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Pyrrolidine dithiocarbamate reduces ischemia-reperfusion injury of the small intestine

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World Journal of Gastroenterology 2005年第46期11卷 7308-7313页

作者： ismail h mallick Wen-Xuan Yang Marc C Winslet Alexander M Seifalian GI and hepatobiliary Research Unit University Department of Surgery Royal Free and University College Medical School University College London LondonUnited Kingdom Department of Surgery Royal Free Hospital Hampstead NHS Trust London United Kingdom

AIM： To evaluate whether pyrrolidine dithiocarbamate （PDTC）, an enhancer of hO production, attenuates intestinal IR injury. METhODS： Eighteen male rats were randomly allocated into three groups：（a） sham; （b） IR, consisting of 30 min of intestinal ischemia, followed by 2-h period of reperfusion; and （c） PDTC treatment before IR. Intestinal microvascular perfusion （IMP） was monitored continuously by laser Doppler flowmetry. At the end of the reperfusion, serum samples for lactate dehydrogenase （LDh） levels and biopsies of ileum were obtained. hO activity in the ileum was assessed at the end of the reperfusion period. RESULTS： At the end of the reperfusion in the IR group, IMP recovered partially to 42.5% of baseline （P〈0.05 vs sham）, whereas PDTC improved IMP to 67.3% of baseline （P〈0.01 vs IR）. There was a twofold increase in hO activity in PDTC group （2 062.66±106.11） as compared to IR （842.3±85.12）（P〈0.001）. LDh was significantly reduced （P〈0.001） in PDTC group （585.6±102.4） as compared to IR group （1 973.8±306.5）. histological examination showed that the ileal mucosa was significantly less injured in PDTC group as compared with IR group. CONCLUSION： Our study demonstrates that PDTC improves the IMP and attenuates IR injury of the intestine possibly via hO production. Additional studies are warranted to evaluate the clinical efficacy of PDTC in the prevention of IR injury of the small intestine.

关键词： Intestine Ischemia-reperfusion injury heme oxygenase Pyrrolidine

Optimized system for combined production of electricity/green hydrogen for multiple energy pathways:a case study of Egypt

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Clean Energy 2024年第4期8卷 219-236页

作者： Reda Ragab Mohamed hamdihafez A.El Salmawy Mohamed A.ismail Mechanical Power Engineering Department Zagazig UniversityZagazig 44519Egypt Mechanical Engineering Department College of EngineeringKing Faisal UniversityAl-Ahsa 31982Saudi Arabia

By optimal sizing of a wind/photovoltaic hybrid renewable-energy(RE)system,trimming the surplus capacity to reduce the fluctuations in the electricity supplied to the grid,and using it to produce green hydrogen through electrolysis,a stable output with maximum possible capacity factor(CF)is generated to maintain the electricity grid ***,the trimmed energy is used in a secondary conversion path that minimizes the weighted average cost of the energy generated from the entire *** surplus power-to-gas conversion allows the use of green hydrogen to produce electricity,methanol,or ammonia subject to the resource availability,site characteristics,and financial *** on robust site selection criteria,the best performance is obtained at two sites:Ras Ghareb and Minya,achieving the lowest energy cost with some variance in their *** the Ras Ghareb site,the optimally sized RE plant provided the grid with a quasi-steady capacity of 423 MW with a CF of 80.04%and was capable of injecting 2965.8648 GWh throughout the year with the lowest cost of 2.4355¢/kWh.A surplus of 3.9%of the total energy produced from the plant was directed to produce 1922-ton h_(2)/year,achieving the lowest cost of hydrogen production of$1.9745/kg h_(2).For the other selected site,Minya,the clipped energy is used to produce 3330.47-ton h_(2)/year with an optimized lowest cost of$3.5268/kg h_(2).The difference in hydrogen costs was attributed to the number of full operating hours of the electrolyser in both *** cost is mainly affected by the electricity price and the electrolyser *** both tending to decrease,future forecasts show hydrogen cost reductions.

关键词： hybrid renewable-energy system(hRES) green hydrogen electrolysis power-to-gas methanol ammonia

Inclusion of CoTiO_(3) to ameliorate the re/dehydrogenation properties of the Mg–Na–Al system

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Journal of Magnesium and Alloys 2024年第3期12卷 1215-1226页

作者： N.A.Ali N.Y.Yusnizam N.A.Sazelee Sami-ullah Rather haizhen Liu M.ismail Energy Storage Research Group Faculty of Ocean Engineering TechnologyUniversiti Malaysia Terengganu21030 Kuala NerusTerengganuMalaysia Department of Chemical and Materials Engineering King Abdulaziz UniversityP.O.Box80204Jeddah 21589Saudi Arabia Guangxi Novel Battery Materials Research Center of Engineering Technology School of Physical Science and TechnologyGuangxi UniversityNanning 530004China State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures Nanning 530004China

For the first time,the Mgh_(2)–NaAlh_(4)(ratio 4:1)destabilized system with CoTiO_(3) addition has been *** CoTiO_(3)-doped Mgh_(2)–NaAlh_(4) sample begins to dehydrogenate at 130℃,which is declined by 40℃ compared to the undoped Mgh_(2)–NaAlh_(4).Moreover,the de/rehydrogenation kinetics characteristics of the CoTiO_(3)-doped Mgh_(2)–NaAlh_(4) were greatly *** the inclusion of CoTiO_(3),the Mgh_(2)–NaAlh_(4) composite absorbed 5.2 wt.%h_(2),higher than undoped Mgh_(2)–NaAlh_(4).In the context of dehydrogenation,the CoTiO_(3)-doped Mgh_(2)–NaAlh_(4) sample desorbed 2.6 wt.%h_(2),almost doubled compared to the amount of hydrogen desorbed from the undoped Mgh_(2)–NaAlh_(4) *** activation energy obtained by the Kissinger analysis for Mgh_(2) decomposition was significantly lower by 35.9 kJ/mol than the undoped Mgh_(2)–NaAlh_(4) *** reaction mechanism demonstrated that new phases of MgCo and AlTi_(3) were generated in situ during the heating process and are likely to play a substantial catalytic function and be useful in ameliorating the de/rehydrogenation properties of the destabilized Mgh_(2)–NaAlh_(4) system with the inclusion of CoTiO_(3).

关键词： Destabilize system Magnesium hydride Sodium alanate hydrogen storage Additive.

Characterization of hydroxyapatite Extracted from Crab Shell Using the hydrothermal Method with Varying holding Times

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Journal of Renewable Materials 2024年第6期12卷 1145-1163页

作者： Deni Fajar Fitriyana Rifky ismail Athanasius Priharyoto Bayuseno Januar Parlaungan Siregar Tezara Cionita Department of Mechanical Engineering Faculty of EngineeringDiponegoro UniversitySemarangJawa Tengah50275Indonesia Department of Mechanical Engineering Faculty of EngineeringUniversitas Negeri SemarangGunung PatiSemarang50229Indonesia Center for Biomechanics BiomaterialBiomechatronicsand Biosignal Processing(CBIOM3s)Diponegoro UniversitySemarang50275Indonesia Automotive Engineering Center(AEC) Universiti Malaysia Pahang Al-Sultan Abdullah(UMPSA)PahangMalaysia Faculty of Mechanical&Automotive Engineering Technology Universiti Malaysia Pahang Al-Sultan AbdullahPekan26600Malaysia Faculty of Engineering and Quantity Surveying INTI International UniversityNilaiMalaysia

hydroxyapatite(hA)is a bio ceramic commonly utilized in bone tissue engineering due to its bioactive and osteoconductive *** shells are usually disregarded as waste material despite their significant CaCO_(3) content,and have not been widely utilized in the synthesis of *** study aims to synthesize and analyze hA derived from crab shells using the hydrothermal method with different durations of holding *** study utilized precipitated calcium carbonate(PCC)derived from crab *** a hydrothermal reactor set at 160℃ and varying holding times of 14(hA_14),16(hA_16),and 18(hA_18)h,a PCC and(Nh4)2hPO4 mixture was used to synthesize *** synthesis results were analyzed using scanning electron microscopy(SEM),fourier transform infrared spectroscopy(FTIR),and X-ray diffraction(XRD)*** study has accomplished the synthesis of hA from crab ***,the final product of synthesis still contained CaCO_(3) as an *** prolonged hydrothermal holding time of 14 to 18 h resulted in a reduction of impurities while increasing the percentage of crystal weight and crystallite size of *** Ch_18 is the best-quality product generated in this *** specimen produced hA with the highest percentage of crystal weight and crystallite size compared to the other ***,specimen Ch_18 exhibited the lowest concentration of *** Ca/P ratio in this specimen was also the closest to *** Ca/P ratio,crystallite size,and crystal weight percentage of this specimen are 1.54,19.06 nm,and 99.1%,respectively.

关键词： hydroxyapatite crab shells CaCO_(3) hydrothermal holding time

Sepsis Prediction Using CNNBDLSTM and Temporal Derivatives Feature Extraction in the IoT Medical Environment

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Computers, Materials & Continua 2024年第4期79卷 1157-1185页

作者： Sapiah Sakri Shakila Basheer Zuhaira Muhammad Zain Nurul halimatul Asmak ismail Dua’Abdellatef Nassar Manal Abdullah Alohali Mais Ayman Alharaki Department of Information Systems College of Computer and Information SciencesPrincess Nourah Bint Abdulrahman UniversityRiyadh11671Kingdom of Saudi Arabia Department of Computer Science and Information Technology Applied CollegePrincess Nourah Bint Abdulrahman UniversityRiyadh11671Kingdom of Saudi Arabia

Background:Sepsis,a potentially fatal inflammatory disease triggered by infection,carries significant healthimplications *** detection is crucial as sepsis can rapidly escalate if left *** in deep learning(DL)offer powerful tools to address this ***:Thus,this study proposeda hybrid CNNBDLSTM,a combination of a convolutional neural network(CNN)with a bi-directional long shorttermmemory(BDLSTM)model to predict sepsis *** the proposed model provides a robustframework that capitalizes on the complementary strengths of both architectures,resulting in more accurate andtimelier ***:The sepsis prediction method proposed here utilizes temporal feature extraction todelineate six distinct time frames before the onset of *** time frames adhere to the sepsis-3 standardrequirement,which incorporates 12-h observation windows preceding sepsis *** models were trained usingthe Medical Information Mart for Intensive Care III(MIMIC-III)dataset,which sourced 61,522 patients with 40clinical variables obtained from the IoT medical *** confusion matrix,the area under the receiveroperating characteristic curve(AUCROC)curve,the accuracy,the precision,the F1-score,and the recall weredeployed to evaluate ***:The CNNBDLSTMmodel demonstrated superior performance comparedto the benchmark and other models,achieving an AUCROC of 99.74%and an accuracy of 99.15%one hour beforesepsis *** results indicate that the CNNBDLSTM model is highly effective in predicting sepsis onset,particularly within a close proximity of one ***:The results could assist practitioners in increasingthe potential survival of the patient one hour before sepsis onset.

关键词： Temporal derivatives hybrid deep learning predicting sepsis onset MIMIC III machine learning(ML) deep learning

累积叠轧焊Al/Mg/Al多层复合材料的腐蚀行为

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Transactions of Nonferrous Metals Society of China 2024年第1期34卷 122-138页

作者： ismail BENChERIFA Khadidja ABIB Khereddine ABDEL YAZID Baya ALILI Djamal BRADAI Laboratory of Metallic and Semiconducting Materials(LMSM) Department of Mechanical EngineeringUniversity of BiskraB.P.14507000BiskraAlgeria Laboratory of Materials Physics Faculty of PhysicsUniversity of Sciences and Technology-Houari Boumediene(U.S.T.H.B.)P.O.Box 32El-AliaBab-EzzouarDZ-16111AlgiersAlgeria Center for Development of Advanced Technologies CDTACitédu 20 août 1956Baba-Hassen16303 AlgiersAlgeria

研究累积叠轧焊(ARB)Al1050/AZ31/Al1050多层复合材料的腐蚀行为,腐蚀介质为3.5%Na Cl(质量分数)溶液,分析测试手段包括动电位极化测试(PDP)、电化学阻抗谱(EIS)、扫描电子显微镜(SEM-EDS)、拉曼光谱和X射线衍射(XRD)等。为了深入研究Al... 详细信息

研究累积叠轧焊(ARB)Al1050/AZ31/Al1050多层复合材料的腐蚀行为,腐蚀介质为3.5%Na Cl(质量分数)溶液,分析测试手段包括动电位极化测试(PDP)、电化学阻抗谱(EIS)、扫描电子显微镜(SEM-EDS)、拉曼光谱和X射线衍射(XRD)等。为了深入研究Al1050/AZ31/Al1050多层复合材料的耐腐蚀性和腐蚀产物,对ARB制备的Al1050/Al1050/Al1050多层复合材料进行了相似的测试作为对比。动电位极化曲线和电化学阻抗谱显示,ARB应变水平会显著影响腐蚀速率。与Al1050/Al1050/Al1050样品相比,Al1050/AZ31/Al1050多层复合材料具有更高的腐蚀速率和更低的极化电阻。AZ31层对腐蚀过程起主导作用。拉曼和XRD分析结果表明主要腐蚀产物为Mg(Oh)2,且不含任何氯化合物(如(Mg(Oh)_(2))·MgCl_(2))。

关键词：累积叠轧焊 Al1050/AZ31/Al1050 多层复合材料腐蚀金属间化合物

Layered niobium carbide enabling excellent kinetics and cycling stability of Li-Mg-B-h hydrogen storage material Layered niobium carbide enabling excellent kinetics

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Rare Metals 2024年第3期43卷 1153-1166页

作者： Li-Wen Lu hui Luo Guang-Xu Li Yun Li Xin-hua Wang Cun-Ke huang Zhi-QiangLan Wen-Zheng Zhou Jin Guo Mohammad ismail hai-Zhen Liu Guangxi Novel Battery Materials Research Center of Engineering Technology Guangxi Colleges and Universities Key Laboratory of Blue Energy and Systems IntegrationSchool of Physical Science and TechnologyGuangxi UniversityNanning530004China State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures Nanning530004China School of Mechanical and Electrical Engineering Quzhou College of TechnologyQuzhou324000China Department of Materials Science and Engineering Zhejiang UniversityHangzhou310027China Faculty of Ocean Engineering Technology and Informatics Universiti Malaysia Terengganu21030Kuala NerusTerengganuMalaysia Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin300071China

The Li-Mg-B-h composite(2LiBh_(4)+Mgh_(2))has a high capacity of 11.4 wt%as a hydrogen storage ***,the slow kinetics and poor cycling stability severely restrict its practical *** this work,a layered Nb_(2)C MXene was first synthesized and then introduced to tailor the kinetics and cycling stability of the Li-Mg-B-h *** milled 2Lih+MgB_(2)composites were initially hydrogenated to obtain the 2LiBh_(4)+Mgh_(2)*** 2LiBh_(4)+Mgh_(2)+5wt%Nb_(2)C can release 9.0 wt%h_(2)in 30 min at 400℃,while it is only 2.7 wt%for the undoped 2LiBh_(4)+Mgh_(2).The dehydrogenation activation energies of Mgh_(2)and LiBh_(4)are 123 and 154 kJ·mol^(-1)respectively for the 5 wt%Nb_(2)C-doped composite,lower than the undoped composite(164 and 165 kJ·mol^(-1)).The 2LiBh_(4)+Mgh_(2)+5 wt%Nb_(2)C possesses excellent cycling stability,with the reversible capacity only slightly reduced from 9.4 wt%for the 1st cycle to 9.3 wt%for the 20th ***_(2)C keeps stable in the composite and acts as an efficient catalyst for the Li-Mg-B-h *** is believed that both the layered structure and the active Nb element contribu te to the enhanced hydrogen storage performances of the Li-Mg-B-h *** work confirms that the Nb_(2)C MXene with layered stru cture has a significant enhancing impact on the Li-Mg-B-h hydrogen storage materials,which is different from the bulk NbC.

关键词： hydrogen storage Lithium borohydride Magnesium hydride Nb_(2)C MXene

Multi-site Passivation of ZnO Metal Oxides via Biomolecules for Efficient and highly Stable Organic Solar Cells

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Chinese Journal of Chemistry 2024年第14期42卷 1582-1592页

作者： Irfan ismail Maria Khalil Xiaomei Gao Xingze Chen Muhammad Jawad Rong huang Zhiyun Li Emmanuel Acheampong Tsiwah Wei-shi Li Qun Luo Chang-Qi Ma i-Lab&Printable Electronics Research Center Suzhou Institute of Nano-Tech and Nano-Bionics(SINANO)Chinese Academy of Sciences(CAS)SuzhouJiangsu215123 China University of Chinese Academy of Sciences(UCAS) Beijing100040 China School of Nano-Tech and Nano-Bionics University of Science and Technology of China(USTC)HefeiAnhui230027 China Shanghai Institute of Organic Chemistry(SIOC) Chinese Academy of Sciences(CAS)Shanghai200032 China Vacuum Interconnected Nanotech Workstation(Nano-X) SuzhouJiangsu215123 China

ZnO nanoparticles(nps)among metal oxide(MOs)are proven to be essential electron transporting layers(ETLs)applied in organic solar cells(OSCs).however,intrinsic defects,interfacial charge recombination,and catalytic behavior towards the active layer restrict the applications of ZnO nps for efficient and long-term stable *** commonly available biomolecule cytidine 5'-monophosphate(CMP-Oh)with phosphonic acid,its salt cytidine 5'-monophosphate disodium salt(CMP-ONa)with a phosphate group as an anchoring group and conjugated terminal functional in both analogous molecules provide carrier transfer bridge at bottom interface of the active *** theoretical investigations and characterizations have discovered the multi-site coordination of CMP-Oh towards acceptor molecules and ZnO *** dual-side alignment of CMP analogous molecules hinders interfacial charge recombination and enhances charge transfer potential at ***,PM6:L8-BO-based OSCs with modified ETL obtain 18.13%efficiency,12%higher than that of unmodified *** higher efficiency,CMP-Oh-based OSC devices illustrate remarkably improved thermal stability for 500 h at 85℃with 72%of initial PCE and operation stability for 2000 h with 90.1%of initial *** work reveals the passivation mechanism of multi-anchoring groups towards MOs and single-functional groups towards the active layer to optimize the interface for efficient and highly stable OSCs.

关键词： Organic solar cells Nanoparticles Nucleotides Interfacial interactions Surface chemistry Multi-site passivation

Controversies in the treatment of common anal problems

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World Journal of Gastroenterology 2006年第20期12卷 3146-3154页

作者： ismail Sagap Feza h Remzi Department of Colorectal Surgery(A-30) Cleveland Clinic Foundation 9500 Euclid AvenueClevelandOH 44195United States

Treating common benign anal diseases has evolved towards more outpatient procedures with better outcome. however, minimizing post-procedure morbidities such as pain and the avoidance incontinence remain the most significant concerns. We introduce some controversies and highlight the developments in current surgical practice for the treatment of common anal problems.

关键词： Anal problems Treatment