检索结果-南通市图书馆

Polymer-on-HOF:a new strategy for fabricating“armour-plated”HOFs to sequester radioactive anions

Science China Chemistry 2024年第9期67卷 2958-2967页

作者： Hai-Ruo li Shitao Wu Xuezhuo jing Zhengyi Di Kun liu Lu Wang Cheng-Peng li Zhong liu Miao Du College of Chemistry Tianjin Key Laboratory of Structure and Performance for Functional MoleculesTianjin Normal UniversityTianjin 300387China Shanghai Key Laboratory of High-Resolution Electron Microscopy School of Physical Science and TechnologyShanghaiTech UniversityShanghai 201210China Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources Qinghai Provincial Key Laboratory of Resources and Chemistry of Salt LakesQinghai Institute of Salt LakesChinese Academy of SciencesXining 810008China College of Material and Chemical Engineering Institute of New Energy Science and TechnologySchool of Future Hydrogen Energy TechnologyZhengzhou University of Light IndustryZhengzhou 450001China

The development of hydrogen-bonded organic frameworks(HOFs)faces significant constraints,primarily attributed to their fragile architectures and limited functionalization *** overcome these limitations,this work presents a new polymeron-HOF strategy by covalently tethering armor-like polymers onto the surface of *** application of this approach not only bolsters the stability of HOFs,but also facilitates the customization of their functional expansion in radionuclide *** optimized HOF-polymer materials display extraordinary ability in radionuclide sequestration,achieving uptake of I^(-)(0.699 g g^(-1)),IO_(3)^(-)(0.285 g g^(-1))and ReO_(4)^(-)(1.616 g g^(-1),setting a world record),fast adsorption kinetics(~100% removal within 45 s),and exceptional regeneration capability(>30 cycles)under continuous flow *** outstanding performances benefit from the internal porous channels and surface imidazolium polymer coatings of HOFs,as proved by density functional theory calculation and molecular dynamics *** work paves the way for the rational design of HOF-based hybrid materials tailored to versatile applications.

关键词： hydrogen-bonded organic frameworks(HOFs) post-synthetic modification radionuclide sequestration

来源：

维普期刊数据库

同方期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Organic ligand nanoarchitectonics for BiVO_(4) photoanodes surface passivation and cocatalyst grafting

引用

Nano Research 2024年第5期17卷 3667-3674页

作者： jingyi lin Xin li Zhiliang Wang Runlu liu Hui Pan Yixin Zhao lingti Kong Yao li Shenmin Zhu lianzhou Wang State Key Laboratory of Metal Matrix Composites School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China Nanomaterials Centre School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnologythe University of QueenslandQLD 4072Australia School of Environmental Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China Hubei Key Laboratory of Plasma Chemistry and Advanced Materials Wuhan Institute of TechnologyWuhan 430205China

Bismuth vanadate(BiVO_(4))is a promising photoanode material for efficient photoelectrochemical(PEC)water splitting,whereas its performance is inhibited by detrimental surface *** solve the problem,herein,a low-cost organic molecule 1,3,5-benzenetricarboxylic acid(BTC)is selected for surface passivation of BiVO_(4) photoanodes(BVOs),which also provides bonding sites for Co^(2+)to anchor,resulting in a Co-BTC-BVO *** to its strong coordination with metal ions,BTC not only passivates surface states of BVO,but also provides bonding between BVO and catalytic active sites(Co^(2+))to form a molecular *** study and interfacial charge kinetic investigation reveal that chemical bonding formed at the interface greatly suppresses charge recombination and accelerates charge *** obtained Co-BTC-BVO photoanode exhibits a photocurrent density of 4.82 mA/cm^(2) at 1.23 V *** hydrogen electrode(RHE)and a low onset potential of 0.22 VRHE under AM 1.5 G illumination,which ranks among the best photoanodes coupled with Co-based *** work presents a novel selection of passivation layers and emphasizes the significance of interfacial chemical bonding for the construction of efficient photoanodes.

关键词： bismuth vanadate photoanode water splitting surface passivation bridging ligands

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Photoinduced generation of alkyl and phthalimide nitrogen radicals from N-hydroxyphthalimide esters for the synthesis of benzophenone-type bioisosteres

引用

Science China Chemistry 2024年第10期67卷 3389-3396页

作者： Fei li jianyang Dong Huijuan liao jiayi Dang Xuechen Zhou Yuying Wang Chenya Wang Qin jiang Gang li Dong Xue Key Laboratory of Applied Surface and Colloid Chemistry Ministry of Education and School of Chemistry and Chemical EngineeringShaanxi Normal University

N-Hydroxyphthalimide（NHPI） esters have emerged as powerful sources of alkyl radicals generated by single-electron transfer,but homolysis of NHPI ester to produce an alkyl radical and a phthalimide nitrogen radical is still in its infancy. In this study, we developed a light-induced method for generation of alkyl and phthalimide nitrogen radicals from NHPI esters and subsequent reactions of the radicals with [1.1.1]propellane and aryl aldehydes for rapid generation of bicycle [1.1.1]pentane ketones. This method does not require metals or photosensitizers, features a broad substrate scope（90 examples） and excellent functional group tolerance, and can be used for the functionalization of structurally complex natural products and drugs. Mechanistic investigations indicate that the reaction involves photoinduced homolytic cleavage of the Cs2CO3-NHPI ester complex to produce alkyl and phthalimide nitrogen radicals and subsequent hydrogen atom transfer between the phthalimide nitrogen radical and the aldehyde to generate an acyl radical.

关键词： phthalimide nitrogen radicals aryl aldehydes hydrogen atom transfer bicycle[1.1.1]pentane ketones bioisosteres

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Mechanism of photon-induced performance changes in silicon heterojunction solar cells

引用

Science China Materials 2024年第9期67卷 2873-2879页

作者： Qi Deng Haoran Ye Shenglei Huang Zehua Sun Yanyun yang Lei li Zhu Ma Rong Su Wei Long Fangdan jiang Heng Guo Guoqiang Xing Wenzhu liu jian Yu School of New Energy and Materials Southwest Petroleum UniversityChengdu610500China Shanghai Institute of Microsystem and Information Technology Chinese Academy of Sciences(CAS)Shanghai201800China Tongwei Solar(Chengdu)Ltd. Chengdu600200China School of Physics and Electronical Science Chuxiong Normal UniversityChuxiong675000China School of Physical Science and Technology ShanghaiTech UniversityShanghai201210China Tianfu Yongxing Laboratory Chengdu610213China

Short-wavelength ultraviolet(UV)photons adversely affect hydrogenated amorphous silicon thin films,as well as on silicon heterojunction(SHJ)solar cells and *** research examines the impact and mechanisms of photon-induced performance *** A exposure disrupts Si-H bonds,significantly reducing hydrogen content in both intrinsic and doped hydrogenated amorphous silicon(a-Si:H)*** disruption impairs the interface passivation effect,leading to the degradation of SHJ solar cells and modules,primarily indicated by a decrease in open-circuit voltage(V_(oc))and fill factor(FF).UV irradiation from the front side of SHJ solar cells reduces V_(oc)and FF by 1.38%and 2.28%,respectively,resulting in a 2.28%efficiency *** irradiated from the backside show decreases in V_(oc)and FF of approximately 1.96%and 2.73%,respectively,leading to an overall efficiency reduction of approximately 3.58%.However,subsequent light-soaking increases V_(oc)and FF by approximately 0.96%and 1.37%,respectively,for frontside-irradiated cells,achieving an overall efficiency improvement of approximately 2.51%.Thus,light-soaking effectively recovers performance losses caused by UV irradiation in SHJ solar *** research clarifies the mechanisms influencing the performance of a-Si:H thin films,SHJ solar cells,and modules under UV irradiation and light-soaking,offering significant contributions towards the development of highly efficient and reliable SHJ devices.

关键词： silicon solar cells heterojunction UV irradiation light soaking hydrogen content

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

急性白血病并发肺部感染诊疗的研究进展

引用

中国实验血液学杂志 2024年第4期32卷 1284-1289页

作者：季浩凌小穗李增政杨同华昆明理工大学医学院云南昆明650500 云南省第一人民医院血液科云南昆明650032

急性白血病是一组具有高死亡率的侵袭性恶性肿瘤,由于疾病本身和放化疗等原因导致功能性免疫细胞减少,使患者容易并发感染,其中并发肺部感染是导致患者死亡的重要原因之一。急性白血病并发肺部感染患者的早期准确诊断和合理治疗能阻止... 详细信息

急性白血病是一组具有高死亡率的侵袭性恶性肿瘤,由于疾病本身和放化疗等原因导致功能性免疫细胞减少,使患者容易并发感染,其中并发肺部感染是导致患者死亡的重要原因之一。急性白血病并发肺部感染患者的早期准确诊断和合理治疗能阻止肺部感染的扩散,从而减少脓毒症、呼吸衰竭、多器官功能衰竭等严重并发症。但临床上在急性白血病并发肺部感染的诊断和治疗方面仍然存在困难,因此,本文针对急性白血病患者肺部细菌、真菌及病毒感染诊断和治疗方面的最新研究进展进行综述。

关键词：急性白血病肺部感染诊断治疗

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

MOF-templated tubular Ni_(1−x)Co_(x)S_(2)-CdS heterojunction with intensified direct Z-scheme charge transmission for highly promoted visible-light photocatalysis

引用

Nano Research 2024年第7期17卷 6281-6293页

作者： Chuan jiang Yuanxin Qiu Xinxin Xin Yanyan li Huilin li Hui Wang jixiang Xu Haifeng lin Lei Wang Volodymyr Turkevych Key Laboratory of Eco-chemical Engineering International S&T Cooperation Foundation of Eco-chemical Engineering and Green ManufactureCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization Key Laboratory of Rubber-Plastics of Ministry of EducationSchool of Polymer Science and EngineeringQingdao University of Science and TechnologyQingdao 266042China V.Bakul Institute for Superhard Materials National Academy of Sciences of UkraineKyiv 04074Ukraine

Hollow semiconductor nanostructures with direct Z-scheme heterojunction have significant advantages for photocatalytic reactions,and optimizing the interfacial charge transmission of Z-scheme heterojunction is the hinge to achieve excellent solar conversion *** this work,tubular Ni_(1−x)Co_(x)S_(2)-CdS heterostructures with reinforced Z-scheme charge transmission were constructed through an In-metal-organic framework(MOF)templated *** Z-scheme charge transfer mechanism was sufficiently confirmed by combining density functional theory(DFT)calculation,X-ray photoelectron spectroscopy(XPS),surface photovoltage spectroscopy(SPV),and radical testing ***,the use of sodium citrate complexant contributes to the formation of intimate heterointerface,and the Fermi level gap between CdS and NiS_(2)is enlarged through Co doping into NiS_(2),which enhances the built-in electric field and photo-carriers transmission driving force for Ni_(1−x)Co_(x)S_(2)-CdS heterojunction,resulting in an evidently promoted activity toward H2 evolution reaction(HER).Under visible-light(λ>400 nm)irradiation,the Ni_(1−x)Co_(x)S_(2)-CdS composite with 10 mol%Co doping and 80 wt.%CdS(NC_(0.10)S-80%CdS)achieved an outstanding HER rate up to 35.94 mmol·g^(−1)·h^(−1)(corresponding to the apparent quantum efficiency of 34.7%at 420 nm),approximately 76.4 times that of 3 wt.%Pt-loaded CdS and it is much superior to that of most CdS-based photocatalysts ever ***,the good photocatalytic durability of Ni_(1−x)Co_(x)S_(2)-CdS heterostructures was validated by cycling and long-term HER *** work could inspire the development of high-performance Z-scheme heterojunction via optimizing the morphology and interfacial charge transmission.

关键词： tubular heterostructure Z-scheme charge transmission interfacial coupling built-in electric field visible-light photocatalysis

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Electronic structure engineering of single atomic sites by plasmoninduced hot electrons for highly efficient and selective photocatalysis

引用

Nano Research 2024年第8期17卷 6960-6967页

作者： Xiaoya Huang Xinyuan li Akang Chen Hongfei Gu Shouyuan li Tailei Hou Shuwen Zhu Shuang Yu Yin Song jiatao Zhang Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications MIIT Key Laboratory of Medical Molecule Science and Pharmaceutical EngineeringMOE Key Laboratory of Cluster ScienceSchool of Chemistry and Chemical EngineeringSchool of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China MIIT Key Laboratory of Complex-field Intelligent Exploration School of Optics and PhotonicsBeijing Institute of TechnologyBeijing 100081China

Single atom(SA)catalysts have achieved great success on highly selective heterogeneous catalysis due to their abundant and homogeneous active *** electronic structures of these active sites,restrained by their localized coordination environments,significantly determine their catalytic performances,which are difficult to ***,we investigated the effect of localized surface plasmon resonance(LSPR)on engineering the electronic structures of single atomic ***,core–shell structures consisted of Au core and transition metal SAs loaded N-doped carbon(CN)shell were constructed,namely Au@M-SA/CN(M=Ni,Fe,and Co).It was demonstrated that plasmon-induced hot electrons originated from Au were directionally injected to the M-SAs under visible light irradiation,which significantly changed their electronic structures and meanwhile facilitated improved overall charge separation *** as-prepared Au@Ni-SA/CN exhibited highly efficient and selective photocatalytic CO_(2) reduction to CO performance,which is 20.8,17.5,and 6.9 times those of Au nanoparticles,Au@CN,and Ni-SA/CN,*** spectroscopy analysis and theoretical calculations confirmed that the plasmon enhanced Ni-SA/CN sites featured increased charge density for efficient intermediate activation,contributing to the superb photocatalytic *** work provides a new insight on plasmon and atomic site engineering for efficient and selective catalysis.

关键词： single atom catalysts plasmon enhancement coupling effect photocatalysis CO_(2) reduction

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

相敏操控对制备低频双模正交压缩真空态光场的影响

引用

物理学报 2024年第5期73卷 117-126页

作者：吴炜赵豪冯晋霞 †李俊李渊骥张宽收山西大学光电研究所量子光学与光量子器件国家重点实验室太原030006 湖北师范大学物理与电子科学学院黄石435002 山西大学极端光学协同创新中心太原030006 中国航空工业集团公司西安飞行自动控制研究所西安710076

本文提出了利用单边带移频光实现非简并光学参量放大器相敏操控的方案,实验研究了在对非简并光学参量放大器相敏操控过程中,单边带移频光注入的方案和信号光注入的方案对产生的低频双模正交压缩真空态光场的影响.实验结果表明,信号光注... 详细信息

本文提出了利用单边带移频光实现非简并光学参量放大器相敏操控的方案,实验研究了在对非简并光学参量放大器相敏操控过程中,单边带移频光注入的方案和信号光注入的方案对产生的低频双模正交压缩真空态光场的影响.实验结果表明,信号光注入非简并光学参量放大器实现相敏操控过程中,压缩真空态的压缩度随着注入信号光场功率的增加不断减小直至消失.而在单边带移频光注入非简并光学参量放大器实现相敏操控过程中,正交振幅和正交位相压缩真空态的压缩度对注入移频光场的功率变化都不敏感,压缩度几乎不变.采用单边带移频光方案实现稳定的相敏操控,非简并光学参量放大器运转于相敏放大状态达30 min,获得了稳定输出的低频双模正交压缩真空态光场,在傅里叶分析频率为200 kHz测量的正交振幅分量的压缩度为(4.1±0.1)dB,正交位相分量的压缩度为(4.0±0.2)dB.

关键词：双模正交压缩真空态光学参量放大器相敏操控

来源：

维普期刊数据库博看期刊

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Gastrodin Attenuates Dextran Sulfate Sodium-Induced Colitis in Mice via Modulating Gut Microbiota and Inhibiting NF- κB Signaling Pathway

引用

Food Science and Human Wellness 2024年

作者： Xinyi Gao Xianjun liu Xianglong Meng Mingchuan Wang Mengyuan Wang Boyao Sun Chengxuan jia jintian Gao Chengyi Xu Hao li yang jiang Department of Gastrointestinal Colorectal and Anal Surgery， The China-Japan Union Hospital of jilin University College of Biological and Food Engineering， jilin Engineering Normal University Department of Burns Surgery， The First Hospital of jilin University Medical Faculty， Hetao College Deartment of Nephrology， The Second Hospital of jilin University

Gastrodin (GAS)， the principal bioactive composition of Gastrodia elata Blume， has potential for pharmaceutical applications. Several studies in recent years have shown that GAS may enhance neurotrophic benefits， reduce inflammation， and act as an antioxidant. In this study， we sought to identify the molecular mechanisms underlying the protective benefits of GAS against colitis induced by dextran sodium sulfate (DSS) in mice. GAS (200 mg/kg) significantly ameliorated the severity of colitis in mice caused by DSS， as evidenced by an increase in colon length， a reduction in disease activity index， a decrease in tissue damage， and a reduction in body weight loss. Additionally， GAS inhibited DSS-induced hyperactivation of inflammation-related NF-κB signaling pathways to reduce the production of inflammatory mediators， thereby mitigating the inflammatory response in mice. Furthermore， the administration of GAS restored the function of the gastrointestinal barrier by increasing the count of goblet cells， as well as the levels of tight junction-associated proteins， including ZO-1， Occludin， and Claudin-3. GAS also influenced the overall richness of the gut microbiota， as shown by 16S rRNA sequencing analysis， consequently boosting the proliferative rate of probiotic species， such as Lachnospiraceae and Muribaculaceae， while reducing the richness of harmful bacteria including Escherichia＿Shigella， Enterobacteriaceae， Bacteroidaceae， and Bacteroides. GAS (200 mg/kg) alleviated ulcerative colitis (UC) by modulating gut dysbiosis， as demonstrated by a fecal microbial transplantation (FMT) test. Furthermore， inflammatory damage induced by lipopolysaccharide (LPS) was averted in RAW264.7 cells by GAS administration， hence preventing the NF-κB signaling pathway from being activated in these experimental conditions conducted in vitro. Overall， the data indicate that GAS treatment effectively reduces Colitis caused by DSS by regulating gut microbiota， suppressing inflammation， and

关键词：

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Enhancing alkaline water oxidation with NiFe alloy-encapsulated nitrogen-doped vertical graphene array

引用

Nano Research 2024年第6期17卷 4790-4796页

作者： Jue Nan Beirong Ye Xun He Chen li Wanli Zhang Qian liu Luming li Wei Chu Xuping Sun Yongqi Zhang School of Integrated Circuit Science and Engineering University of Electronic Science and Technology of ChinaChengdu 611731China Institute of Fundamental and Frontier Science University of Electronic Science and Technology of ChinaChengdu 611731China Institute for Advanced Study Chengdu UniversityChengdu 610106China College of Chemistry Chemical Engineering and Materials ScienceShandong Normal UniversityJinan 250014China

Advancing efficient and affordable electrocatalysts to boost the oxygen evolution reaction(OER)is pivotal for sustainable green hydrogen ***,we propose the fabrication of nickel-iron alloy nanoparticles-encapsulated on N-doped vertically aligned graphene array on carbon cloth(NiFe@NVG/CC)as a highly active three-dimensional(3D)catalyst electrode for *** 1 M KOH,such NiFe@NVG/CC demonstrates outstanding catalytic performance,necessitating merely overpotential of 245 mV for achieving a current density of 10 mA·cm^(−2),a remarkably low Tafel slope of 36.2 mV·dec^(−1).Furthermore,density functional theory calculations validate that the incorporate of N species into graphene can reinforce the electrocatalytic activity though reducing the reaction energy barrier during the conversion of*O to*OOH *** outstanding performance and structural benefits of NiFe@NVG/CC offer valuable insights for the development of innovative and efficient electrocatalysts for water oxidation.

关键词： NiFe alloy N-doped vertical graphene array electrocatalyst oxygen evolution reaction density functional theory

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：