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Electrochemical conversion of methane to bridge the gap in the artificial carbon cycle

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Journal of Energy Chemistry 2025年第1期100卷 286-308页

作者： Yuhao Peng Yuefeng Song Ihar Razanau Juanxiu Xiao wei Xiao Di hu Guoxiong Wang College of Chemistry and Molecular Sciences Hubei Key Laboratory of Electrochemical Power Sources Wuhan University State Key Laboratory of Catalysis Dalian National Laboratory for Clean Energy iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Dalian Institute of Chemical Physics Chinese Academy of Sciences Laboratory of Physical-Chemical Technologies SSPA Scientific and Practical Materials Research Centre of NAS of Belarus State Key Laboratory of Marine Resources Utilization in South China Sea Collaborative Innovation Center of Marine Science and Technology School of Marine Science and Engineering Hainan University Department of Chemical and Environmental Engineering University of Nottingham Ningbo China

Methane, an abundant one-carbon（C1） resource, is extensively used in the industrial production of vital fuels and value-added chemicals. However, current industrial methane conversion technologies are energy-and carbon-intensive, mainly due to the high activation energy required to break the inert C–H bond, low selectivity, and problematic side reactions, including CO2emissions and coke deposition. Electrochemical conversion of methane（ECM） using intermittent renewable energy offers an attractive solution, due to its modular reactor design and operational flexibility across a broad spectrum of temperatures and pressures. This review emphasizes conversion pathways of methane in various reaction systems, highlighting the significance and advantages of ECM in facilitating a sustainable artificial carbon cycle. This work provides a comprehensive overview of conventional methane activation mechanisms and delineates the complete pathways of methane conversion in electrolysis contexts. Based on surface/interface chemistry, this work systematically analyzes proposed reaction pathways and corresponding strategies to enhance ECM efficiency towards various target products, including syngas, hydrocarbons, oxygenates, and advanced carbon materials. The discussion also encompasses opportunities and challenges for the ECM process, including insights into ECM pathways, rational electrocatalyst design, establishment of benchmarking protocols, electrolyte engineering, enhancement of CH4conversion rates, and minimization of CO2emission.

关键词： Methane Electrochemical conversion Reaction mechanism Catalyst design Electrode Electrocatalysis

Boosting Oxygen Evolution Reaction Performance on NiFe‑Based Catalysts Through d‑Orbital Hybridization

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Nano-Micro Letters 2025年第1期17卷 281-292页

作者： Xing Wang wei Pi Sheng hu Haifeng Bao Na Yao wei Luo State Key Laboratory of New Textile Materials and Advanced Processing Technology Key Laboratory of New Textile Materials and Applications of Hubei ProvinceSchool of Materials Science and EngineeringWuhan Textile UniversityWuhan 430200People’s Republic of China College of Chemistry and Molecular Sciences Wuhan UniversityWuhan 430072People’s Republic of China

Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based *** introducing a third metal into NiFe-based catalysts to construct asymmetrical M-NiFe units,the d-orbital and electronic structures can be adjusted,which is an important strategy to achieve sufficient oxygen evolution reaction(OER)performance in ***,the ternary NiFeM(M:La,Mo)catalysts featured with distinct M-NiFe units and varying d-orbitals are reported in this *** and theoretical calculation results reveal that the doping of La leads to optimized hybridization between d orbital in NiFeM and 2p in oxygen,resulting in enhanced adsorption strength of oxygen intermediates,and reduced rate-determining step energy barrier,which is responsible for the enhanced OER *** critically,the obtained NiFeLa catalyst only requires 1.58 V to reach 1 A cm^(−2) in an anion exchange membrane electrolyzer and demonstrates excellent long-term stability of up to 600 h.

关键词： NiFe-based catalysts d-orbital coupling Oxygen evolution reaction Anion exchange membrane electrolyzer

考虑粗糙度影响的微凹坑织构化机械密封润滑性能的数值模拟

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流体机械 2017年第5期45卷 16-20页

作者：曹宏涛王伟纪敬虎海军驻沈阳地区舰船配套军事代表室辽宁沈阳110168 江苏华青流体科技有限公司江苏苏州215600 江苏大学江苏镇江212013

采用正弦粗糙峰表征粗糙表面,建立了织构化粗糙机械密封端面流体动压润滑模型,研究了粗糙度、微凹坑织构几何参数对润滑性能的影响。结果表明:利用数值分析方法研究微凹坑织构对机械密封流体动压润滑性能影响时,不能忽略粗糙度、微凹坑... 详细信息

采用正弦粗糙峰表征粗糙表面,建立了织构化粗糙机械密封端面流体动压润滑模型,研究了粗糙度、微凹坑织构几何参数对润滑性能的影响。结果表明:利用数值分析方法研究微凹坑织构对机械密封流体动压润滑性能影响时,不能忽略粗糙度、微凹坑之间的相互影响和边界压力的影响;存在最佳的微凹坑深度和面积密度使织构机械密封端面的流体动压润滑效应达到最佳。

关键词：机械密封表面织构粗糙度流体润滑

SensFL:Privacy-Preserving Vertical Federated Learning with Sensitive Regularization

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Computer Modeling in Engineering & Sciences 2025年第1期142卷 385-404页

作者： Chongzhen Zhang Zhichen Liu Xiangrui Xu Fuqiang hu jiao Dai Baigen Cai wei Wang School of Automation and Intelligence Beijing Jiaotong UniversityBeijing100044China Shuohuang Railway Development Co. Ltd.National Energy GroupCangzhou062350China Beijing Key Laboratory of Security and Privacy in Intelligent Transportation School of Computer Science and TechnologyBeijing Jiaotong UniversityBeijing100044China

In the realm of Intelligent Railway Transportation Systems,effective multi-party collaboration is crucial due to concerns over privacy and data *** Federated Learning(VFL)has emerged as a promising approach to facilitate such collaboration,allowing diverse entities to collectively enhance machine learning models without the need to share sensitive training ***,existing works have highlighted VFL’s susceptibility to privacy inference attacks,where an honest but curious server could potentially reconstruct a client’s raw data from embeddings uploaded by the *** vulnerability poses a significant threat to VFL-based intelligent railway transportation *** this paper,we introduce SensFL,a novel privacy-enhancing method to against privacy inference attacks in ***,SensFL integrates regularization of the sensitivity of embeddings to the original data into the model training process,effectively limiting the information contained in shared *** reducing the sensitivity of embeddings to the original data,SensFL can effectively resist reverse privacy attacks and prevent the reconstruction of the original data from the *** experiments were conducted on four distinct datasets and three different models to demonstrate the efficacy of *** results show that SensFL can effectively mitigate privacy inference attacks while maintaining the accuracy of the primary learning *** results underscore SensFL’s potential to advance privacy protection technologies within VFL-based intelligent railway systems,addressing critical security concerns in collaborative learning environments.

关键词： Vertical federated learning privacy defenses

Repetitive transcranial magnetic stimulation in Alzheimer’s disease:effects on neural and synaptic rehabilitation

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Neural Regeneration Research 2025年第2期20卷 326-342页

作者： Yi ji Chaoyi Yang Xuerui Pang Yibing Yan Yue Wu Zhi Geng Wenjie hu Panpan hu Xingqi Wu Kai Wang Department of Neurology The First Affiliated Hospital of Anhui Medical UniversityHefeiAnhui ProvinceChina Anhui Province Key Laboratory of Cognition and Neuropsychiatric Disorders HefeiAnhui ProvinceChina Collaborative Innovation Center of Neuropsychiatric Disorders and Mental Health HefeiAnhui ProvinceChina Institute of Artificial Intelligence Hefei Comprehensive National Science CenterHefeiAnhui ProvinceChina Department of Psychology and Sleep Medicine The Second Affiliated Hospital of Anhui Medical UniversityHefeiAnhui ProvinceChina

Alzheimer’s disease is a neurodegenerative disease resulting from deficits in synaptic transmission and *** Alzheimer’s disease brain tends to be hyperexcitable and hypersynchronized,thereby causing neurodegeneration and ultimately disrupting the operational abilities in daily life,leaving patients *** transcranial magnetic stimulation is a cost-effective,neuro-modulatory technique used for multiple neurological *** the past two decades,it has been widely used to predict cognitive decline;identify pathophysiological markers;promote neuroplasticity;and assess brain excitability,plasticity,and *** has also been applied to patients with dementia,because it can yield facilitatory effects on cognition and promote brain recovery after a neurological ***,its therapeutic effectiveness at the molecular and synaptic levels has not been elucidated because of a limited number of *** study aimed to characterize the neurobiological changes following repetitive transcranial magnetic stimulation treatment,evaluate its effects on synaptic plasticity,and identify the associated *** review essentially focuses on changes in the pathology,amyloidogenesis,and clearance pathways,given that amyloid deposition is a major hypothesis in the pathogenesis of Alzheimer’s *** mechanisms associated with repetitive transcranial magnetic stimulation procedures and different pathways mediating gene transcription,which are closely related to the neural regeneration process,are also ***,we discuss the outcomes of animal studies in which neuroplasticity is modulated and assessed at the structural and functional levels by using repetitive transcranial magnetic stimulation,with the aim to highlight future directions for better clinical translations.

关键词： Alzheimer’s disease amyloid deposition apoptotic mechanisms biomarker neural regeneration neurodegeneration repetitive transcranial magnetic stimulation synaptic plasticity

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泡沫镍网负载TiO_2薄膜的光催化特性

上海交通大学学报 2009年第5期43卷 755-758页

作者：凌基薇胡海袁坚施建伟上官文峰上海交通大学机械与动力工程学院上海200240

在紫外光照射的静态反应体系中，利用乙醛气体降解试验研究了泡沫镍网负载TiO2／SiO2薄膜的光催化特性，考察了不同光辐射强度和光源波长对光催化效率的影响．结果表明：光辐射强度和光源波长对光催化降解活性影响很大，对于初始浓度为0... 详细信息

在紫外光照射的静态反应体系中，利用乙醛气体降解试验研究了泡沫镍网负载TiO2／SiO2薄膜的光催化特性，考察了不同光辐射强度和光源波长对光催化效率的影响．结果表明：光辐射强度和光源波长对光催化降解活性影响很大，对于初始浓度为0．01％的乙醛气体污染物，紫外线杀菌灯比黑光灯具有更好的光催化降解效果，其合适的光辐射强度在4．0～4．5w／m^2之间；TiO2／SiO2薄膜光催化剂具有良好的稳定性，经多次使用后，通过加热和水洗等简单方法能够完全再生，并继续保持良好的稳定性．

关键词：泡沫镍网 TiO2/SiO2 薄膜光催化乙醛降解光辐射强度

博弈中的平衡——中庸观对中国典籍外译的指导

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宜宾学院学报 2016年第11期16卷 93-97页

作者：季红琴胡微长沙理工大学外国语学院湖南长沙410114

中庸思想是儒家思想的精髓,其"中和"思想、至诚原则和"过犹不及"的方法论,对中国典籍外译具有积极的指导意义。"中和"思想指导译者在选择源语文本时应选取能够反映永恒人性的典籍作品;至诚原则为译者之价值取向追求,要求译者真诚对待源... 详细信息

中庸思想是儒家思想的精髓,其"中和"思想、至诚原则和"过犹不及"的方法论,对中国典籍外译具有积极的指导意义。"中和"思想指导译者在选择源语文本时应选取能够反映永恒人性的典籍作品;至诚原则为译者之价值取向追求,要求译者真诚对待源语文化和目的语文化;"过犹不及"要求译者灵活选择相应的翻译策略——归化或异化,使译文既不失去原文的神韵,又达到最佳的翻译效果。

关键词：中庸观中和至诚过犹不及外译

Decreased levels of phosphorylated synuclein in plasma are correlated with poststroke cognitive impairment

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Neural Regeneration Research 2025年第9期20卷 2598-2610页

作者： Yi Wang Yuning Li Yakun Gu wei Ma Yuying Guan Mengyuan Guo Qianqian Shao Xunming ji jia Liu Department of Clinical Laboratory Beijing Bo’ai HospitalChina Rehabilitation Research CenterCapital Medical UniversityBeijingChina Beijing Institute of Brain Disorders Laboratory of Brain DisordersMinistry of Science and TechnologyCollaborative Innovation Center for Brain DisordersBeijing Advanced Innovation Center for Big Data-based Precision MedicineCapital Medical UniversityBeijingChina Department of Neurosurgery Xuanwu HospitalCapital Medical UniversityBeijingChina

Poststro ke cognitive impairment is a major secondary effect of ischemic stroke in many patients;however,few options are available for the early diagnosis and treatment of this *** aims of this study were to(1)determine the specific relationship between hypoxic andα-synuclein during the occur of poststroke cognitive impairment and(2)assess whether the serum phosphorylatedα-synuclein level can be used as a biomarker for poststro ke cognitive *** found that the phosphorylatedα-synuclein level was significantly increased and showed pathological aggregation around the cerebral infa rct area in a mouse model of ischemic *** addition,neuronalα-synuclein phosphorylation and aggregation were observed in the brain tissue of mice subjected to chronic hypoxia,suggesting that hypoxia is the underlying cause ofα-synuclein-mediated pathology in the brains of mice with ischemic *** phosphorylatedα-synuclein levels in patients with ischemic stroke were significantly lower than those in healt hy subjects,and were positively correlated with cognition levels in patients with ischemic ***,a decrease in serum high-density lipoprotein levels in stroke patie nts was significantly correlated with a decrease in phosphorylatedα-synuclein *** ischemic stroke mice did not show significant cognitive impairment or disrupted lipid metabolism 14 days after injury,some of them exhibited decreased cognitive function and reduced phosphorylatedα-synuclein *** together,our results suggest that serum phosphorylatedα-synuclein is a potential biomarker for poststroke cognitive impairment.

关键词： biomarker high-density lipoprotein ischemic stroke phosphorylatedα-synuclein poststroke cognitive impairment

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新型二维声子晶体带隙特性及调控方法研究

大连理工大学学报 2025年第1期65卷 48-55页

作者：胡启国胡皓魏晨胡豁然重庆交通大学机电与车辆工程学院重庆400074 国网重庆市电力公司信息通信分公司重庆401120

为拓宽声子晶体弹性波带隙,提出一种关于基体双侧对称的声子晶体结构模型.采用有限元法计算了该声子晶体的能带结构和本征模态,基于局域共振机理深入分析了其带隙的形成机理,通过改变几何参数及施加等轴预拉伸应变的方法对该声子晶体的... 详细信息

为拓宽声子晶体弹性波带隙,提出一种关于基体双侧对称的声子晶体结构模型.采用有限元法计算了该声子晶体的能带结构和本征模态,基于局域共振机理深入分析了其带隙的形成机理,通过改变几何参数及施加等轴预拉伸应变的方法对该声子晶体的带隙进行被动调控与主动调控.仿真结果表明:所提声子晶体结构基体中的长波行波与振子的谐振相互耦合作用产生一条局域共振带隙,通过优化几何参数可以获得起始频率更低的宽频带隙,对结构施加等轴预拉伸应变可以有效拓宽带隙且带隙宽度随着预拉伸应变的增大而变宽.研究结果为声子晶体的带隙主动调控提供了方案,为结构减振降噪提供了新思路.

关键词：声子晶体带隙特性带隙调控预拉伸应变