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Bio-capped and green synthesis of ZnO/g-C_(3)N_(4) nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation

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Chinese Journal of Chemical Engineering 2023年第4期56卷 215-224页

作者： iltaf khan Chunjuan Wang Shoaib khan Jinyin Chen Aftab khan Sayyar Ali Shah Aihua Yuan Sohail khan Mehwish KButt Humaira Asghar School of Environmental&Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212100China College of Agriculture Shihezi UniversityShihezi 832003China Key Laboratory of Biology and Genetic Improvement of Horticultural Crops Northeast Agricultural UniversityHarbin 150030China Jiangxi Key Laboratory for Postharvest Technology and Nondestructive Testing of Fruits and Vegetables College of AgronomyJiangxi Agricultural UniversityNanchang 330045China Department of Pharmacy University of SwabiKhyber Pakhtunkhwa 94640Pakistan Department of Physics University of Agriculture FaisalabadFaisalabad 38040Pakistan Department of Chemistry Government College University FaisalabadFaisalabad 38000Pakistan

In this research study, we have synthesized the bio-capped ZnO/g-C_(3)N_(4) nanocomposites by employing lemon juice(Citrus limon) as a stabilizer and mediator. Fruitfully, lemon juice which contains various acidic functional groups and citric acid has the capability to block the surface of g-C_(3)N_(4) from chemical reactivity and activated the surface of g-C_(3)N_(4) for various reactions. Consequently, the agglomeration behavior and controlled shape of g-C_(3)N_(4) has also been achieved. Our experimental results i.e. XRD,TEM, HRTEM, PL, FS, XPS, and PEC have confirmed that the lemon juice mediated and green g-C_(3)N_(4)(L-CN) have good performances and remarkable visible light photocatalytic activities as compared to the chemically synthesized g-C_(3)N_(4)(CN). Furthermore, the small surface area and low charge separation of g-C_(3)N_(4) is upgraded by coupling with Zn O nanoparticles. It is proved that the coupling of Zn O worked as a facilitator and photoelectron modulator to enhance the charge separation of g-C_(3)N_(4). Compared to pristine lemon-mediated green g-C_(3)N_(4)(L-CN), the most active sample 5Zn O/L-CN showed ~ 5-fold improvement in activities for ciprofloxacin(CIP) and methylene blue(MB) degradation. More specifically,the mineralization process and degradation pathways, and the mineralization process of ciprofloxacin(CIP) and methylene blue(MB) are suggested. Finally, our present novel research work will provide new access to synthesize the eco-friendly and bio-caped green g-C_(3)N_(4)nanomaterials and their employment for pollutants degradation and environmental purification.

关键词： Bio-caped green g-C_(3)N_(4) Lemon juice mediators ZnO/g-C_(3)N_(4)nanocomposite Environmental remediation Degradation pathways

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Photocatalytic H2 generation via CoP quantum-dot-modified g-C3N4 synthesized by electroless plating

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Chinese Journal of Catalysis 2020年第1期41卷 114-121页

作者： Kezhen Qi Wenxiu Lv iltaf khan Shu-yuan Liu Institute of Catalysis for Energy and Environment College of Chemistry and Chemical EngineeringShenyang Normal UniversityShenyang 110034LiaoningChina Research Institute of Photocatalysis State Key Laboratory of Photocatalysis on Energy and EnvironmentCollege of ChemistryFuzhou UniversityFuzhou 350116FujianChina Key Laboratory of Functional Inorganic Material Chemistry Ministry of EducationSchool of ChemistryChemical Engineering and MaterialsHeilongjiang UniversityHarbin 158308HeilongjiangChina Department of Pharmacology Shenyang Medical CollegeShenyang 110034LiaoningChina Key Laboratory for Photonic and Electronic Bandgap Materials Ministry of EducationCollege of Physics and Electronic EngineeringHarbin Normal UniversityHarbin 150025HeilongjiangChina

Photocatalytic water splitting is a promising method for hydrogen *** efficient photocatalysts have been synthesized and ***,photocatalysts without a noble metal as the co-catalyst have been rarely ***,a CoP co-catalyst-modified graphitic-C3N4(g-C3N4/CoP)is investigated for photocatalytic water splitting to produce *** g-C3N4/CoP composite is synthesized in two *** first step is related to thermal decomposition,and the second step involves an electroless plating *** photocatalytic activity for hydrogen evolution reactions of g-C3N4 is distinctly increased by loading the appropriate amount of CoP quantum dots(QDs).Among the as-synthesized samples,the optimized one(g-C3N4/CoP-4%)shows exceptional photocatalytic activity as compared with pristine g-C3N4,generating H2 at a rate of 936μmol g^-1 h^-1,even higher than that of g-C3N4 with 4 wt%Pt(665μmol g^-1 h^-1).The UV-visible and optical absorption behavior confirms that g-C3N4 has an absorption edge at 451 nm,but after being composited with CoP,g-C3N4/CoP-4%has an absorption edge at 497 ***,photoluminescence and photocurrent measurements confirm that loading CoP QDs to pristine g-C3N4 not only enhances the charge separation,but also improves the transfer of photogenerated e--h+pairs,thus improving the photocatalytic performance of the catalyst to generate *** work demonstrates a feasible strategy for the synthesis of highly efficient metal phosphide-loaded g-C3N4 for hydrogen generation.

关键词： Photocatalysis CoP quantum dots Electroless plating H2 generation g-C3N4

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优化水泥厂能源管理和生产运作

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软件 2010年第1期31卷 28-30页

作者： iltaf khan Moin Shaikh Lehigh水泥公司西门子过程自动化系统

Lehigh水泥公司在对其位于马里兰州Union Bridge的工厂进行现代化管理的过程中，集成运用了过程控制和能源管理以达到改善整个工厂的生产效率的目的。

关键词：能源管理生产效率水泥厂运作优化 Bridge 现代化管理马里兰州

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A Synergistic Multi-Attribute Decision-Making Method for Educational Institutions Evaluation Using Similarity Measures of Possibility Pythagorean Fuzzy Hypersoft Sets

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Computer Modeling in Engineering & Sciences 2025年第1期142卷 501-530页

作者： Khuram Ali khan Saba Mubeen Ishfaq Atiqe Ur Rahman Salwa El-Morsy Department of Mathematics University of SargodhaSargodha40100Pakistan Department of Mathematics University of Management and TechnologyLahore54000Pakistan Department of Mathematics College of ScienceQassim UniversityBuraydah51452Saudi Arabia

Due to the numerous variables to take into account as well as the inherent ambiguity and uncertainty,evaluating educational institutions can be *** concept of a possibility Pythagorean fuzzy hypersoft set(pPyFHSS)is more flexible in this regard than other theoretical fuzzy set-like models,even though some attempts have been made in the literature to address such *** study investigates the elementary notions of pPyFHSS including its set-theoretic operations union,intersection,complement,OR-and *** results related to these operations are also modified for ***,the similarity measures between pPyFHSSs are formulated with the assistance of numerical examples and ***,an intelligent decision-assisted mechanism is developed with the proposal of a robust algorithm based on similarity measures for solving multi-attribute decision-making(MADM)problems.A case study that helps the decision-makers assess the best educational institution is discussed to validate the suggested *** algorithmic results are compared with the most pertinent model to evaluate the adaptability of pPyFHSS,as it generalizes the classical possibility fuzzy set-like theoretical ***,while considering significant evaluating factors,the flexibility of pPyFHSS is observed through structural comparison.

关键词： Hypersoft set Pythagorean fuzzy hypersoft set computational complexity multi-attribute decision-making optimization similarity measures uncertainty

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A Comparative Numerical Study of Parabolic Partial Integro-Differential Equation Arising from Convection-Diffusion

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Computer Modeling in Engineering & Sciences 2021年第2期126卷 673-692页

作者： Kamil khan Arshed Ali Fazal-i-Haq iltaf Hussain Nudrat Amir Department of Mathematics Islamia CollegePeshawar25000Pakistan Department of Mathematics Statistics and Computer ScienceThe University of AgriculturePeshawar25000Pakistan Department of Basic Sciences&Islamiat University of Engineering&TechnologyPeshawar25000Pakistan Department of Basic Sciences&Humanities CECOS University of Information Technology and Emerging SciencesPeshawar25000Pakistan

This article studies the development of two numerical techniques for solving convection-diffusion type partial integro-differential equation(PIDE)with a weakly singular *** trigonometric B-spline(CTBS)functions are used for interpolation in both *** first method is CTBS based collocation method which reduces the PIDE to an algebraic tridiagonal system of linear *** other method is CTBS based differential quadrature method which converts the PIDE to a system of ODEs by computing spatial derivatives as weighted sum of function *** efficient tridiagonal solver is used for the solution of the linear system obtained in the first method as well as for determination of weighting coefficients in the second *** explicit scheme is employed as time integrator to solve the system of ODEs obtained in the second *** methods are tested with three nonhomogeneous problems for their ***,computational efficiency and numerical convergence of the methods are *** of errors in approximations produced by the present methods versus different values of discretization parameters and convection-diffusion coefficients are *** and diffusion dominant cases are discussed in terms of Peclet *** results are also compared with cubic B-spline collocation method.

关键词： Partial integro-differential equation convection-diffusion collocation method differential quadrature cubic trigonometric B-spline functions weakly singular kernel

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Comparative study of living donor kidney transplants:Right vs left

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World Journal of Transplantation 2025年第1期15卷 115-123页

作者： Taqi khan Nadeem Ahmad Qaisar Iqbal Muneeb Hassan Lajward Asnath Naveed khan Sajid Shakeel Kidney Transplant Unit Rehman Medical InstitutePeshawar 25100Khyber PakhtunkhwaPakistan Department of Surgery Princess Noura Binti AbdulRehman UniversityRiyadh 84428Saudi Arabia

BACKGROUND Transplant teams often hesitate to use the right kidney(RK)in living donor(LD)transplants due to the complexities of anastomosing the short,thin-walled right renal veins,which can potentially lead to graft loss or graft ***,circumstances may arise where selecting the RK over the left kidney(LK)is ***,it is crucial to thoroughly examine the implications of such a choice on the overall transplant *** To compare transplant outcomes between recipients of RK and LK while examining the factors that influence these *** We retrospectively analyzed data from adult patients who received LD kidney transplants involving meticulous patient selection and surgical techniques at our center from January 2020 to December *** included all kidney donors who were over 18,fit to donate,and had undergone diethylenetriamine pentaacetic acid split function and/or computed tomography based *** variables examined comprised donor and recipient demographics,and outcome measures included technical graft loss(TGL),delayed or slow graft function(SGF),and post-transplant serum creatinine(SC)*** used a logistic regression model to assess the likelihood of adverse outcomes considering the donor kidney *** Of the 250 transplants performed during the period,56(22%)were *** recipient demographics and transplant factors were comparable for the right and LKs,except that the donor warm and cold ischemia time were shorter for *** and SGF each occurred in 2%(n=1)of RKs and 0.5%(n=1)of LKs,the difference being *** complications,however,were not related to the venous *** RK(2%)developed delayed graft function after 48 hours,which was attributable to postoperative hypoxia rather than the surgical *** post-transplant SC trend and mean SC at the last follow-up were similar across both kidney *** The donor kidney side has little impact on post-transplant

关键词： Living donor Right kidney Right renal vein Venous anastomosis Technical graft loss Early graft function

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Exploring Nanoscale Perovskite Materials for Next‑Generation Photodetectors:A Comprehensive Review and Future Directions

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Nano-Micro Letters 2025年第2期17卷 46-108页

作者： Xin Li Sikandar Aftab Maria Mukhtar Fahmid Kabir Muhammad Farooq khan Hosameldin Helmy Hegazy Erdi Akman State Key Laboratory of Pulsed Power Laser Technology National University of Defense TechnologyHefei 230037AnhuiPeople’s Republic of China Anhui Laboratory of Advanced Laser Technology Hefei 230037AnhuiPeople’s Republic of China Nanhu Laser Laboratory Changsha 410015HunanPeople’s Republic of China Department of Semiconductor Systems Engineering and Clean Energy Sejong UniversitySeoul 05006Republic of Korea Department of Artificial Intelligence and Robotics Sejong UniversitySeoul 05006Republic of Korea School of Engineering Science Simon Fraser UniversityBurnabyBC V5A 1S6Canada Department of Electrical Engineering Sejong UniversitySeoul 05006South Korea Department of Physics Faculty of ScienceKing Khalid UniversityP.O.Box 9004AbhaSaudi Arabia Central Labs King Khalid UniversityAlQura’aP.O.Box 96061413 AbhaSaudi Arabia Scientific and Technological Research and Application Center Karamanoglu Mehmetbey University70100 KaramanTurkey

The rapid advancement of nanotechnology has sparked much interest in applying nanoscale perovskite materials for photodetection *** materials are promising candidates for next-generation photodetectors(PDs)due to their unique optoelectronic properties and flexible synthesis *** review explores the approaches used in the development and use of optoelectronic devices made of different nanoscale perovskite architectures,including quantum dots,nanosheets,nanorods,nanowires,and *** a thorough analysis of recent literature,the review also addresses common issues like the mechanisms underlying the degradation of perovskite PDs and offers perspectives on potential solutions to improve stability and scalability that impede widespread *** addition,it highlights that photodetection encompasses the detection of light fields in dimensions other than light intensity and suggests potential avenues for future research to overcome these obstacles and fully realize the potential of nanoscale perovskite materials in state-of-the-art photodetection *** review provides a comprehensive overview of nanoscale perovskite PDs and guides future research efforts towards improved performance and wider applicability,making it a valuable resource for researchers.

关键词： Nanoscale perovskites Photodetectors Nanosheets Nanorods Nanowires Quantum dots Nanocrystals

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Modeling and Comprehensive Review of Signaling Storms in 3GPP-Based Mobile Broadband Networks:Causes,Solutions,and Countermeasures

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Computer Modeling in Engineering & Sciences 2025年第1期142卷 123-153页

作者： Muhammad Qasim khan Fazal Malik Fahad Alturise Noor Rahman Department of Computer Science Iqra National UniversityPeshawar25000Pakistan Department of Cybersecurity College of ComputerQassim UniversityBuraydah52555Saudi Arabia Department of Computer Science and Engineering Al-Fayha CollegeAl Jubayl31961Saudi Arabia

Control signaling is mandatory for the operation and management of all types of communication networks,including the Third Generation Partnership Project(3GPP)mobile broadband ***,they consume important and scarce network resources such as bandwidth and processing *** have been several reports of these control signaling turning into signaling storms halting network operations and causing the respective Telecom companies big financial *** paper draws its motivation from such real network disaster incidents attributed to signaling *** this paper,we present a thorough survey of the causes,of the signaling storm problems in 3GPP-based mobile broadband networks and discuss in detail their possible solutions and *** provide relevant analytical models to help quantify the effect of the potential causes and benefits of their corresponding *** important contribution of this paper is the comparison of the possible causes and solutions/countermeasures,concerning their effect on several important network aspects such as architecture,additional signaling,fidelity,etc.,in the form of a *** paper presents an update and an extension of our earlier conference *** our knowledge,no similar survey study exists on the subject.

关键词： Signaling storm problems control signaling load analytical modeling 3GPP networks smart devices diameter signaling mobile broadband data access data traffic mobility management signaling network architecture 5G mobile communication

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2D seismic interpretation of Sawan gas field integrated with petrophysical analysis:A case study from Lower Indus Basin,Pakistan

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Energy Geoscience 2023年第2期4卷 35-48页

作者： Abd Ur Rehman khan Muhammad Amar Gul Rizwan Sarwar Awan Ashar khan Khawaja Hasnain iltaf Sibt.E Hassan Butt Oil and Gas Development Company IslamabadPakistan CAS Key Laboratory of Crust-Mantle Materials and Environments University of Science and Technology of ChinaHefei230026China School of Resources and Environmental Engineering Hefei University of TechnologyHefei230009China Water and Power Development Authority Pakistan Department of Earth&Environmental Sciences The University of Texas at ArlingtonUnited States Geological Survey of Pakistan LahorePakistan

The Lower Indus Basin is the leading hydrocarbon-bearing sedimentary basin in *** study has been conducted on the Sawan gas field located in the Lower Indus Basin,adjacent to a few other wellknown gas fields of Pakistan like Kadanwari,Qadirpur,and Miano gas *** research aims to present the spatial distribution and reservoir potential of the productive zones of the Lower Goru *** present study utilized various two-dimensional(2D)seismic lines and well-log data(Sawan-01 and Sawan-02)to investigate the structural and stratigraphic features of the *** stratigraphic layers are mildly deepening in the southeast *** 2D seismic interpretation of the research area identifies the existence of extensional remanents,i.e.,normal *** extensional structures are associated with horst and graben geometry that acts as a trapping mechanism for *** logs are used to identify the reservoir's diverse lithology and petrophysical *** results indicate fair to good effective porosities,low shale volume,and high hydrocarbon saturation(>55%),signifying good reservoir potential in C interval of the Lower Goru Formation.

关键词： Sawan Seismic Well-logs Goru formation Cretaceous Petrophysics

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Geochemical Characterization of Organic Rich Black Rocks of the Niutitang Formation to Reconstruct the Paleoenvironmental Settings during Early Cambrian Period from Xiangxi Area,Western Hunan,China

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Journal of Earth Science 2023年第6期34卷 1827-1850页

作者： Rizwan Sarwar Awan Chenglin Liu Ashar khan Khawaja Hasnain iltaf Qibiao Zang Yuping Wu Sajjad Ali Muhammad Amar Gul College of Geosciences China University of PetroleumBeijing 102249China State Key Laboratory of Petroleum Resource and Prospecting China University of PetroleumBeijing 102249China Water and Power Development Authority Lahore 54000Pakistan School of Earth and Space Sciences University of Science and TechnologyHefei 230026China

The Niutitang Formation in the South China Block might be a source of hydrocarbon as it contains an enormous quantity of organic *** rock of the Early Cambrian Niutitang Formation is widely distributed in the Yangtze region,but detailed geochemical understanding of it is still *** research discusses the detailed geochemical characteristics of the Niutitang Formation to reconstruct the paleoenvironmental conditions,employing total organic carbon(TOC)content,major,trace,and rare earth element *** this purpose,black rock specimens of the Niutitang Formation from two outcrop sections were utilized for geochemical characterization,and the results compared with another eight sections from the South China *** average total organic carbon in these sediments is significantly higher(5.80 wt.%).In the platform region,lower quantities of TOC indicate a poor potential to produce *** the same time,significantly higher TOC is observed in the deep shelf and slope sediments,indicating a significant potential to produce *** average Ce,Eu and Y anomalies from both Longbizui and Sancha sections studied are 0.74,0.86,1.77,1.07,and 1.19,1.30,*** chemical index of alteration(CAI)throughout the Yangtze block is higher(averaging 71.32)than that of Post Archean Australian Shale(PAAS 69),indicating a moderately weathered source of the Niutitang Formation relative to *** the sediments are moderately weathered,this suggests these rocks might have been derived from felsic rocks,mainly *** normalization of REEs in the black rocks reveals a reduction of light REEs with increase in heavy REEs ***,a positive Eu anomaly,negative Ce anomaly,and a moderate Y/Ho(34.61)are clues to a hybrid depositional mechanism associated with hydrothermal action and terrigenous *** anomalies are also evidence of upwelling in the paleo-ocean and mixing of organic matter,which created anoxic bottom water

关键词： anomaly paleo-ocean paleoenvironment chemical index alteration weathering meta-somatism sediments

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