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Selective lithium recovery from black powder of spent lithiumion batteries via sulfation reaction:phase conversion and impurities influence

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Rare Metals 2023年第7期42卷 2350-2360页

作者： Hao Liu jia-liang zhang Guo-Qiang liang Meng Wang Yong-Qiang Chen Cheng-Yan Wang State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing100083China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing100083China Beijing Key Laboratory of Green Recycling and Extraction of Metals Beijing100083China

The aim of this study is to present a new understanding for the selective lithium recovery from spent lithium-ion batteries(LIBs)via sulfation *** composition of roasting products and reaction behavior of impurity elements were analyzed through thermodynamic ***,the effects of sulfuric acid dosage,roasting temperature,roasting time,and impurity elements were assessed on the leaching efficiency of valuable *** methods such as X-ray diffraction(XRD),scanning electron microscopy-energy dispersive spectroscopy(SEM-EDS),and X-ray photoelectron spectroscopy(XPS)were employed to analyze the phase transformation mechanism during roasting *** results indicate that after sulfation roasting(n(H_(2)SO_(4)):n(Li)=0.5,550℃,2 h),94%lithium can be selectively recovered by water leaching and more than 95%Ni,Co,and Mn can be leached through acid leaching without the addition of reduction *** the sulfation roasting process,the lithium in LiNi_(x)Mn_(y)Co_zO_(2)is mainly converted to Li_(2)SO_(4),while the Ni,Co and Mn are first transformed to sulfate and then converted into oxide *** addition,impurity elements such as Al and F will combine with lithium to form LiF and LiAlO_(2),which will reduce the leaching rate of *** results provide a new understanding on the mechanisms of phase conversion during sulfation roasting and reveal the influence of impurity elements for the lithium recovery from spent LIBs.

关键词： Spent lithium-ion batteries(LIBs) Thermodynamic calculations Sulfation roasting Impurity elements Conversion mechanism

Using monochromatic light to measure attenuation length of liquid scintillator solvent LAB

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Nuclear Science and Techniques 2019年第2期30卷 11-18页

作者： Rui zhang De-Wen Cao Chang-Wei Loh You-Hang Liu Fang-liang Wu jia-liang zhang Ming Qi National Laboratory of Solid State Microstructures and School of Physics Nanjing University

Linear alkylbenzene(LAB) will be used as solvent for the liquid scintillator in the central detector of jiangmen Underground Neutrino Observatory. The sheer size of the detector imposes significant challenges and the necessity to further improve the optical transparency of high-quality LAB. In order to study high optical transparencies, we continuously improve our measurement setup and use monochromatic light to measure the attenuation lengths of LAB samples. Moreover, the effects of organic impurities on LAB samples are studied to understand their interaction mechanisms and further improve the optical transparency of LAB.

关键词： Neutrino detector Linear alkylbenzene Light absorption

Recovery and regeneration of LiFePO_(4)from spent lithium-ion batteries via a novel pretreatment process

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International Journal of Minerals,Metallurgy and Materials 2021年第9期28卷 1478-1487页

作者： Cheng Yang jia-liang zhang Qian-kun Jing Yu-bo Liu Yong-qiang Chen Cheng-yan Wang State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China Beijing Key Laboratory of Green Recycling and Extraction of Metals Beijing 100083China School of Metallurgy Engineering Jiangxi University of Science and TechnologyGanzhou 341000China

The recycling of spent LiFePO_(4)batteries has received extensive attention due to its environmental impact and economic *** the pretreatment process of spent LiFePO_(4)batteries,the separation of active materials and current collectors determines the difficulty of the re-covery process and product *** this work,a facile and efficient pretreatment process is first *** only freezing the electrode pieces and immersing them in boiling water,LiFePO_(4)materials were peeled from the Al ***,after roasting under an inert atmosphere and sieving,all the cathode and anode active materials were easily and efficiently separated from the Al and Cu *** active materials were subjected to acid leaching,and the leaching solution was further used to prepare FePO_(4)and Li_(2)CO_(3).Finally,the battery-grade FePO_(4)and Li_(2)CO_(3)were used to re-synthesize LiFePO_(4)/C via the carbon thermal reduction *** discharge capacities of re-synthesized LiFePO_(4)/C cathode were 144.2,139.0,133.2,125.5,and 110.5 mA·h·g−1 at rates of 0.1,0.5,1,2,and 5 C,which satisfies the requirement for middle-end LiFePO_(4)*** whole process is environmental and has great potential for industrial-scale recycling of spent lithium-ion batteries.

关键词： spent lithium iron phosphate batteries pretreating process recovery regeneration cathode materials

Methodological Framework for a Multi-Scale Study on Hydrological Processes and Soil Erosion in Subtropical Southeast China

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Pedosphere 2005年第6期15卷 695-706页

作者： H. ZEPP TANG jia-liang zhang Bin Geographical Institute Ruhr-University Bochum D-44780 Bochum （Germany） Institute of Soil Science Chinese Academy of Sciences P.O. Box 821 Nanjing 210008 （China）

This paper introduces and illustrates the concepts of geoecological process combinations and geographical or landscape dimensions by outlining the methodology of a Sino-German cooperative project in Southeast China and presents the first results of the modelling process for the catchment scale. The project equipped a catchment in subtropical Southeast China from plot scale to catchment scale in order to study the hydrological and soll erosion processes. Distinct spatial differences in principal water and soil material fluxes were quantified. Deep drainage peaks occurred in May, June and July and even in August and November. Measurements in erosion plots as well as sedimentary deposits revealed that there was soil erosion connected with overland flow. Consistent with the results from the regular catenary variations of soil colors, textural stratification and hydrograph analysis, there was also a clear indication of interflow from measured soil moisture data. The experimental set up has the potential to further deepen the understanding of small-scale processes involved in lateral water fluxes and soil erosion. The expected results and interpretations will lead to a further integration of the collected data. In the future, to understand matter transfer in and between landscape ecological units, agricultural influence on nutrient status and flux data will be incorporated.

关键词： catchment geoecological process combination landscape ecology soil erosion

PATIENT-SPECIFIC BLOOD DYNAMIC SIMULATIONS IN ASSESSING ENDOVASCULAR OCCLUSION OF INTRACRANIAL ANEURYSMS

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Journal of Hydrodynamics 2009年第2期21卷 271-276页

作者： CHEN jia-liang WANG Sheng-zhang DING Guang-hong YANG Xin-jian LI Hai-yun Department of Mechanics and Engineering Science Fudan University Shanghai 200433 China Beijing Institute of Neurosurgery Beijing 100050 China Department of Biomedical Engineering Capital Medical University Beijing 100050 China

According to recent studies, there are various potential predictors for surgical outcome for cerebral aneurysms. An accurate surgical outcome assessment would help make better-informed decisions and avoid the risk of rebleeding. It is well known that hemodynamic factors play an important role in the pathogenesis and treatment of intracranial aneurysms. In this article, a computational fluid dynamic analysis is applied to one patient-specific model of the cerebral aneurysm located at the tip of basilar artery, by which the differences of hemodynamic parameters before and after endovascular treatment may be evaluated. Based on the model, we show that the flow behavior near the neck of the aneurysm sees great differences after endovascular treatment as compared with that before treatment, which also affects the wall shear stress and the displacement distribution. In addition, our whole simulation process is based on a series of CFD commercial software packages, which are easily available for doctors to implement such a method in their daily practice. These results would be used to assess the outcome of endovascular treatment for the aneurysm occlusion.

关键词： hemodynamics numerical simulation intracranial aneurysm

Sensitivity of seismic attenuation and dispersion to dynamic elastic interactions of connected fractures: Quasi-static finite element modeling study

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Petroleum Science 2023年第1期20卷 177-198页

作者： Yan-Xiao He Wen-Tao He Meng-Fan zhang jia-liang zhang Wei-Hua Liu Xiao-Yi Ma Gen-Yang Tang Shang-Xu Wang Guo-Fa Li Jun-Zhou Liu Xiang-Long Song State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development Beijing100083China Sinopec Key Laboratory of Seismic Elastic Wave Technology Beijing100083China State Key Laboratory of Petroleum Resources and Prospecting CNPC Key Lab of Geophysical ExplorationChina University of Petroleum(Beijing)Beijing102249China CNOOC(China)Co. Ltd.Hainan BranchHaikouHainan570311China PetroChina Dagang Oilfield Tianjin300280China Sinopec Geophysical Research Institute NanjingJiangsu211103China Sinopec Petroleum Exploration and Production Research Institute Beijing100083China Chinese Academy of Geological Sciences Beijing100037 China

Prediction of seismic attenuation and dispersion that are inherently sensitive to hydraulic and elastic properties of the medium of interest in the presence of mesoscopic fractures and pores,is of great interest in the characterization of fractured *** has been very difficult,however,considering that stress interactions between fractures and pores,related to their spatial distributions,tend to play a crucial role on affecting overall dynamic elastic properties that are largely *** thus choose to quantitatively investigate frequency-dependent P-wave characteristics in fractured porous rocks at the scale of a representative sample using a numerical scale-up procedure via performing finite element *** on 2-D numerical quasi-static experiments,effects of fracture and fluid properties on energy dissipation in response to wave-induced fluid flow at the mesoscopic scale are quantified via solving Biot's equations of *** show that numerical results are sensitive to some key characteristics of probed synthetic rocks containing unconnected and connected fractures,demonstrating that connectivity,aperture and inclination of fractures as well as fracture infills exhibit strong impacts on the two manifestations of WIFF mechanisms in the connected scenario,and on resulting total wave attenuation and phase ***,in turn,illustrates the importance of these two WIFF mechanisms in fractured rocks and thus,a deeper understanding of them may eventually allow for a better characterization of fracture systems using seismic ***,this presented work combines rock physics predictions with seismic numerical simulations in frequency domain to illustrate the sensitivity of seismic signatures on the monitoring of an idealized geologic CO_(2) sequestration in fractured *** simulation demonstrates that these two WIFF mechanisms can strongly modify seismic records and hence,indicating that incorporating the two energy dis

关键词： Attenuation and dispersion Rock physics Fractured media Frequency dependence Numerical study

Surgical Indications of Exploring Optic Canal and Visual Prognostic Factors in Neurosurgical Treatment of Tuberculum Sellae Meningiomas

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Chinese Medical Journal 2015年第17期128卷 2307-2311页

作者： Hao-Cheng Liu E Qiu jia-liang zhang Jun Kang Yong Li Li-Bin jiang Ji-Di Fu Department of Neurosurgery Tongren Hospital Capital Medical University Beijing 100730 China Department of Radiology Tongren Hospital Capital Medical University Beijing 100730 China Department of Ophthalmology Tongren Hospital Capital Medical University Beijing 100730 China

Background： Tuberculum sellae meningiomas （TSMs） present a special symptom because of the adherence and compression to the optic nerve, optic artery, and the chiasm. A significant number of patients with TSMs appear visual deficits. This study aimed to investigate the surgical indications of exploring the optic canal and visual prognostic factors in the neurosurgical treatment of TSMs. Methods： Totally 21 patients with TSM, who were operated from September 2007 to August 2011 in the Department of Neurosurgery, Tongren Hospital were enrolled in this study. Results of orbital computed tomography （CT） and magnetic resonance imaging （MRI）, visual acuity, Goldmann visual field test, orbital color Doppler flow imaging （CDI） test in these patients were retrospectively analyzed. Results： Visual deficit and optic canal involvement （OCI） were detected in all the 21 patients. Fourteen patients had bone proliferation within the area of the optic canal. After the operation, visual outcomes were improved in 13 patients, unchanged in 7 patients, and deteriorated in 1 patient. All the 21 patients performed orbital CDI test preoperatively, the results showed that if the peak systolic velocity （PSV） of central retinal artery （CRA） value was 〈8 cm/s, the visual outcome would be better. Conclusions： The surgical indications of exploring optic canal in TSM cases included：（1） The neuroimaging evidences of OCI （CT and/ or MR/）; （2） PSV of CRA in orbital CDI test was ≤8 cm/s; （3） visual acuity was below 0.1 ; （4） visual field deficit. The PSV of CRA in CDI test could be a prognostic factor for visual outcomes of TSMs.

关键词： Meningioma Surgical Management Tuberculum Sellae Vision

锌对半乳糖诱导的人晶状体上皮细胞凋亡的影响

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国际眼科杂志 2018年第10期18卷 1774-1777页

作者：贾义张亮亮夏欢贵州医科大学生物与工程学院化学生物学教研室中国贵州省贵阳市550025

目的:研究锌对半乳糖诱导的人晶状体上皮细胞(human lens epithelial cells,HLEC)凋亡的影响。方法:将培养的SRA01/04细胞系分为六组,对照组、半乳糖处理组、补锌组、补锌联合半乳糖处理组、缺锌组、缺锌联合半乳糖处理组。采用MTT法检... 详细信息

目的:研究锌对半乳糖诱导的人晶状体上皮细胞(human lens epithelial cells,HLEC)凋亡的影响。方法:将培养的SRA01/04细胞系分为六组,对照组、半乳糖处理组、补锌组、补锌联合半乳糖处理组、缺锌组、缺锌联合半乳糖处理组。采用MTT法检测半乳糖对HLEC存活率的影响,荧光显微镜和流式细胞仪分别检测各实验分组细胞核形态和细胞凋亡率水平的变化。结果:不同浓度半乳糖(0、25、50、75、100、125mmol/L)处理HLEC细胞后,细胞存活率分别为(100. 0±5. 4)%、(97. 5±3. 2)%、(91. 3±5. 3)%、(93. 4±0. 6)%、(86. 6±1. 4)%和(83. 5±0. 4)%,与未处理细胞相比,半乳糖浓度为100、125mmol/L时,细胞存活率显著下降,差异有统计学意义(P<0. 05)。荧光显微镜结果显示对照组和补锌组的细胞核呈现均一的染色,半乳糖处理组、补锌联合半乳糖处理组、缺锌组和缺锌联合半乳糖处理组中一些细胞的细胞核收缩,表现出典型的细胞凋亡形态。各组的细胞凋亡率分别为(1. 5±0. 1)%、(7. 1±0. 2)%、(1. 4±0. 1)%、(4. 4±0. 2)%、(5. 5±0. 2)%和(15. 8±0. 3)%。与对照组相比,半乳糖处理组、补锌联合半乳糖处理组、缺锌组和缺锌联合半乳糖处理组的细胞凋亡率显著增加,差异有统计学意义(P <0. 05)。与半乳糖处理组相比,补锌联合半乳糖处理组的细胞凋亡率显著下降,差异有统计学意义(P<0. 05),缺锌联合半乳糖处理组的细胞凋亡率则显著升高,差异有统计学意义(P<0. 05)。结论:补锌可以保护人晶状体上皮细胞抵抗由半乳糖引起的细胞凋亡,可能对白内障的形成有抑制作用。

关键词：人晶状体上皮细胞半乳糖锌细胞凋亡

Superhydrophobic and corrosion-resistant siloxane-modified MgAl-LDHs coatings on magnesium alloy prepared under mild conditions

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 450-463页

作者： Wenxi zhang zhangzelong Zhuo Dan Xu liang Wu Zhihui Xie Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province College of Chemistry and Chemical EngineeringChina West Normal UniversityNanchong 637002China College of Materials Science and Engineering/National Engineering Research Center for Magnesium Alloys Chongqing UniversityChongqing 400044China

We have developed a superhydrophobic and corrosion-resistant LDH-W/PFDTMS composite coating on the surface of Mg *** composite comprised a tungstate-intercalated(LDH-W)underlayer that was grown at low temperature(relative to hydrothermal reaction conditions)under atmospheric pressure and an outer polysiloxane layer created from a solution containing perfluorodecyltrimethoxysilane(PFDTMS)using a simple immersion *** successful intercalation of tungstate into the LDH phase and the following formation of the polysiloxane layer were confirmed through X-ray diffraction(XRD),Fourier transform infrared(FTIR)spectroscopy,and X-ray photoelectron spectroscopy(XPS).The corrosion resistance of the LDH-W film,both before and after the PFDTMS modification,was evaluated using electrochemical impedance spectroscopy(EIS),Tafel curves,and immersion *** results showed that Mg coated with LDH-W/PFDTMS exhibited significantly enhanced corrosion protection compared to the unmodified LDHW film,with no apparent signs of corrosion after exposure to 3.5wt%NaCl solution for 15 ***,the LDH-W/PFDTMS coating demonstrated superior superhydrophobicity and self-cleaning properties against water and several common beverages,as confirmed by static contact angle and water-repellency *** results offer valuable insights into preparing superhydrophobic and corrosion-resistant LDH-based composite coatings on Mg alloy surfaces under relatively mild reaction conditions.

关键词： Mg alloy corrosion coating layered double hydroxide