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Chinese Journal of Structural Chemistry 2006年第6期25卷 735-739页

作者： GAO Dong-Zhao LI Li-Cun LIAO Dai-Zheng jiang zong-hui YAN Shi-Ping Department of Chemistry Nankai University Tianjin 300071 China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou 350002 China

A new one-dimensional （1-D） Zn（Ⅱ） nitronyl nitroxide complex bridged by pyridine-2,4-dicarboxylate anion, [Zn（NIT4Py）（2,4-PDA）（H2O）2], （NIT4Py = 2-（4′-pyridyl）-4,4,5,5- tetramethylimidazoline-1-oxyl-3-oxide and 2,4-PDA = pyridine-2,4-dicarboxylate anion）, has been synthesized and structurally characterized by X-ray diffraction. It crystallizes in monoclinic, space group P21/c with a = 16.834（2）, b = 7.4376（10）, c = 18.295（3） A, β = 102.848（2）°, V = 2233.2（5） A^3, C19H23N4O3Zn, Mr = 500.78, Dc = 1.489 g/cm^3,μ（MoKa） = 1.152 mm^-1, F（000） = 1036, Z = 4, the final R = 0.0390 and wR = 0.0915 for 3234 observed reflections. In the complex, each zinc（Ⅱ） ion is six-coordinated by one nitrogen atom of the radical ligand （NIT4Py）, one nitrogen atom and two oxygen atoms of two 2,4-PDA anions and two oxygen atoms of two water molecules. Each 2,4-PDA anion bridges two Zn（Ⅱ） ions via a tridentate mode into a 1-D chain, and these 1-D chains are further linked into a 2-D network via hydrogen-bonding interactions.

关键词： zinc(Ⅱ) complex nitronyl nitroxide radical crystal structure pyridine-2,4-dicarboxylic acid

Synthesis and Magnetism of the Complexes of Hexaisothiocyanatochromate Anions with Radical Cations

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Chemical Research in Chinese Universities 1999年第1期15卷 78-80页

作者： LIU Xin LIAO Dai zheng jiang zong hui YAN Shi ping WANG Geng lin Department of Chemistry Nankai UniversityTianjin300071

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关键词： Synthesis Magnetism Hexaisothiocyanatochromate anion

Synthesis and Crystal Structure of a 1-D Coordination Polymer {[Cu(NIT4py)_2(ip)]·6H_2O}_n

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Chinese Journal of Structural Chemistry 2006年第2期25卷 214-218页

作者： WANG Shu-Ping GAO Dong-Zhao LIAO Dai-Zheng jiang zong-hui YAN Shi-Ping LI Li-Cun Department of Chemistry Nankai University Tianjin 300071 China State Key Laboratory of Structural Chemistry Fujian Instituteof Research on the Structure of MatterThe Chinese Academy of Sciences Fuzhou 350002 China

A new complex { [Cu（NIT4py）2（ip）]·6H2O }, （NIT4py=2-（4＂-pyridinyl）-4,4,5,5-tetra methylimidazoline-1-oxyl-3-oxide and ip = isophthalate dianion） has been synthesized and structurally characterized by X-ray diffraction. It crystallizes in orthorhombic, space group Cmcm with a = 25.161（3）, b =10.045（1）, c = 15.450（2） A°, C32H48N6O14CU, Mr = 804.30, V= 3904.8（8） ,A°^3, Z = 4, De = 1.368 g/cm^3, μ（MoKa） = 0.630 mm^-1, F（000） = 1692, the final R = 0.0326 and wR = 0.0787 for 1843 independent reflections with Rint = 0.0372. Each Cu（Ⅱ） ion is four-coordinated by two carboxylate oxygen atoms and two pyridyl-N atoms from NIT4py radicals to furnish a rhombus geometry. The central Cu（Ⅱ） ion is located at an inversion center and a crystallographic two-fold axis. Each isophthalate dianion binds two Cu（Ⅱ） ions in bis-monodentate mode, leading to a 1-D chain, a＇ these 1-D chains are further linked into a 2-D network via hydrogen-bonding interactions.

关键词： crystal structure nitronyl nitroxide radical copper(Ⅱ) coordination polymer isophthalate

Synthesis and One-dimensional Structure of Cobalt(Ⅱ) Complex [(NaOC_2H_5)CoL_2]_n

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Chemical Research in Chinese Universities 2003年第4期19卷 379-382页

作者： LI Ling GU Wen YAN Shi-ping CHENG Peng LIAO Dai-zheng jiang zong-hui SHEN Pan-wen Department of Chemistry Nankai UniversityTianjin 300071P.R.China

The treatment of bis(2-hydroxybenzyl)-amine(HL) with NaOH and Co(Ⅱ)(NO) 2 gives isostructural one-dimensional coordination polymers [(NaOC2H5)CoL2]n(1). The cobalt ions have an octahedral geometry and are coordinated by two crystallographically independent ligands which are further linked by μ -O\-\{phenol\} bridged Co and Na atoms to give a one-dimentional structure.

关键词： Crystal structure Sodium Cobalt complex One\|dimension Bis(2-hydroxybenzyl)amine

Synthesis, Crystal Structure and Optical Properties of a New Nd(III) Nitronyl Nitroxide Complex [Nd(NIT2Py)_2(NO_3)_3]

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Chinese Journal of Structural Chemistry 2005年第8期24卷 905-908页

作者： LI Dong-Jiao GAO Dong-Zhao LI Li-Cun LIAO Dai-Zheng jiang zong-hui YAN Shi-Ping Department of Chemistry Nankai University ChinaTianjin 300071 State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences ChinaFuzhou Fujian 350002

A new Nd（Ⅲ） nitronyl nitroxide complex [Nd（NIT2Py）2（NO3）3] （NIT2Py = 2-（2＇-pyridyl）-4,4,5,5-tetramethylimidazoline-l-oxyl-3-oxide） has been synthesized and structurally characterized by X-ray diffraction. It crystallizes in monoclinic, space group P21/n with a = 12.396（4）, b =11.134（4）, c = 23.360（7） A°, β = 98.178（6）°, V= 3191.2（18） A°^3, C24H32N9NdO13, Mr = 798.83, Dc =1.663 g/cm^3, μ（MoKa） = 1.704 mm^-1, F（000） = 1612, Z = 4, the final R = 0.0425 and wR = 0.0957 for 6532 independentreflections with Rint = 0.0642 and 4552 observed reflections （I 〉 2σ（I））. The complex exists as discrete mononuclear molecules and the neodymium（Ⅲ） ion is ten-coordinated with three bidentate nitrate anions and two radical ligands （NIT2Py） via bidentate chelating *** optical properties of the complex are discussed.

关键词： neodymium(Ⅲ)complex nitronyl nitroxide radical crystal structure optical properties

Synthesis and Crystal Structure of a New Zn(II) Nitronyl Nitroxide Complex [Zn(NIT4Py)(PDA)(H_2O)_3]

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Chinese Journal of Structural Chemistry 2006年第2期25卷 224-228页

作者： GAO Dong-Zhao WANG Shu-Ping CHEN Jin LI Li-Cun LIAO Dai-Zheng jiang zong-hui YAN Shi-Ping Department of Chemistry Nankai University Tianjin 300071 China State Key Laboratory of Structural Chemistry Fujian Institute of Researchon the Structure of Matter The Chinese Academy of Sciences Fuzhou 350002 China

A new Zn（Ⅱ） nitronyl nitroxide complex [Zn（NIT4Py）（PDA）（HzO）3] （NIT4Py = 2-（4＇-pyridyl）-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, H2PDA = pyridine-2,5-dicarboxylic acid） has been synthesized and structurally characterized by X-ray diffraction. It crystallizes in monoclinic, space group P2 1/c with a = 16.881（8）, b = 7.356（4）, c = 18.857（9） A°,β = 108.616（6）°, V = 2219.1 （19）A°^3 ,C 19H25N4O9Zn, Mr = 518.80, Dc = 1.553 g/cm^3, μ（MoKa） = 1.165 mm^-1, F（000） = 1076, Z = 4, the final R = 0.0269 and wR = 0.0715 for 3193 observed reflections with I 〉 2σ（I）. The complex exists as discrete mononuclear molecules and the zinc（Ⅱ） ion is six-coordinated with one radical ligand （NIT4Py）, one bidentate pyridine-2,5-dicarboxylate anion and three water molecules. A three-dimensional network structure is formed through the intermolecular interactions.

关键词： zinc(Ⅱ) complex nitronyl nitroxide radical crystal structure intermolecularinteraction

Development and validation of a new prognostic model for patients with acute-on-chronic liver failure in intensive care unit

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World Journal of Gastroenterology 2024年第20期30卷 2657-2676页

作者： zong-Yi Zhu Xiu-Hong Huang hui-Qing jiang Li Liu Department of Gastroenterology The Second Hospital of Hebei Medical UniversityShijiazhuang 050000Hebei ProvinceChina Department of Gastroenterology Weixian People's HospitalXingtai 054700Hebei ProvinceChina

BACKGROUND Cirrhotic patients with acute-on-chronic liver failure(ACLF)in the intensive care unit(ICU)have a poor but variable *** prognosis evaluation can guide the rational management of patients with ***,existing prognostic scores for ACLF in the ICU environment lack sufficient *** To develop a new prognostic model for patients with ACLF in *** Data from 938 ACLF patients in the Medical Information Mart for Intensive Care(MIMIC)database were used to develop a new prognostic model(MIMIC ACLF)for ***,calibration and clinical utility of MIMIC ACLF were assessed by area under receiver operating characteristic curve(AUROC),calibration curve and decision curve analysis(DCA),*** ACLF was then externally validated in a multiple-center cohort,the Electronic Intensive Care Collaborative Research Database and a single-center cohort from the Second Hospital of Hebei Medical University in *** The MIMIC ACLF score was determined using nine variables:ln(age)×2.2+ln(white blood cell count)×0.22-ln(mean arterial pressure)×2.7+respiratory failure×0.6+renal failure×0.51+cerebral failure×0.31+ln(total bilirubin)×0.44+ln(internationalized normal ratio)×0.59+ln(serum potassium)×*** MIMIC cohort,the AUROC(0.81/0.79)for MIMIC ACLF for 28/90-day ACLF mortality were significantly greater than those of Chronic Liver Failure Consortium ACLF(0.76/0.74),Model for End-stage Liver Disease(MELD;0.73/0.71)and MELD-Na(0.72/0.70)(all P<0.001).The consistency between actual and predicted 28/90-day survival rates of patients according to MIMIC ACLF score was excellent and superior to that of existing *** net benefit of MIMIC ACLF was greater than that achieved using existing scores within the 50%threshold *** superior predictive accuracy and clinical utility of MIMIC ACLF were validated in the external *** We developed and validated a new prognostic model with satisfactory accuracy

关键词： Acute-on-chronic liver failure Cirrhosis Risk stratification Prognosis Model Scores

Synthesis and magnetism of rare earth (Nd,Gd,Dy,Ho,Er,Y) pentafluoropropionate binuclear complexes with 2-(4'-methoxy-phenyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide

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Chinese Journal of Chemistry 1995年第5期13卷 423-428页

作者： jiang, zong-hui ZHANG, Wei LIAO, Dai-Zheng HUAN, Zhen-Wei SUN, Bai-Wang WANG, Geng-LinDepartment of Chemistry, Nankal University, Tianjin 300071, China Department of Chemistry Nankai University Tianjin 300071 China

Six compounds of the general formula [Ln(pfpr)3]2(NITPhOMe).nH2O, where Ln=Nd, Gd, Dy, Ho, Er, Y, pfpr=pentafluoropropionate, NITPhOMe=2-(4'-methoxyphenyl)-4,4,5, 5-tetra-methylimidazoline-1-oxyl-3-oxide, and n=4 (for Nd, Dy, Er); 3 (for Gd); 6 (for Ho); 5 (for Y), have been synthesized. These complexes were characterized by elemental analyses, IR, electronic spectra and molar conductances. The variable temperature (4-300 K) magnetic susceptibility of the complex [Gd(pfpr)3]2(NITPhOMe).3H2O was determined. The observed susceptibility data were fit to those from theoretical magnetic equation by least-squares method. The exchange integral, J, was found to be equal to 2.14 cm-1. This indicates a weak ferromagnetic spin-exchange interaction between the radical and the gadolinium(III) ion.

关键词： Binuclear complex rare earth nitronyl nitroxides magnetism

Synthesis and Crystal Structure of a Novel Complex [Cu(Phen)_3](ClO_4)_2(btio)(H_2O)

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Chinese Journal of Structural Chemistry 2004年第3期23卷 247-251页

作者： ZHANGChen-Xi LIUZhan-Quan LIAODai-Zheng jiangzong-hui YANShi-Ping ScienceofCollege TianjinUniversityofScienceandTechnologyTianjin300222China DepartmentofChemistry NankaiUniversityTianjin300071China StateKeyLaboratoryofCoordinationChemistry NanjingJiangsu210093China

The title compound [Cu(Phen)3](ClO4)2(btio)(H2O), where btio = 2-(4- benzoyloxyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, has been prepared and structurally characterized by X-ray diffraction. It crystallizes in triclinic, space group P?with a = 13.049(4), b = 13.827(5), c = 14.860(5) , a = 71.736(6), b = 77.076(6), g = 87.054(6)? C50H43Cl2CuN8O13, Mr = 1098.36, V = 2481(1) 3, Z = 2, Dc = 1.470 g/cm3, m(MoKa) = 0.622 mm-1, F(000) = 1132, the final R = 0.0639 and wR = 0.1473 for 8705 independent reflections with Rint =0.0285. The title compound is composed of [Cu(Phen)3]2+ moiety , one btio, two perchlorate ions and one water molecule. The copper(II) ion is octahedrally coordinated by three 1,10-phenanthroline ligands. The outer sphere consisting of one btio, two perchlorate ions and one water molecule is combined with the inner by hydrogen bonds and electrostatic interactions.

关键词： crystal structure nitronyl nitroxide radical Cu(II) complex

Synthesis and Crystal Structure of Dicopper(II) Compound Containing Oxalate and Reduced Imino Nitroxide Radicals

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Chinese Journal of Structural Chemistry 2004年第3期23卷 296-299页

作者： LILi-Cun DONGChao-Ling LIAODai-Zheng jiangzong-hui YANShi-Ping DepartmentofChemistry NankaiUniversityTianjin300071China

A new dicopper(II) compound with oxalate and reduced imino nitroxide radicals [Cu2(m-C2O4)(Him2-py)2(H2O)2](NO3)2 (Him2-py=1-hydroxy-2-(2-pyridyl)-4,4,5,5-tetramethyli- midazoline) has been synthesized and its crystal structure was determined by X-ray diffraction method. The complex crystallizes in monoclinic, space group P21/n with a = 9.913(4), b = 19.057(8), c = 10.169(4) ? b = 114.292(7), V = 1751(1) 3, C26H38Cu2N8O14, Mr = 813.72, Dc = 1.543 g/cm3, m(MoKa) = 1.290 mm-1, F(000) = 840, Z = 2, the final R = 0.0398 and wR = 0.0986 for 1878 observed reflections (I>2s(I)). The imino nitroxide 2-(2-pyridyl)-4,4,5,5-tetramethyl- imidazoline-1-oxyl (im2-py) is reduced in the reaction to yield Him2-py which consists of oxalato-bridged centrosymmetric [Cu2(m-C2O4)(Him2-py)2(H2O)2]2+ ions and noncoordinated NO3- anions. Each copper(II) ion is in a distorted tetragonal pyramid environment: two nitrogen atoms from Him2-py and two oxygen atoms from the oxalate group are in the basal plane, and one water molecule at the axial position.

关键词： crystal structure reduced nitroxide radical dicopper compound oxalate bridge