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Science China Chemistry 2010年第9期53卷 2070-2076页

作者： GOUTAUDIER Christelle TENU Richard COUNIOUX Jean-jacques Université de Lyon Université Claude Bernard Lyon 1Laboratoire Multimatériaux et Interfaces

It is very rare that a one-step process of extraction leads to the pure compound with a high degree of purity specified by an industrial *** various stages of a synthesis process and possible secondary reactions may lead to the synthesis of more or less complex and highly diluted *** this work,the rationale and strategy for extraction and purification of a high added value compound are *** the thinking is based on the knowledge and the exploitation of phase diagrams and then developed for different unit operations of the *** most significant research tools are the experimental data and the modelling of phase equilibrium to estimate the yield of each step of *** significant example chosen involves all the basic methods of phase separation,starting with liquid-vapour equilibrium:stripping of high volatility components and then more or less complex distillation are classically *** theoretical plateau number can be deduced from the equilibrium equation *** second step is based on the study of the liquid-liquid equilibrium and is an intermediate step for enrichment of the solution when distillation is not possible.A final step based on solid-liquid equilibrium consists of the selective crystallization of the pure product at low temperature,in order to satisfy the requirements of purity and safety imposed by industrial *** conclusion includes all isolation operations in the form of a general extraction and purification scheme.

关键词： phase diagram azeotropic distillation liquid-liquid extraction selective crystallization

Simultaneous determination of amino acids in different teas using supercritical fluid chromatography coupled with single quadrupole mass spectrometry

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Journal of Pharmaceutical Analysis 2019年第4期9卷 254-258页

作者： Yang Huang Tiejie Wang Marianne Fillet jacques Crommen Zhengjin Jiang Institute of Pharmaceutical Analysis College of Pharmacy Jinan University Guangzhou 510632 China Shenzhen Institute for Drug Control Shenzhen China Department of Pharmaceutics State Key Laboratory of Natural Medicines China Pharmaceutical University Nanjing China Laboratory for the Analysis of Medicine Department of Pharmaceutical Sciences CIRM University of Liege CHU B36 B-4000 Liege Belgium

Tea is a widely consumed beverage and has many important physiological properties and potential health benefits. In this study, a novel method based on supercritical fluid chromatography coupled with mass spectrometry (SFC-MS) was developed to simultaneously determine 11 amino acids in different types of tea (green teas, Oolong tea, black tea and Pu-erh tea). The separation conditions for the analysis of the selected amino acids including the column type, temperature and backpressure as well as the type of additive, were carefully optimized. The best separation of the 11 amino acids was obtained by adding water (5%, v/v) and trifluoroacetic acid (0.4%, v/v) to the organic modifier (methanol). Finally, the developed SFC-MS method was fully validated and successfully applied to the determination of these amino acids in six different tea samples. Good linearity (r ≥ 0.993), precision (RSDs≤ 2.99%), accuracy (91.95%-107.09%) as well as good sample stability were observed. The limits of detection ranged from 1.42 to 14.69 ng/mL, while the limits of quantification were between 4.53 and 47.0 ng/mL. The results indicate that the contents of the 11 amino acids in the six different tea samples are greatly influenced by the degree of fermentation. The proposed SFC-MS method shows a great potential for further investigation of tea varieties.

关键词： Amino acids Teas Supercritical fluid chromatography with single quadrupole mass spectrometry (SFCMS)

Importance, features and uses of metal oxide catalysts in heterogeneous catalysis

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Chinese Journal of Catalysis 2019年第11期40卷 1627-1636页

作者： jacques C. Védrine Sorbonne Université Laboratoire de réactivité de surface UMR-CNRS 7197 4 place Jussieu. F-75252 Paris France

This short review paper aims at assembling the present state of the art of the multiuses of metal oxides in heterogeneous catalysis, concerning liquid and gaseous phases of the reactant mixtures on solid catalysts. It includes the description of the main types of metal oxide catalysts, of their various preparation procedures and of the main reactions catalysed by them (acid-base type, selective and total oxidations, bi-functional catalysis, photocatalysis, biomass treatments, environmental catalysis and some of the numerous industrial applications). Challenges and prospectives are also discussed.

关键词： Heterogeneous catalysis Metal oxide catalyst Preparation procedure Acid-base reaction Selective and total oxidation reaction Photocatalysis Environmental catalysis Industrial process

Conic hyperspectral dispersion mapping applied to semiconductor plasmonics

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Light(Science & Applications) 2012年第1期1卷 48-55页

作者： Dominic Lepage Alvaro Jimenez jacques Beauvais Jan J Dubowski Department of Electrical and Computer Engineering Interdisciplinary Institute for Technological Innovation(3IT)Universite´de SherbrookeSherbrookeQue´.Canada

The surface plasmon resonance tracking over metal surfaces is a well-established,commercially available,biochemical quantification tool primarily applied in *** utilization of such a tool is,however,constrained to highly specialized industries,capable of justifying the human and instrumental resource investments required by the characterization *** have proposed to expand the field of application of this biosensing approach by redesigning this method through the integration and miniaturization within a semiconductor *** and broadband emission from a light-emitting semiconductor is employed to couple a continuum of surface plasmon modes over a metal–dielectric architecture interfaced with a GaAs–AlGaAs substrate.A tensor version of rigorous coupled wave theory is employed to optimize the various fabrication specifications and to predict the light scatterings over a wide range of *** then present a hyperspectral characterization microscope capable of directly mapping the dispersion relation of scattered light,including diffracted surface plasmons,as an intensity distribution versus photon energy and surface *** carried out in a buffered solution demonstrate the accurate description of the uncollimated and broadband surface plasmon ***,we introduce a simplified method of dispersion mapping,in which quasi-conic cross-sections of the light’s scattering can be acquired directly,thus monitoring surficial responses in as fast as 1.2 *** is over 300 times faster than required by implementing full dispersion *** compromising on the volume of collected information,this method,combined with the solid-state integration of the platform,shows great promise for the fast detection of biochemical agents.

关键词： biosensors light scattering optical devices semiconductors surface plasmon resonance

Differential Geochemical Features of Clinopyroxene from the Floodplain Sediments in Yangtze and Hanjiang Rivers and Its Implication for Detrital Source Identification

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Journal of Earth Science 2014年第4期25卷 638-647页

作者： Jian Yang Chang'an Li Yufen Zhang N'dji dit jacques Dembele Faculty of Earth Sciences China University of Geosciences Key Laboratory of Biogeology and Envirnmental Geology of Ministry of Educations China University of Geosciences Institute of Geophysics and Geomatics China University of Geosciences

The evolution history of the Yangtze River attracted increasing attention in recent years. Comparison of the properties of the floodplain sediments between the upper and lower reaches of the Three Gorges is of significance to identify the material detrital sources for the Yangtze River Basin. Clinopyroxene （Cpx） is the typical mineral widely distributed in the sediments of the Yangtze River Ba- sin. Cpx was extracted from the fine sediments with the grain size ranging from 0.063 to 0.125 mm in the upper and lower reaches of the Three Gorges. The sediments, from which the Cpx was extracted, were taken from the floodplains of the catchments of both the Yangtze River and the Hanjiang River, as well as from the surface of the Zhoulao Core drilled in the center of the Jianghan Basin where the two rivers flow through. Geochemistry of these Cpx was investigated, concerning the contents of major elements measured by electron probe microanalysis （EPMA） and the contents of trace elements analyzed by laser ablation inductively coupled plasma-mass spectrometry （LA-ICP-MS）. The Cpx in the Yangtze River contains titaniferous augite which is sourced from the Panzhihua-Xichang region in South Sichuan Province, whereas the Cpx in the Hanjiang River is mainly from the surroundings without any titanif- erous augite. The REE analysis infers that the titaniferous augite is the diagnostic mineral of the upper Yangtze River, and thus could be used as a tracer mineral to identify the detrital sources for the sedi- ments formed during the evolution of the Yangtze River. The Cpx from the surface sediments of the Jianghan Plain （Zhoulao Core） shows comparable geochemical nature with that of the Yangtze River, but is different in geochemistry from that of the Hanjiang River, implying that the modern sediments in the Jianghan Plain are mainly sourced from the upper Yangtze River.

关键词： provenance Yangtze River Hanjiang River clinopyroxene EPMA LA-ICP-MS geochemistry.

Incipient charnockites from southern India:The role of brines

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Geoscience Frontiers 2019年第5期10卷 1789-1801页

作者： jacques L.R. Touret Robert C. Newton Michel Cuney 121 Rue de la Réunion F-75020ParisFrance Department of Earth Planetary and Space SciencesUCLALos AngelesCAUSA Université de Lorraine CNRS-CREGUGeoRessources BP70239F-54506Vandoeuvre-les-Nancy CedexFrance

Southern India and Sri-Lanka are the places where “incipient charnockites”,*** local transformation of amphibolite-facies gneisses into orthopyroxene-bearing,igneous looking charnockites,have been discovered in the early *** fact that some incipient charnockites occur along a network of brittle fractures,together with CO2 remnants preserved in mineral inclusions,had called for the role of fluids during charnockite *** present work presents new observations on fluid inclusions and microtextures of incipient charnockites from type localities in southern *** addition to CO2-rich fluid inclusions in quartz and feldspar,all of the occurrences have disrupted remnants of concentrated aqueous alkali chloride ***2 inclusions are more abundant in paragneiss (Kerala) than in orthogneiss (Karnataka/Tamil Nadu).The finding of disrupted brine inclusions in the Kabbal charnockite is a key link between closely associated massive charnockites and Closepet Granite,both of which also share the brine *** of the occurrences studied here have feldspar or feldspar-quartz microvein networks along grain boundaries of recrystallized quartz,feldspar and *** metasomatic veins again indicate the action of alkali-exchanging fluids (i.e.,saline solutions).Feldspar microveins,which have been found in most “massive” charnockites,along with the CO2-rich fluid inclusions,suggest a commonality of incipient charnockite and massive charnockite,both types differing in intensity of interaction with metasomatizing pore fluids.

关键词： Incipient charnockite High-grade crustal metamorphism CO2 Brine metasomatism

Complex upper extremity injuries:targeted muscle reinnervation,free functional muscle transfer,and vascularized composite allotransplantation

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Plastic and Aesthetic Research 2022年第1期9卷 14-21页

作者： Jonathan Bekisz jacques H.Hacquebord Hansjörg Wyss Department of Plastic Surgery New York University Langone HealthNew YorkNY 10016USA Department of Orthopedic Surgery/Hansjörg Wyss Department of Plastic Surgery New York University Langone HealthNew YorkNY 10016USA.

Restoration of upper extremity function poses a unique surgical *** considerations ranging from ensuring appropriate skeletal support and musculotendinous and ligamentous anatomy,restoring adequate vascularity and innervation,and providing sufficient soft tissue coverage,upper extremity injuries present a diverse range of reconstructive *** history has been marked by an expansion of novel techniques for addressing these complex *** modalities,such as targeted muscle reinnervation,free functional muscle transfer,and vascularized composite allotransplantation,have become some of the most powerful tools in the armamentarium of the reconstructive *** review article aims to define the distinguishing features of each of these modalities and reviews some of their unique advantages and limitations.

关键词： Targeted muscle reinnervation free functional muscle transfer vascularized composite allotransplantation

Fluid-rock interaction in retrograde granulites of the Southern Marginal Zone,Limpopo high grade terrain,South Africa

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Geoscience Frontiers 2014年第5期5卷 673-682页

作者： Jan Marten Huizenga Dirk van Reenen jacques L.R.Touret Unit of Environmental Sciences and Management North-West UniversityPrivate Bag X60012520South Africa Economic Geology Research Institute(EGRU) School of Earth and Environmental SciencesJames Cook UniversityTownsvilleQLD 4811Australia Department of Geology University of JohannesburgJohannesburgSouth Africa Institut de Mineralogie.de Physique des Materiaux et de Cosmochimie(IMPMC) Sorbonne Universites UPMC Univ Paris 06UMR CNRS 7590 Museum National d'Histoire Naturelle.IRD UMR 206.4 Place Jussieu.F-75005

Fluid infiltration into retrograde granulites of the Southern Marginal Zone （Limpopo high grade terrain） is exemplified by hydration reactions, shear zone hosted metasomatism, and lode gold mineralisation. Hydration reactions include the breakdown of cordierite and orthopyroxene to gedrite ＋ kyanite, and anthophyllite, respectively. Metamorphic petrology, fluid inclusions, and field data indicate that a low H2O-activity carbon-saturated CO2-rich and a saline aqueous fluid infiltrated the Southern Marginal Zone during exhumation. The formation of anthophyllite after orthopyroxene established a regional retrograde anthophyllite-in isograd and occurred at P-Tconditions of -6 kbar and 610 ℃, which fixes the minimum mole fraction of H20 in the CO2-rich fluid phase at ~ 0.1. The maximum H20 mole fraction is fixed by the lower temperature limit （~800 ℃） for partial melting at -0.3. C-O-H fluid calculations show that the CO2-rich fluid had an oxygen fugacity that was 0.6 log10 units higher than that of the fayalite-magnetite- quartz buffer and that the CO2/（CO2＋CH4） mole ratio of this fluid was 1. The presence of dominantly relatively low density CO2-rich fluid inclusions in the hydrated granulites indicates that the fluid pressure was less than the lithostatic pressure. This can be explained by strike slip faulting and/or an increase of the rock permeability caused by hydration reactions.

关键词： GranuliteFluidLimpopoRetrogradeSouthern Marginal Zone

Real-time detection of influenza A virus using semiconductor nanophotonics

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Light(Science & Applications) 2013年第1期2卷 184-191页

作者： Dominic Lepage Alvaro Jimenez jacques Beauvais Jan J Dubowski Laboratory for Quantum Semiconductors and Photon-based BioNanotechnology Interdisciplinary Institute for Technological Innovation(3IT)Department of Electrical and Computer EngineeringUniversite´de SherbrookeSherbrookeQC J1K 2R1Canada

Modern miniaturization and the digitalization of characterization instruments greatly facilitate the diffusion of technological advances in new fields and generate innovative *** concept of a portable,inexpensive and semi-automated biosensing platform,or lab-on-a-chip,is a vision shared by many researchers and venture *** this scope,we present a semiconductor monolithic integration approach to conduct surface plasmon resonance *** technology is already commonly used for biochemical characterization in pharmaceutical industries,but we have reduced the technological platform to a few nanometers in scale on a semiconductor *** evaluate the signal quality of this nanophotonic device using hyperspectral-imaging technology,and we compare its performance with that of a standard prism-based commercial *** standard biochemical agents are employed for this characterization study:bovine serum albumin and inactivated influenza A *** resolutions of data acquisition varying between 360 and 2.2 s are presented,yielding 2.731025–1.531026 RIU resolutions,respectively.

关键词： GaAs/AlGaAs quantum well device hyperspectral imaging technology influenza A virus integrated surface plasmon resonance biosensor

Model-independent constraints on spin observables

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Chinese Physics C 2009年第12期33卷 1153-1158页

作者： Jean-Marc Richard Xavier Artru Mokhtar Elchikh jacques Soffer Oleg Teryaev LPSC Université Joseph Fourier CNRS/IN2P3 INPG Grenoble France Université de Lyon IPNL Université Lyon 1 and CNRS/IN2P3 Villeurbanne France Université des Sciences et de Technologie d'Oran El Menauoer Oran Algeria Physics Department Temple University Philadelphia PA 19122 -6082 USA Bogoliubov Laboratory of Theoretical Physics JINR 141980 Dubna Russia

We discuss model-independent constraints on spin observables in exclusive and inclusive reactions, with special attention to the case of photoproduction.

关键词： spin observables positivity exclusive reactions inclusive reactions