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A novel Mg-Gd-y-Zn-Cu-Ni alloy with excellent combination of strength and dissolution via peak-aging treatment

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journal of Magnesium and Alloys 2023年第2期11卷 720-734页

作者： y.H.Liu Z.R.Zhang j.Wang y.Li H.X.Li L.y.jia j.H.Wang j.S.Zhang State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing 100083China Dekai Intelligent Casting Co. Ltd.Hebei 072750China

Inferior absolute strength and dissolution properties are the main bottlenecks for the widespread application of dissolvable magnesium alloys in complex working environments for unconventional oil and gas ***,a novel functional peak-aged Mg-9.5Gd-2.7y-0.9Zn-0.8Cu-0.4Ni(wt.%) alloy for fracturing tools is reported,and it possesses an ultimate tensile strength of 457.6 MPa,ultimate compressive strength of 620.7 MPa and dissolution rate of ~43.7 mg·cm^(-2)·h^(-1) in 3 wt.% KCl solutions at 93℃.The excellent strength of the agedalloy is primarily attributed to the combination of grain refinement,long-period stacking ordered(LPSO) strengthening,and precipitation strengthening induced by stacking fault and β’ phase,among which the precipitation strengthening is *** investigations confirm that the corrosion is triggered from the micro-galvanic coupling between the Mg matrix and the cathodic lamellar and block LPSO ***-shaped corrosion pits along with LPSO phases are subsequently formed,significantly accelerating *** β’ precipitates can effectively improve the strength without compromising the dissolution rate because of their nanoscale *** study provides an excellent material selection for dissolvable fracturing tools and presents a strategy by which a synergistic combination of strength and dissolution rate is achieved via peak-aging treatment.

关键词： Dissolvable magnesium alloy Peak-aging treatment Mechanical properties Micro-galvanic corrosion

Mechanical Relaxation of a Ti36.2Zr30.3Cu8.3Fe4Be21.2 Bulk Metallic Glass: Experiments and Theoretical Analysis

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Acta Metallurgica Sinica(English Letters) 2019年第6期32卷 726-732页

作者： j.C.Qiao y.H.Chen G.j.Lyu K.K.Song j.M.Pelletier y.yao School of Mechanics Civil Engineering and ArchitectureNorthwestern Polytechnical UniversityXi'an 710072China School of Mechanical Electrical and Information EngineeringShandong University(Weihai)Weihai 264209China MATEIS UMR CNRS5510Bat.B.PascalINSA-LyonUniversite de Lyon69621 Villeurbanne CedexFrance

The dynamic mechanical relaxation behavior of Ti36.2Zr30.3Cu8.3Fe4Be21.2 bulk metallic glass with good glass-forming ability was investigated by mechanical *** mechanical relaxation behavior was analyzed in the framework of quasi-point defects *** experimental results demonstrate that the atomic mobility of the metallic glass is closely associated with the correlation factorχ.The physical aging below the glass transition temperature T g shows a non-Debye relaxation behavior,which could be well described by stretched Kohlrausch exponential *** Kohlrausch exponentβaging reflects the dynamic heterogeneities of the metallic *** concentration of"defects"and atomic mobility decrease caused by the in situ successive heating during the mechanical spectroscopy experiments.

关键词： Metallic glasses Mechanical relaxation Physical aging Quasi-point defects

THE　ALLOyING　BEHAVIOR　OF　BORON　AND　CARBON　INNi_3Al

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中国有色金属学会会刊：英文版 1997年第1期7卷 102-106页

作者： Zhang, y Huang, j Lin, DL SHANGHAI jIAO TONG UNIV SHANGHAI 200030PEOPLES R CHINA

ＴＨＥＡＬＬＯＹＩＮＧＢＥＨＡＶＩＯＲＯＦＢＯＲＯＮＡＮＤＣＡＲＢＯＮＩＮＮｉ３Ａｌ①ＺｈａｎｇＹｕｎ，ＨｕａｎｇＪｉｎ，ＬｉｎＤｏｎｇｌｉａｎｇＳｈａｎｇｈａｉＪｉａｏｔｏｎｇＵｎｉｖｅｒｓｉｔｙ，Ｓｈａｎｇｈａｉ... 详细信息

ＴＨＥＡＬＬＯＹＩＮＧＢＥＨＡＶＩＯＲＯＦＢＯＲＯＮＡＮＤＣＡＲＢＯＮＩＮＮｉ３Ａｌ①ＺｈａｎｇＹｕｎ，ＨｕａｎｇＪｉｎ，ＬｉｎＤｏｎｇｌｉａｎｇＳｈａｎｇｈａｉＪｉａｏｔｏｎｇＵｎｉｖｅｒｓｉｔｙ，Ｓｈａｎｇｈａｉ２０００３０ＡＢＳＴＲＡＣＴＴｏｆ...

关键词： intermetallics Ni 3Al stoichiometry solid solution alloying lattice parameter

CHARACTERIZATION OF Si_(1-x-y)Ge_xC_y FILMS GROWN By ION IMPLANTATION AND SUBSEQUENT SOLID PHASE EPITAXy

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Acta Metallurgica Sinica(English Letters) 2002年第1期15卷 49-52页

作者： X.Q. Liu y.y. Wang W.j. Cheng j. Zhang S.y. Ma Dept. of Phys. Lanzhou Univ. Lanzhou 730000 China

Si1-x-yGexCy ternary alloy films were grown on monocrystalline silicon substrates by C+ ion implantation and subsequent solid phase epitaxy (SPE). Two-step annealing technique was employed in the SPE. The structure and electrical properties of the alloy films were determined using Fourier transform infrared spectroscopy and van der Pauw Hall measurements, respectively. With the optimization of two-step annealing technique for the implanted Si1-x-yGexCy layers, a certain amount of C atoms occupied substitutional sites and no SiC was formed.

关键词： Si1-x-yGexCu film ion implantation SPE

Heavy Metals in Brown Rice(Oryza sativa L.) and Soil After Long-Term Irrigation of Wastewater Discharged from Domestic Sewage Treatment Plants

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Pedosphere 2011年第5期21卷 621-627页

作者： B.y.CHUNG C.H.SONG B.j.PARK j.y.CHO Advanced Radiation Technology Institute Korea Atomic Energy Research Institute(KAERI) Korea Testing & Research Institute(KTR) Department of Horticultural Science Chungbuk National University Department of Bio-environmental Chemistry Chonbuk National University

A pot experiment was conducted in a plastic film house to evaluate the translocation and uptake of heavy metals(Pb,Cd,Cu,and Zn) into brown rice(Oryza sativa L.) and the heavy metals residues in soils which had previously been irrigated with domestic wastewater for a long time(3 years).The range of Pb,Cd,Cu,and Zn was 5.10 ± 0.01,0.105 ± 0.017,5.76 ± 0.42,and 23.56 ± 1.40 mg kg-1,respectively in the domestic wastewater-irrigated soil,and 0.370 ± 0.006,0.011 ± 0.001,0.340 ± 0.04,and 2.05 ± 0.18 mg kg-1,respectively,in the domestic wastewater-irrigated brown *** results indicated that application of domestic wastewater to arable land slightly increased the levels of Pb,Cd,Cu,and Zn in soil and brown rice(P y metals in brown rice were lower than the recommended tolerable levels proposed by the joint FAO/WHO Expert Committee on Food ***,the continuous monitoring and pollution control of hazardous materials from domestic wastewater are needed in order to prevent excessive build-up of heavy metals in the food chain.

关键词： accumulation domestic wastewater ground water irrigation P2O5 total N

Rare-earth-niobate high-entropy ceramic foams with enhanced thermal insulation performance

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journal of Materials Science & Technology 2022年第21期116卷 94-102页

作者： R.W.yang y.P.Liang j.Xu X.y.Meng j.T.Zhu S.y.Cao M.y.Wei R.X.Zhang j.L.yang F.Gao State Key Laboratory of Solidification Processing MIIT Key Laboratory of Radiation Detection Materials and DevicesSchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an710072China NPU-QMUL joint Research Institute of Advanced Materials and Structure Northwestern Polytechnical UniversityXi’an710072China State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing100084China State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan430074China

The introduction of porous structures into high-entropy ceramics is expected to further improve its thermal insulation *** this work,a series of novel rare-earth-niobate high-entropy ceramic foams((Dy_(0.2)Ho_(0.2)y_(0.2)Er_(0.2)yb_(0.2))_(3)NbO_(7))with hierarchical pore structures were prepared by a particle-stabilized foaming ***-scale analysis reveals that high entropy causes atom displacement and lattice *** high-entropy ceramic foams exhibit high porosity(90.13%-96.13%)and ultralow thermal conductivity(0.0343-0.0592 W/(m·K))at room ***-entropy ceramic foam prepared by a 20 wt%slurry sintered at 1500℃has the porosity of 96.12%and extremely low thermal conductivity of 0.0343 W/(m·K).The existence of walls and secondary pores contributes to reduced thermal *** is a temperature difference of over 800℃between frontside and backside of the sample under fire resistance *** research indicates that these as-prepared high-entropy ceramic foams are expected to be promising thermal insulation materials.

关键词： Rare-earth niobate High-entropy ceramic foams Particle-stabilized foaming Atomic-scale analysis Thermal conductivity

Strengthening and deformation mechanism of high-strength CrMnFeCoNi high entropy alloy prepared by powder metallurgy

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journal of Materials Science & Technology 2023年第1期132卷 119-131页

作者： y.Xing C.j.Li y.K.Mu y.D.jia K.K.Song j.Tan G.Wang Z.Q.Zhang j.H.yi j.Eckert Faculty of Materials Science and Engineering Kunming University of Science and TechnologyKunming 650093China Laboratory for Microstructures Institute of MaterialsShanghai UniversityShanghai 200444China School of Mechanical Electrical&Information EngineeringShandong UniversityWeihai 264209China College of Materials Science and Engineering Chongqing UniversityChongqing 400044China Erich Schmid Institute of Materials Science Austrian Academy of SciencesJahnstraße 12Leoben A-8700Austria Department of Materials Science Chair of Materials PhysicsMontanuniversität LeobenJahnstraße 12Leoben A-8700Austria Adjunct with National University of Science and Technology«MISiS» Leninsky Prosp.4Moscow 119049Russia

Multiphase CrMnFeCoNi high-entropy alloys(HEAs)were prepared by a powder metallurgy process com-bining mechanical alloying(MA)and vacuum hot-pressing sintering(HPS).The single-phase face-centered cubic(FCC)HEA powder prepared by MA was sintered into a bulk HEA specimen containing FCC phase matrix along with precipitated M 23 C 6 phase and nanoscaleσphase *** the sintering temper-ature was 1223 K,the ultimate strength reaches 1300±11.6 MPa,and the elongation exceeds 4%±0.6%.Microstructural characterization reveals that the formation of nanoscale particles and deformation twins play critical roles in improving the strain hardening(SH)*** the MA time promoted the formation of the precipitated phase and enhanced the SH ability by increasing the number of precip-itated *** SH capacity increases significantly with increasing sintering temperature,which is attributed to a significant enhancement in the twinning capacity due to grain growth and the reduced number ofσphase *** systematic studies,the planar glide of dislocations was found to be the main mode of deformation,while deformation twinning appeared as an auxiliary deformation mode when the twinning stress was *** the formation of precipitates leads to grain bound-ary and precipitation strengthening effects,crack initiation is more prominent owing to increased grain boundary brittleness around the precipitated M 23 C 6 *** prominence of crack initiation is a contra-diction that must be reconciled with regard to precipitation *** work serves as a useful reference for the preparation of high-strength HEA parts by powder metallurgy.

关键词： High entropy alloy Powder processing Grain reﬁnement Precipitation strengthening Deformation twinning

3D Printing of Polylactic Acid Bioplastic–Carbon Fibres and Twisted Kevlar Composites Through Coextrusion Using Fused Deposition Modeling

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journal of Renewable Materials 2020年第12期8卷 1671-1680页

作者： j.y.Tey W.H.yeo y.j.King W.O.Ding Department of Mechanical and Material Engineering Lee Kong Chian Faculty of Engineering and ScienceUniversiti Tunku Abdul RahmanJalan Sungai LongBandar Sungai LongCheras43000 KajangSelangorMalaysia

Polylactic acid(PLA)bioplastic is a common material used in Fused Deposition Modeling(FDM)3D *** is biodegradable and environmentally friendly biopolymer which made out of ***,it exhibits weak mechanical properties which reduced its usability as a functional prototype in a real-world *** the present study,two PLA composites are created through coextruded with 3K carbon fibres and twisted Kevlar string(as core fibre)to form a fibre reinforced parts(FRP).The mechanical strength of printed parts was examined using ASTM D638 standard with a strain rate of 1 mm/*** has been demonstrated that the FRPs coextruded with 3K carbon fibres had achieved significant improvement in young’s modulus(+180.6%,9.205 GPa),ultimate tensile strength(+175.3%,103 MPa)and maximum tensile strain(+21.6%,1.833%).Although the young’s modulus of Kevlar FRP was found to be similar to as compared to unreinforced PLA(~3.29 GPa),it has gained significant increment in terms of maximum tensile strain(+179.7%,104.64 MPa),and maximum tensile strain(+257%,5.384%).Thus,this study revealed two unique composite materials,in which the 3K carbon FRP can offer stiff and high strength structure while Kevlar FRP offers similar strength but at a higher elasticity.

关键词： 3D printing Kevlar fibre 3K carbon fibre coextruded reinforced plastic polylactic acid bioplastic

Hepatocellular transport proteins and their role in liver disease

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World journal of Gastroenterology 2001年第2期7卷 157-169页

作者： Carmen Stanca Diana jung Peter j.Meier Gerd A.Kullak-Ublick Division of Gastroenterology and Hepatology and Division of Clinical Pharmacology and Toxicology Department of Internal MedicineUniversity HospitalCH-8091 Zurich/Switzerland

MOLECULAR PHySIOLLGy OF HEPATOCELLULAR TRANSPORT PROTEINS Basolaferal transport systems Na+-dependent bile salt uptake Uptake of bile salts into the liver was first isolated perfused rat liver[1],isolated hepatocyte... 详细信息

关键词： ATP-Binding Cassette Transporters Animals Carrier Proteins Hepatocytes Humans Liver Liver Diseases Organic Anion Transporters Organic Cation Transport Proteins Research Support, Non-U.S. Gov't