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Analysis of convective-radiative heat transfer in dovetail longitudinal fins with shape-dependent hybrid nanofluids: a study using the Hermite wavelet method

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Applied Mathematics and Mechanics(English Edition) 2025年第2期46卷 357-372页

作者： C.G.PAVITHRA b.j.GIREESHA S.SUSHMA K.j.GoWTHAM Department of PG Studies and Research in Mathematics Kuvempu University

A distinguished category of operational fluids, known as hybrid nanofluids,occupies a prominent role among various fluid types owing to its superior heat transfer properties. by employing a dovetail fin profile, this work investigates the thermal reaction of a dynamic fin system to a hybrid nanofluid with shape-based properties, flowing uniformly at a velocity U. The analysis focuses on four distinct types of nanoparticles,i.e., Al2o3, Ag, carbon nanotube (CNT), and graphene. Specifically, two of these particles exhibit a spherical shape, one possesses a cylindrical form, and the final type adopts a platelet morphology. The investigation delves into the pairing of these *** examination employs a combined approach to assess the constructional and thermal exchange characteristics of the hybrid nanofluid. The fin design, under the specified circumstances, gives rise to the derivation of a differential equation. The given equation is then transformed into a dimensionless form. Notably, the Hermite wavelet method is introduced for the first time to address the challenge posed by a moving fin submerged in a hybrid nanofluid with shape-dependent features. To validate the credibility of this research, the results obtained in this study are systematically compared with the numerical simulations. The examination discloses that the highest heat flux is achieved when combining nanoparticles with spherical and platelet shapes.

关键词： Hermite wavelet method radiation convection dovetail fin nanoparticle configuration o351.2

Atmospheric chemistry of trifluorodicarbonyls initiated by Cl atoms:Reactivity trends,mechanism,and acid formation yields

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journal of Environmental Sciences 2025年第5期151卷 12-25页

作者： Pedro L.Lugo Vianni G.Straccia Cynthia b.Rivela Mariano A.Teruel María b.blanco Laboratorio Universitario de Química y Contaminación del Aire(L.U.Q.C.A) Instituto de Investigaciones en Fisicoquímica de Córdoba(I.N.F.I.Q.C.)Dpto.de Fisicoquímica.Facultad de Ciencias QuímicasUniversidad Nacional de Córdoba.Ciudad Universitaria5000 CórdobaArgentina Institute for Atmospheric and Environmental Research University of WuppertalDE-42097 WuppertalGermany

Rate coefficients of the gas-phase reactions of Cl atoms with a series of fluorinated diketones(FDKs):CF_(3)C(o)CH_(2)C(o)CH_(3)(TFP),CF_(3)C(o)CH_(2)C(o)CH_(2)CH_(3)(TFH)and CF_(3)C(o)CH_(2)C(o)CH(CH_(3))2(TFMH),have been measured at(298±2)K and under atmospheric *** experiments were performed using the relative-rate method with a GC-FID detection *** different determinations and references used,the following rate coefficients were obtained(in cm3/(molecule·sec)):k_(4)(TFP+Cl)=(1.75±0.21)×10^(−10),k_(5)(TFH+Cl)=(2.05±0.23)×10^(−10),k_(6)(TFMH+Cl)=(2.71±0.34)×10^(−10).Reactivity trends of FDKs were discussed and Free Energy Relationships analysis was *** expression lgkoH=1.68 lgkCl+5.71 was obtained for the reactivity of the studied FDKs together with similar unsaturated VoCs with Cl and oH radicals Additionally,acetic acid(CH_(3)C(o)oH)and trifluoroacetic acid(CF_(3)C(o)oH)were positively identified and quantified as degradation products using in situ FTIR *** to the identified products,atmospheric chemical mechanisms were *** atmospheric implications of the studied reactions were assessed by the estimation of the tropospheric lifetimes of TFP,TFH,and TFMH concerning their reaction with Cl atoms to be 48,41,and 31 hours,*** relatively short residence in the atmosphere of the fluorocarbons studied will have a local/regional impact with restricted *** warming potential(GWP(20 yr))calculated for the studied fluoro diketones were 0.014,0.003 and 0.001 for TFP,TFH and TFMH,respectively with a negligible contribution to the greenhouse effect.

关键词： Fluorinated diketones Kinetics SPME-GC-FID FTIR in situ SAR Free energy relationships

biopolymer Decorated Pencil Graphite Electrode for the In-situ Quantification of L-Tryptophan in Dietary Supplements

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journal of Analysis and Testing 2025年第01期 82-95页

作者： V.Devika P.j.Sreelekshmi b.Vedhanarayanan Sandhya Sadanandan R.Rejithamol Department of Chemistry Amrita Vishwa Vidyapeetham Graduate School of Science Chiba University Department of Chemistry School of Advanced SciencesVIT-AP University

A simplistic and novel electrochemical sensor for selectively detecting the essential amino acid tryptophan in dietary supplements was fabricated on a pencil graphite electrode modified with a tryptophan-based dipeptide. The dipeptide was synthesized using common synthetic strategy for amino acid couplings. The modified electrode was characterized by scanning electron microscopy, impedance spectroscopy, cyclic voltammetry, and infrared spectroscopy. Differential pulse voltammetry was used to study the electrochemical response of the fabricated electrode to tryptophan in dietary supplements. Under the optimized experimental conditions, a distinct oxidation peak at + 0.671 V corresponding to tryptophan was noticed in differential pulse voltammetry, which indicated the detection of tryptophan by the fabricated electrode. The oxidation peak current for tryptophan was found to be linear within a concentration range of 10–350 μM with a lower detection limit of 1.2 μM, and the sensitivity of the fabricated electrode was 6.9 μA/μM/cm 2. Excellent selectivity, permissible reproducibility, and good stability of the sensor make it undoubtedly suitable for determining tryptophan in dietary supplements.

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Clpb chaperone as a promising target for antimicrobial therapy: A narrative review

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Asian Pacific journal of Tropical biomedicine 2025年第1期15卷 1-10,I0001-I0007页

作者： Sachini j.Udari Sayoka Shamodhi Rumesh M.Nelumdeniya Udayana Ranatunga Nimesha N.Senadeera Chathuranga b.Ranaweera Department of Medical Laboratory Sciences Faculty of Allied Health SciencesGeneral Sir John Kotelawala Defence UniversityWerahera10718Sri Lanka Department of Pharmacy Faculty of Allied Health SciencesGeneral Sir John Kotelawala Defence UniversityWerahera10718Sri Lanka Department of Chemistry Faculty of ScienceUniversity of PeradeniyaPeradeniya20400Sri Lanka Department of Zoology and Environment Sciences Faculty of ScienceUniversity of ColomboColombo 0300300Sri Lanka

The Clp/Hsp100 family,part of the ATPase associated with various cellular activities(AAA+)superfamily,includes caseinolytic peptidase b(Clpb),a highly conserved protein found in bacteria,fungi,protozoa,and ***,Clpb is present in all ESKAPE pathogens:Enterococcus faecium,Staphylococcus aureus,Klebsiella pneumoniae,Acinetobacter baumannii,Pseudomonas aeruginosa,and Enterobacter *** plays a crucial role in reactivating and disaggregating proteins,enabling pathogens to survive under host-induced stress and conferring thermotolerance to bacterial *** caused by ESKAPE pathogens are particularly challenging due to their resistance to broad-spectrum antibiotics and biofilm formation,posing a significant global health threat as they are often multidrug-resistant,extensively drug-resistant,and *** its absence in human cells and its essential role in bacterial survival under stress,Clpb is a promising target for antimicrobial *** Hsp100 family proteins could lead to the development of novel antifungal and antiprotozoal *** review explores the function of Clpb in the survival of ESKAPE pathogens and the protozoan Plasmodium *** research findings were compiled using academic databases,and data analysis was performed using Clustal omega Multiple Sequence Alignment and boxshade tools.

关键词： Molecular chaperone Clpb ESKAPE pathogens Thermotolerance Heat shock proteins Plasmodium falciparum

Platform for laser-driven X-ray diagnostics of heavy-ion heated extreme states of matter

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Matter and Radiation at Extremes 2025年第1期10卷 57-71页

作者： P.Hesselbach j.Lütgert V.bagnoud R.belikov o.Humphries b.Lindqvist G.Schaumann A.Sokolov A.Tauschwitz D.Varentsov K.Weyrich b.Winkler X.Yu b.Zielbauer D.Kraus D.Riley Zs.Major P.Neumayer Institut für Angewandte Physik Goethe-Universität Frankfurt am MainMax-von-Laue Str.160438 FrankfurtGermany GSI Helmholtzzentrum für Schwerionenforschung GmbH Planckstr.164291 DarmstadtGermany Institut für Physik Universität RostockAlbert-Einstein-Str.2318059 RostockGermany Institut für Angewandte Physik Technische Universität DarmstadtSchlossgartenstr.764289 DarmstadtGermany Helmholtz Institut jena Fröbelstieg 307743 JenaGermany Institut für Geowissenschaften Goethe-Universität Frankfurt am MainAltenhöferallee 160438 Frankfurt am MainGermany Helmholtz-Zentrum Dresden-Rossendorf Bautzner Landstr.40001328 DresdenGermany European XFEL GmbH Holzkoppel 422869 SchenefeldGermany Institut für Kernphysik Technische Universität DarmstadtSchlossgartenstr.964289 DarmstadtGermany Centre for Light-Matter Interaction School of Mathematics and PhysicsQueen’s University BelfastUniversity RoadBelfast BT71NNUnited Kingdom

We report on commissioning experiments at the high-energy,high-temperature(HHT)target area at the GSI Helmholtzzentrum für Schwerionenforschung GmbH,Darmstadt,Germany,combining for the first time intense pulses of heavy ions from the SIS18 synchrotron with high-energy laser pulses from the PHELIX laser *** demonstrate the use of X-ray diagnostic techniques based on intense laserdriven X-ray sources,which will allow probing of large samples volumetrically heated by the intense heavy-ion beams.A new target chamber as well as optical diagnostics for ion-beam characterization and fast pyrometric temperature measurements complement the experimental *** platform is designed for experiments at the future Facility for Antiproton and Ion Research in Europe GmbH(FAIR),where unprecedented ion-beam intensities will enable the generation of millimeter-sized samples under high-energy-density conditions.

关键词： heated intense extreme

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Kinetics of the reaction of oH radical with ethylfluoroacetate,ethyl 4,4,4-trifluorobutyrate,and butylfluoroacetate

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journal of Environmental Sciences 2025年第5期151卷 273-283页

作者： Pedro L.Lugo Vianni Straccia Mariano A.Teruel María b.blanco Laboratorio Universitario de Química y Contaminación del Aire(L.U.Q.C.A) Institute for Research in Physical Chemistry of Córdoba(I.N.F.I.Q.C.)Department of Physical ChemistryFaculty of Chemical SciencesNational University of CórdobaUniversity CityCórdoba 5000Argentina Institute for Atmospheric and Environmental Research University of WuppertalWuppertal DE-42097Germany

Kinetics of the gas-phase reactions of•oH radicals with a series of fluoroesters were studied for the first time at 298±3 K and atmospheric *** rate coefficients were determined by in situ FTIR spectroscopy in nitrogen and GC-FID in air to monitor the decay of reactants and *** following coefficient values(in 10^(−12)cm^(3)/(molecule•sec))were obtained for ethyl fluoroacetate(EFA),ethyl 4,4,4-trifluorobutyrate(ETb),and butyl fluoroacetate(bFA),respectively:k_(1)(EFA+oH)=1.15±0.25 by FTIR and 1.34±0.23 by GC-FID;k_(2)(ETb+oH)=1.61±0.36 by FTIR and 2.02±0.30 by GC-FID;k_(3)(bFA+oH)=2.24±0.37 by *** trends were developed and correlated with the number of CH_(3)and F substituents in the fluoroester,and structure-activity relationships(SARs)calculations were *** addition,the tropospheric lifetimes of EFA,ETb,and bFA upon degradation by oH radicals were calculated to be 9,6,and 5 days,respectively,indicating that these fluorinated compounds could have a possible regional effect from the emission *** small photochemical ozone creation potentials of 9,7,and 19 were estimated for EFA,ETb,and bFA,*** GlobalWarming Potentials(GWPs)for EFA,ETb,and bFA were calculated for different time *** a 20-year time horizon,the GWPs were 1.393,0.063,and 0.062,*** the case of a 100-year time horizon,the GWPs were 0.379,0.017,and 0.017,and for a 500-year time horizon,the GWPs were 0.108,0.005,and 0.005 for EFA,ETb,and bFA.

关键词： CFC replacements sinks in situ FTIR SAR Acidification potentials Greenhouse gases

Hydrogen production from dry reforming of methane,using Co_(2)previously chemisorbed in the Li_(6)Zn_(1-x)Ni_(x)o_(4)solid solution

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journal of Environmental Sciences 2025年第3期149卷 535-550页

作者： Yocelin b.González-González Fernando Plascencia-Hernández Rubén Mendoza-Cruz Heriberto Pfeiffer Instituto de Investigaciones en Materiales Universidad Nacional Autónoma de MéxicoCircuito exterior s/nCiudad UniversitariaDel.CoyoacánCP 04510CdMxMexico

Li_(6)Zno_(4)was chemically modified by nickel addition,in order to develop different compositions of the solid solution Li_(6)Zn_(1-x)Ni_(x)o_(4).These materials were evaluated bifunctionally;analyzing their Co_(2)capture performances,aswell as on their catalytic properties for H_(2)production via dry reforming of methane(DRM).The crystal structures of Li_(6)Zn_(1-x)Ni_(x)o_(4)solid solution samples were determined through X-ray diffraction,which confirmed the integration of nickel ions up to a concentration around 20 mol%,meanwhile beyond this value,a secondary phase was *** results were supported by XPS and TEM ***,dynamic and isothermal thermogravimetric analyses of Co_(2)capture revealed that Li_(6)Zn_(1-x)Ni_(x)o_(4)solid solution samples exhibited good Co_(2)chemisorption efficiencies,similarly to the pristine Li_(6)Zno_(4)chemisorption trends ***,a kinetic analysis of Co_(2)isothermal chemisorptions,using the Avrami-Erofeev model,evidenced an increment of the constant rates as a function of the Ni *** Ni^(2+)ions incorporation did not reduce the Co_(2)capture efficiency and kinetics,the catalytic properties of thesematerialswere evaluated in the DRM *** demonstrated that nickel ions favored hydrogen(H_(2))production over the pristine Li_(6)Zno_(4)phase,despite a second H2 production reaction was determined,methane ***,Li_(6)Zn_(1-x)Ni_(x)o_(4)ceramics can be employed as bifunctional materials.

关键词： Dry reforming of methane(DRM) Co_(2)chemisorption H_(2)production Solid solution Li_(6)Zno_(4)

Plant-substrate biochar properties critical for mediating reductive debromination of 1,2-dibromoethane

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journal of Environmental Sciences 2025年第1期147卷 1-10页

作者： jonathan H.Lindhardt Peter E.Holm Yong-Guan Zhu Changyong Lu Hans Christian b.Hansen Department of Plant and Environmental Sciences Faculty of ScienceUniversity of CopenhagenThorvaldsensvej 401871 Frederiksberg CDenmark Key lab of Urban Environment and Health Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Sino-Danish Center for education and research China and DenmarkDalgas Avenue 4DK-8000 Aarhus C.Denmark

Dibromoethane is a widespread,persistent organic *** are known mediators of reductive dehalogenation by layered Fe^(Ⅱ)-Fe^(Ⅲ)hydroxides(green rust),which can reduce 1,2-dibromoethane to innocuous bromide and ***,the critical characteristics that determine mediator functionality are lesser *** biochar substrates were pyrolyzed at 600℃and 800℃,characterized by elemental analysis,X-ray photo spectrometry C and N surface speciation,X-ray powder diffraction,specific surface area analysis,and tested for mediation of reductive debromination of 1,2-dibromoethane by a green rust reductant under anoxic conditions.A statistical analysis was performed to determine the biochar properties,critical for debromination kinetics and total debromination *** was shown that selected plant based biochars can mediate debromination of 1,2-dibromoethane,that the highest first order rate constant was 0.082/hr,and the highest debromination extent was 27%in reactivity experiments with 0.1μmol(20μmol/L)1,2-dibromoethane,≈22 mmol/L Fe^(Ⅱ)GR,and 0.12 g/L soybean meal biochar(7 days).Contents of Ni,Zn,N,and P,and the relative contribution of quinone surface functional groups were significantly(positively correlated with 1,2-dibromoethane debromination,while adsorption,specific surface area,and the relative contribution of pyridinic N oxide surface groups were significantly negatively correlated with debromination.

关键词： Environmental remediation biochar Persistent organic pollutants(PoPs) Environmental catalysis Green rust

Primary Polydipsia and sIDH Type D Due to Water-Electrolytic Disturbance in a Schizophrenic Patient: A Case Report and Systematic Review

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open journal of Psychiatry 2025年第1期15卷 1-15页

作者： bianca F. Pires júlia Maria de oliveira Guilherme V. Kitayama Vitória C. Tahan Flávia R. Darwin Luiz Antônio L. C. Saraiva Carolina C. T. Vilarinho Gabriela b. Dorilêo joão Pedro F. Amaral Lucas P. b. de Santana Sarah P. Farid Tiago V. C. Albuquerque André b. Villani Fernanda S. Nascimento Larissa D. G. Pelegrino Renato Augusto Tambelli álvaro Tavares de Figueiredo Department of Psychiatry Faculdade de Medicina de Marlia Marlia So Paulo Brazil

Introduction: Primary polydipsia, frequently observed in patients with schizophrenia, can cause severe hyponatremia, leading to serious complications. objective: This study reviews the management and prevalence of psychogenic polydipsia, focusing on treatments and clinical outcomes. Methods: Following the PRISMA guidelines, studies on polydipsia in psychiatric patients were included. Data were extracted from databases such as PubMed and Scopus, and a meta-analysis was performed. Results: Fifteen studies were analyzed, totaling 586 patients. The use of urea was effective in correcting hyponatremia, while antipsychotics showed mixed results. Heterogeneity between studies was moderate (I2 = 56%). Conclusion: Psychogenic polydipsia is a severe condition in schizophrenic patients. The use of urea has shown promise, but further studies are needed to optimize treatments.

关键词： Schizophrenia Psychogenic Polydipsia Water intoxication Inappropriate ADH Syndrome