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Depressing behaviors and mechanism of disodium bis(carboxymethyl) trithiocarbonate on separation of chalcopyrite and molybdenite

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Transactions of Nonferrous Metals Society of China 2017年第4期27卷 883-890页

作者： Zhi-gang YIN Wei SUN Yue-hua HU Qing-jun GUAN Chen-hu ZHANG Yue-sheng GAO ji-hua zhai School of Minerals Processing and Bioengineering Central South University Changsha 410083 China

This work focuses on the organic depressant,disodium bis(carboxymethyl)trithiocarbonate(DBT),as a selectivedepressant in copper?molybdenum sulfide flotation ***-flotation,Zeta potential,FTIR and XPS measurements werecarried out to investigate the selective depression mechanism of DBT on *** potential and FTIR measurementsrevealed that DBT had higher affinity for chalcopyrite than molybdenite and the XPS results of chalcopyrite before and aftertreatment with DBT further proved that DBT adsorbed on chalcopyrite *** investigation indicates that the mechanism ofDBT adsorbing on chalcopyrite is mainly physical *** circuit experiments were carried out and the results showedthat DBT could be considered as a cleaner option in commercial Cu?Mo flotation separation circuits.

关键词： copper.molybdenum sulfide ore disodium bis(carboxymethyl) trithiocarbonate depressant flotation separation physical adsorption

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Overhead-free Noise-tolerant Federated Learning: A New Baseline

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Machine Intelligence Research 2024年第3期21卷 526-537页

作者： Shiyi Lin Deming zhai Feilong Zhang Junjun jiang Xianming Liu Xiangyang ji Department of Computer Science and Technology Harbin Institute of TechnologyHarbin150000China Department of Automation Tsinghua UniversityBeijing100084China

Federated learning (FL) is a promising decentralized machine learning approach that enables multiple distributed clients to train a model jointly while keeping their data private. However, in real-world scenarios, the supervised training data stored in local clients inevitably suffer from imperfect annotations, resulting in subjective, inconsistent and biased labels. These noisy labels can harm the collaborative aggregation process of FL by inducing inconsistent decision boundaries. Unfortunately, few attempts have been made towards noise-tolerant federated learning, with most of them relying on the strategy of transmitting overhead messages to assist noisy labels detection and correction, which increases the communication burden as well as privacy risks. In this paper, we propose a simple yet effective method for noise-tolerant FL based on the well-established co-training framework. Our method leverages the inherent discrepancy in the learning ability of the local and global models in FL, which can be regarded as two complementary views. By iteratively exchanging samples with their high confident predictions, the two models “teach each other” to suppress the influence of noisy labels. The proposed scheme enjoys the benefit of overhead cost-free and can serve as a robust and efficient baseline for noise-tolerant federated learning. Experimental results demonstrate that our method outperforms existing approaches, highlighting the superiority of our method.

关键词： Federated learning noise-label learning privacy-preserving machine learning edge intelligence distributed machine learning

Multifunctional phase change film with high recyclability, adjustable thermal responsiveness, and intrinsic self-healing ability for thermal energy storage

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Journal of Energy Chemistry 2024年第10期97卷 216-227页

作者： Bo Yang Xuelai Zhang Jun ji Weisan hua Miaomiao jiang Institute of Cool Thermal Storage Technology Shanghai Maritime University

Phase change materials(PCMs) present promising potential for guaranteeing safety in thermal management ***,most reported PCMs have a single application in energy storage for thermal management systems,which does not meet the growing demand for multi-functional *** this paper,the flexible material and hydrogen-bonding function are innovatively combined to design and prepare a novel multi-functional flexible phase change film(PPL).The 0.2PPL-2 film exhibits solid-solid phase change behavior with energy storage density of 131.8 J/g at the transition temperature of42.1℃,thermal cycling stability(500 cycles),wide-temperature range flexibility(0-60℃) and selfhealing ***,the PPL film can be recycled up to 98.5% by intrinsic ***,the PPL film can be tailored to the desired colors and configurations and can be cleverly assembled on several thermal management systems at ambient temperature through its flexibility combined with shape-memory *** interestingly,the transmittance of PPL will be altered when the ambient temperature changes(60℃),conveying a clear thermal ***,the thermal energy storage performance of the PPL film is successfully tested by human thermotherapy and electronic device temperature control *** proposed functional integration strategy provides innovative ideas to design PCMs for multifunctionality,and makes significant contributions in green chemistry,highefficiency thermal management,and energy sustainability.

关键词： Energy storage Multifunctional material Phase change film Recyclability Self-healing

Heteroatom doping regulates the catalytic performance of singleatom catalyst supported on graphene for ORR

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Nano Research 2024年第3期17卷 1086-1093页

作者： ji-Kai Sun Yu-Wei Pan Meng-Qian Xu Lei Sun Shaolong Zhang Wei-Qiao Deng Dong zhai Institute of Molecular Sciences and Engineering Institute of Frontier and Interdisciplinary ScienceShandong UniversityQingdao 266237China College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060China

Replacing fossil fuels with fuel cells is a feasible way to reduce global energy shortages and environmental ***,the oxygen reduction reaction(ORR)at the cathode has sluggish kinetics,which limits the development of fuel *** is significant to develop catalysts with high catalytic activity of *** single-atom catalysts(SACs)of Pt supported on heteroatom-doped graphene are potential candidates for *** we studied the SACs of Pt with different heteroatoms doping and screened out Pt-C_(4) and Pt-C_(3)O_(1) structures with only 0.13 V overpotential for ***,it is found that B atoms doping could weaken the adsorption capacity of Pt,while N or O atoms doping could enhance *** regularity was verified on Fe *** the electronic interaction analysis between Pt and adsorbate,we explained the mechanism of this regularity and further proposed a new descriptor named corrected d-band center(ε_(d-corr))to describe *** descriptor is an appropriate reflection of the number of free electrons of the SACs,which could evaluate its adsorption *** work provides a purposeful regulatory strategy for the design of ORR catalysts.

关键词： single-atom catalyst(SAC) oxygen reduction reaction(ORR) heteroatom doping corrected d-band center descriptor

Successful splenic artery embolization in a patient with Behçet’s syndrome-associated splenic rupture:A case report

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World Journal of Gastrointestinal Surgery 2024年第4期16卷 1184-1188页

作者： Guang-Zhao Zhu Dong-hua ji Department of Interventional Therapy The First Affiliated Hospital of Dalian Medical UniversityDalian 116011Liaoning ProvinceChina

BACKGROUND Splenic rupture associated with Behçet’s syndrome(BS)is extremely rare,and there is no consensus on its *** this case report,a patient with BSassociated splenic rupture was successfully treated with splenic artery embolization(SAE)and had a good prognosis after the *** SUMMARY The patient was admitted for pain in the left upper abdominal *** was diagnosed with splenic *** oral and genital aphthous ulcers were observed,and acne scars were found on his *** had a 2-year history of BS diagnosis,with symptoms of oral and genital *** that time,he was treated with oral corticosteroids for 1 month,but the symptoms did not *** underwent SAE to treat the *** the first day after SAE,the patient reported a complete resolution of abdominal pain and was discharged 5 d *** months after the intervention,a computed tomography examination showed that the splenic hematoma had formed a stable cystic effusion,suggesting a good *** SAE might be a good choice for BS-associated splenic rupture based on good surgical practice and material selection.

关键词： Splenic artery embolization Behçet’s syndrome Splenic rupture Case report

The dynamics beamline at SSRF

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Nuclear Science and Techniques 2024年第9期35卷 56-67页

作者： Zhen Liu Li-hua Wang Yong jiang Ya-Jun Tong hua-Chun Zhu Te ji Min Chen Zheng jiang Xiang-Jun Wei Shanghai Advanced Research Institute Chinese Academy of SciencesShanghai 201204China ShanghaiTech University Shanghai 201210China

The dynamics beamline(D-Line),which combines synchrotron radiation infrared spectroscopy(SR-IR)and energy-disper-sive X-ray absorption spectroscopy(ED-XAS),is the first beamline in the world to realize concurrent ED-XAS and SR-IR measurements at the same sample position on a millisecond time-resolved *** combined technique is effective for investigating rapid structural changes in atoms,electrons,and molecules in complicated disorder systems,such as those used in physics,chemistry,materials science,and extreme ***,ED-XAS and SR-IR can be used independently in the two branches of the *** ED-XAS branch is the first ED-XAS beamline in China,which uses a tapered undulator light source and can achieve approximately 2.5×10^(12)photons/s·300 eV BW@7.2 keV at the sample *** exchange-able polychromator operating in the Bragg-reflection or Laue-transmission configuration is used in different energy ranges to satisfy the requirements for beam size and energy *** focused beam size is approximately 3.5μm(H)×21.5μm(V),and the X-ray energy range is 5–25 *** one-and two-dimensional position-sensitive detectors with frame rates of up to 400 kHz enables time resolutions of tens of microseconds to be *** distinctive techniques,such as the concurrent measurement of in situ ED-XAS and infrared spectroscopy,time-resolved ED-XAS,high-pressure ED-XAS,XMCD,and pump-probe ED-XAS,can be applied to achieve different scientific goals.

关键词： ED-XAS SR-IR Time-resolved D-line SSRF

Intelligent diagnosis of retinal vein occlusion based on color fundus photographs

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International Journal of Ophthalmology(English edition) 2024年第1期17卷 1-6页

作者： Yu-Ke ji Rong-Rong hua Sha Liu Cui-Juan Xie Shao-Chong Zhang Wei-hua Yang Eye Hospital Nanjing Medical UniversityNanjing 210000Jiangsu ProvinceChina College of Electronic Information Engineering Nanjing University of Aeronautics and AstronauticsNanjing 210000Jiangsu ProvinceChina Shenzhen Eye Institute Shenzhen Eye HospitalJinan UniversityShenzhen 518000Guangdong ProvinceChina

AIM:To develop an artificial intelligence(AI)diagnosis model based on deep learning(DL)algorithm to diagnose different types of retinal vein occlusion(RVO)by recognizing color fundus photographs(CFPs).METHODS:Totally 914 CFPs of healthy people and patients with RVO were collected as experimental data sets,and used to train,verify and test the diagnostic model of *** the images were divided into four categories[normal,central retinal vein occlusion(CRVO),branch retinal vein occlusion(BRVO),and macular retinal vein occlusion(MRVO)]by three fundus disease *** Transformer was used to build the RVO diagnosis model,and different types of RVO diagnosis experiments were *** model’s performance was compared to that of the ***:The accuracy of the model in the diagnosis of normal,CRVO,BRVO,and MRVO reached 1.000,0.978,0.957,and 0.978;the specificity reached 1.000,0.986,0.982,and 0.976;the sensitivity reached 1.000,0.955,0.917,and 1.000;the F1-Sore reached 1.000,0.9550.943,and 0.887 *** addition,the area under curve of normal,CRVO,BRVO,and MRVO diagnosed by the diagnostic model were 1.000,0.900,0.959 and 0.970,*** diagnostic results were highly consistent with those of fundus disease experts,and the diagnostic performance was ***:The diagnostic model developed in this study can well diagnose different types of RVO,effectively relieve the work pressure of clinicians,and provide help for the follow-up clinical diagnosis and treatment of RVO patients.

关键词： deep learning artificial intelligence Swin Transformer diagnostic model retinal vein occlusion color fundus photographs

3D printed modular Bouligand dissipative structures with adjustable mechanical properties for gradient energy absorbing

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Materials Futures 2024年第2期3卷 104-116页

作者： Junfeng Xiao Mengxing Zhang Fei zhai Hongrui Wei Sen Liu Peng Wang Zhiyang Liu Zhongying ji Xiaolong Wang Shenzhen Institute of Information Technology Shenzhen 518172People’s Republic of China Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai Yantai Zhongke Research Institute of Advanced Materials and Green Chemical EngineeringYantai 264006People’s Republic of China School of Chemistry and Chemical Engineering Key Laboratory of Materials-Oriented Chemical Engineering of Xinjiang Uygur Autonomous RegionShihezi UniversityShihezi 832003People’s Republic of China School of Transportation Engineering Shandong Jianzhu UniversityJinan 250101People’s Republic of China College of Civil and Transportation Engineering Shenzhen UniversityShenzhen 518061People’s Republic of China State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesGansu Lanzhou 730000People’s Republic of China

Three-dimensional(3D)printing allows for the creation of complex,layered structures with precise micro and macro architectures that are not achievable through traditional *** designing 3D structures with geometric precision,it is possible to achieve selective regulation of mechanical properties,enabling efficient dissipation of mechanical *** this study,a series of modular samples inspired by the Bouligand structure were designed and produced using a direct ink writing system,along with a classical printable polydimethylsiloxane *** altering the angles of filaments in adjacent layers(from 30◦to 90◦)and the filament spacing during printing(from 0.8 mm to 2.4 mm),the mechanical properties of these modular samples can be *** mechanical testing revealed that the 3D printed modular Bouligand structures exhibit stress-strain responses that enable multiple adjustments of the elastic modulus from 0.06 MPa to over 0.8 *** mechanical properties were adjusted more than 10 times in printed samples prepared using uniform *** gradient control mechanism of mechanical properties during this process was analyzed using finite element ***,3D printed customized modular Bouligand structures can be assembled to create an array with Bouligand structures displaying various orientations and interlayer details tailored to specific *** decomposing the original Bouligand structure and then assembling the modular samples into a specialized array,this research aims to provide parameters for achieving gradient energy absorption structures through modular 3D printing.

关键词： 3D printing additive manufacturing Bouligand structure energy absorbing structures

Safflower Yellow Inhibits Progression of Hepatocellular Carcinoma by Modulating Immunological Tolerance via FAK Pathway

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Chinese Journal of Integrative Medicine 2024年第4期30卷 339-347页

作者： ji hua-feng YANG Zi-qiang HAN Jun-jun LI He-fang jiN Zhao-qing CHEN Wei-qing CHEN Fei-hua GONG Mou-chun Department of General Surgery First People's Hospital of Hangzhou Lin'an DistrictHangzhou(311300)China

Objective To explore the anti-tumor effect of safflower yellow(SY)against hepatocellular carcinoma(HCC)and the underlying potential *** An in vitro model was established by mixing Luc-Hepa1-6 cells and CD3^(+)CD8^(+)T cells,followed by adding programmed cell death protein 1(PD-1)antibody(Anti-mPD-1)with or without *** apoptosis was detected by flow cytometry and the level of inflammatory cytokines was determined by enzyme-linked immunosorbent *** protein levels of programmed cell death 1 ligand 1(PD-L1),chemokine ligand(CCL5),C-X-C motif chemokine ligand 10(CXCL10)were measured by Western *** in situ animal model was established in mice followed by treatment with anti-mPD-1 with or without *** imaging was monitored with an AniView 100 imaging *** establish the FAK-overexpressed Luc-Hepa1-6 cells,cells were transfected with adenovirus containing pcDNA3.1-FAK for 48 *** The fluorescence intensity,apoptotic rate,release of inflammatory cytokines,and CCL5/CXCL10 secretion were dramatically facilitated by anti-mPD-1(P<0.01),accompanied by an inactivation of PD-1/PD-L1 axis,which were extremely further enhanced by SY(P<0.05 or P<0.01).Increased fluorescence intensity,elevated percentage of CD3+CD8+T cells,facilitated release of inflammatory cytokines,inactivated PD-1/PD-L1 axis,and increased CCL5/CXCL10 secretion were observed in Anti-mPD-1 treated mice(P<0.01),which were markedly enhanced by SY(P<0.05 or P<0.01).Furthermore,the enhanced effects of SY on inhibiting tumor cell growth,facilitating apoptosis and inflammatory cytokine releasing,suppressing the PD-1/PD-L1 axis,and inducing the CCL5/CXCL10 secretion in Anti-mPD-1 treated mixture of Luc-Hepa1-6 cells and CD3+CD8+T cells were abolished by FAK overexpression(P<0.01).Conclusion SY inhibited the progression of HCC by mediating immunological tolerance through inhibiting FAK.

关键词： hepatocellular carcinoma safflower yellow Chinese medicine tumor microenvironment programmed cell death protein 1 focal adhesion kinase

维普期刊数据库