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16.48% Efficient solution-processed CIGS solar cells with crystal growth and defects engineering enabled by Ag doping strategy

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Journal of Energy Chemistry 2025年第1期100卷 59-65页

作者： Mengyu Xu Shaocong Yan Ting Liang jia jia Shengjie Yuan Dongxing Kou Zhengji Zhou Wenhui Zhou Yafang Qi Yuena Meng Litao han Sixin Wu Key Laboratory for Special Functional Materials of MOE National & Local Joint Engineering Research Centre for High-efficiency Display and Lighting Technology School of Nanoscience and Materials Engineering Henan University

Solution-processed Cu（In,Ga）Se2（CIGS） solar cells suffer from serious carrier recombination and power conversion efficiency（PCE） loss because of the poor film properties and easy formation of ***, we propose Ag&Se co-selenization strategy to enhance the crystallization and passivate harmful defects of the CIGS films. The formation of Ag-Se phase during the selenization process enables the formation of large grains and suppresses the deep level defects. It is found that Ag doping can enlarge the depletion region width, lower the Urbach energy and prolong the carrier lifetime. As a result, a champion solution-processed CIGS solar cell presents a high efficiency of 16.48% with the highly improved opencircuit voltage（VOC） of 662 m V and fill factor（FF） of 75.8%. This work provides an efficient strategy to prepare high quality solution-processed CIGS films for high-performance CIGS solar cells.

关键词： CIGS solar cells Solution-processed method Ag doping Crystal growth Defects engineering

Anomalous quality factor evolution of induced transparency in a virtualized coupled-oscillator system

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Science China(Physics,Mechanics & Astronomy) 2025年第1期Mechanics & Astronomy) .卷 148-155页

作者： Yunhan Yang han jia Tuo Liu Yuzhen Yang Jun Yang Key Laboratory of Noise and Vibration Research Institute of Acoustics Chinese Academy of Sciences University of Chinese Academy of Sciences State Key Laboratory of Acoustics Institute of Acoustics Chinese Academy of Sciences

The phenomenon of induced transparency, characterized by a high quality(Q) factor, holds significant importance in the fields of high-precision sensing, energy storage and wave manipulation. Conventional transparency systems are often constrained by the limited experimentally accessible parameter space and the lack of independent control over intrinsic parameters, thereby hindering advanced research on high-Q effects. Here we propose a virtualized coupled-oscillator system that enables reconfigurable induced transparency in the reflection spectrum. By virtually incorporating a pair of coupled oscillators into an individual acoustic meta-atom, we achieve the manipulation of induced transparency in a decoupled, wide-ranging, and elaborate manner. Exploiting the diverse evolutions across the intrinsic parameter space, we show experimentally a counter-intuitive increase in the Q-factor of the transparency window, which is attributed to the enhanced dissipation of the bright ***, a constant group delay at the center frequency is observed accompanying this evolution. Our work demonstrates an intriguing platform as well as a novel strategy to engineer high-Q induced transparency phenomenon, and paves the way towards applications in programmable acoustic sensors, filters and slow-wave devices.

关键词： induced transparency acoustic meta-atom high quality-factor scattering programmable intrinsic parameter

Synergistic promotion strategy of “dual-site” and “dual-path” to enhance the C–C coupling between CO2 and HCHO driven by photoelectrocatalysis

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Journal of Energy Chemistry 2025年第1期100卷 39-49页

作者： Hongqiang Yang jianfeng Zheng Guoyu Wang Yifei Gao Yatao Yang jia Li Xiaojin han Yan Cui Zhanggen Huang National Key Laboratory of High Efficiency and Low Carbon Utilization of Coal Institute of Coal Chemistry Chinese Academy of Science University of Chinese Academy of Science Shenyang University of Chemical Technology

Photoelectrocatalytic coupling CO2and volatile organic compounds （VOCs） is a promising green strategy for the synergistic conversion of the two carbon-containing resources to *** catalytic efficiency is always at the mercy of chemical inertness of CO2and the competitive hydrogen evolution of ***,a modified g-C3N4/ZnAl-LDH Z-scheme heterojunction catalyst with dual reaction site was rationally designed and precisely *** Faraday efficiency of ethanol reached 68.67%with a corresponding formation rate of 227.3μmol *** revealed by in-situ characterizations and density functional theory calculations,CO2and HCHO were absorbed at Zn site and N site,***,*CO generated from CO2and HCHO was converted to*CH3O and*CHO on the dual-active-site *** detailed reaction mechanism experiments indicated that C–C coupling only occurred between*CO and*CH3O in electrocatalysis *** from the“*CO+*CH3O”path,another“*CO+*CHO”coupling path was also detected in photoelectrocatalytic *** selectivity of ethanol was significantly enhanced due to the synthesis of dual-site catalyst and the dual-path coupling path between CO2and HCHO simultaneously driven by light and electricity.

关键词： Photoelectrocatalysis Z-scheme C–C coupling Ethanol

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干细胞的趋电性迁移及机制

中国组织工程研究 2025年第23期29卷 4984-4992页

作者：韩芳舒晴贾绍辉田峻武汉体育学院运动医学院湖北省武汉市430079 武汉大学中南医院骨科康复科湖北省武汉市430071

背景:随着对干细胞技术研究的深入,如何使其准确归巢成为临床应用中的一大难题。除药物和趋化因子等信号的诱导外,电场也被广泛应用于指导干细胞的定向迁移,并可增强其迁移速度和定向性。目的:旨在分析总结电场对干细胞迁移特性的影响,... 详细信息

背景:随着对干细胞技术研究的深入,如何使其准确归巢成为临床应用中的一大难题。除药物和趋化因子等信号的诱导外,电场也被广泛应用于指导干细胞的定向迁移,并可增强其迁移速度和定向性。目的:旨在分析总结电场对干细胞迁移特性的影响,同时综述可能的作用机制。方法:通过检索Pub Med和中国知网数据库,收集截至2024年3月的相关文献,英文检索词:“stem cells,direct current electric field,pulsed electric field,migration,electric field device,mechanism”;中文检索词:“干细胞,直流电场,脉冲电场,迁移,电场装置,机制”。排除不能获取全文和与主题无关的文献。结果与结论:根据筛选要求共纳入58篇文献,包括中文文献15篇及英文文献43篇。文献以脂肪间充质干细胞、骨髓间充质干细胞、神经干细胞、表皮干细胞、人胚胎干细胞和人诱导性多功能干细胞为研究对象,在迁移装置中研究电场的不同参数对上述干细胞迁移的影响及其机制。(1)电场作为一种简单、无创且稳定的干预方式在指导干细胞定向迁移的过程中起着积极作用;(2)不同类型的干细胞发生趋电性迁移的方向不同,同时大部分干细胞的迁移速度和定向性是随着电场强度增加而增加的;(3)不同的电场装置在观测干细胞迁移时的侧重点不同,可根据实验目的而择优选择相关装置;(4)不同干细胞趋电性迁移的机制不完全相同,多数干细胞迁移过程中有MAPK通路、ROCK活化以及PI3K功能的参与,同时还有其他蛋白质复合物与信号通路参与调控该过程;(5)除电场参数不同之外,细胞本身的衰老情况和培养环境也会对趋电性迁移的结果产生影响。总而言之,电场作为一种影响干细胞迁移特性的重要信号,与其他新兴材料结合在组织工程应用中展现出了一定的潜力,有望在指导干细胞归巢方面发挥更加重要的作用,促进骨组织再生和修复以及神经系统、自身免疫系统以及肿瘤等疾病的研究取得更大的突破。

关键词：干细胞电场趋电性迁移机制归巢效应物理因子电场装置细胞衰老培养环境

Analysis on damage causes of built-in corridor in core rock-fill dam on thick overburden:A case study

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Frontiers of Structural and Civil Engineering 2022年第6期16卷 762-780页

作者： jia’ao YU Zhenzhong SHEN Zhangxin HUANG College of Water Conservancy and Hydropower Engineering Hohai UniversityNanjing 210024China State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering Hohai UniversityNanjing 210024China

The stress state of the built-in corridor in core rock-fill dam on thick overburden is extremely complex,which may produce cracking and *** purpose of this paper was to investigate the effect of thick overburden on the stress and deformation of the built-in corridor in a rock-fill dam,and ascertain the damage causes of the *** rationality of the analysis method for corridor with similar structure is another *** approach is based on finiteelement method and the calculation result accuracy is verified by the field monitoring *** improved analysis method for corridors with similar structure is proposed by comparing various corridor load calculation methods and concrete constitutive *** demonstrate that the damage causes of the corridor are the deformability difference between the overburden and concrete and the special structural *** the calculation model considering dam construction process,contact between concrete and surrounding soil,and concrete damage plasticity can reasonably reflect the mechanical behavior of the *** research conclusions may have a reference significance for the analysis of tunnels similar to built-in corridors.

关键词： thick overburden built-in corridor stress deformation causes for damage concrete damaged plasticity

Fractional Coloring Planar Graphs under Steinberg-type Conditions

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Acta Mathematica Sinica,English Series 2023年第5期39卷 904-922页

作者： Xiao Lan HU jia ao LI School of Mathematics and Statistics&Hubei Key Laboratory of Mathematical Sciences Central China Normal UniversityWuhan 430079P.R.China School of Mathematical Sciences and LPMC Nankai UniversityTianjin 300071P.R.China

A Steinberg-type conjecture on circular coloring is recently proposed that for any prime p≥5,every planar graph of girth p without cycles of length from p+1 to p(p-2)is Cp-colorable(that is,it admits a homomorphism to the odd cycle Cp).The assumption of p≥5 being prime number is necessary,and this conjecture implies a special case of Jaeger’s Conjecture that every planar graph of girth 2p-2 is Cp-colorable for prime p≥*** this paper,combining our previous results,we show the fractional coloring version of this conjecture is ***,the p=5 case of our fractional coloring result shows that every planar graph of girth 5 without cycles of length from 6 to 15 admits a homomorphism to the Petersen graph.

关键词： Fractional coloring circular coloring planar graphs girth homomorphism

Molecular understanding of cation effects on double layers and their significance to CO-CO dimerization

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National Science Review 2023年第9期10卷 125-135页

作者： jia-Bo Le ao Chen Yongbo Kuang Jun Cheng Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province Ningbo Institute of Materials Technology and EngineeringChinese Academy of Sciences State Key Laboratory of Physical Chemistry of Solid Surfaces iChEM College of Chemistry and Chemical EngineeringXiamen University Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province(IKKEM)

Cation effects have been shown in numerous experiments to play a significant role in electro *** understand these effects at the molecular level,we systematically investigate the structures and capacitances of electric double layers with a variety of cations as counter charges at Pt(111)-COad/water interfaces with ab initio molecular *** is encouraging to find that the computed Helmholtz capacitances for different cations are in quantitative agreement with experiments,and that the trend of cation effects on capacitances shows clear correlation with the structures of interface cations of differing sizes and hydration *** importantly,we demonstrate the Helmholtz capacitance as the key descriptor for measuring the activity of CO-CO dimerization,the rate-determining step for C2+formation in electroreduction of CO and *** work provides atomistic insights into cation effects on electric double layers and electrocatalysis that are crucial for optimizing electrode and electrolyte materials.

关键词： cation effect electrocatalysis electric double layer CO-CO dimerization ab initio molecular dynamics

Optimization design of anti-seismic engineering measures for intake tower based on non-dominated sorting genetic algorithm-Ⅱ

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Frontiers of Structural and Civil Engineering 2023年第9期17卷 1428-1441页

作者： jia’ao YU Zhenzhong SHEN Zhangxin HUANG Haoxuan LI State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering Hohai UniversityNanjing 210024China College of Water Conservancy and Hydropower Engineering Hohai UniversityNanjing 210024China

High-rise intake towers in high-intensity seismic areas are prone to structural safety problems under ***,effective and low-cost anti-seismic engineering measures must be designed for *** intake tower in northwest China was considered the research object,and its natural vibration characteristics and dynamic response were first analyzed using the mode decomposition response spectrum method based on a three-dimensional finite element *** non-dominated sorting genetic algorithm-II(NSGA-II)was adopted to optimize the anti-seismic scheme combination by comprehensively considering the dynamic tower response and variable project ***,the rationality of the original intake tower antiseismic design scheme was evaluated according to the obtained optimal solution set,and recommendations for improvement were *** method adopted in this study may provide significant references for designing anti-seismic measures for high-rise structures such as intake towers located in high-intensity earthquake areas.

关键词： intake tower NSGA-II mode decomposition response spectrum method anti-seismic engineering measures optimization design variable project cost

Three Types of Expression in Dark-Soliton Perturbation Theory Based on Squared Jost Solutions

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Communications in Theoretical Physics 2007年第1期47卷 15-18页

作者： ao Sheng-Mei YAN jia-Ren College of Physics and Information Science Hunan Normal University Changsha 410081 China

Three types of expression in the dark-soliton perturbation theory based on squared Jost solutions are invesgigaged in ghis paper. It is shown that there are three formally different results about the effects of perturbagion on a dark soliton, and it is proved by means of a transformation between two integral variables that they are essentially equivalent.

关键词： dark soliton perturbation theory squared Jost solution soliton velocity first-order correction