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Aluminium and cerium co-doped ZnO nanoparticles:Facile and inexpensive synthesis and visible light photocatalytic performances

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Journal of Rare Earths 2021年第2期39卷 151-159页

作者： irshad ahmad Muhammad Shoaib Akhtar Ejaz Ahmed Mukhtar ahmad Department of Physics Bahauddin Zakariya UniversityMultan60800Pakistan School of Computer and Communication Lanzhou University of TechnologyLanzhou 730000China

Facile combustion route synthesized Al and Ce co-doped ZnO nanoparticles photocatalysts were characterized using XRD,SEM,BET,EDS,UV-visible DRS,PL,photocurrent and EIS *** and SEM analyses identify that crystallite and particle size is reduced from 13.26 to 11.88 nm with introduction of Al and Ce into ZnO which assists inhibiting the recombination of photo generated charge *** DRS spectra indicate that optical assimilation of ZnO is significantly increased to visible region(-406 nm)and band gap reduces from 3.18 to 3.06 eV with introduction of Al and Ce *** impedance spectroscopy analysis under visible light illumination confirms the enhancement in visible light activity of Al and Ce co-doped ZnO nanoparticles as *** enhanced activity of Al and Ce co-doped ZnO photocatalyst can be ascribed to enhanced light assimilation,high surface area and efficient charge transfer *** results reveal that by incorporating precise amount of Al(~2%)and Ce(~2%)into ZnO,a highly efficient catalyst can be synthesized that have degraded almost 95%methyl orange(MO)dye in just 45 ***,the influence of various operational parameters such as solution pH,catalyst dose,dye concentration,airflow rate and light intensity on photodecomposition of MO was *** rmore,a possible mechanism for Al and Ce modified ZnO was proposed and designed photocatalysts demonstrates good stability in aqueous medium.

关键词： Nanoparticles ZnO Combustion MO decomposition PL Rare earths

Kinetics of Acid Blue 1 Adsorption from Aqueous Solution by Carbonaceous Substrate Produced from Biotic Precursor

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Chinese Journal of Chemistry 2007年第5期25卷 596-604页

作者： FAZLULLAH, Khan Bangash SULTAN, Alam irshad, ahmad Institute of Chemical Sciences University of Peshawar Peshawar 25120 Pakistan National Center of Excellence in Geology University of Peshawar Peshawar 25120 Pakistan

Adsorption of acid blue 1 from aqueous solution onto carbonaceous substrate produced from the wood of Paulownia tomentosa was investigated. The samples characterized by FTIR, SEM, EDS and XRD techniques, indicated that the surface functional groups like carboxyl, lactones or phenols and ethers have disappeared at high activation temperature （800 ℃） and as a result porous structure was developed that has a positive effect on the adsorption capacity. Bangham and parabolic diffusion models were applied to the kinetic adsorption data, which show that the adsorption of acid blue 1 was a diffusion controlled process. The reaction rate increased with the increase in temperatures of both the adsorption and activation. Thermodynamic parameters like △E^≠, △H^≠, △S^≠ and △G^≠ were calculated from the kinetic data. The negative values of △S^≠ reflected the decrease in the disorder of the system at the solid-solution interface during adsorption. Gibbs free energy （△G^≠）, representing the driving force for the affinity of dye for the carbon surface, increased with the increase in sample activation and the adsorption temperatures.

关键词： activated carbon chemical treatment thermal activation adsorption functional group XRD SEM EDS FTIR

Response of basement wall in tall buildings foundation under lateral loading

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Frontiers of Structural and Civil Engineering 2022年第11期16卷 1415-1423页

作者： Irfan JAMIL irshad ahmad Aqeel Ur REHMAN Aqib AHMED Ameer HAMZA Wali ULLAH Department of Civil Engineering University of Engineering and TechnologyPeshawar 25000Pakistan

With increasing population and limitation of availability of land,tall buildings supported on piled raft foundations are increasingly used in the modern *** increase the ratio of floor area to height,and to fulfill storage and parking facilities requirements,these tall buildings usually have more than one basement ***,during the foundation design,engineers have not considered the basement wall contribution to resisting lateral load induced by earthquake or wind and this can result in an uneconomical construction of *** this research work,an experimental study was performed on small-scale models,in order to study basement wall contribution,and the raft contribution including for piled raft foundations,to resisting lateral *** configurations of piles in 2×2,2×3,and 3×3 patterns were tested as a pile group,piled raft and piled raft with a basement *** show that when a basement wall is present,the lateral displacement decreases and the demand on each pile *** piled raft design can become more economical for tall buildings if the basement’s walls are taken into account.

关键词： basement wall lateral load displacement piled raft

Structural modeling of a typical gas turbine system

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Frontiers in Energy 2012年第1期6卷 57-79页

作者： Naresh YADAV irshad ahmad KHAN Sandeep GROVER Mechanical Engineering Department Jamia Millia IslamiaNew Delhi 110025India Mechanical Engineering Department YMCA University of Science and TechnologyFaridabad 121006India

This paper presents an approach for the structural modeling and analysis of a typical gas turbine system. This approach has been applied to the systems and subsystems, which are integral parts of a typical gas turbine system. Since a gas turbine system performance is measured in terms of fluid flow ene：rgy transformations across its various assemblies and subassemblies, the performance of such subsystems affects the overall performance of the gas turbine system. An attempt has been made to correlate the associativity of such subsystems contributing to overall gas turbine system functional evaluation using graph theoretic approach. The characteristic equations at the system level as well as subsystem level have been developed on the basi.s of associativity of various factors affecting their performance. A permanent function has been proposed for the functional model of a gas turbine system, which further leads to selection, identification and optimal evaluation of gas turbine systems.

关键词： system modeling gas turbine system evaluation graph theoretic approach

Effects of uniconazole with or without micronutrient on the lignin biosynthesis,lodging resistance,and winter wheat production in semiarid regions

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Journal of Integrative Agriculture 2020年第1期19卷 62-77页

作者： irshad ahmad MENG Xiang-ping Muhammad KAMRAN Shahzad ALI Shakeel ahmad LIU Tie-ning CAI Tie HAN Qing-fang Key Laboratory of Crop Physio-Ecology and Tillage Science in North-Western Loess Plateau Ministry of Agriculture/College of AgronomyNorthwest A&F UniversityYangling 712100P.R.China Key Laboratory of Agricultural Soil and Water Engineering in Arid and Semiarid Areas Ministry of Education/Institute of Water Saving Agriculture in Arid Areas of ChinaNorthwest A&F UniversityYangling 712100P.R.China

Lodging stress results in grain yield and quality reduction in wheat. Uniconazole, a potential plant growth regulator significantly enhances lignin biosynthesis and thus provides mechanical strength to plants in order to cope with lodging stress. A field study was conducted during the 2015–2016 and 2016–2017 growing seasons, to investigate the effects of uniconazole sole application or with micronutrient on the lignin biosynthesis, lodging resistance, and production of winter wheat. In the first experiment, uniconazole at concentrations of 0(CK), 15(US1), 30(US2), and 45(US3) mg L^-1 was applied as sole seed soaking, while in the second experiment with manganese(Mn) at concentration of 0.06 g L^-1 Mn, 0.06 g L^-1 Mn+ 15 mg L^-1 uniconazole(UMS1), 0.06 g L^-1 Mn+30 mg L^-1 uniconazole(UMS2), and 0.06 g L^-1 Mn+45 mg L^-1 uniconazole(UMS3), respectively. Uniconazole sole application or with micronutrient significantly increased the lignin content by improving the lignin-related enzyme activities of phenylalanine ammonia-lyase, cinnamyl alcohol dehydrogenase, tyrosine ammonialyase, and peroxidase, ameliorating basal internode characteristics, and breaking strength. The spike length, spike diameter, spikes/plant, weight/spike, yield/spike, and grain yield increased and then decreased with uniconazole application at a higher concentration, where their maximum values were recorded with UMS2 and US2 treatments. The lignin accumulation was positively correlated with lignin-related enzyme activities and breaking strength while, negatively correlated with lodging rate. Uniconazole significantly improved the lignin biosynthesis, lodging resistance, and grain yield of winter wheat and the treatments which showed the greatest effects were uniconazole seed soaking with micronutrient at a concentration of 30 mg L^-1 and 0.06 g L^-1 , and uniconazole sole seed soaking at a concentration of 30 mg L^-1 .

关键词： lignin biosynthesis lodging resistance semi-arid regions manganese uniconazole wheat

An Adaptive Edge Detection Algorithm for Weed Image Analysis

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Computer Systems Science & Engineering 2023年第12期47卷 3011-3031页

作者： Yousef Alhwaiti Muhammad Hameed Siddiqi irshad ahmad College of Computer and Information Sciences Jouf UniversitySakakaAljouf73211Saudi Arabia Department of Computer Science Islamia College(Chartered University)Peshawar25000Pakistan

Weeds are one of the utmost damaging agricultural annoyers that have a major influence on *** have the responsibility to get higher production costs due to the waste of crops and also have a major influence on the worldwide agricultural *** significance of such concern got motivation in the research community to explore the usage of technology for the detection of weeds at early stages that support farmers in agricultural *** weed methods have been proposed for these fields;however,these algorithms still have challenges as they were implemented against controlled ***,in this paper,a weed image analysis approach has been proposed for the system of weed *** this system,for preprocessing,a Homomorphic filter is exploited to diminish the environmental ***,for feature extraction,an adaptive feature extraction method is proposed that exploited edge *** proposed technique estimates the directions of the edges while accounting for non-maximum *** method has several benefits,including its ease of use and ability to extend to other types of ***,low-level details in the formof features are extracted to identify weeds,and additional techniques for detecting cultured weeds are utilized if *** the processing of weed images,certain edges may be verified as a footstep function,and our technique may outperform other operators such as gradient *** relevant details are extracted to generate a feature vector that is further given to a classifier for weed ***,the features have been used in logistic regression for weed *** model was assessed against logistic regression that accurately identified different kinds of weed images in naturalistic *** proposed approach attained weighted average recognition of 98.5%against the weed images ***,it is assumed that the proposed approach might help in the weed classification s

关键词： Weeds images classification enhancement logistic regression agricultural fields remote sensing

Nitrogen management improves lodging resistance and production in maize(Zea mays L.)at a high plant density

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Journal of Integrative Agriculture 2023年第2期22卷 417-433页

作者： irshad ahmad Maksat BATYRBEK Khushnuma IKRAM Shakeel ahmad Muhammad KAMRAN Misbah Raham Sher KHAN HOU Fu-jiang HAN Qing-fang Key Laboratory of Crop Physio-Ecology and Tillage Science in North-Western Loess Plateau Ministry of Agriculture/College of AgronomyNorthwest A&F UniversityYangling 712100P.R.China State Key Laboratory of Herbage Improvement and Grassland Agro-Ecosystems/Key Laboratory of Grassland Livestock Industry Innovation Ministry of Agriculture and Rural Affairs/Engineering Research Center of Grassland IndustryMinistry of Education/College of Pastoral Agriculture Science and TechnologyLanzhou UniversityLanzhou 730020P.R.China Department of Biotechnology Abdul Wali Khan University MardanMardan 23200Pakistan

Lodging in maize leads to yield losses *** this study,we determined the effects of traditional and optimized nitrogen management strategies on culm morphological characteristics,culm mechanical strength,lignin content,root growth,lodging percentage and production in maize at a high plant *** compared a traditional nitrogen(N)application rate of 300 kg ha–1(R)and an optimized N application rate of 225 kg ha^(–1)(O)under four N application modes:50%of N applied at sowing and 50%at the 10th-leaf stage(N1);100%of N applied at sowing(N2);40%of N applied at sowing,40%at the 10th-leaf stage and 20%at tasseling stage(N3);and 30%of N applied at sowing,30%at the 10th-leaf stage,20%at the tasseling stage,and 20%at the silking stage(N4).The optimized N rate(225 kg ha^(–1))significantly reduced internode lengths,plant height,ear height,center of gravity height and lodging *** optimized N rate significantly increased internode diameters,filling degrees,culm mechanical strength,root growth and lignin *** application of N in four split doses(N4)significantly improved culm morphological characteristics,culm mechanical strength,lignin content,and root growth,while it reduced internode lengths,plant height,ear height,center of gravity height and lodging *** diameters,filling degrees,culm mechanical strength,lignin content,number and diameter of brace roots,root volume,root dry weight,bleeding safe and grain yield were significantly negatively correlated with plant height,ear height,center of gravity height,internode lengths and lodging *** conclusion,treatment ON4 significantly reduced the lodging percentage by improving the culm morphological characteristics,culm mechanical strength,lignin content,and root growth,so it improved the production of the maize crop at a high plant density.

关键词： high plant density lodging resistance maize nitrogen rates nitrogen application modes

Synthesis of yttrium and cerium doped ZnO nanoparticles as highly inexpensive and stable photocatalysts for hydrogen evolution

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Journal of Rare Earths 2021年第4期39卷 440-445页

作者： irshad ahmad Muhammad Shoaib Akhtar Mian Faisal Manzoor Muhammad Wajid Muhammad Noman Ejaz Ahmed Mukhtar ahmad Waheed Qamar Khan Anwar M.Rana Department of Physics.Bahauddin Zakariya University Multan60800Pakistan School of Computer and Communication Lanzhou University of Technology.Lanzhou730050China Department of Physics University of Agriculture Faisalabad38040Pakistan Institute of Advanced Materials Bahauddin Zakariya UniversityMultan6800Pakistan

Yttrium and cerium co-doped ZnO nanoparticles were synthesized by combustion route and characterized using X-ray diffraction(XRD),scanning electron microscopy(SEM),Brunauer-Emmett-Teller(BET),energy dispersive spectroscopy(EDS),X-ray photoelectron spectroscopy(XPS),UV-visible diffuse reflectance spectroscopy(UV-vis DRS),photoluminescence(PL)and electrochemical impedance spectroscopy(EIS)*** introduction of yttrium ions has efficiently increased the relative percentage of Ce^(3+)ions in *** and cerium co-doped ZnO shows efficient photo activity for hydrogen evolution(10.61 mmol/((g·h))higher than previously reported optimal value for rare earth codoped ZnO *** remarkably increased hydrogen evolution can be ascribed to the synergy between electronic anchoring effect of Y^(3+)/Y^(2+)and Ce^(4+)/Ce^(3+)redox *** report presents new idea for the synthesis of efficient photocatalyst using economical route and ion anchoring *** hydrogen evolution was also tested using Na_(2)S and Na_(2)SO_(3)as electron donors under visible light *** synthesized photocatalysts also exhibit high stability.

关键词： ZnO H_(2)evolution Na_(2)SO_(3) PL Stability Rare earths

Salt Stress Affects the Growth and Yield of Wheat (Triticum aestivum L.) by Altering the Antioxidant Machinery and Expression of Hormones and Stress- Specific Genes

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Phyton-International Journal of Experimental Botany 2023年第3期92卷 861-881页

作者： Shahid Hussain Rui Zhang Shuli Liu Yang Wang irshad ahmad Yinglong Chen Hongyan Hou Qigen Dai Jiangsu Key Laboratory of Crop Genetics and Physiology Jiangsu Key Laboratory of Crop Cultivation and PhysiologyJiangsu Coinnovation Center for Modern Production Technology of Grain CropsResearch Institute of Rice Industrial Engineering TechnologyKey Laboratory of Saline-Alkali Soil Improvement and Utilization(Coastal Saline-Alkali Lands)Ministry of Agriculture and Rural AffairsYangzhou UniversityYangzhou225000China Joint International Research Laboratory of Agriculture and Agri-Product Safety of the Ministry of Education of China Yangzhou UniversityYangzhou225009China Yibang Agriculture Technology Development Co. Ltd.Dongying257000China

Understanding physiological responses in saline agriculture may facilitate wheat breeding *** on a screening test,the Ningmai-14(NM-14)and Yangmai-23(YM-23)wheat cultivars were selected for further experiments to understand the underlying salinity tolerance *** study investigated the effects of five salinity levels such as Control(CK)=0(without NaCl stress),S1=0.20%,S2=0.25%,S3=0.30%and S4=0.35%of NaCl concentrations of soil on wheat *** results showed that increased salinity concentration reduced the growth and yield of wheat cultivars(NM-14 and YM-23).However,YM-23(12.7%)yielded more than NM-14 at maximum salinity *** higher salinity(S4)increased the concentration of Na^(+)(4.3 to 5.8-fold)and P contents(2.5 to 2.2-fold),while reducing the average concentrations of K^(+),Cu,and K^(+)/Na^(+)*** higher salinity(S4)reduced the spikelet length by 21.35%(followed by grain spike−1),and the starch content by 18.81%.In the YM-23 cultivar,higher salinity increased superoxide dismutase(SOD),total antioxidant capacity(TAC),and *** to NM-14,induced expression of TaYUC2,6,and TaGA13ox,20ox genes were recorded in ***,in YM-23 the stress-specific genes such as TaHSP70,90 were enhanced whereas,TaSOS1,2 were ***,our study revealed that salt tolerant cultivars modulate hormonal and antioxidant activities,thus maintaining high growth.

关键词： Salinity wheat hormones K^(+)/Na^(+)ratio growth and yield gene expression