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Depleted uranium oxide supported nickel catalyst for autothermal CO_(2)methanation in non-adiabatic reactor under induction heating

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Journal of Energy Chemistry 2023年第10期85卷 310-323,I0010页

作者： Lai Truong-Phuoc jean-mario nhut Loïc Vidal Cuong Duong-Viet Sécou Sall Corinne Petit Christophe Sutter Mehdi Arab Alex Jourdan Cuong Pham-Huu Institute of Chemistry and Processes for Energy Environment and Health(ICPEES)ECPMUMR 7515 CNRS-University of Strasbourg25 rue Becquerel67087 Strasbourg Cedex 02France BlackLeaf SAS 210 rue Geiler de Kaysersberg67400 IllkirchFrance Institute of Materials Science of Mulhouse IS2MUMR 7361Universitéde Haute-AlsaceCNRS15rue Jean Starcky-BP 248868057 MulhouseFrance ORANO Tricastin Direction de La Recherche&DéveloppementSite du TRICASTIN BP 1626701 Pierrelatte CedexFrance

Undoped nickel-based catalysts supported on depleted uranium oxide allow one to carry out CO_(2)methanation process under extremely low reaction temperature under atmospheric pressure and powered by a contactless induction heating.By adjusting the reaction conditions,the catalyst is able to perform CO_(2)methanation reaction under autothermal process operated inside a non-adiabatic reactor,without any external energy supply.Such autothermal process is possible thanks to the high apparent density of the UO_x which allows one to confine the reaction heat in a small catalyst volume in order to confine the exothermicity of the reaction inside the catalyst and to operate the reaction at equilibrium heat in-heat out.Such autothermal operation mode allows one to significantly reduce the complexity of the process compared to that operated using adiabatic reactor,where complete insulation is required to prevent heat disequilibrium,in order to reduce as much as possible,the heat exchange with the external medium.The catalyst displays an extremely high stability as a function of time on stream as no apparent deactivation.It is expected that such new catalyst with unprecedented catalytic performance could open new era in the field of heterogeneous catalysis where traditional supports show their limitations to operate catalytic processes under severe reaction conditions.

关键词： CO_(2)methanation Auto-methanation Induction heating Depleted uranium oxide Electrification process Operando DRIFTS

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氮掺杂碳纳米管包覆碳化硅作为不含金属的催化剂(英文)

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催化学报 2014年第6期35卷 906-913页

作者： Cuong Duong-Viet Housseinou Ba Yuefeng Liu Lai Truong-Phuoc jean-mario nhut Cuong Pham-Huu Institute of Chemistry and Processes for Energy Environment and Health (ICPEES) ECPM UMR 7515 du CNRS-University of Strasbourg 25 rue Becquerel 67087 Strasbourg Cedex 02 France Hanoi University of Mining and Geology Dong Ngac Tu Liem Hanoi Viet Nam

A hierarchical metal-free catalyst consisting of nitrogen-doped carbon nanotubes decorated onto a silicon carbide (N-CNTs/SiC) macroscopic host structure was prepared. The influence of N-CNTs incorporation on the physical properties of the support was evaluated using different characterization techniques. The catalyst was tested as a metal-free catalyst in the selective oxidation of H2S and steam-free dehydrogenation of ethylbenzene. The N-CNTs/SiC catalyst exhibited extremely good desulfurization performance compared to a Fe2O3/SiC catalyst under less conducive reaction conditions such as low temperature, high space velocity, and a low O2-to-H2S molar ratio. For the dehy-drogenation of ethylbenzene, a higher dehydrogenation activity was obtained with the N-CNTs/SiC catalyst compared to a commercial K-Fe/Al2O3 catalyst. The N-CNTs/SiC catalyst also displayed good stability as a function of time on stream for both reactions, which was attributed to the strong anchoring of the nitrogen dopant in the carbon matrix. The extrudate shape of the SiC support allowed the direct macroscopic shaping of the catalyst for use in a conventional fixed-bed reactor without the problems of catalyst handling, transportation, and pressure drop across the catalyst bed that are encountered with nanoscopic carbon-based catalysts.

关键词：催化剂组成碳纳米管碳化硅含金属氮掺杂固定床反应器复合材料氧化铝催化剂

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