrospray ionization mass ***-crystal X-ray diffraction analysis of trimetallic Au_(12)(AgCu)_(38)confirmed the layer-by-layer alloying under reducing *** is more,(AgCu)_(50)and Au12(AgCu)_(38)both show broad photoluminescence(PL)peak in the second near-infrared(NIR-II)window,and the Au doping in the innermost shell considerably enhances the photoluminescence *** work not only offers an insight in the process of metal cluster alloying but also provides a platform to study the doping-directed PL properties in the multimetallic cluster system.

关键词： alloy nanocluster second near infrared(NIR-II)emission superatom doping

C–H bond activation in the total syntheses of natural products

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Science China Chemistry 2016年第9期59卷 1109-1125页

作者： Pengyu tao Yanxing jia State Key Laboratory of Natural and Biomimetic Drugs School of Pharmaceutical Sciences Peking University

The transition metal-mediated C–H bond activation has emerged as a powerful and ideal method for the total syntheses of natural products and pharmaceuticals, and has had a significant impact on synthetic planning and strategy in complex natural *** this review, we describe selected recent examples of the transition metal-mediated C–H bond activation strategies for the rapid syntheses of natural products.

关键词： C-H activation transition metal natural product total synthesis

Spatial transcriptomics combined with single-nucleus RNA sequencing reveals glial cell heterogeneity in the human spinal cord

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Neural Regeneration Research 2025年第11期20卷 3302-3316页

作者： Yali Chen Yiyong Wei Jin Liu tao Zhu Cheng Zhou Donghang Zhang Department of Anesthesiology West China HospitalSichuan UniversityChengduSichuan ProvinceChina Laboratory of Anesthesia and Critical Care Medicine National-Local Joint Engineering Research Center of Translational Medicine of AnesthesiologyWest China HospitalSichuan UniversityChengduSichuan ProvinceChina Department of Anesthesiology Longgang District Maternity&Child Healthcare Hospital of Shenzhen City(Longgang Maternity and Child Institute of Shantou University Medical College)ShenzhenGuangdong ProvinceChina Department of Anesthesiology Affiliated Hospital of Zunyi Medical UniversityZunyiGuizhou ProvinceChina

Glial cells play crucial roles in regulating physiological and pathological functions,including sensation,the response to infection and acute injury,and chronic neurodegenerative *** cells include astrocytes,microglia,and oligodendrocytes in the central nervous system,and satellite glial cells and Schwann cells in the peripheral nervous *** the greater understanding of glial cell types and functional heterogeneity achieved through single-cell and single-nucleus RNA sequencing in animal models,few studies have investigated the transcriptomic profiles of glial cells in the human spinal ***,we used high-throughput single-nucleus RNA sequencing and spatial transcriptomics to map the cellular and molecular heterogeneity of astrocytes,microglia,and oligodendrocytes in the human spinal *** explore the conservation and divergence across species,we compared these findings with those from *** the human spinal cord,astrocytes,microglia,and oligodendrocytes were each divided into six distinct transcriptomic *** the mouse spinal cord,astrocytes,microglia,and oligodendrocytes were divided into five,four,and five distinct transcriptomic subclusters,*** comparative results revealed substantial heterogeneity in all glial cell types between humans and ***,we detected sex differences in gene expression in human spinal cord glial ***,in all astrocyte subtypes,the levels of NEAT1 and CHI3L1 were higher in males than in females,whereas the levels of CST3 were lower in males than in *** all microglial subtypes,all differentially expressed genes were located on the sex *** addition to sex-specific gene differences,the levels of MT-ND4,MT2A,MT-ATP6,MT-CO3,MT-ND2,MT-ND3,and MT-CO_(2) in all spinal cord oligodendrocyte subtypes were higher in females than in ***,the present dataset extensively characterizes glial cell heterogeneity and offers a valuable resource for explo

关键词： astrocyte glial cell human microglia oligodendrocyte sex differentiation single-nucleus RNA sequencing spatial transcriptomics species variation spinal cord

Mechanical Properties of Interlocked-ring Polymers: A Molecular Dynamics Simulation Study

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Chinese Journal of Polymer Science 2019年第12期37卷 1298-1304,I0008页

作者： Zheng-tao Wu jia-jia Zhou College of Engineering Zhejiang Normal UniversityJinhua 321004China School of Chemistry Beihang UniversityBeijing 100191China

Interlocked-ring polymers,also known as polycatenanes,possess an interesting molecular *** polymers are composed of many interlocked rings in a linear *** topological constrain between neighboring rings distinguishes the interlockedring polymer from its linear *** we present extensive molecular dynamic simulations on the interlocked-ring polymers and analyze the static properties of the *** applying external forces to the polymer,we also study the force-extension curves of the polymer,which provides rich information about the mechanical properties of the interlockedring polymers.

关键词： Poly catenanes Molecular dynamics simulation Force-extension Entanglement

Merging bound states in the continuum in an open acoustic resonator

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Science China(Physics,Mechanics & Astronomy) 2025年第1期Mechanics & Astronomy) .卷 124-131页

作者： Lujun Huang Bin jia Artem S.Pilipchuk Sibo Huang Chen Shen Almas F.Sadreev Yong Li Andrey E.Miroshnichenko School of Physics and Electronic Sciences East China Normal University Institute of Acoustics Tongji University L.V.Kirensky Institute of Physics Department of Mechanical Engineering Rowan University School of Engineering and Technology University of New South Wales at Canberra

Bound states in the continuum （BICs） are perfectly localized resonances despite embedding in the continuum ***,an isolated BIC is very sensitive to the structure ***,we report merging acoustic BICs in a single open resonator,robust against the structure *** find that both symmetry-protected BIC and Friedrich-Wintgen BIC are sustained in a single coupled waveguide-resonator *** varying the height and length of the resonator,these two BICs move toward each other and merge into a single one at a critical *** to an individual BIC,the merged BIC is robust against fabrication error because its Q-factor is proportional to ΔL-4,whereΔL embodies the structure *** essence of this extraordinary phenomenon is perfectly explained by the two-and three-level approximations of the effective nonHermitian ***,we present direct experimental demonstrations of the moving and merging of BICs in a coupled 3D waveguide-resonator,which are evidenced by the vanishing of the linewidth of Fano resonance in the transmission *** results may find exciting applications in designing high-quality acoustic sources,sensors and filters.

关键词： acoustic resonances bound state in the continuum high-Q resonances

Mechanistic insight into the synergy between nickel single atoms and nanoparticles on N-doped carbon for electroreduction of CO2

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Journal of Energy Chemistry 2025年第1期100卷 327-336页

作者： Mingdong Sun Wenwen Guan Cailing Chen Chao Wu Xiaoling Liu Biao Meng tao Chen Yu Han Jun Wang Shibo Xi Yu Zhou State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Advanced Membranes and Porous Materials Center Physical Sciences and Engineering Division King Abdullah University of Science and Technology Institute of Sustainability for Chemicals Energy and Environment A*STAR (Agency for Science Technology and Research) College of Materials Science and Engineering Sichuan University

The synergy of single atoms （SAs） and nanoparticles （NPs） has demonstrated great potential in promoting the electrocatalytic carbon dioxide reduction reaction （CO2RR）;however,the rationalization of the SAs/NPs proportion remains one challenge for the catalyst ***,a Ni2+-loaded porous poly（ionic liquids）(PIL) precursor synthesized through the free radical self-polymerization of the ionic liquid monomer,1-allyl-3-vinylimidazolium chloride,was pyrolyzed to prepare the Ni,N co-doped carbon materials,in which the proportion of Ni SAs and NPs could be facilely modulated by controlling the annealing *** catalyst Ni-NC-1000 with a moderate proportion of Ni SAs and NPs exhibited high efficiency in the electrocatalytic conversion of CO2into *** Ni K-edge X-ray absorption near-edge structure （XANES） spectra and theoretical calculations were conducted to gain insight into the synergy of Ni SAs and *** charge transfer from Ni NPs to the surrounding carbon layer and then to the Ni SAs resulted in the electron-enriched Ni SAs active *** the electroreduction of CO2,the coexistence of Ni SAs and NPs strengthened the CO2activation and the affinity towards the key intermediate of*COOH,lowering the free energy for the potential-determining*CO2→*COOH step,and therefore promoted the catalysis efficiency.

关键词： Activation energy

内孤立波对同反向传播的表面波的调制特征研究

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中国海洋大学学报（自然科学版） 2025年第1期55卷 1-12页

作者：林一帆徐滔贾村陈旭中国海洋大学海洋与大气学院山东青岛266100 自然资源部第三海洋研究所海洋动力研究室福建厦门361005

当内孤立波在海洋内部传播时,会引起表层水体的辐聚辐散,从而对海表波浪进行调制作用。本文使用计算流体力学(Computational fluid dynamics,CFD)技术,针对内孤立波对表面波的调制问题进行数值模拟研究。建立两层模型,模拟了表面波在同... 详细信息

当内孤立波在海洋内部传播时,会引起表层水体的辐聚辐散,从而对海表波浪进行调制作用。本文使用计算流体力学(Computational fluid dynamics,CFD)技术,针对内孤立波对表面波的调制问题进行数值模拟研究。建立两层模型,模拟了表面波在同反向传播的情况下,不同振幅内孤立波对不同波长表面波的调制过程。基于表面波的波长和波高这两个基本特征,发现内孤立波引起的表层水平流速变化会调制表面波的波高,相同方向传播时,表面波波高会在最大水平流速附近处减小,而相反传播时会增大。同时内孤立波引起的水体辐聚辐散(水平流速梯度)的分布会调制表面波的波长特征,表面波波长会在流场辐散的区域变长,在流场辐聚的区域变短。表面波受调制作用变化的强弱与内孤立波振幅、表面波初始波长相关。内孤立波振幅的增加会加强调制作用,使得表面波波高与波长的变化程度更显著。表面波初始波长增加会减弱调制作用。本研究着重分析了内孤立波对表面波的调制作用,得到了内孤立波引起的上层水体流动和受调制的表面波具体的对应关系与变化规律,有助于更好地理解内孤立波对表面波调制的水动力过程,对于解读内波成像的过程有重要意义。

关键词：内孤立波表面波数值模拟计算流体力学小波分析

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Müller cells are activated in response to retinal outer nuclear layer degeneration in rats subjected to simulated weightlessness conditions

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Neural Regeneration Research 2025年第7期20卷 2116-2128页

作者： Yuxue Mu Ning Zhang Dongyu Wei Guoqing Yang Lilingxuan Yao Xinyue Xu Yang Li Junhui Xue Zuoming Zhang tao Chen Aerospace Clinical Medical Center School of Aerospace MedicineAir Force Medical UniversityXi’anShaanxi ProvinceChina Department of Aviation Medicine Xijing HospitalAir Force Medical UniversityXi’anShaanxi ProvinceChina Department of Emergency Medicine Wuhan No.1 HospitalWuhanHubei ProvinceChina Third Regiment School of Basic MedicineAir Force Medical UniversityXi’anShaanxi ProvinceChina Fourth Regiment School of Basic MedicineAir Force Medical UniversityXi’anShaanxi ProvinceChina

A microgravity environment has been shown to cause ocular damage and affect visual acuity,but the underlying mechanisms remain ***,we established an animal model of weightlessness via tail suspension to examine the pathological changes and molecular mechanisms of retinal damage under *** 4 weeks of tail suspension,there were no notable alterations in retinal function and morphology,while after 8 weeks of tail suspension,significant reductions in retinal function were observed,and the outer nuclear layer was thinner,with abundant apoptotic *** investigate the mechanism underlying the degenerative changes that occurred in the outer nuclear layer of the retina,proteomics was used to analyze differentially expressed proteins in rat retinas after 8 weeks of tail *** results showed that the expression levels of fibroblast growth factor 2(also known as basic fibroblast growth factor)and glial fibrillary acidic protein,which are closely related to Müller cell activation,were significantly *** addition,Müller cell regeneration and Müller cell gliosis were observed after 4 and 8 weeks,respectively,of simulated *** findings indicate that Müller cells play an important regulatory role in retinal outer nuclear layer degeneration during weightlessness.

关键词： glial fibrous acidic protein gliosis Müller cells nerve growth factor neural differentiation neurodegeneration proteomic retinal degeneration retinal outer nuclear layer simulated weightlessness