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Green Energy & Environment 2024年第10期9卷 1489-1496页

作者： Wenhao Jing zihao jiao Mengmeng Song Ya Liu Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi'an Jiaotong UniversityShaanxi710049Xi'anChina Department of Energy and Power Engineering Shandong University of TechnologyZibo255000ShandongChina

Machine learning combined with density functional theory(DFT)enables rapid exploration of catalyst descriptors space such as adsorption energy,facilitating rapid and effective catalyst ***,there is still a lack of models for predicting adsorption energies on oxides,due to the complexity of elemental species and the ambiguous coordination *** work proposes an active learning workflow(LeNN)founded on local electronic transfer features(e)and the principle of coordinate rotation *** accurately characterizing the electron transfer to adsorption site atoms and their surrounding geometric structures,LeNN mitigates abrupt feature changes due to different element types and clarifies coordination *** a result,it enables the prediction of^(*)H adsorption energy on binary oxide surfaces with a mean absolute error(MAE)below 0.18 ***,we incorporate local coverage(θ_(l))and leverage neutral network ensemble to establish an active learning workflow,attaining a prediction MAE below 0.2 eV for 5419 multi-^(*)H adsorption *** findings validate the universality and capability of the proposed features in predicting^(*)H adsorption energy on binary oxide surfaces.

关键词： Machine learning Adsorption energy Binary oxide Electron transfer Active learning

A 16-bit, ±10-V Input Range SAR ADC with a 5-V Supply Voltage and Mixed-Signal Nonlinearity Calibration

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Chinese Journal of Electronics 2022年第4期31卷 690-697页

作者： LUO Hongrui ZHAO Xianlong jiao zihao ZHANG Jie WANG Xiaofei ZHANG Ruizhi ZHANG Hong School of Microelectronics Xi'an Jiaotong University Beijing Smartchip Microelectronics Company Limited

This paper presents a high-precision, successive approximation register(SAR) analog-to-digital converter(ADC) with resistive analog front-end for lowvoltage and wide input range applications. To suppress the serious nonlinearity brought by the voltage coefficients of analog front-end without deteriorating differential nonlinearity performance, a mixed-signal calibration scheme based on piecewise-linear method with calibration digital-to-analog converter is proposed. A compensation current is designed to sink or source from the reference to keep it independent of input signal, which greatly improves the linearity performance. Fabricated in a 0.5-μm CMOS process, the proposed ADC achieves 88-d B signalto-noise-and-distortion ratio and 103-d B spurious free dynamic range with 5-V supply voltage and 2.5-V reference voltage, and the total power consumption is 37.5 m W.

关键词： Wide input range Resistive scaling front-end Mixed-signal nonlinearity calibration Precision Successive approximation register (SAR) Current compensation circuit

Photochemical Systems for Solar‑to‑Fuel Production

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Electrochemical Energy Reviews 2022年第3期5卷 137-177页

作者： Ya Liu Feng Wang zihao jiao Shengjie Bai Haoran Qiu Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049ShaanxiChina

The photochemical system,which utilizes only solar energy and H_(2)O/CO_(2) to produce hydrogen/carbon-based fuels,is considered a promising approach to reduce CO_(2) emissions and achieve the goal of carbon *** date,numerous photochemical systems have been developed to obtain a viable solar-to-fuel production system with sufficient energy ***,more effort is still needed to meet the requirements of industrial *** this review,we systematically discuss a typical photochemical system for solar-to-fuel production,from classical theories and fundamental mechanisms to raw material selection,reaction condition optimization,and unit device/system advancement,from the viewpoint of ordered energy ***-of-the-art photochemical systems,including photocatalytic,photovoltaic-electrochemical,photoelectrochemical,solar thermochemical,and other emerging systems,are *** highlight the existing bottlenecks and discuss the developing trend of this ***,optimization strategies and new opportunities are proposed to enhance photochemical systems with higher energy efficiency.

关键词： Solar energy Photochemical Hydrogen Carbon-based fuels

Synergistic effect of oxygen species and vacancy for enhanced electrochemical CO_(2) conversion to formate on indium oxide

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eScience 2024年第3期4卷 134-141页

作者： Tengfei Ma zihao jiao Haoran Qiu Feng Wang Ya Liu Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi'an Jiaotong UniversityXi'an 710049China

Indium-based oxides are promising electrocatalysts for producing formate via CO_(2) reduction reaction,in which*OCHO is considered the key ***,we identified that the*COOH pathway could be preferential to produce formate on In_(2)O_(3)of In/In_(2)O_(3) heterojunction due to the synergistic effect of oxygen species and ***,*CO_(2) and *COOH were observed on In_(2)O_(3) and related to formate production by in situ Raman *** theoretical calculations further demonstrated that the energy barrier of the*COOH formation on In_(2)O_(3) was decreased in the presence of oxygen vacancy,similar to or lower than that of the*OCHO formation on the In *** a result,a formate selectivity of over 90%was obtained on prepared In/In_(2)O_(3) heterojunction with 343±7mAcm^(-2) partial current ***,when using a Si-based photovoltaic as an energy supplier,10.11%solar-to-fuel energy efficiency was achieved.

关键词： Electrocatalytic CO_(2)reduction Formate In_(2)O_(3) Oxygen species Oxygen vacancy

Technological innovations on direct carbon mitigation by ordered energy conversion and full resource utilization

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Carbon Neutrality 2022年第1期1卷 598-619页

作者： Liejin Guo Zhisong Ou Ya Liu Zhiwei Ge Hui Jin Guobiao Ou Mengmeng Song zihao jiao Wenhao Jing State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityNo.28Xianning West RoadXi’an 710049People’s Republic of China

Coal consumption leads to over 15 billion tons of global CO_(2) emissions annually,which will continue at a considerable intensity in the foreseeable *** remove the huge amount of CO_(2),a practically feasible way of direct carbon mitigation,instead of capturing that from dilute tail gases,should be developed;as intended,we developed two innovative supporting technologies,of which the status,strengths,applications,and perspective are discussed in this *** is supercritical water gasification-based coal/biomass utilization technology,which orderly converts chemical energy of coal and low-grade heat into hydrogen energy,and can achieve poly-generation of steam,heat,hydrogen,power,pure CO_(2),and *** other one is the renewables-powered CO_(2) reduction techniques,which uses CO_(2) as the resource for carbon-based fuel *** combining the above two technical loops,one can achieve a full resource utilization and zero CO_(2) emission,making it a practically feasible way for China and global countries to achieve carbon neutrality while creating substantial domestic benefits of economic growth,competitiveness,well-beings,and new industries.

关键词： Carbon neutrality Coal utilization Direct carbon mitigation Supercritical water gasification Renewable energy CO_(2)reduction

采用电荷平衡模数转换器的高精度CMOS温度传感器

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西安交通大学学报 2018年第10期52卷 124-131页

作者：陈阳张瑞智金锴焦子豪张鸿西安交通大学微电子学院西安710049

针对传统CMOS温度传感器芯片精度低,功耗高和温度范围窄的问题,提出了一种采用电荷平衡模数转换器(ADC)的高精度CMOS温度传感器。为了避免使用高精度带隙基准源,传感器中基于寄生双极晶体管的温度感知电路分别产生与温度成正比和反比的... 详细信息

针对传统CMOS温度传感器芯片精度低,功耗高和温度范围窄的问题,提出了一种采用电荷平衡模数转换器(ADC)的高精度CMOS温度传感器。为了避免使用高精度带隙基准源,传感器中基于寄生双极晶体管的温度感知电路分别产生与温度成正比和反比的两个电压,再用一个电荷平衡ADC对这两个电压交替量化,得到与实时温度对应的数字量;工艺波动引起的感知误差采用一个外置基准电压来校准;整个温度传感器电路采用0.18μm CMOS工艺设计。仿真结果表明:在-40～125℃的温度范围内,传感器的测量精度可达±0.2℃,完成一次测量的时间仅为42ms,工作电流为130μA,芯片版图面积为0.55mm^2。该温度传感器可应用在植入式医疗、射频标签和物联网等系统中实现对温度的高精度测量。

关键词：温度传感器高精度低功耗宽测量范围

用于高速模数转换器的非对称全差分参考电压缓冲器

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西安交通大学学报 2020年第5期54卷 109-116页

作者：焦子豪张瑞智金锴盛炜张鸿西安交通大学微电子学院西安710049 中国电子科技集团公司第五十八研究所江苏无锡214000

针对现有高速高精度模数转换器(ADC)芯片内部参考电压缓冲器需要牺牲很大功耗来满足精度和速度要求的问题,提出了一种具有非对称AB类输出级的全差分参考电压缓冲器,能够以较低的运放增益满足缓冲器高精度的需求,从而显著降低缓冲器的功... 详细信息

针对现有高速高精度模数转换器(ADC)芯片内部参考电压缓冲器需要牺牲很大功耗来满足精度和速度要求的问题,提出了一种具有非对称AB类输出级的全差分参考电压缓冲器,能够以较低的运放增益满足缓冲器高精度的需求,从而显著降低缓冲器的功耗。通过引入非对称的输出结构,参考电压缓冲器只需要满足高带宽,不再需要较高的开环增益;输入级采用互补结构进一步降低了功耗;为了消除传统结构所引入的高阻节点,提出了低输出阻抗的AB类驱动电路,提高了带宽。仿真结果表明,在负载为20 pF的片内滤波电容的情况下,参考电压缓冲器的功耗为27 mW,建立时间小于2.5 ns,与相近性能的电路相比,所提电路的功耗更低。其中运放的单位增益带宽为602 MHz,相位裕度为61°。所提出的参考电压缓冲器应用于一款双通道14位200 MHz的流水线ADC中,测试结果表明,ADC的信号噪声失真比达到73 dB,所提出的电路结构能以较低的功耗实现较高的精度和速度。

关键词：高速模数转换器参考电压缓冲器 AB类放大器非对称输出

不确定需求下基于分布式鲁棒机会约束的车辆调度问题研究

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系统工程理论与实践 2018年第7期38卷 1792-1801页

作者：冉伦吴东来焦子豪王珊珊袁书宁北京理工大学管理与经济学院

随着新能源汽车共享模式的迅速发展,允许异地还车导致车辆不均衡问题日益突出.本文考虑不确定的车辆需求,基于需求量的均值和方差等部分信息,最小化最坏情况下系统可用车辆和空闲停车位的机会约束,建立分布式鲁棒优化机会约束车辆调度模... 详细信息

随着新能源汽车共享模式的迅速发展,允许异地还车导致车辆不均衡问题日益突出.本文考虑不确定的车辆需求,基于需求量的均值和方差等部分信息,最小化最坏情况下系统可用车辆和空闲停车位的机会约束,建立分布式鲁棒优化机会约束车辆调度模型,以总成本最小化为目标,得出模型的数学性质和易求解的等价形式,确定停车桩之间的车辆调度数量.最后,以北京市15个停车桩的车辆调度为例,确定最优的车辆调度方案.结果表明,随着服务水平的增加,调度成本和车辆调度数量增加明显,当服务水平增加到一定程度后,应增加系统的车辆数和停车位以满足服务水平的要求.决策者可根据自己的偏好及系统的服务要求,选择恰当的服务水平参数组合,以获得最优的车辆调度方案.

关键词：车辆调度分布式鲁棒机会约束需求不确定

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降黄曲霉毒素B_1菌株发酵条件的研究

食品科学 2009年第13期30卷 157-162页

作者：李俊霞焦自好王斐关舒牛天贵梁志宏中国农业大学食品科学与营养工程学院北京100083 中国农业大学动物科技学院北京100094

对黄曲霉毒素B1(AFB1)降解菌株NMO-3进行发酵培养基和培养条件优化,以期提高AFB1降解率。方法:研究不同碳源、氮源、金属离子对AFB1降解率的影响,最后选出最佳碳源、氮源和金属离子,通过正交回归试验,最后得出三者配方比。培养条件研究... 详细信息

对黄曲霉毒素B1(AFB1)降解菌株NMO-3进行发酵培养基和培养条件优化,以期提高AFB1降解率。方法:研究不同碳源、氮源、金属离子对AFB1降解率的影响,最后选出最佳碳源、氮源和金属离子,通过正交回归试验,最后得出三者配方比。培养条件研究主要包括:初始pH值、接种量、温度、种龄和降解时间等因素。结果:最终确定优化发酵培养基配方:果糖1.0%、胰蛋白胨1.0%、MgCl2 0.05mmol/L、其他发酵条件:起始pH值为7.5、装液量25ml/300ml、接种量5%(V/V)、种子液培养时间为12h、控制降解温度为35℃、摇床转速140r/min、降解时间为72h。结论:经培养基成分和发酵参数的优化,AFB1的降解率达到94.29%。

关键词：黄曲霉毒素B1 发酵培养基发酵条件优化

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一种16位高精度分段式电阻型DAC设计

微电子学 2022年第4期52卷 608-613页

作者：张皓然焦子豪盛炜章宇新曹燕杰陈旻琦中国电子科技集团公司第五十八研究所江苏无锡214000 西安交通大学微电子学院西安710049

采用0.5μm BCD工艺,设计了一种16位分段式电阻型高精度DAC。根据集成电路工艺中电阻的一般失配特性,确定电阻型DAC采用“4+12”的分段结构,分别为高位温度计码结构和低位二进制码结构。整个电路中的电阻类型均采用高阻型电阻,减小了DA... 详细信息

采用0.5μm BCD工艺,设计了一种16位分段式电阻型高精度DAC。根据集成电路工艺中电阻的一般失配特性,确定电阻型DAC采用“4+12”的分段结构,分别为高位温度计码结构和低位二进制码结构。整个电路中的电阻类型均采用高阻型电阻,减小了DAC开关结构中的失配,极大降低了整体功耗。电路结构紧凑,整体面积小,仅有2.3976 mm^(2)。结合后仿真结果,对版图进行合理调整,使电路具有较低的微分非线性(DNL),之后采用校正结构,进一步降低DNL。电路测试结果表明,输入数字信号为10 kHz的正弦波时,DAC的无杂散动态范围(SFDR)为57.72 dB,DNL为0.5 LSB,积分非线性(INL)为1 LSB,功耗为1.5 mW。

关键词：分段式电阻型DAC 温度计码二进制码无杂散动态范围校准模块