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Structural characteristics and petroliferous features of Tarim Basin

Chinese Science Bulletin 2002年第S1期47卷 1-11页

作者： jia chengzao~1 & wei guoqi~2 1. petrochina company limited,{1., china 2. Langfang Branch of Research Institute of Petroleum Exploration & Development, petrochina, Langfang 065007, china petrochina {1. limited Beijing China Langfang Branch of Research Institute of Petroleum Exploration & Development PetroChina Langfang China

Using the modern tectonic geology theories andmethods such as the plate tectonic analysis, the paleo-struc-ture analysis, the structural-Iithofacies analysis, and the faultrelated fold and petroleum system, and combining with theseismic data, well drilling data and the circumferential fieldgeology, study on the structural characteristics and petro-leum prospect in the Tarim Basin has been carried out. Re-sults show that the Tarim Basin is a large superimpositionand combination basin with continental crustal basement,composed of a Paleozoic craton and Meso-Cenozoic forelandbasins. The characteristics of the basin are: the kernel partof the basin is the marine facies Paleozoic craton, superim-posed 4 continental facies foreland basins. Though the scaleof the paleozoic craton of the Tarim Basin is relatively small,the structure is steady. The petroleum prospect of the Paleo-zoic craton is: multiphase pool-generation and accumulationcontrolled by ancient uplift. The Meso-Cenozoic forelandbasins in the Tarim Basin, which are distributed on the era-tonic circumference and are a long-term subsidence, turnedinto rejuvenated foreland basins after the Meso-Cenozoicperiod. The petroleum prospects are: coal-bed generatinghydrocarbon, abundant natural gas, pool-generation in laterand recent periods, the oil and gas distribution controlled bythe foreland thrust belt. The structural characteristics ofTarim provide it with a superimposition and combinationpetroleum system of multiple resources, multiple reservoirsand multiphase pool-generation. The oil and gas explorationprospect covers two large fields: the Paleozoic craton and theMeso-Cenozoic foreland thrust belt.

关键词： Tarim superimposition and combination basin craton foreland basin superimposition and combination petroleum system.

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Significantly Enhanced Melt Memory Effect of Metallocene-made Isotactic Polypropylene Containing Talc

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Chinese Journal of Polymer Science 2024年第2期42卷 213-222,I0008页

作者： Hong-Wen Sun Fu-Shan Wang Yan Gao Fu-Qing wei {1.-Chun Feng State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular ScienceFudan UniversityShanghai200433China Lanzhou Petrochemical Corporation of petrochina Lanzhou730060China Lanzhou Petrochemical Research Center Petrochemical Research Institute of PetroChinaLanzhou730060China

The melt memory effect is a widely observed phenomenon in semi-crystalline polymers. In practical applications, various additives are usually introduced into polymers, which may affect their melt memory behavior. In this work, the effect of talc on the melt memory effect of metallocene-made isotactic polypropylene(M-PP) was investigated in detail by using the differential scanning calorimetry. The results indicated that the introduction of talc significantly strengthened the melt memory effect of M-PP. Specifically, the upper limit temperature of Domain II increased from 1.1.℃ to 1.4 ℃, resulting in a substantial widening of the temperature range of Domain IIa from 1.℃ to 1. ℃. Analysis of the crystal orientation of the M-PP containing talc cooled from various Ts suggested that the remarkably enhanced melt memory effect could be ascribed to the stabilization of oriented nuclei facilitated by talc. This stabilizing effect was likely attributable to the prefreezing effect or the sorption interaction between talc and the M-PP chains.

关键词： Metallocene-made isotactic polypropylene Talc Melt memory effect Crystal orientation

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Science china Earth Sciences 2004年第10期47卷 886-895页

作者： TANG Liangjie1.2, jia {1.3, PI Xuejun4, CHEN Suping1.2, WANG Zhiyu5, XIE Huiwen4 1. Key Laboratory for Hydrocarbon Accumulation of Education Ministry, beijing 1.2249, china 2. Basin & Reservoir Research Center, University of Petroleum, beijing 1.2249, china 3. petrochina company limited, beijing 100011, china 4. Tarim Oilfield company, petrochina company Ltd., Kurle 841.00, china 5. Department of Geology, University of Petroleum, beijing 1.2249, china Key Laboratory for Hydrocarbon Accumulation of Education Ministry Beijing China Basin & Reservoir Research Center University of Petroleum Beijing China petrochina {1. limited Beijing China Tarim Oilfield company PetroChina Company Ltd. Kurle China Department of Geology University of Petroleum Beijing China

The salt beds of Lower Tertiary developed in the mid-segment of Kuqa foreland fold belt, northern Tarim basin. They considerably controlled structural deformation of the belt. Ac- cording to the field observation, seismic profile interpretation and drilling data, three different structural styles of supra-salt, intra-salt and sub-salt occurred in the Kuqa foreland fold belt. Su- pra-salt structural styles mainly include thrust faults and fault-related sags. Intra-slat structural styles essentially are salt-pillows, intra-salt faults and folds, and salt weld structures. Sub-salt structural styles mainly consist of imbricated thrust faults, duplex structures, pop-up and fault-related folds. It is indicated that great differences exist among supra-salt, intra-salt and sub-salt structures of Kuqa foreland fold belt. The salt-related structures were formed in the same structural stress field. The dynamic mechanism of the salt-related structures is mainly associated with gravitation, compression and plastic flow of salt beds.

关键词： salt-related structural style, supra-salt structure, intra-salt structure, sub-salt structure, Kuga foreland fold belt.

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Hydrogen production from hydrolysis of NaBH_(4) solution over Co-Fe-B@g-C_(3)N_(4)/NF thin film catalyst

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Rare Metals 2024年第6期43卷 2648-2659页

作者： Yan Wang jia-Xin Ma jian Ren Di Zhang Feng-Yan Xu Ke Zhang Zhong-Qiu Cao Qiu-Ju Sun Guo-De Li Shi-wei Wu Hong-Hui Chen College of Chemistry and Chemical Engineering Shenyang Normal UniversityShenyang 110034China Experimental Center Shenyang Normal UniversityShenyang 110034China Hunan Shande Energy Storage New Materials Research Institute limited {1. Changde 415000China

In this study,the double loaded Co-Fe-B@g-C_(3)N_(4)/NF(NF:Ni foam)thin film catalysts were prepared for the first time via chemical deposition method at room *** optimizing the reducing agent concentration to 0.9 mol·L^(-1.,the as-obtained Co-Fe-B@g-C_(3)N_(4)/NF exhibited the twisted ribbon structure with more distinct three-dimensional hierarchy and the smaller particle size,showing the good catalytic property for the hydrolysis of NaBH_(4)*** H_(2)generation rate of Co-Fe-B@g-C_(3)N_(4)/NF and binary Co-B@g-C_(3)N_(4)/NF under visible light irradiation surpassed the value under natural *** apparent activation energy of Co-Fe-B@g-C_(3)N_(4)/NF(45.0 kJ·mol^(-1.)under visible light irradiation was obviously reduced when compared with the natural condition(48.4 kJ·mol^(-1.)and binary Co-B@g-C_(3)N_(4)/NF(60.6 kJ·mol^(-1.)under visible light ***,the catalytic performance of the optimized Co-Fe-B@g-C_(3)N_(4)/NF thin film catalyst was superior to most of the reported non-noble metal and even noble metal ***,it illustrated that the catalytic H_(2)production performance of Co-Fe-B@g-C_(3)N_(4)/NF thin film was distinctly improved after the introduction of light and multicomponent recombination.

关键词： Sodium borohydride Co-Fe-B@g-C_(3)N_(4)/NF catalyst Chemical deposition Hydrogen production

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Silurian to Devonian foreland basin in the south edge of Tarim Basin

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Chinese Science Bulletin 2002年第S1期47卷 42-46页

作者： wei {1. jia chengzao LI Benliang CHEN Hanlin Langfang Branch Research Institute of Exploration and Development petrochina Langfang 065007China petrochina {1. limited Beijing 100011China Earth Science Department Zhejiang UniversityHangzhou 310013 China

Based on the theory of plate tectonics, combin-ing with the isotopic dating of ophiolite, igneous and volcan-ics, geochemical test, rare earth element analyze and seismicinterpretation, this paper studies the pre-Carboniferous tec-tonics and sedimentary formation of the south edge of theTarim Basin and proves that there exists the Kunlun Oceanunder tensional tectonics during the Sinian and Cambrian inthe south edge of the Tarim Plate. After that, due to the colli-sion orogenesis, there formed the peripheral foreland basinin the south edge of Tarim. The Upper Silurian and Devo-nian molasses sedimentary system superposed on the Sinianand Middle Silurian passive margin flysch sedimentary sys-tem and formed the bivariate structure of the foreland *** at the same time, based on the field geology and seismicinterpretation, we have identified that the formation of theSilurian and Devonian have the character of half depositwhich shows thick in the south area and thin in the north,and the pre-Carboniferous thrust compression tectonics re-mained in the foreland thrust belt, which further demon-strates that there existed the Silurian and Devonian periph-eral foreland basin on the south edge of the Tarim Basin.

关键词： Tarim Basin ophiolite igneous volcanics peripheral foreland basin foreland thrust belt.

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Meso-Cenozoic Tectonic Events Recorded by Apatite Fission Track in the Northern Longmen-Micang Mountains Region

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Acta Geologica Sinica(English Edition) 2012年第1期86卷 153-165页

作者： LEI Yongliang jia {1. LI Benliang wei guoqi CHEN Zhuxin SHI Xin State Key Laboratory of Enhanced Oil Recovery Beijing 100083China Research Institute of Petroleum Exploration and Development(RIPED) PetroChinaBeijing 100083China petrochina {1. limited Beijing 100010China Research Institute of Petroleum Exploration and Development-Langfang Langfang 065007China

There is a cross-cutting relationship between the E-W trending structures and the NE- trending structures in the northern Longmen-Micang Mountains region, which reflects possible regional tectonic transition and migration. Apatite fission track （AFT） analyses of 1. samples collected from this area yield apparent ages varying from 30.3±4.2 Ma to 1.1.7±9.0 Ma and confined-track-lengths ranging from 1..6±0.3 pm to 1..4±0.1.μm. Four specific groups were identified on the basis of the Track Age Spectrum Calculation （TASC） patterns, i.e., 1.3-1.2 Ma, 93.6-88 Ma, 42-40 Ma and -25.6 Ma. These age groups correspond to the spatial distributions of datasets and may represent four tectonic events. Together with the regional deformation patterns, the four age groups are interpreted to indicate tectonic superposition, transition and migration during the Meso-Cenozoic with the following possible order：（1. the Micang Mountains belt was dominated by the E-W trending structure during 1.3-1.2 Ma; （2） the contraction of the Longmen Mountains belt from the NW to the SE during 93.6-88 Ma led to the superposition of the NE-trending structures over the E-W trendinding structures; （3） dextral strike-slip shear dominated the Longmen Mountains belt at 42-40 Ma; （4） westward migration of the active tectonic belt occurred from 93.6-25.6 Ma in a break-back sequence in the northern Longmen Mountains belt. The Late Cenozoic tectonics in the northern Longmen Mountains belt are characterized by the dextral strike-slip shear and the occurrence of westward break-back sequence of deformations. As a result, north-south differences in deformations along the Longmen Mountains belt were intensified since the Miocene time and strains were mainly accumulated in the hinterland of the Longmen Mountains instead of being propagated to the foreland basin.

关键词： apatite fission track tectonic events Longmen Mountains Micang Mountains Meso-Cenozoic

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Quantitative estimation of the shrub canopy LAI from atmosphere-corrected HJ-1.CCD data in Mu Us Sandland

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Science china Earth Sciences 2010年第S1期53卷 26-33页

The leaf area index(LAI) is an important ecological parameter that characterizes the interface between vegetation canopy and the *** addition,it is used by most process-oriented ecosystem *** paper investigates the potential of HJ-1.CCD data combined with linear spectral unmixing and an inverted geometric-optical model for the retrieval of the shrub LAI in Wushen Banner of Inner Mongolia in the Mu Us ***(Moderate Resolution Atmospheric Radiance and Transmittance Model) was used for atmospheric *** was extracted using the threshold of the normalized difference vegetation index,with which water bodies and farmland were separated,in combination with a vegetation map of the People's Republic of china(1.1.00000).Using the geometric-optical model,we derive the per-pixel reflectance as a simple linear combination of two components,namely sunlit background and *** fraction of sunlit background is related to the shrub *** the support of HJ-1.CCD data,we employ linear spectral unmixing to obtain the fraction of sunlit background in an atmospherically corrected HJ *** addition,we use the measured shrub canopy structural parameters for shrub communities to invert the geometric-optical model and retrieve the pixel-based shrub *** total,1. sample plots collected in Wushen Banner of Inner Mongolia are used for *** results of the shrub LAI show good agreement with R2 of 0.81. and a root-mean-squared error of 0.1.3.

关键词： shrub leaf area index inversion HJ-1 data geometric-optical model MODTRAN Mu Us Sandland

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Fe原位改性小晶粒Silicalite-1.子筛催化醛氨缩合性能研究

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燃料化学学报（中英文） 2024年第9期52卷 1280-1289页

作者：陶金泉贾亦静白天瑜黄文斌崔岩周亚松魏强中国石油大学(北京) 北京102206 中国石油天然气股份有限公司石油化工研究院北京102206

吡啶及其衍生物统称为吡啶碱,其广泛应用于农药、医药等领域。Chichibabin醛氨缩合反应是目前工业制取吡啶碱最广泛的路线。目前,使用最广泛的ZSM-5分子筛受制于硅铝骨架结构的不稳定性,高活性反应周期较短(5 h),针对这一问题,本研究选... 详细信息

吡啶及其衍生物统称为吡啶碱,其广泛应用于农药、医药等领域。Chichibabin醛氨缩合反应是目前工业制取吡啶碱最广泛的路线。目前,使用最广泛的ZSM-5分子筛受制于硅铝骨架结构的不稳定性,高活性反应周期较短(5 h),针对这一问题,本研究选用热稳定性、水热稳定性优异的Silicalite-1.子筛,使用聚乙烯吡咯烷酮(PVP)作为胶体分散剂,在水热合成分子筛的过程中向骨架中引入Fe,结合XRD、SEM、TG、BET、NH3-TPD、Py-FTIR等表征方法探究了晶化条件对Silicalite-1.子筛结晶度、孔结构和酸性质的影响。实验结果表明,在晶种投入量1.%、PVP添加量3.75%时产品相对结晶度达到最高(1.3%),粒径约为200 nm。改性后的Silicalite-1.有更丰富的酸位点,醛氨缩合反应的初始活性由66%增加至85%,在反应进行1. h后,原料转化率和吡啶碱收率分别保持在66%和40%以上。研究提出的原位改性Silicalite-1.子筛策略极大扩宽了纯硅沸石在酸催化领域的应用,具有显著的科研价值和工业化潜力。

关键词： Silicalite-1.子筛原位改性水热法催化剂醛氨缩合反应

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Tectono–sedimentary Evolution of the Late Triassic Xujiahe Formation in the Sichuan Basin

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Acta Geologica Sinica(English Edition) 2013年第6期87卷 1554-1568页

作者： LUO Liang jia Dong QI jiafu wei guoqi DENG Fei State Key Laboratory of Petroleum Resources and Prospecting China University of Petroleum College of Geosciences China University of Petroleum School of Earth Sciences And Engineering Nanjing University Research Institute of Petroleum Exploration and Development PetroChina Company Limited Foshan Geological Survey

The early stage of Sichuan Basin formation was controlled by the convergence of three major Chinese continental blocks during the Indosinian orogeny that include South china,North china,and Qiangtang *** the Late Triassic Xujiahe Formation is assumed to represent the commencement of continental deposition in the Sichuan Basin,little research is available on the details of this particular *** stratigraphic analysis reveals that the Xujiahe Formation comprises four third-order depositional ***,two tectono-sedimentary evolution stages,deposition and denudation,have been *** wedge-shaped geometry revealed in a cross section of the southern Sichuan Basin normal to the Longmen Shan fold-thrust belt is displayed for the entire Xujiahe *** depositional extent did not cover the Luzhou paleohigh during the LST1.to LST2 （LST,TST and HST mean Iowstand,transgressive and highstand systems tracts,1.2,3 and 4 represent depositional sequence 1.2,3 and 4）,deltaic and fluvial systems fed sediments from the Longmen Shan belt,Luzhou paleohigh,Hannan dome,and Daba Shan paleohigh into a foreland basin with a centrally located *** forebulge of the western Sichuan foreland basin was located southeast of the Luzhou paleohigh after *** to the principle of nonmarine sequence stratigraphy and the lithology of the Xujiahe Formation,four thrusting events in the Longmen Shan fold-thrust belt were distinguished,corresponding to the basal boundaries of sequences 1.2,3,and *** northern Sichuan Basin was tilted after the deposition of sequence 3,inducing intensive erosion of sequences 3 and 4,and formation of wedge-shaped deposition geometry in sequence 4 from south to *** tilting probably resulted from small-scale subduction and exhumation of the western South china block during the South and North china block collision.

关键词： Xujiahe Formation tectono-sedimentary denudation Longmen Shan Sichuan Basin

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P-RE-USY沸石的稳定性、酸性和裂化反应特性

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燃料化学学报 2004年第2期32卷 244-248页

作者：刘从华沈兰邓友全高雄厚谭争国丁伟中国科学院兰州化学物理研究所甘肃兰州730000 中国石油天然气股份公司兰州石化公司催化剂厂甘肃兰州730060 中国石油天然气股份公司兰州石化公司石油化工研究院甘肃兰州730060

采用NH3 TPD、FT IR、XRD和元素分析方法研究了稀土和磷改性沸石P RE USY的酸性、水热稳定性,并在小型固定流化床反应装置中评价了含有这种改性沸石催化剂的反应性能。结果表明,由于磷促进了稀土离子由超笼向方钠石笼中的迁移,阻止了沸... 详细信息

采用NH3 TPD、FT IR、XRD和元素分析方法研究了稀土和磷改性沸石P RE USY的酸性、水热稳定性,并在小型固定流化床反应装置中评价了含有这种改性沸石催化剂的反应性能。结果表明,由于磷促进了稀土离子由超笼向方钠石笼中的迁移,阻止了沸石在水热条件下的脱铝作用,从而改善了P RE USY沸石的水热稳定性;P RE USY沸石酸性分布更集中在中强酸范围,有利于发生氢转移反应,而强酸数量的降低有利于减少焦炭形成,改善了焦炭选择性。评价表明含有这种改性沸石的催化剂显示了优越的降低汽油烯烃的效果,柴油产率可增加2.31.。

关键词： FCC催化剂磷稀土氢转移酸性分布水热稳定性

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