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Waste acid recovery utilizing monovalent cation permselective membranes through selective electrodialysis

Chinese Journal of Chemical Engineering 2024年第7期71卷 45-57页

作者： Yanran Zhu Yue Zhou Qian Chen Rongqiang Fu Zhaoming Liu liang Ge Tongwen xu Anhui Provincial Engineering Laboratory of Functional Membrane Materials and Technology Department of Applied ChemistrySchool of Chemistry and Materials ScienceUniversity of Science and Technology of ChinaHefei 230026China Key Laboratory of Charged Polymeric Membrane Materials of Shandong Province Shandong Tianwei Membrane Technology Co.Ltd.Weifang 261000China

Selective electrodialysis(SED)has surfaced as a highly promising membrane separation technique in the realm of acid recovery owing to its ability to effectively separate monovalent ions through the utilization of a potential ***,the current SED process is limited by conventional commercial monovalent cation permselective membranes(MCPMs).This study systematically investigates the use of an independently developed MCPM in the SED process for acid *** factors such as current density,volume ratio,initial ion concentration,and waste acid systems are *** independently developed MCPM offers several advantages over the commercial monovalent selective cation-exchange membrane(CIMS),including higher recovered acid concentration,better ion flux ratio,improved acid recovery efficiency,increased recovered acid purity,and higher current *** SED process with the MCPM achieves a recovered acid of 95.9%and a concentration of 2.3 mol·L^(–1) in the HCl/FeCl_(2) system,when a current density of 20 mA·cm^(-2) and a volume ratio of 1:2 are ***,in the H_(2)SO_(4)/FeSO_(4) system,a purity of over 99%and a concentration of 2.1 mol·L^(–1) can be achieved in the recovered *** study thoroughly examines the impact of operation conditions on acid recovery performance in the SED *** independently developed MCPM demonstrates outstanding acid recovery performance,highlighting its potential for future commercial utilization.

关键词： Selective electrodialysis Wastewater Monovalent cation permselective membranes Separation Recovery

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Alloy strategy to synthesize Pt-early transition metal oxide interfacial catalysts

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Nano Research 2024年第4期17卷 3390-3397页

作者： Shi-Long xu Hang Nan Wanqun Zhang Yue Lin Sheng-Qi Chu Hai-Wei liang Hefei National Research Center for Physical Sciences at the Microscale Department of ChemistryUniversity of Science and Technology of ChinaHefei 230026China School of Materials and Chemical Engineering Anhui Jianzhu UniversityHefei 230601China Institute of High Energy Physics Chinese Academy of SciencesBeijing 100049China

Metal oxide supported metal catalysts show promising catalytic performance in many industry-relevant ***,the enhancement of performance is often limited by the insufficient metal/metal oxide *** this work,we demonstrate a general synthesis of Pt-early transition metal oxide(Pt-MO_(x),M=Ti,Zr,V,and Y)catalysts with rich interfacial sites,which is based on the air-induced surface segregation and oxidation of M in the supported Pt-M alloy *** characterizations verify the dynamic structural response of Pt-M alloy catalysts to air and the formation of Pt-MO_(x) catalysts with abundant interfacial *** prepared Pt-TiO_(x) interfacial catalysts exhibit improved performance in hydrogenation reactions of benzaldehyde,nitrobenzene,styrene,and furfural,as a result of the heterolytic dissociation of H_(2) at Pt-metal oxide interfacial sites.

关键词： Pt-early transition metal oxide interfacial catalyst alloy oxidation strategy interfacial sites hydrogenation reactions heterolytic dissociation

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Yolk-shell FeCu/NC electrocatalyst boosting high-performance zinc-air battery

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Nano Research 2024年第9期17卷 7918-7925页

作者： Chen liang Tianyu Zhang Shilun Sun Aijuan Han Zenghui Qiu Haijun xu Junfeng Liu State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China College of Mathematics&Physics Beijing University of Chemical TechnologyBeijing 100029China Beijing Bioprocess Key Laboratory Beijing University of Chemical TechnologyBeijing 100029China

Iron-nitrogen-carbon single-atom catalysts(Fe-N-C SACs)are widely acknowledged for their effective oxygen reduction activity,however,their activity requires further ***,additional structural optimization is necessary to enhance mass transport and achieve higher power density in practical ***,using ZIF-8 as a template,we synthesized yolk-shell catalysts featuring complex sites of Fe single atoms and Cu nanoclusters(y-FeCu/NC)via partial etching and liquid-phase *** synthesized y-FeCu/NC catalyst exhibits high specific surface area and mesoporous *** with the advantages of highly active sites and yolk-shell structure,the y-FeCu/NC catalyst demonstrated outstanding catalytic performance in the oxygen reduction reaction,achieving a half-wave potential(E_(1/2))of 0.97 V in 0.1 M *** a practical energy device,Zn-air battery(ZAB)assembled with y-FeCu/NC catalyst achieved a remarkable power density of 356.3 mW·cm^(-2),representing an improvement of approximately 28.5%compared to its solid FeCu/NC ***,it showcased impressive stability,surpassing all control samples.

关键词： atomic Fe-N4 sites Cu nanoclusters yolk-shell structure oxygen reduction reaction zinc-air battery

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Charge Accumulation Characteristics of SF6-Epoxy Interface Under Negative Repetitive Nanosecond Pulses

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CSEE Journal of Power and Energy Systems 2024年第4期10卷 1808-1815页

作者： Shaocong Wu Geng Chen Yuming Shao Hao xu xuanning Zhang Yanyu liang Youping Tu State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources and the Beijing Key Laboratory of High Voltage and EMC North China Electric Power UniversityBeijing 102206China

Repetitve nanosecond impulses in gas-insulated metal-enclosed switchgear (GIS) are likely to trigger inside flashover. Interface charges on the spacer in GIS are considered one of the main factors damaging insulation performance and may be induced by overvoltage. For good understanding of insulation failures, accumulation characteristics of charges between SF6 and epoxy spacers under repetitive nanosecond impulses are investigated. It can be found under nanosecond impulses, the charge source in gas volume contributes to interface charge accumulation predominantly. Interface charges will be promoted by impulse number and amplitude. Accumulation processes are analyzed based on runaway electrons mechanism. When impulse amplitude exceeds a threshold value, discharge in the gas volume turns to a runaway mode. A runaway electron leads to the interface charge accumulation. Affected by motion of the runaway electrons, the potential peak gradually moves close to the grounded electrode when impulse amplitude is raised. Meanwhile, increasing impulse number can enhance surface potential. Surface potential will reach saturation eventually. However, memory effect of the repetitive impulse discharge makes the half-peak width of the surface potential at the interface change little. Design of GIS gas-solid insulations can refer to this research.

关键词： GIS interface charge repetitive nano-second pulse SF6

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Recovery of rare earth elements from rare earth molten salt electrolytic slag via fluorine fixation by MgCl2 roasting

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Journal of Rare Earths 2024年第10期42卷 1979-1987页

作者： Minghui Zhang Bingxuan He Yinliang Liu Luewei xu Yong liang Faculty of Metallurgical Engineering Jiangxi University of Science and Technology Key Laboratory of Ionic Rare Earth Resources and Environment Ministry of Natural Resources jiangxi Provincial Key Laboratory of Green and Low Carbon Metallurgy for Strategic Nonferrous Metals

Rare earth fluoride molten-salt electrolytic slag（REFES） is a precious rare earth element（REE） secondary resource,and conside rable amounts of REEs exist in REFES as REF3;they are difficult to dissolve in acid or water and impede efficient REE *** REFES recovery,the REF3species in REFES are usually transformed into acid-soluble rare earth compounds by NaOH roasting or sulfating roasting and then extracted by acid leaching,Moreover,the fluorides in REFES are released as HF gas in the roasting process or enter the liquid phase during the water washing process;both of these processes cause fluorine *** the fluorine into the solid slag provides a way to avoid fluorine *** this study,a novel method was proposed to extract REEs from REFES via MgCl2roasting followed by HCl *** calculations and the rmogravimetry-differential thermal analyses（TG-DTA） were conducted to investigate the reactions occurring in the roasting process,First,MgCl2reacts with the REF3and RE2O3to form RECl3and REOCl,***,the RECI3absorbs water and forms RE（OH）***,MgCl2·6H2O is gradually dehydrated to MgCl2·2H2O and reacts with REF3and RE（OH）3,and REOCl,MgF2and MgO are *** HCl leaching,the REOCl in the roasting products is leached by HCl acid,while fluoride re mains in the solid slag as *** optimum experimental conditions are as follows:mass ratio of MgCl2to REFES of 30%,roasting temperature of 700℃,roasting time of 2 h,hydrochloride acid concentration of 4 mol/L,leaching time of 2 h,leaching temperature of 90 ℃ and leaching L/S ratio of 20:*** efficiencies for total leaching of the REEs,La,Ce,Pr,and Nd are 99.13%,99.20%,98.42%,99.38%,and 99.08%,***,the concentration of fluoride in the leaching solution is 2.191×10-6mol/*** method has a short process flow with low reagent costs,and the problem of fluoride pollution from REFES recovery is solved;thus,our study has great industrial application pot

关键词： Rare earths molten-salt electrolytic slag fluorine recovery leaching

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Analysis of light propagation characteristic in the aero-optic flow field of cone-headed vehicle with side window

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Optoelectronics Letters 2024年第1期20卷 58-64页

作者： xu liang ZHOU Liye WANG Luyang ZHAO Shiwei WANG Tao Tianjin Key Laboratory of Complex Control Theory and Application School of Electrical Engineering and AutomationTianjin University of TechnologyTianjin 300384China School of Intelligent Engineering Sun Yat-sen UniversityGuangzhou 510275China Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai) Zhuhai 519000China

Aero-optic imaging deviation research is carried out for infrared-guided vehicle with cone-head side window,with a focus on the propagation characteristics of light in an aero-optic flow *** the light entering the aero-optic flow field from the free-stream should be close to the normal,numerous data indicate that the light is refracted away from the *** paper divides the aero-optic flow field into two parts and uses the gas density distribution in the aero-optic flow field to propose the hypothesis that there are two modes of refraction when light propagates through the flow *** results show that light propagates from the optically denser medium to the optically thinner medium after passing through the shock wave and eventually leads to refraction away from the normal when the light enters the aero-optic flow field.

关键词： flow propagation light

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Three-dimensional nanoscale vortex line visualization and chiral nanostructure fabrication of tightly focused multi-vortex beams via direct laser writing

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Photonics Research 2024年第1期12卷 70-77页

作者： MENGDI LUO jiSEN WEN PENGCHENG MA QIUYUAN SUN XIANMENG XIA GANGYAO ZHAN ZHENYAO YANG liang xu DAZHAO ZHU CUIFANG KUANG xu LIU Research Center for Intelligent Chips and Devices Zhejiang LabHangzhou 311100China State Key Laboratory of Extreme Photonics and Instrumentation College of Optical Science and EngineeringZhejiang UniversityHangzhou 310027China ZJU-Hangzhou Global Scientific and Technological Innovation Center Hangzhou 311200China

Optical singularity is pivotal in nature and has attracted wide interest from many disciplines nowadays,including optical communication,quantum optics,and biomedical *** vortex lines formed by phase singularities and fabricating chiral nanostructures using the evolution of vortex lines are of great *** this paper,we introduce a promising method based on two-photon polymerization direct laser writing(2PP-DLW)to record the morphology of vortex lines generated by tightly focused multi-vortex beams(MVBs)at the *** to Gouy phase,the singularities of the MVBs rotate around the optical axis and move towards each other when approaching the focal *** propagation dynamics of vortex lines are recorded by 2PP-DLW,which explicitly exhibits the evolution of the phase ***,the MVBs are employed to fabricate stable three-dimensional chiral nanostructures due to the spiral-forward property of the vortex *** of the obvious chiral features of the manufactured nanostructures,a strong vortical dichroism is observed when excited by the light carrying orbital angular momentum.A number of applications can be envisioned with these chiral nanostructures,such as optical sensing,chiral separation,and information storage.

关键词： vortex chiral singularity

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Experimental Study on the Performance of ORC System Based on Ultra-Low Temperature Heat Sources

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Energy Engineering 2024年第1期121卷 145-168页

作者： Tianyu Zhou liang Hao Xin xu Meng Si Lian Zhang College of Mechanical Engineering Tianjin University of Science&TechnologyTianjin300222China School of Energy Engineering Tianjin Sino-German University of Applied SciencesTianjin300350China Tianjin“The Belt and Road”Joint Laboratory Tianjin Sino-German University of Applied SciencesTianjin300350China

This paper discussed the experimental results of the performance of an organic Rankine cycle(ORC)system with an ultra-low temperature heat *** low boiling point working medium R134a was adopted in the *** simulated heat source temperature(SHST)in this work was set from 39.51°C to 48.60°C by the simulated heat source *** influence of load percentage of simulated heat source(LPSHS)between 50%and 70%,the rotary valve opening(RVO)between 20%and 100%,the resistive load between 36Ωand 180Ωor the no-load of the generator,as well as the autumn and winter ambient temperature on the system performance were *** results showed that the stability of the system was promoted when the generator had a resistive *** power generation(PG)and generator speed(GS)of the system in autumn were better than in winter,but the expander pressure ratio(EPR)was lower than in *** RVO unchanged,the SHST,the mass flow rate(MFR)of the working medium,GS,and the PG of the system increased with the increasing of LPSHS for different generator resistance load *** the RVO was 60%,LPSHS was 70%,the SHST was 44.15°C and the resistive load was 72Ω,the highest PG reached 15.11 ***,a simulation formula was obtained for LPSHS,resistance load,and PG,and its correlation coefficient was between 0.9818 and *** formula can accurately predict the *** experimental results showed that the standard deviation between the experimental and simulated values was below 0.0792,and the relative error was within±5%.

关键词： ORC load percentage of simulated heat source resistive load rotary valve opening power generation

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Analysis of Fatty Acid in Biological Samples Using Liquid Chromatography–Quadrupole-Orbitrap Mass Spectrometry Under Parallel Reaction Monitoring Mode

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Journal of Analysis and Testing 2024年第2期8卷 210-217页

作者： jingxuan Yang Wenjun Guo Xiaohang xu liang Zhao Yajuan xu Yang Wang School of Pharmaceutical Sciences Changchun University of Chinese MedicineChangchun130117China Key Laboratory of Medicinal Materials Jilin Academy of Chinese Medicine SciencesChangchun130021China jilin Ginseng Academy Changchun University of Chinese MedicineChangchun130117China

Fatty acids(FAs)are an important class of functional small molecules and participate in a variety of life biological *** experiment proposed a liquid chromatography–quadrupole-Qrbitrap mass spectrometry(LC–Q-Orbitrap MS)method to perform FA profiling under parallel reaction monitoring(PRM)acquisition *** FA was derivatized by 2-dimethylaminoethylamine(DMED)to increase the ionization e fficiency and provide the characterized fragment *** mass spectra obtained from full scan,multiple ion monitoring(MIM),and PRM were *** results showed that the protonated ion of FA+DMED–H2O was detected and the neutral loss of 45.06 Da was observed in the tandem mass *** PRM method provided the highest selectivity and sensitivity for FA detection with the help of accurate mass weight and specific neutral loss-based *** method validation was performed using the FA standards and pooled quality control serum sample,which showed that the established method had good repeatability,stability,and ***,the developed method was successfully applied to analyze the rat serum and brain tissue samples for the drug e ffi-cacy evaluation of gross saponin of Tribulus terrestris ***(GSTTF)against middle cerebral artery occlusion(MCAO)-induced ischemic *** method has extensive practicability and great potential in the detection of FA,especially for the analysis of samples with complex matrices.

关键词： Fatty acid Derivatization LC-Q-Orbitrap MS Parallel reaction monitoring Biological sample

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Laparoscopic surgery for trans-anal barotrauma: a case report

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World Journal of Emergency Medicine 2024年第5期15卷 425-427页

作者： Chengxi Liu liang Zong Huadong Zhu Jun xu Emergency Department Peking Union Medical College HospitalChinese Academy of Medical Sciences&Peking Union Medical CollegeBeijing 100730China

Trans-anal barotrauma resulting from the use of air guns is rare in the emergency *** diagnosis and timely treatment can yield a good *** first published case of trans-anal barotrauma caused by a manually operated force pump was reported in 1904.[1]Colorectal injuries have the potential to progress to high-mortality complications,such as abdominal infection,peritonitis,and septic shock.[2,3]Herein,we report a case of trans-anal barotrauma in a man who presented with pneumoperitoneum,pneumomediastinum,and *** performed laparoscopic exploration and loop ileostomy on this patient.

关键词： trauma diagnosis Laparoscopic

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