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Isotherm and kinetic studies on the adsorption of humic acid molecular size fractions onto clay minerals

Acta Geochimica 2019年第6期38卷 863-871页

作者： mohamed E.A.El-Sayed moustafa m.R.Khalaf james A.Rice Department of Chemistry and Biochemistry South Dakota State UniversityBrookingsSD 57007USA Soils Waterand Environmental Research InstituteAgriculture Research CenterEl-GizaEgypt Chemistry Department Faculty of ScienceMinia UniversityEl-Minia 61519Egypt

Humic acid(HA)can adsorb onto mineral surfaces,modifying the physicochemical properties of the ***,understanding the sorption behavior of HA onto mineral surfaces is of particular interest,since the fate and transport of many organic and inorganic contaminants are highly correlated to HA adsorbed onto clay *** to the extreme heterogeneity of HA,the extracted IHSS Leonardite humic acid(LHA)used in this work was fractionated using an ultrafiltration technique(UF)into different molecular size fractions(Fr1,>0.2μm;Fr2,0.2 pm-300,000 daltons;Fr3,300,000-50,000 daltons;Fr4,50,000-10,000 daltons;Fr5,10,000-1000 daltons).Equilibrium and the kinetics of LHA and fraction adsorption onto kaolinite and montmorillonite were *** results demonstrated that the maximum adsorption capacity of LHA,Frl,Fr2,Fr3,Fr4,and Fr5 was 5.99,13.69,10.29,7.02,5.9&and 5.09 on kaolinite while it was 8.29,22.62,13.17,8.91,8.62,and 5.69 on montmorillonite,*** adsorption equilibrium data showed that the adsorption behavior of LHA and its fractions could be described more practically by the Langmuir model than the Freundlich *** rate of humic acid fraction adsorption onto clays increased with decreasing molecular size fraction and increasing carboxylic group ***-first-and second-order models were used to assess the kinetic data and the rate *** results explained that LHA and its fractions adsorption on clay minerals conformed more to pseudosecondo rder.

关键词： Kaolinite montmorillonite Leonardite humic acid Humic acid fractions Kinetics Equilibrium

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Understanding the impact of disease and vaccine mechanisms on the importance of optimal vaccine allocation

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Infectious Disease modelling 2023年第2期8卷 539-550页

作者： Isobel R.Abell james m.mcCaw Christopher m.Baker School of mathematics and Statistics The University of MelbourneMelbourneAustralia melbourne Centre for Data Science The University of MelbourneMelbourneAustralia Centre for Epidemiology and Biostatistics Melbourne School of Population and Global HealthThe University of MelbourneMelbourneAustralia Peter Doherty Institute for Infection and Immunity The Royal Melbourne Hospital and the University of MelbourneMelbourneAustralia Centre of Excellence for Biosecurity Risk Analysis The University of MelbourneMelbourneAustralia

Vaccination is an important epidemic intervention ***,it is generally unclear how the outcomes of different vaccine strategies change depending on population characteristics,vaccine mechanisms and allocation *** this paper we develop a conceptual mathematical model to simulate strategies for pre-epidemic *** extend the SEIR model to incorporate a range of vaccine mechanisms and disease *** then compare the outcomes of optimal and suboptimal vaccination strategies for three public health objectives(total infections,total symptomatic infections and total deaths)using numerical *** comparison shows that the difference in outcomes between vaccinating optimally and suboptimally depends on vaccine mechanisms,disease characteristics,and objective *** modelling finds vaccines that impact transmission produce better outcomes as transmission is reduced for all *** vaccines that impact the likelihood of symptomatic disease or dying due to infection,the improvement in outcome as we decrease these variables is dependent on the strategy *** a principled model-based process,this work highlights the importance of designing effective vaccine allocation *** conclude that efficient allocation of resources can be just as crucial to the success of a vaccination strategy as the vaccine effectiveness and/or amount of vaccines available.

关键词： mathematical modelling Epidemiology

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The First Stegosaur (Dinosauria, Ornithischia) from the Upper Jurassic Shishugou Formation of Xinjiang, China

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Acta Geologica Sinica(English Edition) 2007年第3期81卷 351-356页

作者： JIA Chengkai Catherine A. FOSTER XU Xing james m. CLARK Institute of Vertebrate Paleontology Paleoanthropology Chinese Academy of Sciences Beijing 100044 China Research Institute of Exploration and Development Xinjiang Oilfield Company Karamay Xinjiang 834000 China Graduate University of the Chinese Academy of Sciences Beijing 100039 China Department of Anatomical Sciences Stony Brook University Stony Brook New York 11794 USA Department of Biological Sciences George Washington University Washington DC 20052 USA

A new stegosaur species, Jiangjunosaurusjunggarensis, gen. et sp. nov., is erected based on a specimen collected from the Upper Jurassic upper section of the Shishugou Formation in the Junggar Basin, Xinjiang, China. It represents the first stegosaur from the Jurassic of Xinjiang and increases the diversity of the dinosaur fauna in the Shishugou Formation. The new genus is characterized by symmetrical and proportionally wide tooth crowns, a sub-rectangular axial neural spine seen in lateral view, and large openings on the lateral surfaces of the cervical centra. A preliminary character analysis suggests that this new taxon is more derived than the middle Jurassic stegosaur Huayangosaurus but more primitive than most other known stegosaur species.

关键词： Dinosauria Stegosauria Upper Jurassic Shishugou Formation Xinjiang

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Rising tide: The global surge of type 2 diabetes in children and adolescents demands action now

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World Journal of Diabetes 2024年第5期15卷 797-809页

作者： Joseph m Pappachan Cornelius james Fernandez Ambika P Ashraf Department of Endocrinology and metabolism Lancashire Teaching Hospitals NHS TrustPreston PR29HTUnited Kingdom Faculty of Science Manchester Metropolitan UniversityManchester M156BHUnited Kingdom Faculty of Biology Medicine&HealthThe University of ManchesterManchester M139PLUnited Kingdom Department of Endocrinology&metabolism Pilgrim HospitalUnited Lincolnshire Hospitals NHS TrustBoston PE219QSUnited Kingdom Division of Pediatric Endocrinology and Diabetes Department of PediatricsUniversity of Alabama at BirminghamBirminghamAL 35233United States

Childhood-onset obesity has emerged as a major public healthcare challenge across the globe,fueled by an obesogenic environment and influenced by both genetic and epigenetic *** has led to an exponential rise in the incidence of type 2 diabetes mellitus in children and *** looming wave of diabetes-related complications in early adulthood is anticipated to strain the healthcare budgets in most *** there is a collective global effort to curb the devastation caused by the situation,the impact is poised to be pro-found.A multifaceted research effort,governmental legislation,and effective social action are crucial in attaining this *** article delves into the current epidemiological landscape,explores evidence concerning potential risks and consequences,delves into the pathobiology of childhood obesity,and discusses the latest evidence-based management strategies for diabesity.

关键词： Childhood obesity Diabesity Type 2 diabetes mellitus Adolescence Cardiovascular disease Pharmacotherapy

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modified model of Crack Tip Stress Field Considering Dislocation Slip Accumulation and Crack Tip Blunting

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Chinese Journal of mechanical Engineering 2023年第2期36卷 327-340页

作者： Jian Li Bing Yang Shuancheng Wang m.N.james Shoune Xiao Tao Zhu Guangwu Yang State Key Laboratory of Traction Power Southwest Jiaotong UniversityChengdu 610031China School of Engineering Computing&MathematicsUniversity of PlymouthPlymouth PL48AAEngland Department of mechanical Engineering Nelson Mandela UniversityPort Elizabeth 6001South Africa

This study uses the digital image correlation technique to measure the crack tip displacement field at various crack lengths in U71mnG rail steel,and the interpolated continuous displacement field was obtained by fitting with a back propagation(BP)neural *** slip and stacking of dislocations affect crack initiation and growth,leading to changes in the crack tip field and the fatigue characteristics of crack *** Christopher-james-Patterson(CJP)model describes the elastic stress field around a growing fatigue crack that experiences plasticity-induced *** the present work,this model is modified by including the effect of the dislocation field on the plastic zone of the crack tip and hence on the elastic field by introducing a plastic flow factorρ,which represents the amount of blunting of the crack *** Levenberg-marquardt(L-m)nonlinear least squares method was used to solve for the stress intensity *** verify the accuracy of this modified CJP model,the theoretical and experimental plastic zone errors before and after modification were compared,and the variation trends of the stress intensity factors and the plastic flow factorρwere *** results show that the CJP model,with the introduction ofρ,exhibits a good blunting *** the low plasticity state,the modified model can accurately describe the experimental plastic zone,and the modified stress intensity factors are more accurate,which proves the effectiveness of dislocation *** plastic flow correction provides a more accurate crack tip field model and improves the CJP crack growth relationship.

关键词： Digital image correlation Back propagation neural network Plastic zone CJP model Dislocation field

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migmatite-like textures in anthracite:Further evidence for low-grade metamorphic melting and resolidification in high-rank coals

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Geoscience Frontiers 2021年第3期12卷 428-436页

作者： james C.Hower Susan m.Rimmer maria mastalerz Nicola J.Wagner University of Kentucky Center for Applied Energy Research 2540 Research Park DriveLexingtonKY 40511USA School of Earth Systems and Sustainability Southern Illinois University CarbondaleCarbondaleIL 62901USA Indiana Geological&Water Survey Indiana UniversityBloomingtonIN 47405USA Department of Geology University of JohannesburgJohannesburgSouth Africa

Previous studies demonstrated that melting,initiated by supercritical fluids in the 375-400℃range,occurred as part of anthracite metamorphism in the Appalachian *** on the known behavior of vitrinite at high temperatures and,to a lesser extent,at high pressures,it was determined that the duration of the heating,melting,and resolidification event was about 1 *** the current study,featureless vitrinite within banded maceral assemblages demonstratesthe intimate association of melted and resolidified vitrinite with anthracite-rank *** analogy with metamorphosed inorganic rocks,such associations represent diadysites and embrechites,i.e.,cross-cutting and layered migmatites,*** though the temperature of formation of the anthracite structures is several hundred℃lower than that seen in metamorphosed inorganic rocks,anthracites are metamorphic rocks and the nomenclature for metamorphic rocks may be appropriate for coal.

关键词： Igneous metamorphic texture Pennsylvania mesozoic basins South Africa

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Biliary endoscopy in the management of primary sclerosing cholangitis and its complications

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Liver Research 2019年第2期3卷 106-117页

作者： Brian m.Fung james H.Tabibian University of California Los Angeles-Olive View Internal medicine Residency Program SylmarCAUSA Division of Gastroenterology Department of MedicineOlive View-University of California Los Angeles Medical CenterSylmarCAUSA

Primary sclerosing cholangitis(PSC)is a chronic,idiopathic,cholestatic liver disease characterized by inflammation and fibrosis of the intrahepatic and/or extrahepatic bile *** can affect individuals of all age groups and gender,has no established pharmacotherapy,and is associated with a variety of neoplastic(***)and non-neoplastic(*** strictures)hepatobiliary *** these considerations,endoscopy plays a major role in the care of patients with *** this review,we discuss and provide updates regarding endoscopic considerations in the management of hepatobiliary manifestations and complications of *** evidence is limited,we suggest pragmatic approaches based on currently available data and expert opinion.

关键词： Primary sclerosing cholangitis(PSC) Biliary tract disease Balloon dilation Cholangioscopy Dominant stricture Cholangiocarcinoma(CCA) Endoscopic retrograde cholangiopancreatography(ERCP)

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Usability Assessment of Steering Wheel Control Interfaces in motorsport

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Automotive Innovation 2020年第1期3卷 42-52页

作者： james W.H.Brown Neville A.Stanton Kirsten m.A.Revell University of Southampton SouthamptonUK

In order to assess the usability of steering wheel control interfaces in motorsport,it is necessary to employ a set of appropriate *** method selection process first involves identifying the relevant motorsport-based usability *** unique factors associated with context of use in motorsport are then *** are employed to synthesize a set of key performance indicators(KPIs)that require specific *** first KPI relates to error rates;these should be minimized,particularly under high cognitive load on the *** second KPI involves task times;these should be minimized not just to reduce distraction,but also to improve competitive *** third KPI states that usability should be optimized to minimize visual *** fourth KPI advocates the minimizing of interface task load to reduce the effect on the primary *** final KPI states that interface functionality should be easy to learn and *** KPIs provide clear goals to guide the identification of the most appropriate methods for each aspect of *** categories are devised and sets of appropriate methods selected based on the *** then combine into a toolset with an associated application process with the overall goal of providing a means by which motorsport interfaces may be both analysed and improved.

关键词： Usability motorsport Steering wheel Analysis Assessment

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Astaxanthin Accumulation in the Green Alga Haematococcus pluvialis： Effects of Cultivation Parameters

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Journal of Integrative Plant Biology 2007年第4期49卷 447-451页

作者： Ping He james Duncan james Barber Institute of Botany the Chinese Academy of Sciences Beijing 100093 China Division of molecular Biosciences Imperial College London London SW7 2AY UK Graduate School of Beijing Forestry University Beijing 100083 China

The green alga, Haematococcus pluvlalis Flotow is used as a source of the ketocarotenoid astaxanthin for application in fish aquaculture, pharmaceutical and cosmetic industries. Ceils of the green alga were induced by the application of different light and starvation conditions to evaluate the effect in astaxanthin accumulate. The conditions used for the Induction were high light intensity （170 μmol·m^-2·s^-1）, iron starvation, sulfur starvation and phosphate starvation. The results show that stresses applied in culture, which interfere with cell division, trigger the accumulation of astaxanthin. Notably, sulfur starvation results in a massive accumulation of this commercially important carotenoid.

关键词： astaxanthin Haematococcus pluvialis iron light phosphate stress sulfur.

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Trends and outcomes of transarterial chemoembolization in hepatocellular carcinoma:a national survey

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Hepatobiliary & Pancreatic Diseases International 2017年第6期16卷 624-630页

作者： Khalid mumtaz Nishi Patel Rohan m modi Vihang Patel Alice Hinton james Hanje Sylvester m Black Somashaker Krishna Division of Gastroenterology Hepatology and NutritionThe Ohio State University Wexner Medical Center Columbus OHUSA Department of Internal medicine The Ohio State University Wexner Medical Center Columbus OHUSA Department of Surgery The Ohio State University Wexner Medical Center Columbus OHUSA Division of Biostatistics College of Public Health The Ohio State University Columbus OH USA

BACKGROUND:Transarterial chemoembolization(TACE) is a palliative procedure frequently used in patients with advanced hepatocellular carcinoma(HCC). We examined the national inpatient trends of TACE and related outcomes in the United States over the last ***:We utilized the National Inpatient Sample(2002 to 2012) and performed trend analyses of TACE for HCC in all adult patients(age >18 years). multivariate analyses for the outcomes of in-hospital "procedure-related complications"(PRCs) and "post-procedure complications"(PPCs) were performed. We also compared early(2002 to 2006) and late(2007 to 2012) eras by multivariate analyses to identify predictors of complications, healthcare resource utilization and ***:Overall, 19058 patients underwent TACE for HCC where PRCs and PPCs were seen in 24.2% and 17.6% of patients, respectively. The overall trends in the use of TACE(Pmortality [adjusted Odds ratio(a OR):0.58; 95% CI:0.41, 0.82], reduced length of hospital stay(-1.87 days; 95% CI:-2.77,-0.97) and increased hospital charges($19232; 95% CI:11013, 27451) in the late era. Additionally, there was increased mortality(a OR:4.07; 95% CI:2.96, 5.59), PRCs(a OR:3.21; 95% CI:2.56, 4.02), and PPCs(a OR:2.70; 95% CI:2.11, 3.46) among patients with ***:There is an increasing trend of TACE utilization in HCC. However, the outcomes are worse in patients with coagulopathy. Although PRCs have increased, mortality has decreased in recent years. These findings should be considered during TACE evaluation in patients with HCC.

关键词： transarterial chemoembolization hepatocellular carcinoma procedural complications mortality

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