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All‑Covalent Organic Framework Nanofilms Assembled Lithium‑Ion Capacitor to Solve the Imbalanced Charge Storage Kinetics

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Nano-Micro Letters 2024年第6期16卷 246-260页

作者： Xiaoyang Xu jia Zhang Zihao Zhang Guandan Lu wei Cao Ning wang Yunmeng Xia Qingliang Feng Shanlin Qiao College of Chemistry and Pharmaceutical Engineering Hebei University of Science and TechnologyShijiazhuang 050018People’s Republic of China School of Chemistry and Chemical Engineering Northwestern Polytechnical UniversityXi’an 710072People’s Republic of China Hebei Engineering Research Center of Organic Solid Photoelectric Materials for Electronic Information Shijiazhuang 050018People’s Republic of China

Free-standing covalent organic framework(COFs)nanofilms exhibit a remarkable ability to rapidly intercalate/de-intercalate Li^(+) in lithium-ion batteries,while simultaneously exposing affluent active sites in *** development of these nanofilms offers a promising solution to address the persistent challenge of imbalanced charge storage kinetics between battery-type anode and capacitor-type cathode in lithium-ion capacitors(LICs).Herein,for the first time,custom-made COFBTMB-TP and COFTAPB-BPY nanofilms are synthesized as the anode and cathode,respectively,for an all-COF nanofilm-structured *** COFBTMB-TP nanofilm with strong electronegative–CF3 groups enables tuning the partial electron cloud density for Li^(+) migration to ensure the rapid anode kinetic *** thickness-regulated cathodic COFTAPB-BPY nanofilm can fit the anodic COF nanofilm in the *** to the aligned 1D channel,2D aromatic skeleton and accessible active sites of COF nanofilms,the whole COFTAPB-BPY//COFBTMB-TP LIC demonstrates a high energy density of 318 mWh cm^(−3) at a high-power density of 6 W cm^(−3),excellent rate capability,good cycle stability with the capacity retention rate of 77%after *** COFTAPB-BPY//COFBTMB-TP LIC represents a new benchmark for currently reported film-type LICs and even film-type *** being comprehensively explored via ex situ XPS,7Li solid-state NMR analyses,and DFT calculation,it is found that the COFBTMB-TP nanofilm facilitates the reversible conversion of semi-ionic to ionic C–F bonds during lithium ***-TP exhibits a strong interaction with Li^(+) due to the C–F,C=O,and C–N bonds,facilitating Li^(+) desolation and absorption from the *** work addresses the challenge of imbalanced charge storage kinetics and capacity between the anode and cathode and also pave the way for future miniaturized and wearable LIC devices.

关键词： Covalent organic frameworks Lithium-ion capacitor Charge storage kinetic

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Sustainable and practical semi-heterogeneous photosynthesis of 5-amino-1,2,4-thiadiazoles over WS_(2)/TEMPO

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Chinese Chemical Letters 2024年第8期35卷 250-253页

作者： jia-Cheng Hou Hong-Tao Ji Yu-Han Lu jia-Sheng wang Yao-Dan Xu Yan-Yan Zeng wei-Min He School of Chemistry and Chemical Engineering University of South ChinaHengyang 421001China

An eco-friendly and practical method for the clean preparation of 5-amino-1,2,4-thiadiazoles was *** WS_(2)as the semiconductor photocatalyst,both TEMPO and O_(2)(in air)as the redox catalysts,a variety of thiadiazoles were semi-heterogeneously formed in high to quantitative yields and could be easily collected by CPME extraction and ***,the catalytic system can be reusable for at least 5 reaction runs.

关键词： Green chemistry Thiadiazoles Heterogeneous catalyst Redox catalyst Extraction

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Degradation of o-dichlorobenzene by DBD-NTP co-modified titanium gel catalyst

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Journal of Environmental Sciences 2024年第9期143卷 71-84页

作者： Wenbo Zhang Yi Xing wei Su jiaqing wang Haoqi jia Yongkang Cui Jing Chen Hui Zhang School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants University of Science and Technology BeijingBeijing 100083China Guangdong Province Engineering Laboratory for Air Pollution Control Guangzhou 510530China College of Environmental and Resource Sciences Shanxi UniversityTaiyuan 030006China Sinosteel Maanshan Mine Research Institute Co.Ltd. Anhui 243071China

In order to study the degradation process of dioxins in industrial flue gas,the decomposition of o-dichlorobenzene(o-DCB)in a DBD plasma catalytic reactor was *** results showed that an NTP-catalyzed system,especially using the Cu Mn Ti Oxcatalyst,had better o-DCB degradation performance compared to plasma *** combination of the Cu Mn Ti Oxcatalyst with NTP can achieve a degradation efficiency of up to 97.2%for o-DCB;the selectivity of CO and CO_(2)and the carbon balance were 40%,45%,and 85%,*** dielectric constant and electrical property results indicated that the surface discharge capacity of the catalysts played a major role in the degradation of o-DCB,and a higher dielectric constant could suppress the plasma expansion and enhance the duration of the plasma discharge per discharge *** to the O1s XPS and O_(2)-TPD results,the conversion of CO to CO_(2)follows the M-v-K mechanism;thus,the active species on the catalyst surface play an important ***,the Cu Mn Ti Oxand NTP mixed system exhibited excellent stability,which is probably because Cu doping improved the lifetime of the *** work can provide an experimental and theoretical basis for research in the degradation of o-DCB by plasma catalyst systems.

关键词： o-dichlorobenzene(o-DCB) Non-thermal plasma catalysis Ozone concentration

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Multi-scale persistent spatiotemporal transformer for long-term urban traffic flow prediction

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Journal of Electronic Science and Technology 2024年第1期22卷 53-69页

作者： jia-Jun Zhong Yong Ma Xin-Zheng Niu Philippe Fournier-Viger Bing wang Zu-kuan wei School of Computer Science and Engineering University of Electronic Science and Technology of ChinaChengdu611731China College of Computer Science&Software Engineering Shenzhen UniversityShenzhen518060China School of Computer Science Southwest Petroleum UniversityChengdu610500China

Long-term urban traffic flow prediction is an important task in the field of intelligent transportation,as it can help optimize traffic management and improve travel *** improve prediction accuracy,a crucial issue is how to model spatiotemporal dependency in urban traffic *** recent years,many studies have adopted spatiotemporal neural networks to extract key information from traffic ***,most models ignore the semantic spatial similarity between long-distance areas when mining spatial *** also ignore the impact of predicted time steps on the next unpredicted time step for making long-term ***,these models lack a comprehensive data embedding process to represent complex spatiotemporal *** paper proposes a multi-scale persistent spatiotemporal transformer(MSPSTT)model to perform accurate long-term traffic flow prediction in *** adopts an encoder-decoder structure and incorporates temporal,periodic,and spatial features to fully embed urban traffic data to address these *** model consists of a spatiotemporal encoder and a spatiotemporal decoder,which rely on temporal,geospatial,and semantic space multi-head attention modules to dynamically extract temporal,geospatial,and semantic *** spatiotemporal decoder combines the context information provided by the encoder,integrates the predicted time step information,and is iteratively updated to learn the correlation between different time steps in the broader time range to improve the model’s accuracy for long-term *** on four public transportation datasets demonstrate that MSPSTT outperforms the existing models by up to 9.5%on three common metrics.

关键词： Graph neural network Multi-head attention mechanism Spatio-temporal dependency Traffic flow prediction

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Graphite recycling from spent lithium-ion batteries for fabrication of high-performance aluminum-ion batteries

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Rare Metals 2024年第5期43卷 2161-2171页

作者： Li wang Chao wang Jing-Yi Zhang jia-Cheng Qiu Xu-wang Fu Zi-Rui Zhang jian-Min Feng Lei Dong Cong-Lai Long De-Jun Li Xiao-wei wang Bao Zhang jia-Feng Zhang Rui-Rui Zhao College of Physics and Materials Science Tianjin Normal UniversityTianjin300387China National Engineering Laboratory for High Efficiency Recovery of Refractory Nonferrous Metals School of Metallurgy and EnvironmentCentral South UniversityChangsha 410083China School of Chemistry South China Normal UniversityGuangzhou510631China

Efficient extraction of electrode components from recycled lithium-ion batteries(LIBs)and their highvalue applications are critical for the sustainable and ecofriendly utilization of *** work demonstrates a novel approach to stripping graphite anodes embedded with Li^(+)from spent LIBs directly in anhydrous ethanol which can be utilized as high efficiency cathodes for aluminum-ion batteries(AIBs).Recycled graphite(RG)with foam morphology and crystal structure defects was obtained under the action of ultrasonic peeling and gas generation reaction between residual lithium-graphite interlayer compound and *** inherent open structure of RG facilitates the intercalation/deintercalation of chloralum anions(AlCl_(4)^(-))and enhances its AIB cathode *** electrochemical measurements revea that the RG cathode has a specific capacity of 123 m Ah·g^(-1)at a current of 5 A·g^(-1),which is 1.55 times higher than tha of unprocessed natural graphite and 1.25 times higher than that of commercial artificial ***,the RG cathode demonstrated remarkable stability,retaining its high particular capacity of 138.15 mAh·g^(-1)even through2000 times at 10 A·g^(-1)in a low-cost electrolyte consisting of an ionic liquid/urea/AlCl_(3)*** work offers a novel approach to reusing of graphite anode waste materials from LIBs.

关键词： Aluminum ion batteries Lithium-ion batteries Graphite anode Recycling

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Multi-Objective Optimization of the Ultrasonic Scalpel Rod and Tip with Improved Performance:Vibration Frequency,Amplitude,and Service Life

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Chinese Journal of Mechanical Engineering 2024年第4期37卷 107-119页

作者： jiaqi Zhao Yuhao Zhai Xuzhe jia Naiwen Deng Kunxu Li Guangchao Han Rong Chen Dong wang wei Bai School of Mechanical Engineering and Electronic Information China University of GeosciencesWuhan 430074China Shenzhen Research Institute China University of GeosciencesShenzhen 518057China College of Engineering Mathematics and Physical SciencesUniversity of ExeterExeter EX44QFUK Shenzhen Huazhong University of Science and Technology Research Institute Shenzhen 518000China

Ultrasonic scalpel design for minimally invasive surgical procedures is mainly focused on optimizing cutting ***,an important issue is the low fatigue life of traditional ultrasonic scalpels,which affects their long-term reliability and effectiveness and creates hidden dangers for *** this study,a multi-objective optimal design for the cutting performance and fatigue life of ultrasonic scalpels was proposed using finite element analysis and fatigue *** optimal design parameters of resonance frequency and amplitude were *** setting the transition fillet and keeping the gain structure away from the node position to enable the scalpel to have a high service life with excellent cutting *** frequency modulation method of setting the vibration node bosses at the node position and setting the vibration antinode grooves at the antinode position was ***,the mechanism of the influence of various design elements,such as tip,shank,node position,and antinode position,on the resonance frequency,amplitude,and fatigue life of the ultrasonic scalpel was analyzed,and the optimal design principles of the ultrasonic scalpel were *** proposed ultrasonic scalpel design was confirmed by simulations,impedance measurements,and liver tissue cutting experiments,demonstrating its feasibility and enhanced *** research introduces innovative design strategies to improve the fatigue life and performance of ultrasonic scalpels to address an important issue in minimally invasive surgery.

关键词： Multi-objective optimal design Minimally invasive surgical procedures Service life Ultrasonic scalpel

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Chiral liquid crystals based on pillararene and supramolecular self-assembly-induced chirality amplification

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Science China Chemistry 2024年第10期67卷 3373-3381页

作者： Bicong Liang Yujie Cheng Xiong Liu Lan jia Xuehong wei Qiang Zheng Pi wang Danyu Xia Xuzhou Yan College of Materials Science and Engineering Taiyuan University of TechnologyTaiyuan 030024China Scientific Instrument Center Shanxi UniversityTaiyuan 030006China School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong UniversityShanghai 200240China

Macrocyclic liquid crystals combine the unique property of liquid crystals and excellent supramolecular assembly ability of macrocyclic *** is a significant challenge to make rational use of the advantages of macrocyclic compounds to prepare new macrocyclic ***,a type of macrocycles with rigid pillar-shaped frameworks and easy-tofunctionalize property,are excellent building blocks to fabricate liquid crystal ***,the site-selective modification property of pillararene has been rarely exploited to tailor liquid crystal *** reported pillararene-based liquid crystal systems are almost prepared by per-functionalized ***,we report the regulation of chiral liquid crystal behaviors by different derivatization of *** and thermotropic liquid crystals with different chirality were obtained by self-assembly of pillararene with different numbers of cholesterol *** bridge between thermotropic liquid crystal and lyotropic liquid crystal based on pillararene is *** addition,the chirality of the mesogens can be amplified through supramolecular self-assembly driven by noncovalent *** on the different liquid crystal behaviors,the optical signal of the pillararene-based chiral liquid crystals was used to fabricate an information encryption *** work provides a simple strategy to regulate liquid crystal behaviors via pillararene-based mesogens and realizes information encryption through the combination of different types of liquid crystals.

关键词： chiral liquid crystal pillararene self-assembly cholesterol information encryption

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Constructing the metabolic network of wheat kernels based on structure-guided chemical modification and multi-omics data

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Journal of Genetics and Genomics 2024年第7期51卷 714-722页

作者： Zhitao Tian Jingqi jia Bo Yin wei Chen National Key Laboratory of Crop Genetic Improvement and National Center of Plant Gene Research(Wuhan) Huazhong Agricultural UniversityWuhanHubei 430070China Hubei Hongshan Laboratory WuhanHubei 430070China

Metabolic network construction plays a pivotal role in unraveling the regulatory mechanism of biological activities,although it often proves to be challenging and labor-intensive,particularly with non-model *** this study,we develop a computational approach that employs reaction models based on the structure-guided chemical modification and related compounds to construct a metabolic network in *** construction results in a comprehensive structure-guided network,including 625 identified metabolites and additional 333 putative reactions compared with the Kyoto Encyclopedia of Genes and Genomes *** a combination of gene annotation,reaction classification,structure similarity,and correlations from transcriptome and metabolome analysis,a total of 229 potential genes related to these reactions are identified within this *** validate the network,the functionality of a hydroxycinnamoyltransferase(TraesCS3D01G314900)for the synthesis of polyphenols and a rhamnosyltransferase(TraesCS2D01G078700)for the modification of flavonoids are verified through in vitro enzymatic studies and wheat mutant tests,*** research thus supports the utility of structure-guided chemical modification as an effective tool in identifying causal candidate genes for constructing metabolic networks and further in metabolomic genetic studies.

关键词： Metabolic network Chemical modification Genetic study Wheat kernel Multi-omics

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Anisotropic swelling pressures of compacted GMZ bentonite infiltrated with salt solutions

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第9期16卷 3772-3785页

作者： Jing Ma Yong-Gui Chen Ling-Yan jia wei-Min Ye Dong-Bei Wu Qiong wang Department of Geotechnical Engineering College of Civil EngineeringTongji UniversityShanghai200092China State Key Laboratory of Disaster Reduction in Civil Engineering College of Civil EngineeringTongji UniversityShanghai200092China School of Chemical Science and Engineering Tongji UniversityShanghai200092China

In the high-level radioactive waste(HLW)deep geological repository,bentonite is compacted uniaxially,and then arranged vertically in engineered *** assembly scheme induces the initial anisotropy,and with hydration,it develops more evidently under chemical *** investigate the anisotropic swelling of compacted Gaomiaozi(GMZ)bentonite and the further response to saline effects,a series of constant-volume swelling pressure tests were *** showed that dry density enhanced the bentonite swelling and raised the final anisotropy,whereas saline inhibited the bentonite swelling but still promoted the final *** final anisotropy coefficient(ratio of radial to axial pressure)obeyed the Boltzmann sigmoid attenuation function,decreasing with concentration and dry density,converging to a minimum value of *** staged evolution of anisotropy coefficient was discovered,that saline inhibited the rise of the anisotropy coefficient(Dd)in the isotropic process greater than the valley(d1)in the anisotropic process,leading to the final anisotropy *** isotropic stage amplified the impact of soil structure rearrangement on the macro-swelling pressure ***,a new method for predicting swelling pressures of compacted bentonite was proposed,by expanding the equations of Gouy-Chapman theory with a dissipative wedge *** evolutionary function was constructed,revealing the correlation between the occurrence time and the pressure value due to the structure rearrangement and the former crystalline ***,a design reference for dry density was given,based on the chemical conditions around the pre-site in Beishan,*** anisotropy promoted by saline would cause a greater drop of radial pressure,making the previous threshold on axial swelling fail.

关键词： HLW deep geological repository Compacted GMZ bentonite Anisotropic swelling pressure Multi-scale structure Saline effect

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Pathogen-induced methylglyoxal negatively regulates rice bacterial blight resistance by inhibiting OsCDR1 protease activity

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Molecular Plant 2024年第2期17卷 325-341页

作者： Zheng-wei Fu jian-Hui Li Xiang Gao Shi-jia wang Ting-Ting Yuan Ying-Tang Lu State Key Laboratory of Hybrid Rice College of Life SciencesRenmin Hospital of Wuhan UniversityWuhan UniversityWuhan 430072China Key Laboratory of Biology and Genetic Improvement of OilCrops Ministry of Agriculture and Rural AffairsOilCrops Research Institute of the Chinese Academy of Agricultural SciencesWuhan 430062China

Xanthomonas oryzae ***(Xoo)causes bacterial blight(BB),a globally devastating disease of rice(Oryza sativa)that is responsible for significant crop *** and sugar metabolites are important for pathogen infection,providing energy and regulating events associated with defense responses;howev-er,the mechanisms by which they regulate such events in BB are *** an inevitable sugar metabolite,methylglyoxal(MG)is involved in plant growth and responses to various abiotic stresses,but the underlying mechanisms remain *** and how MG functions in plant biotic stress responses is almost completely ***,we report that the Xoo strain PXO99 induces OsWRKY62.1 to repress transcrip-tion of OsGLY Il genes by directly binding to their promoters,resulting in overaccumulation of *** negatively regulates rice resistance against Pxo99:osglyll2 mutants with higher MG levels are more sus-ceptible to the pathogen,whereas OsGLYIl2-overexpressing plants with lower MG content show greater resistance than the wild *** of OsGLYll2 to prevent excessive MG accumulation confers broad-spectrum resistance against the biotrophic bacterial pathogens Xoo and Xanthomonas oryzae *** and the necrotrophic fungal pathogen Rhizoctonia solani,which causes rice sheath *** evidence shows that MG reduces rice resistance against PXO99 through CONSTITUTIVE DISEASE RESISTANCE 1(OsCDR1).MGmodifies the Arg97 residue of OsCDR1to inhibit its aspartic protease activ-ity,which is essential for OsCDR1-enhanced *** together,these findings illustrate how Xoo promotes infection by hijacking a sugar metabolite in the host plant.

关键词： Oryza sativa bacterial blight OsWRKY62.1 methylglyoxal OsCDR1

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