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Hydrotreating of light gas oil using a NiMo catalyst supported on activated carbon produced from fluid petroleum coke

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Frontiers of Chemical Science and Engineering 2014年第2期8卷 161-170页

作者： N. Rambabu Sandeep Badoga Kapil K. Soni A.K. Dalai j. adjaye Catalysis and Chemical Reaction Engineering Laboratories Department of Chemical and Biological Engineering University of Saskatchewan Saskatoon SK S7N 5A9 Canada Syncrude Edmonton Research Centre Edmonton AB T6N 1H4 Canada

Nitric acid functionalized steam activated carbon （NAFSAC） was prepared from waste fluid petroleum coke （FPC） and used as a support material for the synthesis ofa NiMo catalyst （2.5 wt-% Ni and 13 wt-% Mo）. The catalyst was then used for the hydrotreatment of light gas oil. The support and catalysts were characterized by Brunauer-Emmett-Teller （BET） gas adsorption method, X-ray diffraction, H2-temperature programmed reduction, NH3-temperature programmed desorption, CO-chemisorption, mass spetrography, scanning electron microscopy （SEM）, Boehm titration, and Fourier transform infrared spectroscopy （FTIR）. The SEM results showed that the carbon material retained a needle like structure after functionalization with HNO3. The Boehm titration, FTIR, and BET results confirmed that the HNO3 functionalized material had moderate acidity, surface functional groups, and mesoporosity respectively. The produced NAFSAC had an inert nature, exhibited the sink effect and few metal support interactions, and contained functional groups. All of which make it a suitable support material for the preparation of a NiMo hydrotreating catalyst. Hydrotreating activity studies of the NiMo/NAFSAC catalyst were carried out under industrial operating conditions in a laboratory trickle bed reactor using coker light gas oil as the feedstock. A parallel study was performed on the hydrotreating activity of NiMo/7-A1203 as a reference catalyst. The hydrodesulfurization and hydrodenitrogena- tion activities of the NiMo/NAFSAC catalyst were 62% and 30%, respectively.

关键词： activated carbon fluid petroleum coke NiMocatalyst hydrotreating light gas oil

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A mitochondrial strategy for safeguarding the reprogrammed genome

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Cell Regeneration 2014年第1期3卷 44-46页

作者： Alessandro Prigione j.mes adjaye Max Delbrueck Center for Molecular Medicine(MDC) Robert-Roessle-Str.10D-13125 Berlin-BuchGermany Department of Vertebrate Genomics Molecular Embryology and Aging GroupMax Planck Institute for Molecular GeneticsBerlinGermany Institute for Stem Cell Research and Regenerative Medicine Heinrich Heine UniversityDuesseldorfGermany

Genomic aberrations induced by somatic cell reprogramming are a maj.r drawback for future applications of this technology in regenerative medicine.A new study by j. et *** in Stem Cell Reports suggests a counteracting... 详细信息

关键词： Antioxidants Mitochondria Reprogramming iPSCs Genomic aberrations

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