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Low-temperature synthesis of Fe_(2)(MoO_(4))_(3) nanosheets: A cathode for sodium ion batteries with kinetics enhancement

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Nano Research 2021年第11期14卷 3977-3987页

作者： ha Tran Huu N.S.M.Viswanath Ngoc Hung Vu Jong-Won Lee Won bin im Division of Materials Science and Engineering Hanyang University222Wangsimni-roSeongdong-guSeoul04763Republic of Korea School of Materials Science and Engineering Chonnam National University77 Yongbong-roBuk-guGwangju61186Republic of Korea Falcuty of biotechnology Chemistry and Environmental EngineeringPhenikaa UniversityHanoi10000Vietnam A&A Green Phoenix Group Phenikaa Research and Technology Institute(PRATI)167 Hoang NganHanoi10000Vietnam Department of Energy Science and Engineering Daegu Gyeongbuk Institute of Science and Technology(DGIST)333 Techno Jungang-daeroHyeonpung-eupDalseonggunDaegu42988Republic of Korea

Sodium ion batteries (SIBs) are alternatives to lithium ion batteries (LIBs), and offer some significant benefits such as cost reduction and a lower environmental impact;however, to compete with LIBs, further research is required to improve the performance of SIBs. In this study, an orthorhombic Na super ionic conductor structural Fe_(2)(MoO_(4))_(3) nanosheet with amorphous-crystalline core-shell alignment was synthesized using a facile low-temperature water-vapor-assisted solid-state reaction and applied as a cathode material for SIBs. The obtained material has a well-defined three-dimensional stacking structure, and exhibits a high specific capacity of 87.8 mAh·g^(−1) at a current density of 1 C = 91 mA·g^(−1) after 1,000 cycles, which is due to the considerable contribution of extra surface-related reaction such as the pseudo-capacitive process. This material shows significantly improved cycling and rated behavior as well as enhanced performance under high- and low-temperature conditions, as compared to the same materials prepared by the conventional high-temperature solid-state reaction. This enhancement is explained by the unique morphology in combination with the improved kinetics of the electrochemical reaction due to its lower charge transfer resistance and higher sodium ion conductivity.

关键词： low-temperature synthesis cathode sodium ion batteries kinetics Na+super ionic conductor(NASICON)

Clinical analysis of risk factors contributing to recurrence of pterygium after excision and graft surgery

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International Journal of Ophthalmology(English edition) 2015年第3期8卷 522-527页

作者： Sang Won ha Joon Ho Park im Hee Shin Hong Kyun Kim Department of Ophthalmology Kyungpook National University School of Medicine Department of Medical Statistics Catholic University of Daegu School of medicine

Aim: To find the risk factors related to the reproliferation of the pterygial tissue after excision and graft ***: Charts of 130 eyes of 130 patients who had pterygial excision from March 2006 to April 2011 were reviewed. Preoperative pterygium morphology, surgical methods, and adjunctive treatments were statistically analyzed for their relationship with ***: During the follow-up period, recurrence was observed in 20 eyes(15.4%). None of the preoperative morphologic features were affected the rate of the recurrence. However, an age hat intraoperative mitomycin C(MMC)(P =0.072, OR 0.298, 95% CI 0.080-1.115)decreased the rate of recurrence. CONCLUSION: Younger age is a risk factor for reproliferation of pterygial tissue after excision and amniotic membrane transplantation(AMT) are less effective in preventing recurrence of pterygium after excision based on the comparison between conjunctival autograft and AMT. Intraoperative MMC application and conjunctival autograft reduce recurrence.

关键词： pterygium recurrence conjunctival autograft amniotic membrane graft mitomycin C

Classification-based self-adaptive differential evolution and its application in multi-lateral multi-issue negotiation

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Frontiers of Computer Science 2012年第4期6卷 442-461页

作者： Xiaojun bi Jing XIAO School of Information and Communication Engineering Harbin Engineering UniversityHarbin 150001China School of Information Engineering Liaoning Provincial College of CommunicationsShenyang 110122China

Multi-lateral multi-issue negotiations are the most complex realistic negotiation problems. Automated ap- proaches have proven particularly promising for complex ne- gotiations and previous research indicates evolutionary com- putation could be useful for such complex systems. To im- prove the efficiency of realistic multi-lateral multi-issue ne- gotiations and avoid the requirement of complete informa- tion about negotiators, a novel negotiation model based on art improved evolutionary algorithm p-ADE is proposed. The new model includes a new multi-agent negotiation protocol and strategy which utilize p-ADE to improve the negotia- tion efficiency by generating more acceptable solutions with stronger suitability for all the participants. Where p-ADE is improved based on the well-known differential evolution （DE）, in which a new classification-based mutation strategy DE/rand-to-best/pbest as well as a dynamic self-adaptive pa- rameter setting strategy are proposed. Experimental results confirm the superiority of p-ADE over several state-of-the-art evolutionary optimizers. In addition, the p-ADE based multi- agent negotiation model shows good performance in solving realistic multi-lateral multi-issue negotiations.

关键词： differential evolution global optimum e-commerce agent multi-lateral multi-issue negotiation

融入劳动教育的初中地理实践课程设计研究——以农耕活动为例

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科教文汇 2025年第1期 175-179页

作者：戚杨梅王碧四川师范大学地理与资源科学学院

劳动教育是“五育”的重要组成部分，也是培养学生劳动素养和地理核心素养的主要途径，更是实现建设社会主义现代化强国目标的重要依托。在当前的中学教育中，存在系统的劳动教育缺失、学生劳动素养亟待提高等问题。将劳动教育融入地理... 详细信息

劳动教育是“五育”的重要组成部分，也是培养学生劳动素养和地理核心素养的主要途径，更是实现建设社会主义现代化强国目标的重要依托。在当前的中学教育中，存在系统的劳动教育缺失、学生劳动素养亟待提高等问题。将劳动教育融入地理实践课程，通过开展“春耕、夏耘、秋收、冬藏”等一系列劳动实践，有利于学生获得劳动知识、提高劳动能力、养成正确劳动观念、形成良好劳动品质，进而促进学生地理实践力、区域认识、综合思维、人地协调观等核心素养的培养与提升。

关键词：劳动教育地理实践课程农耕活动核心素养

Anti-MMP-2 and MMP-9 activity of Salsola komarovii Iljin extract and its solvent fractions

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Asian Pacific Journal of Tropical biomedicine 2020年第10期10卷 460-469页

作者： Jung-ha Kil Fatih Karadeniz Ga Hyun Yu Hojun Kim Junse Kim Jung Hwan Oh Jung im Lee Chang-SukKong Youngwan Seo Marine biotechnology Center for Pharmaceuticals and Foods Silla UniversityBaegyang-daero 700 beon-gil 140Sasang-guBusan 46958Korea Department of Food and Nutrition College of Medical and Life SciencesSilla UniversityBaegyang-daero 700 beon-gil 140Sasang-guBusan 46958Korea Division of Marine bioscience Korea Maritime and Ocean UniversityBusan 49112Korea

Objective: To investigate matrix metalloproteinases(MMP)-2 and MMP-9 inhibitory effect of Salsola komarovii Iljin, an edible halophyte with health beneficial ***: Salsola komarovii crude extracts(SKI), and solvent(n-hexane, 85% aq. MeOH, n-BuOH, and H2O) fractionated extracts of SKI were prepared. Gelatin zymography was carried out to observe MMP enzymatic activity. The release of the MMP enzymes was measured by enzyme-linked immunosorbent assay. Expression of MMPs in m RNA and protein level were investigated by polymerase chain reaction analysis and immunoblotting, ***: SKI and SKI fractions inhibited active MMP-2 and MMP-9 amount in the treated cell culture medium. Also, SKI suppressed the release of MMP-2 and MMP-9 from stimulated HT1080 human fibrosarcoma cells. Furthermore, SKI suppressed the m RNA and protein expression of MMP-2 and MMP-9. SKI fractions showed parallel effects except for H2O fraction which did not yield any significant MMP inhibitory effect. Among fractions, 85% aq. Me OH was the most active fraction to inhibit both the enzymatic effect and expression of MMP-2 and ***: SKI may contain potential MMP release inhibitory compounds. Salsola komarovii is a promising source of compounds against MMP and could be utilized in the development of antitumor agents.

关键词： release utilized effect

Therapeutic angiogenesis induced by human hepatocyte growth factor gene in hindlimb ischemia of dogs

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Chinese Science Bulletin 2003年第7期48卷 676-680页

作者： ha Xiaoqin, REN Jianping, bi Jianjin, ZhaNG Jinhui & WU Zuze (Wu Chu-tse) Beijing Institute of Radiation Medicine, Beijing 100850, China 1. Beijing Institute of Radiation Medicine Beijing 100850 China

A preclinical study of treating peripheral ar-tery occlusive disease (PAD) was performed by using ahepatocyte growth factor (HGF) gene-expressing vector,plasmid pUDKH, in a dog model with complete ischemia of one hindlimb. After ligation of femoral artery of onehindlimb, pUDKH was transferred directly into the ischemic limb muscles. The angiogenic activity of the plasmid pUDKH was evaluated. On D 30 after injecting once of pUDKH at different doses into local muscles immediately after opera-tion, the degree of augmentation of collateral vessel forma-tion was significantly greater than that treated by blankvector. In addition, the blood flow rate of femoral artery in dogs treated with pUDKH was recovered on D 90, while the flow rate was only 1/5 to 1/3 in control dogs. The pulse am-plitude of pUDKH-treated dogs was recovered on D 90, but it was hardly detectable in most of the control dogs. The sideeffects of intramuscular transfection of pUDKH were alsoinvestigated, and no significant positive change was found. It is suggested that angiogenesis induced by HGF gene has the potential for clinical use in the treatment of peripheral arte-rial diseases.

关键词：外周动脉闭塞疾病肝细胞生长因子基因治疗动物模型下肢局部缺血血管生成

Optimally arranged TiO_(2)@MoS_(2) heterostructures with effectively induced built-in electric field for high-performance lithium-sulfur batteries

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Journal of Energy Chemistry 2023年第8期83卷 496-508,I0012页

作者： Jeongyoub Lee Changhoon Choi Jung Been Park Seungho Yu Jinho ha Hyungsoo Lee Gyumin Jang Young Sun Park Juwon Yun hayoung im Subin Moon Soobin Lee Jung-Il Choi Dong-Wan Kim Jooho Moon Department of Materials Science and Engineering Yonsei UniversitySeoul 03722Republic of Korea School of Civil Environmental and Architectural EngineeringKorea UniversitySeoul 02841Republic of Korea Energy Storage Research Center Korea Institute of Science and Technology(KIST)Seoul 02792Republic of Korea School of Mathematics and Computing(Computational Science and Engineering) Yonsei UniversitySeoul 03722Republic of Korea

To overcome the serious technological issues affecting lithium-sulfur(Li-S) batteries,such as sluggish sulfur redox kinetics and the detrimental shuttle effect,heterostructure engineering has been investigated as a strategy to effectively capture soluble lithium polysulfide intermediates and promote their conversion reaction by integrating highly polar metal oxides with catalytically active metals ***,to fully exploit the outstanding properties of heterostructure-based composites,their detailed structure and interfacial contacts should be designed ***,optimally arranged TiO_(2)and MoS_(2)-based heterostructures(TiO_(2)@MoS_(2)) are fabricated on carbon cloth as a multifunctional interlayer to efficiently trap polysulfide intermediates and accelerate their redox *** to the synergistic effects between TiO_(2)and MoS_(2)and the uniform heterointerface distribution that induces the ideally oriented built-in electric field,Li-S batteries with TiO_(2)@MoS_(2)interlayers exhibit high rate capability(601 mA h g^(-1)at 5 C),good cycling stability(capacity-fade rate of 0.067% per cycle over 500 cycles at2 C),and satisfactory areal capacity(5.2 mA h cm^(-2)) under an increased sulfur loading of 5.2 mg cm^(-2).Moreover,by comparing with a MoS_(2)@TiO_(2)interlayer composed of reversely arranged heterostructures,the effect of the built-in electric field’s direction on the electrocatalytic reactions of polysulfide intermediates is thoroughly investigated for the first *** superior electrocatalytic activities of the rationally arranged TiO_(2)@MoS_(2)interlayer demonstrate the importance of optimizing the built-in electric field of heterostructures for producing high-performance Li-S batteries.

关键词： Lithium-sulfur batteries Shuttle effect TiO_(2)-MoS_(2)heterostructure engineering Built-in electric field Multifunctional interlayers

Heterostructures in two-dimensional colloidal metal chalcogenides:Synthetic fundamentals and applications

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Nano Research 2019年第8期12卷 1750-1769页

作者： Yuho Min Eunmi im Geon-Tae Hwang Jong-Woo Kim Cheol-Woo Ahn Jong-Jin Choi Byung-Dong hahn Joon-Hwan Choi Woon-ha Yoon Dong-Soo Park Dong Choon Hyun Geon Dae Moon Functional Ceramics Department Powder & Ceramics DivisionKorea Institute of Materials Science (KIMS)ChangwonGyeongnam51508Republic of Korea Department of Polymer Science and Engineering Kyungpook National UniversityDaegu41566Republic of Korea Dongrtam Regional Division Korea Institute of Industrial TechnologyBusan46938Republic of Korea

As a new class of two-dimensional materials, two-dimensional (2D) heterostructures constructed from metal chalcogenides (MCs) have been gaining tremendous attention due to their unprecedented physical and chemical phenomena, mainly originated from their distinct structural features such as composition, architecture type, spatial arrangement of each component, crystal structure, exposed facet and interface, dimensionality in their heterostructures. Towards the realization of practical applications, synthetic approaches need a rational design with a variety of architecture types including laterally-combined, vertically-aligned, and conformally-coated 2D MC heterostructures. Among various synthetic routes, solution-based synthesis is thought of as an alternative to fabrication through high-cost setups since it can control those structural features in a cheap fashion. This review presents recent progress on solution-based synthesis to produce various 2D MC heterostructures with a focus on the synthetic fundamentals in terms of thermodynamic and kinetic aspects related to the growth mechanism. Four different synthetic approaches are reviewed: seeded growth, cation exchange reaction, colloidal atomic layer deposition, direct synthesis including one-step process and modified electrochemical method. We also provide some representative applications of 2D MC heterostructures and their hybrid composites in various fields including optoelectronics, thermoelectrics, catalysis, and battery. Finally, we offer an insight into challenges and future directions in a synthetic improvement of 2D MC heterostructures.

关键词： metal chalcogenide heterostructure anisotropic nanomaterials two-dimensional (2D) nanomaterials solution-based synthesis

Sulphate attack resistance of high-performance concrete under compressive loading

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2013年第7期14卷 459-468页

作者： Hui XU Yu-xi ZhaO Lei CUI bi XU Institute of Structural Engineering Zhejiang University School of Civil Engineering Newcastle University CCCC Tianjin Dredging Co. Ltd.

In this paper, an experimental study on the sulphate attack resistance of high-performance concrete (HPC) with two different water-to-binder ratios (w/b) under compressive loading is presented. The sulphate concentration, compressive strength, and the mass change in the HPC specimens were determined for immersion in a Na2SO4 solution over different durations under external compressive loading by self-regulating loading equipment. The effects of the compressive stress, the w/b ratio, and the Na2SO4 solution concentration on the HPC sulphate attack resistance under compressive loading were analysed. The results showed that the HPC sulphate attack resistance under compressive loading was closely related to the stress level, the w/b ratio, and the Na2SO4 solution concentration. Applying a 0.3 stress ratio for the compressive loading or reducing the w/b ratio clearly improved the HPC sulphate attack resistance, whereas applying a 0.6 stress ratio for the compressive loading or exposing the HPC to a more concentrated Na2SO4 solution accelerated the sulphate attack and HPC deterioration.

关键词： Sulphate attack resistance High-performance concrete (HPC) Compressive loading