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Ionized jet deposition of antimicrobial and stem cell friendly silver-substituted tricalcium phosphate nanocoatings on titanium alloy

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Bioactive Materials 2021年第8期6卷 2629-2642页

作者： Gabriela Graziani Katia Barbaro inna v.fadeeva Daniele Ghezzi Marco Fosca Enrico Sassoni Gianluca vadalà Martina Cappelletti Francesco valle Nicola Baldini Julietta v.Rau IRCSS Istituto Ortopedico Rizzoli Laboratory of NanoBiotechnologyvia di Barbiano 1/1040136BolognaItaly Istituto Zooprofilattico Sperimentale Lazio e Toscana“M.Aleandri” Via Appia Nuova 1411-00178RomeItaly A.A.Baikov Institute of Metallurgy and Materials Science Russian Academy of SciencesLeninsky prospect 49119334MoscowRussia Istituto di Struttura della Materia Consiglio Nazionale delle Ricerche(ISM-CNR)Via del Fosso del Cavaliere100-00133RomeItaly University of Bologna Department of CivilChemicalEnvironmental and Materials Engineeringvia Terracini 2840131BolognaItaly UniversitàCampus Bio-Medico di Roma Research Unit of Orthopaedic SurgeryFaculty of Medicine and SurgeryVia Alvaro del Portillo 2100128RomeItaly University of Bologna Department of Pharmacy and Biotechnologyvia Irnerio 4240126BolognaItaly Institute of Nanostructured Materials National Research Council(ISMN-CNR)Via Piero Gobetti10140129BolognaItaly IRCSS Istituto Ortopedico Rizzoli BST Biomedical Science and Technologies Labvia di Barbiano 1/1040136BolognaItaly University of Bologna Department of Biomedical and Neuromotor SciencesVia Massarenti940128BolognaItaly Sechenov First Moscow State Medical University Institute of PharmacyDepartment of AnalyticalPhysical and Colloid ChemistryTrubetskaya 8build.2119991MoscowRussia

Orthopedic infections pose severe societal and economic burden and interfere with the capability of the implanted devices to integrate in the host bone,thus significantly increasing implants failure *** address infection and promote integration,here nanostructured antibacterial and bioactive thin films are proposed,obtained,for the first time,by Ionized Jet Deposition(IJD)of silver-substituted tricalcium phosphate(Ag-TCP)targets on *** morphology,composition and mechanical properties are characterized and proof-of-concept of biocompatibility is *** efficacy is investigated against four Gram positive and Gram negative bacterial strains and against *** fungus,by investigating the modifications in planktonic bacterial growth in the absence and presence of ***,for all bacterial strains,the capability of the film to inhibit bacterial adhesion is also *** indicate that IJD permits a fine control over films composition and morphology and deposition of films with suitable mechanical *** studies show a good efficacy against Escherichia coli,Staphylococcus aureus,Pseudomonas aeruginosa,Enterococcus faecalis and against fungus Candida albicans,with evidences of efficacy against planktonic growth and significant reduction of bacterial cell *** cytotoxic effects are evidenced for equine adipose tissue derived mesenchymal stem cells(ADMSCs),as no reductions are caused to cells viability and no interference is assessed in cells differentiation towards osteogenic lineage,in the presence of ***,thanks to nanostructuration and biomimetic composition,tricalcium phosphate(TCP)coatings favor cells viability,also when *** findings show that silver-substituted nanostructured coatings are promising for orthopedic implant applications.

关键词： Tricalcium phosphate Silver Nanostructured coatings Antibacterial coatings Orthopedics Antibacterial ceramics

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Structural traits of woody plants and geomorphological conditions to the vegetation recovery at Ksudach caldera(Southern Kamchatka) since the explosive eruption in 1907

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Journal of Mountain Science 2020年第7期17卷 1613-1635页

作者： KOPANINA Anna v LEBEDEvA Ekaterina v vLASOvA inna I TALSKIKH Anastasia v Institute of Marine Geology and Geophysics Far Eastern Branch of the Russian Academy of SciencesNauka street1 B693022Yuzhno-SakhalinskRussia Institute of Geography Russian Academy of SciencesStaromonetny s-str.29119017MoscowRussia

This study considers the restoration of the plant cover destroyed by a catastrophic volcano eruption in the south of Kamchatka Peninsula(the Ksudach caldera,Shtyubel cone),with a particular attention to the role of woody *** aims to qualitatively estimate(at a qualitative level)the rate of the primary succession development depending on the microrelief and the modern relief-forming *** vegetation recovery in the caldera after the Shtyubel cone eruption 109 years ago proceeds slowly and *** proceeds most slowly on a thick tephra mantle continuously disturbed by water and wind erosion,lahars,debris flows,landslides,*** conditions are most typical of the western part of the caldera dominated by pumice fields with occasional patches of pioneer herbs and dwarf *** tundra communities with gradually expanding patches of shrub alder develop in the southern,eastern and northeastern parts of the Ksudach *** 1997 the area of the shrub alder communities has increased by 1.9 times,while the alpine tundra–by 1.3 times *** woody plants(dwarf shrubs and prostrate shrubs)are of particular importance in the process of the vegetation recovery on pumice *** suggest that the bark thickness of woody plants is an integrated indicator,which may serve for estimating the state of ecosystem in the course of the primary succession development on juvenile *** extremely inhospitable environments cause changes in physiological processes in the plant body and in its bark in *** results show that woody plants have a"thin"bark and develop some structural-functional arrangements for keeping bark tissues at their ***,the woody plant structure and the rate of changes in plant communities are under control of the geomorphic conditions and primarily–of physicochemical features of the pyroclastic cover.

关键词： Ksudach caldera Pioneer species Woody plants Bark Pyroclastic deposits Geomorphological processes

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Interactive effects of metal pollution and ocean acidification on physiology of marine organisms

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Current Zoology 2015年第4期61卷 653-668页

作者： Anna v. Ivanina inna M. Sokolova Department of Biological Sciences University of North Carolina at Charlotte Charlotte NC 28223 USA

Changes in the global environment such as ocean acidification （OA） may interact with anthropogenic pollutants including trace metals threatening the integrity of marine ecosystems. We analyze recent studies on the interactive effects of OA and trace metals on marine organisms with a focus on the physiological basis of these interactions. Our analysis shows that the responses to elevated CO2 and metals are strongly dependent on the species, developmental stage, metal biochemistry and the degree of environmental hypercapnia, and cannot be directly predicted from the CO2-induced changes in metal solubility and speciation. The key physiological functions affected by both the OA and trace metal exposures involve acid-base regulation, pro- tein turnover and mitochondrial bioenergetics, reflecting the sensitivity of the underlying molecular and cellular pathways to CO2 and metals. Physiological interactions between elevated CO2 and metals may impact the organisms＇ capacity to maintain ac- id-base homeostasis and reduce the amount of energy available for fitness-related functions such as growth, development and re- production thereby affecting survival and performance of estuarine populations. Environmental hypercapnia may also affect the marine food webs by altering predator-prey interactions and the trophic transfer of metals in the food chain. However, our under- standing of the degree to which these effects can impact the function and integrity of marine ecosystems is limited due the scar- city of the published research and its bias towards certain taxonomic groups. Future research priorities should include studies of metal x Pco2 interactions focusing on critical physiological functions （including acid-base, protein and energy homeostasis） in a greater range of ecologically and economically important marine species, as well as including the field populations naturally ex- posed （and potentially adapted） to different levels of metals and CO2 in their environments [Curre

关键词： CO2 Trace metals Metal accumulation Acid-base homeostasis Bioenergetics Estuaries

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The Russian-Kazakh Altai orogen:An overview and main debatable issues

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Geoscience Frontiers 2014年第4期5卷 537-552页

作者： inna Safonova Institute of Geology and Mineralogy SB RASKoptyuga Ave.3Novosibirsk 630090Russia Novosibirsk State University Pirogova St.2Novosibirsk 630090Russia

The paper reviews previous and recently obtained geological, stratigraphic and geochronological data on the Russian-Kazakh Altai orogen, which is located in the western Central Asian Orogenic Belt （CAOB）, between the Kazakhstan and Siberian continental blocks. The Russian-Kazakh Altai is a typical Pacific-type orogen, which represents a collage of oceanic, accretionary, fore-arc, island-arc and continental margin terranes of different ages separated by strike-slip faults and thrusts. Evidence for this comes from key indicative rock associations, such as boninite- and turbidite （graywacke）-bearing volcanogenic-sedimentary units, accreted pelagic chert, oceanic islands and plateaus, MORB-OIB-protolith blueschists. The three major tectonic domains of the Russian-Kazakh Altai are：（1） Altai-Mongolian terrane （AMT）; （2） subduction-accretionary （Rudny Altai, Gorny Altai） and collisional （Kalba-Narym） terranes; （3） Kurai, Charysh-Terekta, North-East, Irtysh and Char suture-shear zones （SSZ）. The evolution of this orogen proceeded in five major stages：（i） late Neoproterozoic-early Paleozoic subduction-accretion in the Paleo-Asian Ocean; （ii） Ordovician-Silurian passive margin; （iii） Devonian-Carboniferous active margin and collision of AMT with the Siberian conti- nent; （iv） late Paleozoic closure of the PAO and coeval collisional magmatism; （v） Mesozoic post-collisional deformation and anarogenic magmatism, which created the modern structural collage of the Russian- Kazakh Altai orogen. The major still unsolved problem of Altai geology is origin of the Altai-Mongolian terrane （continental versus active margin）, age of Altai basement, proportion of juvenile and recycled crust and origin of the middle Paleozoic units of the Gorny Altai and Rudny Altai terranes.

关键词： Altai-Mongolian terraneGorny and Rudny Altai terranesKalba-NarymIsland arcsPaleo-Asian Ocean

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Studying the direction of hydraulic fracture in carbonate reservoirs:Using machine learning to determine reservoir pressure

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Petroleum Research 2023年第2期8卷 226-233页

作者： Dmitriy A.Martyushev inna N.Ponomareva Evgenii v.Filippov Department of Oil and Gas Technologies Perm National Research Polytechnic UniversityPerm614990Russia Department of Oil and Gas Fields Development LLC《LUKOIL-PERM》Perm614068Russia

Hydraulic fracturing(HF)is an effective way to intensify oil production,which is currently widely used in various conditions,including complex carbonate *** the conditions of the field under consideration,the hydraulic fracturing leads to a significant differentiation of technological efficiency indicators,which makes it expedient to study the patterns of crack formation in *** were carried out for all wells,which were considered as the objects of impact,to assess the spatial orientation of the cracks *** developed indirect method was used for this purpose,the reliability of which was confirmed by geophysical *** the analysis,it was found that in all cases,the crack is oriented in the direction of the section of the development system element characterized by the maximum reservoir *** the same time,the reservoir pressure values for all wells were determined at one point in time(at the beginning of HF)using machine learning *** reliability of the machine learning methods used is confirmed by the high convergence with the actual(historical)reservoir pressures obtained during hydrodynamic studies of *** obtained conclusion about the influence of the reservoir pressure on the patterns of fracture formation should be taken into account when planning hydraulic fracturing under the conditions studied.

关键词： Hydraulic fracturing direction Machine learning Actual field data Correlation coefficient Well flow rate Well geophysical studies Carbonate reservoir

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Triggers and sources of volatile-bearing plumes in the mantle transition zone

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Geoscience Frontiers 2015年第5期6卷 679-685页

作者： inna Safonova Konstantin Litasov Shigenori Maruyama v.S.Sobolev Institute of Geology and Mineralogy SB RAS Novosibirsk State University Earth-Life Science Institute Tokyo Institute of Technology

The paper discusses generation of volatile-bearing plumes in the mantle transition zone(MTZ) in terms of mineral-fluid petrology and their related formation of numerous localities of intra-plate bimodal volcanic series in Central and East *** plume generation in the MTZ can be triggered by the tectonic erosion of continental crust at Pacific-type convergent margins and by the presence of water and carbon dioxide in the *** probable sources of volatiles are the hyclrated/carbonated sediments and basalts and serpentinite of oceanic slabs,which can be subducted down to the deep *** erosion of continental crust supplies crustal material enriched in uranium and thorium into the mantle,which can serve source of heat in the *** heating in the MTZ induces melting of subducted slabs and continental crust and mantle upwelling,to produce OIB-type mafic and felsic melts,respectively.

关键词： Asis Pacific-type convergent margin Continental cr

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On the Possibilities of using Some Modern Three-dimensional Modeling Means in Forensic Examination

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Journal of Forensic Science and Medicine 2022年第1期8卷 17-23页

作者： Dmitry S Afonin Iryna v Hora valerii A Kolesnyk inna I Popovych Iryna v Kuchynska Department of Administrative Activity of Police Odesa State University of Internal AffairsOdesa Scientific Center National Academy of the Security Service of Ukraine Department of Criminal Law and Procedure Uzhhorod National UniversityUzhhorod Center for Forensic and Special Examinations The Ukrainian Scientific and Research Institute of Special Equipment and Forensic Expertise of the Security Service of UlaaineKyivUkraine

Background:The paper examines the state and prospects of using 3D modeling in solving identification,classification,diagnostic and situational tasks of forensic *** and Objectives:The aim of this study is to analyze the world expert practice of using scientific and technical means of three-dimensional modeling in solving problems of forensic examination,using the example of our country,the leading countries of Europe,as well as the United *** and Methods:The empirical basis of the study is the results of the systematization of scientific and technical means for 3D modeling in solving identification,classification,diagnostic and situational problems of forensic examinations used in the expert practice of Ukraine,the United Kingdom,France,Germany,and the ***:The systematization of modem scientific and technical means for 3D modeling,used in solving identification,classification,diagnostic and situational tasks of forensic examination,has been carried *** analyzed and identified 3D modeling software that most fully meets the requirements of effective forensic expert *** features of the use of effective 3D modeling mean for solving identification,classification,diagnostic and situational tasks of forensic examination,namely the software systems"ToolScan"and"TrasoScan",and the SketchUp program have been ***:The introduction of the SketchUp 8 software into forensic expert activities will increase the effectiveness of the modeling method in forensic examinations,which,in turn,will have an impact on the effectiveness of expert conclusions,increase their evidentiary value and,as a result,contribute to the entire process of a criminal investigation.

关键词： Classification tasks diagnostic tasks forensic practice identification tasks photogrammetric modeling simulation modeling three-dimensional model

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Electrolyte materials for protonic ceramic electrochemical cells:Main limitations and potential solutions

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Materials Reports(Energy) 2022年第4期2卷 19-35页

作者： Anna v.Kasyanova inna A.Zvonareva Natalia A.Tarasova Lei Bi Dmitry A.Medvedev Zongping Shao Laboratory of Electrochemical Devices Based on Solid Oxide Proton Electrolytes Institute of High Temperature Electrochemistry620990YekaterinburgRussia Hydrogen Energy Laboratory Ural Federal University620002YekaterinburgRussia School of Resource and Environment and Safety Engineering University of South ChinaHengyangHunan421001China State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical EngineeringNanjing Tech UniversityNanjing210009China WA School of Mines:Minerals Energy and Chemical Engineering(WASM-MECE)Curtin UniversityPerthWA6845Australia

Solid oxide fuel cells(SOFCs)and electrolysis cells(SOECs)are promising energy conversion devices,on whose basis green hydrogen energy technologies can be developed to support the transition to a carbon-free *** compared with oxygen-conducting cells,the operational temperatures of protonic ceramic fuel cells(PCFCs)and electrolysis cells(PCECs)can be reduced by several hundreds of degrees(down to low-and intermediatetemperature ranges of 400–700C)while maintaining high performance and *** is due to the distinctive characteristics of charge carriers for proton-conducting ***,despite achieving outstanding lab-scale performance,the prospects for industrial scaling of PCFCs and PCECs remain hazy,at least in the near future,in contrast to commercially available SOFCs and *** this review,we reveal the reasons for the delayed technological development,which need to be addressed in order to transfer fundamental findings into industrial *** solutions to the identified problems are also highlighted.

关键词： Protonic ceramic fuel cells(PCFCs) Protonic ceramic electrolysis cells(PCECs) Proton transport Electrochemistry Hydrogen energy

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Quality of drinking water and risk to the health of the population of the south Baikal region (Russia)

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Emerging Contaminants 2024年第2期10卷 106-114页

作者： viktor S.Rukavishnikov Natalia v.Efimova Mikhail F.Savchenkov inna v.Mylnikova Alexander A.Lisovtsov East-Siberian Institute of Medical and Ecological Research 665827AngarskRussia

Providing good quality water in sufficient quantities is a major challenge in the *** purpose of the study is to assess the quality of drinking water and the health risk of various population groups in the southern Baikal region(Siberia,Russia)under changing hydrological *** Baikal is the largest freshwater body of water and is one of the sites protected by *** and *** analysis of centralized and non-centralized water supply was carried out in the south-eastern part of the Irkutsk region,adjacent to Lake *** data used are from the Baikal(regional)Information Center for 2011–2022,and they include the results of monitoring the water quality of the centralized domestic and drinking water supply(CDW)with 140 thousand samples,and non-centralized domestic and drinking water supply(NDW)with 108 thousand *** all samples,17 substances were *** addition,during the flood period,accompanied by additional water disinfection,trihalomethanes were determined in populated areas exposed to negative *** quality of drinking water was assessed in comparison with the maximum permissible concentrations of substances(MPCs)approved by regulatory documents of *** assessment of the characteristics of drinking water consumption by the population of the Baikal region was carried out,based on interview data from sample groups of the *** assessment of the risk to public health,due to chronic oral intake of chemicals,was carried out using the values of the hazard coefficient(HQi),the hazard index(HI),individual carcinogenic risk(ICR),and population carcinogenic risk(PCR).village residents more often use underground water sources(centralized and non-centralized).Residents of cities are provided with water from surface sources(Lake Baikal and the Angara River).Significant concentrations of iron,nitrates,and manganese were found in drinking water used by *** concentrations of iron-2.25 mg/dl,manganese

关键词： Drinking water Noncarcinogenic risk Carcinogenic risk Population South Baikal region

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Porous Shish-Kebab Structure Prepared from Oriented UHMWPE Films by Processing in Supercritical CO_(2)

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Chinese Journal of Polymer Science 2024年第1期42卷 97-104,I0009页

作者： Sergey A.Lermontov Aleksey v.Maksimkin Nataliya A.Sipyagina Tarek Dayyoub Alena N.Malkova Evgeniy A.Kolesnikov Elena A.Straumal inna O.Gozhikova Saidkhodzha G.Nematulloev Dmitry v.Telyshev Institute of Physiologically Active Compounds of the Russian Academy of Sciences Chernogolovka 142432Russia Institute for Bionic Technologies and Engineering I.M.Sechenov First Moscow State Medical University(Sechenov University)Moscow 19991Russia National University of Science and Technology"MISIS"Moscow 119049 Russia Institute of Biomedical Systems National Research University of Electronic TechnologyZelenogradMoscow 124498Russia

For the first time, a highly crystalline porous shish-kebab structure with a high degree of crystallinity was obtained by using a combination of two methods for the formation of porous polymeric materials. A treatment procedure using supercritical carbon dioxide(sc CO_(2))was carried out for oriented ultrahigh molecular weight polyethylene(UHMWPE) films, which provided special conditions for the crystallization of dissolved UHMWPE macromolecules on the surface of oriented UHMWPE crystals. The prepared porous materials were investigated by scanning electron microscopy(SEM) and differential scanning calorimetry(DSC). The particularity of the obtained porous shish-kebab is the absence of the amorphous phase between lamellar crystals(kebabs). The obtained pores had an oval shape, and they were oriented in the orientation direction of the UHMWPE macromolecules. The pore size ranged from 0.05 μm to 4 μm. Controlling the conditions for the crystallization of the UHMWPE macromolecules using supercritical CO_(2) gives the possibility to control the size of both lamellar disks and pores formed.

关键词： UHMWPE Supercritical CO_(2) Porous shish-kebab structure

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