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Transformation of Supercapacitive Charge Storage Behaviour in a Multi elemental Spinel CuMn_(2)O_(4) Nanofibers with Alkaline and Neutral Electrolytes

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Advanced Fiber Materials 2021年第4期3卷 265-274页

作者： Ria Kunwar Syam G.Krishnan izan izwan misnon Fatemeh Zabihi Shengyuan Yang Chun-Chen Yang Rajan Jose Nanostructured Renewable Materials Research Laboratory Faculty of Industrial Sciences and TechnologyUniversity Malaysia Pahang26300 KuantanMalaysia Graphene&Advanced 2D Materials Research Group(GAMRG) School of Engineering and TechnologySunway UniversityNo.5 Jalan UniversitiBandar Sunway47500 Petaling JayaSelangorMalaysia State Key Laboratory for Modification of Chemical Fibers and Polymer Materials International Joint Laboratory for Advanced Fiber and Low-Dimension MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghaiPeople’s Republic of China Battery Research Center for Green Energy Ming Chi University of TechnologyNew Taipei CityTaiwan

Electrode material has been cited as one of the most important determining factors in classifying an energy storage system’s charge storage mechanism,i.e.,as battery-type or *** this paper,we show that along with the electrode material,the electrolyte also plays a role in determining the charge storage behaviour of the *** the purpose of our research,we chose multi-elemental spinal type CuMn_(2)O_(4) metal oxide nanofibers to prove the *** material is synthesized as nanofibers of diameter~120 to 150 nm in large scales by a pilot scale electrospinning set *** was then tested in three different electrolytes(1 M KOH,1 M Na_(2)SO_(4) and 1 M Li_(2)SO_(4)),two of which are neutral and the third is alkaline(KOH).The cyclic voltammograms and the galvanostatic charge-discharge of the electrode material in a three-electrode sys-tem measurement showed that it exhibit different charge storage mechanism in different electrolyte *** the neutral electrolytes,a capacitive behaviour was observed whereas a battery-type behaviour was seen for the alkaline *** leads us to conclude that the charge storage mechanism,along with the active material,also depends on the electrolyte used.

关键词： Energy storage materials Electrochemical double layer capacitors Capacitive charge storage Ternary manganates Pseudocapacitors

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Pseudocapacitive Charge Storage in Thin Nanobelts

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Advanced Fiber Materials 2019年第3期1卷 205-213页

作者： Ria Kunwar Midhun Harilal Syam G.Krishnan Bhupender Pal izan izwan misnon C.R.Mariappan Fabian I.Ezema Hendry Izaac Elim Chun-Chen Yang Rajan Jose Nanostructured Renewable Energy Materials Laboratory Faculty of Industrial Sciences and TechnologyUniversiti Malaysia Pahang26300 KuantanPahangMalaysia Department of Physics National Institute of TechnologyKurukshetraHaryana 136119India Department of Physics and Astronomy University of NigeriaNsukkaNigeria Department of Physics University of PattimuraAmbonIndonesia Battery Research Centre of Green Energy Ming Chi University of TechnologyNew TaipeiTaiwan

This article reports that extremely thin nanobelts(thickness~10 nm)exhibit pseudocapacitive(PC)charge storage in the asymmetric supercapacitor(ASC)configuration,while show battery-type charge storage in their single *** types of nanobelts,***-Co_(3)O_(4) hybrid and spinal-type NiCo_(2)O_(4),developed by electrospinning technique are used in this *** charge storage behaviour of the nanobelts is benchmarked against their binary metal oxide nanowires,i.e.,NiO and Co_(3)O_(4),as well as a hybrid of similar chemistry,CuO-Co_(3)O_(4).The nanobelts have thickness of~10 nm and width~200 nm,whereas the nanowires have diameter of~100 *** differences in charge storage behaviours are observed in NiO-Co_(3)O_(4) hybrid nanobelts based ASCs compared to those fabricated using the other materials-the former showed capacitive behav-iour whereas the others revealed battery-type discharge *** of pseudocapacitance in nanobelts based ASCs is shown to arise from their nanobelts morphology with thickness less than typical electron diffusion lengths(~20 nm).Among all the five type of devices fabricated,the NiO-Co_(3)O_(4) hybrid ASCs exhibited the highest specific energy,specific power and cycling stability.

关键词： Battery-supercapacitor hybrid devices Energy storage materials Hybrid materials

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Self-rechargeable energizers for sustainability

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eScience 2022年第4期2卷 347-364页

作者： JinKiong Ling Ria Kunwar Linlin Li Shengjie Peng izan izwan misnon Mohd Hasbi Ab Rahim Chun-Chen Yang Rajan Jose Center for Advanced Intelligent Materials Universiti Malaysia Pahang26300KuantanPahang Faculty of Industrial Sciences and Technology Universiti Malaysia Pahang26300KuantanPahang College of Material Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing210016 Battery Research Center for Green Energy(BRCGE) Ming Chi University of Technology24301New Taipei City Department of Chemical Engineering Ming Chi University of Technology24301New Taipei City Department of Chemical and Materials Engineering Chang Gung UniversityKwei-shan333Taoyuan

Electrical energy generation and storage have always been complementary to each other but are often disconnected in practical electrical ***,efforts to combine both energy generation and storage into self-powered energizers have demonstrated promising power sources for wearable and implantable *** line with these efforts,achieving self-rechargeability in energy storage from ambient energy is envisioned as a tertiary energy storage(3rd-ES)*** review examines a few of the possible 3rd-ES capable of harvesting ambient energy(photo-,thermo-,piezo-,tribo-,and bio-electrochemical energizers),focusing also on the devices'*** self-rechargeability mechanisms of these devices,which function through modifications of the energizers’constituents,are analyzed,and designs for wearable electronics are also *** challenges for self-rechargeable energizers and avenues for further electrochemical performance enhancement are *** article serves as a one-stop source of information on self-rechargeable energizers,which are anticipated to drive the revolution in 3rd-ES technologies.

关键词： Batteries Supercapacitors Self-powered Textile electronics Yarns

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The Conservation of Ground Water Levels in the Peat Swamp Forest at Ayer Hitam North Forest Reserve, Muar in Johor, Malaysia

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Journal of Water Resource and Protection 2021年第12期13卷 957-975页

作者： Siti Aisah Shamsuddin Mohd Azahari Faidi Hyrul izwan Mohd Husin Mohamad Fakhri Ishak Ismail Parlan Habsah Marjuni Forestry & Environment Division Forest Research Institute Malaysia Kepong Selangor Malaysia Forest Biotechnology Division Forest Research Institute Malaysia Kepong Selangor Malaysia Director General Forest Research Institute Malaysia Kepong Selangor Malaysia Yayasan Kemanusiaan Muslim Aid Malaysia Menara Mutiara Bangsar Jalan Liku Off Jalan Riong Kuala Lumpur Malaysia

The management of peat swamp forests in Malaysia contends with two major issues: forest fires and the effects of abandoned forest-logging drainage systems or canals. Forest fire occurs during low rainfall season related to the local people activities. The drainage networks change the hydrological function of the intact forest ecosystem. A key function of the hydrological system in the undisturbed forest is to absorb water during rainfall season, thus delaying downstream runoff and preventing flash floods. The objective of the project described here is to restore the hydrological function of peat swamp forest (PSF) at Ayer Hitam North Forest Reserve (AHNFR) in Muar, Johor, Malaysia. The oil palm plantations, especially in the southern part of the area affect the forest reserve. Water flows out of the forest reserve through the drainage system constructed for managing these plantations. In 2016 and 2017, two water block structures or check dams were constructed near the boundaries of the forest reserve to hold the water and raise the groundwater level in the forest reserve. The implementation of the check dams at the two locations has conserved the groundwater level and subsequently, about 1.2 million m3 of water was saved annually from leaving the forest reserve from each of the check dam. This project is also part of the Coca-Cola Company’s sustainability commitment for water strategy with the global that is to replenish 100% of the equivalent volume of water consumed in their products and production by 2020. Replenishment is the key sustainability commitment for the Company.

关键词： Hydrology Oil Palm Plantation Water Blockage Peat Swamp Forest Ground Water Level Conservation

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