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Matrix Assisted Laser Desorption Ionization Time of Flight(MALDI-TOF)-Mass Spectrometry and^(13)C-NMR-Identified New Compounds in Paraberlinia bifoliolata(Ekop-Beli)Bark Tannins

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Journal of Renewable Materials 2024年第3期12卷 553-568页

作者： Liliane Nga Benoit Ndiwe Achille Bernard Biwolé Antonio Pizzi jean Jalin Eyinga Biwole Joseph Zobo Mfomo Laboratory of Forest Resources and Wood Valorization Training Unit in Engineering SciencesPost Graduate School of Fundamental and Applied SciencesUniversity of DoualaP.O.Box 1872DoualaCameroun Laboratory of Mechanics Training Unit in Engineering SciencesPost Graduate School of Fundamental and Applied SciencesUniversity of DoualaP.O.Box 2701DoualaCameroun Laboratory of Studies and Research on Wood Material(LERMAB) University of LorraineNancyFrance

Extracts of plant origin,particularly tannins,are attracting growing interest for the sustainable development of materials in the industrial *** discovery of new tannins is therefore *** aim of this work was to contribute to the understanding of the properties of Paraberlinia bifoliolata tannin by Matrix Assisted Laser Desorption Ionization Time of Flight Mass Spectroscopy MALDI-TOF/MS and Carbon 13 Nuclear Magnetic Resonance(13C NMR).The chemical composition of tannin extracted from Paraberlinia bifoliolata bark was determined,as was the mechanical strength of the resin hardened with Acacia nilotica *** by successive water extraction was 35%.MALDI-TOF/MS analysis revealed the presence of three new compounds in this tannin,previously unknown in this family of *** are 3-hydroxyproline acid,N-methyl-4-hydroxypipecolic acid and N-methyl-5-dihydroxypipecolic *** identification of the above molecules means that this tannin can be used for industrial applications,as a resin in the manufacture of particleboard and in the formulation of green corrosion *** information is reinforced by 13C NMR spectrometry,which indicates the presence of several polyflavonoid units,confirming the condensed nature of the *** analysis of the resin formed by the purified tannin of Paraberlinia bifoliolata to which a vegetal biohardener has been added provided a Modulus of Elasticity(MOE)value of 4840 MPa at 150℃,confirming its possible use as a binder resin in the manufacture of wood panels as well as for the formulation of a corrosion inhibitor.

关键词： Tannin Paraberlinia bifoliolata Central African wood species MALDI-TOF/MS 13C NMR bark extracts thermomechanical behaviour wood-binder

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A Global Group of Friends

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Beijing Review 2024年第29期67卷 26-27页

作者： jean Paul Vargas the Sustainable Development Innovation Laboratory Central American Institute of Public Administration the Center for Historical Research of Central America University of Costa Rica

China's Global Development Initiative(GDI)is emerging as a transformative force in the international *** President Xi Jinping first publicized the conceplal the United Nations General Assembly in September *** its announcemen,the GDT's main components and objectives,aimed at fostering cunnectily and coperation between coninents,hawe atractod workdwide atentin.

关键词： Global foster objectives

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Hf元素添加对CuZr基非晶合金动态弛豫的影响

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力学学报 2024年第8期56卷 2282-2293页

作者：朱凡邢光辉 jean-Marc Pelletier 乔吉超西北工业大学力学与土木建筑学院西安710072 东莞市三航军民融合创新研究院广东东莞523808 INSA-Lyon MATEIS UMR5510F-69621 VilleurbanneFrance

考虑到非晶合金具有独特的无序微观结构,其表现出极为复杂的弛豫动力学特性.动态弛豫行为在非晶合金中普遍存在,深刻理解其机制对于解构非晶合金固有的非均匀微观结构至关重要.少量元素的添加是调控非晶合金微观结构有效手段之一.本研... 详细信息

考虑到非晶合金具有独特的无序微观结构,其表现出极为复杂的弛豫动力学特性.动态弛豫行为在非晶合金中普遍存在,深刻理解其机制对于解构非晶合金固有的非均匀微观结构至关重要.少量元素的添加是调控非晶合金微观结构有效手段之一.本研究以玻璃形成能力良好的Cu_(46)Zr_(47-x)Hf_(x)Al_(7)(x=0,8)非晶合金为模型合金,运用动态力学分析方法研究复模量随频率和温度的变化,进而探究Hf元素取代Zr元素对动态弛豫的影响.在动态力学频率谱中,借助准点缺陷理论阐明非晶合金在玻璃转变温度T_(g)以下处于等构型状态,准点缺陷浓度保持恒定;而在T_(g)以上,准点缺陷浓度随温度的上升呈线性增加.Hf元素的添加会降低玻璃体系等构型状态下的准点缺陷浓度,并抑制原子迁移能力.通过获取连续和离散的弛豫时间分布,直观展示了非晶合金的动力学非均匀性特征.在动态力学温度谱中,Hf元素的引入增加了玻璃体系的混合焓,抑制了β弛豫强度.进一步从内耗角度表明,Hf元素的引入不仅提高了与β弛豫相关的基本结构单元的激活难度,还增加了整个β弛豫过程的激活能.

关键词：非晶合金动态弛豫微合金化准点缺陷微观结构非均匀性

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New Insights in the Biodegradability and the Ecotoxicological Effects of Solar Products Containing Mineral and Chemical UV-Filters on Marine Zoo- and Phytoplanktons: An in silico and in vitro Study

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Journal of Cosmetics, Dermatological Sciences and Applications 2024年第1期14卷 98-111页

作者： jean-Claude Hubaud Karim Mekideche jean-Eric Branka Luc Lefeuvre HELIOSCIENCE Cité de la cosmétique 2 rue Odette Jasse Marseille France EPHYSCIENCE 498ter route de Saint Joseph de Porterie Nantes France Laboratoires Dermatologiques d’Uriage Neuilly-sur-Seine France

Background: Cosmetic formulations, and particularly solar products which contain mineral and chemical UV-filters, are often suspected of causing harmful effects on marine fauna and flora. After the publication of our work in 2019 concerning the ecotoxicological effects of such formulations on corals (Seriatopora hystrix), we here provide some new information about the biodegradability and the ecotoxicological effects of these products on marine zoo- and phytoplankton. Therefore, we choose to realize in silico and in vitro studies of the biodegradability of several solar products but also to evaluate the ecotoxicological effects of these products on one phytoplankton, i.e. Phaeodactylum tricornutum, and one zooplankton, i.e. Acartia tonsa, of a great importance for sea species survival (notably as sources of food). Materials and methods: Two different approaches were used to study the biodegradability of the tested products: One in silico method and an in vitro one. 2 solar products were involved in the in silico study which consisted in the determination of the degradation factor (DF) of each ingredient of the tested formulas in order to finally obtain their estimated biodegradability percentage. Already available data concerning each ingredient coupled to a computer model developed with one of our partners were used to achieve this study. The in vitro study involved 8 formulas containing UV-filters and was led by following the OECD 301 F guidelines. Ecotoxicological studies of 7 of the formulas containing UV-filters were for their part realized by following the ISO 10253 guidelines for the experiments led with Phaeodactylum tricornutum, and the ISO 14669 guidelines for the experiments led with Acartia tonsa. In these studies, the effect of each tested product on crustaceans’ mortality and algal growth inhibition was assessed. Results: The in silico study predicted that formulas containing chemical UV-filters display a high biodegradability (superior to the threshol

关键词： UV-Filters Chemical UV-Filter Biodegradability Ecotoxicology in silico in vitro Zooplankton Phytoplankton Phaeodactylum tricornutum Acartia tonsa

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Meat products consumption and risk for Alzheimer dementia and type 2 diabetes: a systematic review and meta-analysis of cohort studies

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Food Science and Human Wellness 2024年

作者： Mingyu Li Xiaoyue Yang Lu Sun Hongwei Xiao Chongxin Liu Chunjiang Zhang Zhenyu Wang christophe Blecker Dequan Zhang Key Laboratory of Agro-Products Processing， Institute of Food Science and Technology， Chinese Academy of Agricultural Sciences， Ministry of Agriculture and Rural Affairs Gembloux Agro-Bio Tech， Unit of Food Science and Formulation， University of Liège College of Engineering， China Agricultural University School of Agriculture and Food Science， University College Dublin

Alzheimer dementia （AD） and type 2 diabetes （T2D） are interrelated global public health problems， and the current epidemics of both AD and T2D are insulin resistance diseases. Thus， AD and T2D may share common risk factors such as an unhealthy diet， lifestyle， and obesity. Meat products is an important part of the diet of consumers worldwide. This systematic review and meta-analysis aims to assess and estimate the effect of meat products consumption on AD and T2D in humans. Web of Science， MEDLINE， PubMed， Cochrane Library， and Embase were searched from January 2012 to April 2024. 29 articles reported 32 cohort studies with 1，785，769 subjects， with 3，546 AD cases and 91，092 T2D cases that met the inclusion criteria and were included in our analysis. Consumption of various meat products increased the risk of T2D (HR = 1.19， 95% CI: 1.13 - 1.26， p = 0.000; I2= 88.5%)， consumption of smoked， grilled/roasted and fried meat products was more likely to induce T2D (HR = 1.24， 95% CI: 1.18 - 1.30， p = 0. 000; I2= 76.1%)， but was borderline significant for the risk of AD (HR = 1.11， 95% CI: 0.98 - 1.25， p = 0.094; I2= 58.8%)， with consumption of mainly livestock and poultry products increasing the risk (HR = 1.21， 95% CI: 1.03 - 1.42， p = 0.017; I2= 66.8%). The association between meat products consumption and AD risk was influenced by meat type and sample size， while the risk of T2D was influenced by meat type， follow-up and sex. A daily intake of 27 g， 123 g and 170 g of livestock products increased the risk of T2D by 10%， 51% and 70% respectively， whereas the risk of T2D was reduced when the intake of various meat products was less than 23 g/d.

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Programming nonlinear propagation for efficient optical learning machines

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Advanced Photonics 2024年第1期6卷 73-83页

作者： Ilker Oguz Jih-Liang Hsieh Niyazi Ulas Dinc Ugur Tegin Mustafa Yildirim Carlo Gigli christophe Moser Demetri Psaltis École Polytechnique Fédérale de Lausanne Institute of Electrical and Micro EngineeringEcublensSwitzerland Koc University Department of Electrical and Electronics EngineeringIstanbulTurkey

The ever-increasing demand for training and inferring with larger machine-learning models requires more efficient hardware solutions due to limitations such as power dissipation and *** is a promising contender for providing lower power computation,since light propagation through a nonabsorbing medium is a lossless ***,to carry out useful and efficient computations with light,generating and controlling nonlinearity optically is a necessity that is still *** fibers(MMFs)have been shown that they can provide nonlinear effects with microwatts of average power while maintaining parallelism and low *** propose an optical neural network architecture that performs nonlinear optical computation by controlling the propagation of ultrashort pulses in MMF by wavefront *** a surrogate model,optimal sets of parameters are found to program this optical computer for different tasks with minimal utilization of an electronic *** show a remarkable decrease of 97%in the number of model parameters,which leads to an overall 99%digital operation reduction compared to an equivalently performing digital neural *** further demonstrate that a fully optical implementation can also be performed with competitive accuracies.

关键词： neural networks nonlinear optics fiber optics surrogate optimization neuromorphic computing wavefront shaping

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Interleukin-mediated therapies in liver diseases and comorbidity effects

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World Journal of Hepatology 2024年第7期16卷 980-989页

作者： Nouhoum Bouare jean Delwaide Department of Quality HygienBiosafety/Biosecurity and PharmacovigilenceNational Institute of Public HealthBamako 1771Mali Department of Gastroenterology and Hepatology CHULiegeLiege 4000Belgium

Cytokines like interleukins(ILs)play important roles in inflammation and innate *** and Zhang carried out an interesting study related to ILs and hepatic *** described the role of ILs in the pathogenesis and resolution of hepatic *** authors summarized alcohol-related liver disease and virus-induced hepatitis,as far as clinical studies a fortiori carried out on ILmediated treatments pertaining to these *** editorial contributes to the review by Yang and Zhang titled,"Interleukins in liver disease treatment",and focuses on therapies mediated by ILs in comorbid liver *** documentary search was conducted on recent pertinent literature,primarily using the Google Scholar and PubMed databases.

关键词： Cytokines Interleukins Liver diseases Therapy Comorbidity

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Virtual brain twins: from basic neuroscience to clinical use

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National Science Review 2024年第5期11卷 72-86页

作者： Huifang E.Wang Paul Triebkorn Martin Breyton Borana Dollomaja jean-Didier Lemarechal Spase Petkoski Pierpaolo Sorrentino Damien Depannemaecker Meysam Hashemi Viktor K.Jirsa Aix Marseille Université Institut National de la Santéet de la Recherche Médicale Institut de Neurosciences des Systèmes(INS) UMR1106 Service de Pharmacologie Clinique et Pharmacosurveillance AP–HM

Virtual brain twins are personalized, generative and adaptive brain models based on data from an individual's brain for scientific and clinical use. After a description of the key elements of virtual brain twins,we present the standard model for personalized whole-brain network models. The personalization is accomplished using a subject's brain imaging data by three means:(1) assemble cortical and subcortical areas in the subject-specific brain space;(2) directly map connectivity into the brain models, which can be generalized to other parameters; and(3) estimate relevant parameters through model inversion, typically using probabilistic machine learning. We present the use of personalized whole-brain network models in healthy ageing and five clinical diseases: epilepsy, Alzheimer's disease, multiple sclerosis, Parkinson's disease and psychiatric disorders. Specifically, we introduce spatial masks for relevant parameters and demonstrate their use based on the physiological and pathophysiological hypotheses. Finally, we pinpoint the key challenges and future directions.

关键词： virtual brain twin personalized modeling inference neuroscience brain disorder

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Sustainable Ride

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ChinAfrica 2024年第9期16卷 54-55页

作者： jean D’AMOUR MBONYINSHUTI 不详

Chinese electric vehicle makers fuel Rwanda’s drive for pollution-free *** a growing demand to electrify Rwanda’s public transport,companies are rushing into the sector to import electric vehicles(EVs)and related se... 详细信息

关键词： companies Sustainable China.

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Late-onset Very long-chain acyl-CoA dehydrogenase deficiency diagnosis complicated by fulminant myocarditis in adult patient

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Journal of Intensive Medicine 2024年第3期4卷 400-402页

作者： Martin Gérard Clair Douillard Julien Poissy Mehdi Marzouk christophe Vinsonneau Intensive Care Unit Centre Hospitalier de Bethune-BeuvryBethuneFrance Endocrinology diabetologymetabolism departmentLille reference centre of inborn errors of metabolismLille University HospitalLilleFrance Inserm U1285 CHU LillePôle de réanimationCNRSUMR 8576-UGSF-Unitéde Glycobiologie Structurale et FonctionnelleUniv.LilleLilleFrance

Introduction A 21-year-old woman presented to the emergency department with fatigue,abdominal pain and *** physical activity in school was strictly *** had no family medical history and no personal history but reported frequent episodes of nausea and vomiting lasting 2 to 7 days during the past two years,as well as a weight loss of 9 kg due to reactive anorexia(Body Mass Index 17.5),without triggering factors or *** gastrointestinal symptoms led to the detection of isolated elevated transaminases(aspartate aminotransferase[AST]190 U/L and alanine aminotransferase[ALT]170 U/L);however,the patient did not pursue the proposed etiological *** has been using cannabis once a day for several years,with an increase in consumption over the past year,but no *** reported no other recent change in her habits.

关键词： diagnosis patient elevated

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