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Effects of certain phenolic acids on advanced glycation end products formation in glucose-lysine Maillard reaction models

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Food Science and Human Wellness 2024年

作者： He Li Meng-Yao jin Zi-Ze Liang Dan Li jia-hao ji Lin Kong Zi-Qing Zhao Rui-jie Wu School of Chemistry and Chemical Engineering， North University of China Shanxi jinshuo Biomedical Technology Co.Ltd.

Advanced glycation end products (AGEs)， a group of complex compounds generated by nonenzymatic interactions between amino acids， proteins and reducing sugars or lipids， accumulate in vivo and activate various signaling pathways closely related to the occurrence of various chronic metabolic diseases. This study aims to explore the structure-activity relationship between phenolic acids with different structure and affecting the AGEs generation， and to provide data support for AGEs control. Phenolic acids (4-hydroxybenzoic， protocatechuic， gallic， ρ-coumaric， caffeic， ferulic and sinapic acids) were employed to indicate the AGEs formation condition in Maillard reaction performed in the glucose-lysine model system. Three 1，2-dicarbonyl compounds were reacted with phenolic acids and then tested by liquid chromatography-mass spectrometry. The results showed that Nε-carboxy-methyl-lysine (CML)， Nε-carboxy-ethyl-lysine (CEL)， and pyrraline formation inhibited by phenolic acids varied from (8.7 ± 2.5)% to (33.2 ± 2.5)%， (10.5 ± 0.8)% to (57.1 ± 3.2)% and (1.3 ± 0.3)% to (23.3 ± 0.8)%， respectively. The ρ-coumaric acid has no inhibitory effect on CML and CEL formation. Gallic acid shows the best inhibitory effect on CML formation due to its strong antioxidant activity. Sinapic acid showed the best glyoxal (GO) trapping rate and thus had the stronger inhibitory effect on CML formation. Ferulic acid can react with mono-， di- tri-methylglyoxal (MGO) to form adduct products， showing the best MGO scavenging rate and a good inhibitory effect on CEL formation. The main role of phenolic acid is an antioxidant agent to inhibit pyrraline formation. The glucose itself or ammonia-induced degradation and ARP oxidation were lowered by protocatechuic， gallic and caffeic acids due to their antioxidant activities to form AGEs， while AGEs inhibited by ferulic and sinapic acids were mainly dependent on their trapping ability on 1，2-dicarbonyl compounds.

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干旱胁迫下油菜素内酯对植物-土壤化学计量特征及内稳性的影响

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草地学报 2024年第4期32卷 1068-1077页

作者：李铭怡王冉贾濠基耿启明郭士维王福豪刘黎明董文豪许文年三峡库区地质灾害教育部重点实验室(三峡大学) 湖北宜昌443002 三峡大学土木与建筑学院湖北宜昌443002 水泥基生态修复技术湖北省工程研究中心(三峡大学) 湖北宜昌443002 湖北润智生态科技有限公司湖北宜昌443002

为探究施用油菜素内酯(Brassinosteroid,BR)对不同干旱条件下植物与土壤的生态化学计量特征及其相互关系,本研究以黄花决明(Cassia glauca Lam.)为研究对象,采用盆栽控水法,设置正常水分、中度胁迫、重度胁迫处理(田间持水量的75%±5%,... 详细信息

为探究施用油菜素内酯(Brassinosteroid,BR)对不同干旱条件下植物与土壤的生态化学计量特征及其相互关系,本研究以黄花决明(Cassia glauca Lam.)为研究对象,采用盆栽控水法,设置正常水分、中度胁迫、重度胁迫处理(田间持水量的75%±5%,55%±5%,35%±5%)及4种BR浓度处理(0,0.05,0.2和0.5 mg·L^(-1)),在干旱90天后测定株高、生物量和植物、土壤的养分含量及化学计量特征。研究发现:干旱胁迫导致株高、地上和地下生物量降低;随着施用BR浓度的增加,株高、生物量表现为先上升后下降;0.2 mg·L^(-1)BR有利于植物养分含量提升,地上部提升效果更好;干旱区生态修复中黄花决明的生长对N元素的供应需求较大;施用BR有助于提高黄花决明株高和生物量,调节养分分配策略,缓解干旱对植物的不利影响。本研究可为干旱地区的生态修复和植被重建提供新思路与新方法。

关键词：生态修复干旱胁迫油菜素内酯化学计量养分特征内稳性

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Flow characterization of macroporous W-4.8 vol.%ZrO2 alloy during hot deformation with improved constitutive equation and processing maps

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Tungsten 2024年第3期6卷 610-620页

作者： jia-hao Ye Liu-jie Xu ji-Kang Hu School of Materials Science and Engineering Henan University of Science and Technology National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials Henan University of Science and Technology

In this work,isothermal compression experiments of macroporous W-4.8 vol.%ZrO2（W-4.8ZrO2） at 1300-1600℃ and strain rate of 0.005-1 s-1were carried out on a Gleeble-1500D thermo-mechanical *** dynamic recovery of W-4.8ZrO2is the main "softening" *** the basis of Arrhenius model,the initial constitutive equation is established by exploring the influence of temperature,strain rate and rheological *** on Arrhenius model,the relationship between flow stress,strain rate and deformation temperature is *** the influence of strain,the improved constitutive equation and the law of material constant changing with the strain are *** that,the hot processing maps were drawn on the basis of the dynamic material model,which is used to analyze the instability mechanism of the W-4.8ZrO2,and determine the appropriate hot working process parameters(temperature:1350-1450℃,strain rate:0.1-1 s-1).

关键词： Tungsten alloy Flow characteristics Constitutive equation Hot processing maps

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Simultaneous Bulk-and Surface-initiated Living Polymerization Studied with a Heterogeneous Stochastic Reaction Model

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Chinese Journal of Polymer Science 2024年第3期42卷 364-372,I0008页

作者： jia-Shu Ma Zhi-Ning Huang jia-hao Li Bang-Ping jiang Yan-Da Liao Shi-Chen ji Xing-Can Shen State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources(Ministry of Education of China)School of Chemistry and Pharmaceutical SciencesGuangxi Normal UniversityGuilin 541004China School of Computer Science and Engineering&School of Software Guangxi Normal UniversityGuilin 541004China

To better characterize the properties of surface-initiated polymers, simultaneous bulk-and surface-initiated polymerizations are usually carried out by assuming that the properties of the surface-initiated polymers resemble those of the bulk-initiated polymers. Through a Monte Carlo simulation using a heterogeneous stochastic reaction model, it was discovered that the bulk-initiated polymers exhibit a higher molecular weight and a lower dispersity than the corresponding surface-initiated polymers, which indicates that the equivalent assumption is invalid. Furthermore, the molecular weight distributions of the two types of polymers are also different, suggesting different polymerization mechanisms. The results can be simply explained by the heterogeneous distributions of reactants in the system. This study is helpful to better understand surface-initiated polymerization.

关键词： Surface-initiated polymerization Polymer brush Stochastic reaction model Heterogeneous polymerization Simultaneous polymerization

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Review of Iron-Based Catalysts for Carbon Dioxide Fischer-Tropsch Synthesis

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Transactions of Tianjin University 2024年第2期30卷 178-197页

作者： ji-Yue jia Yu-Ling Shan Yong-Xiao Tuo hao Yan Xiang Feng De Chen State Key Laboratory of Heavy Oil Processing China University of PetroleumQingdao 266580China College of Chemical Engineering Qingdao University of Science and TechnologyQingdao 266042China Department of Chemical Engineering Norwegian University of Science and Technology7491 TrondheimNorway

Capturing and utilizing CO_(2)from the production process is the key to solving the excessive CO_(2)emission problem. CO_(2)hydrogenation with green hydrogen to produce olefins is an effective and promising way to utilize CO_(2)and produce valuable chemicals. The olefins can be produced by CO_(2)hydrogenation through two routes, i.e., CO_(2)-FTS (carbon dioxide Fischer- Tropsch synthesis) and MeOH (methanol-mediated), among which CO_(2)-FTS has significant advantages over MeOH in practical applications due to its relatively high CO_(2)conversion and low energy consumption potentials. However, the CO_(2)-FTS faces challenges of difficult CO_(2)activation and low olefins selectivity. Iron-based catalysts are promising for CO_(2)-FTS due to their dual functionality of catalyzing RWGS and CO-FTS reactions. This review summarizes the recent progress on iron-based catalysts for CO_(2)hydrogenation via the FTS route and analyzes the catalyst optimization from the perspectives of additives, active sites, and reaction mechanisms. Furthermore, we also outline principles and challenges for rational design of high-performance CO_(2)-FTS catalysts.

关键词： CO_(2)hydrogenation Olefins CO_(2)-FTS Iron-based catalysts

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Restricted Arc-Connectivity of Harary Digraphs

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Journal of the Operations Research Society of China 2024年第2期12卷 540-547页

作者： Jun-hao Zhang ji-Xiang Meng College of Mathematics and System Science Xinjiang UniversityUrumqi 830046XinJiangChina

The h-restricted arc-connectivity of a digraph is an important parameter to measure fault-tolerance of interconnection *** paper determines that the h-restricted arc-connectivity of the Harary digraph D=G(n;1,2,.:,k)i... 详细信息

关键词： Restricted arc-connectivity λ_(h)(D) Super-λ_(h) λ_(h)-Atom λ_(h)-Superatom

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A real-time calibration method based on time-to-digital converter for accelerator timing system

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NUCLEAR SCIENCE AND TECHNIQUES 2024年第9期35卷 1-14页

作者： Duan, Qi-hao Ge, Liang jia, Yan-hao Zhu, jie-Yu Zhang, Wei Chinese Acad Sci Inst modern Phys Lanzhou 730000 Peoples R China Univ Chinese Acad Sci Beijing 100049 Peoples R China

The high-intensity heavy-ion accelerator facility (HIAF) is a scientific research facility complex composed of multiple cascade accelerators of different types, which pose a scheduling problem for devices distributed over a certain range of 2 km, involving over a hundred devices. The white rabbit, a technology-enhancing Gigabit Ethernet, has shown the capability of scheduling distributed timing devices but still faces the challenge of obtaining real-time synchronization calibration parameters with high precision. This study presents a calibration system based on a time-to-digital converter implemented on an ARM-based System-on-Chip (SoC). The system consists of four multi-sample delay lines, a bubble-proof encoder, an edge controller for managing data from different channels, and a highly effective calibration module that benefits from the SoC architecture. The performance was evaluated with an average RMS precision of 5.51 ps by measuring the time intervals from 0 to 24,000 ps with 120,000 data for every test. The design presented in this study refines the calibration precision of the HIAF timing system. This eliminates the errors caused by manual calibration without efficiency loss and provides data support for fault diagnosis. It can also be easily tailored or ported to other devices for specific applications and provides more space for developing timing systems for particle accelerators, such as white rabbits on HIAF.

关键词： HIAF White rabbit Calibration system Time-to-digital converter (TDC) FPGA

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Copper-catalyzed enantioselective desymmetrizing C(sp^(2))-H functionalization of azide-ynamides via α-imino copper carbenes

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Science China Chemistry 2024年第9期67卷 2982-2988页

作者： En-He Huang Li-Gao Liu You-Wei Yin hao-Xuan Dong ji-jia Zhou Xin Lu Bo Zhou Long-Wu Ye Key Laboratory for Chemical Biology of Fujian Province and State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China

α-Imino metal carbenes are versatile intermediates in organic synthesis,and have broad applications in the assembly of divergent ***,the catalytic enantioselective desymmetrization based onα-imino metal carbenes has not been developed to ***,we disclose an enantioselective desymmetrizing C(sp^(2))-H functionalization of azide-ynamides viaα-imino copper carbenes,leading to the efficient assembly of divergent chiral indoloazepines in generally moderate to excellent yields with high ***,this reaction represents the first enantioselective desymmetrization based onα-imino metal *** synthetic transformations and biological tests show the potential utility of this ***,computational studies are employed to elucidate the reaction mechanism and the origin of enantioselectivity.

关键词： enantioselective desymmetrization metal carbenes copper catalysis nitrene transfer alkynes

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Vertically aligned montmorillonite aerogel-encapsulated polyethylene glycol with directional heat transfer paths for efficient solar thermal energy harvesting and storage

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International Journal of Minerals,Metallurgy and Materials 2024年第5期31卷 907-916页

作者： Qijing Guo Cong Guo hao Yi Feifei jia Shaoxian Song Key Laboratory of Green Utilization of Critical Non-metallic Mineral Resources Ministry of EducationWuhan University of TechnologyWuhan 430070China School of Resources and Environmental Engineering Wuhan University of TechnologyWuhan 430070China Hubei Key Laboratory of Mineral Resources Processing and Environment Wuhan University of TechnologyWuhan 430070China

The conversion and storage of photothermal energy using phase change materials(PCMs)represent an optimal approach for harnessing clean and sustainable solar ***,we encapsulated polyethylene glycol(PEG)in montmorillonite aerogels(3D-Mt)through vacuum impregnation to prepare 3D-Mt/PEG composite *** used as a support matrix,3D-Mt can effectively prevent PEG leakage and act as a flame-retardant barrier to reduce the flammability of ***,3D-Mt/PEG demonstrates outstanding shape retention,increased thermal energy storage density,and commendable thermal and chemical *** phase transition enthalpy of 3D-Mt/PEG can reach 167.53 J/g and remains stable even after 50 heating-cooling ***,the vertical sheet-like structure of 3D-Mt establishes directional heat transport channels,facilitating efficient phonon *** configuration results in highly anisotropic thermal conductivities that ensure swift thermal responses and efficient heat *** study addresses the shortcomings of PCMs,including the issues of leakage and inadequate flame *** achieves the development and design of 3D-Mt/PEG with ultrahigh strength,superior flame retardancy,and directional heat ***,this work offers a design strategy for the preparation of high-performance composite *** 3D-Mt/PEG with vertically aligned and well-ordered array structure developed in this research shows great potential for thermal management and photothermal conversion applications.

关键词： montmorillonite aerogel polyethylene glycol phase change materials solar thermal energy storage flame retardant

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Activity promotion of Rh_(1)Ca_(x)/Al_(2)O_(3) single-atom catalyst in 1-octene hydroformylation:a volcano curve exists between Ca adding ratio and catalytic activity

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Science China Chemistry 2024年第4期67卷 1187-1192页

作者： hao Zhang Xingcong Zhang Xilun Wang Qingdi Sun hao Liu Hongbing ji Xiaohui He Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education Fine Chemical Industry Research InstituteSchool of ChemistryIGCMESun Yat-sen UniversityGuangzhou 510275China Huizhou Research Institute Sun Yat-sen UniversityHuizhou 516081China State Key Laboratory Breeding Base of Green-Chemical Synthesis Technology Institute of Green Petroleum Processing and Light Hydrocarbon ConversionCollege of Chemical EngineeringZhejiang University of TechnologyHangzhou 310014China

Single-atom catalysts(SACs)are considered the best candidates for olefin hydroformylation due to their combined advantages of homogeneous and heterogeneous *** conventional organo-phosphine modification,Rh SAC is modified by introducing Ca,resulting in a significant increase in activity(maximum~5.7-fold)and ***,a volcano curve between Ca addition ratio and catalytic activity is *** Ca significantly increases activity by decreasing the energy barrier,but excessive Ca decreases activity due to hindering substrate adsorption and reaction.

关键词： hydroformylation bimetallic single-atom catalysts rhodium heterogeneous catalyst

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